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Grain Growth upon Annealing and Its Influence on Biodegradation Rate for Pure Iron
Authors:Yu Zhang  Ke Zhang  Weidong Liu  Zhongren Zheng  Mingchun Zhao
Affiliation:1.Xiangya Hospital, Central South University, Changsha 410008, China;2.National Clinical Research Center for Geriatric Disorders, Xiangya Hospital, Changsha 410008, China;3.International Joint Research Center of Minimally Invasive Endoscopic Technology Equipment & Standards, Changsha 410008, China;4.School of Materials Science and Engineering, Central South University, Changsha 410083, China
Abstract:Biodegradable pure iron has gained significant interest as a biomedical material. For biodegradable implant applications, the biodegradation behavior of pure iron is important. In this work, the influence of ferrite grain size on the biodegradation rate for pure iron was studied by means of heat treatment that was annealed below the austenized temperature using as-forged pure iron. Grains were coarsened and a spectrum of ferrite grain sizes was gained by changing the annealed temperature. Biodegradation behavior was studied through weight loss tests, electrochemical measurements and microscopic analyses. Hardness (HV) and biodegradation rate (Pi or Pw) were linearly ferrite grain size-dependent: HV=58.9+383.2d12, and Pi=0.023+0.425d12 or Pw=0.056+0.631d12. The mechanism by which the role of grain size on biodegradation rate was attributed to the ferrite grain boundary traits.
Keywords:pure iron   annealing   grain refinement   biodegradation   implant material
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