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Echinamines A and B, first aminated hydroxynaphthazarins from the sea urchin Scaphechinus mirabilis
Authors:Mischenko Natalia P  Fedoreyev Sergey A  Pokhilo Nataly D  Anufriev Victor Ph  Denisenko Vladimir A  Glazunov Valery P
Affiliation:Pacific Institute of Bioorganic Chemistry, Far East Branch of the Russian Academy of Sciences, 159, Prospect 100 let Vladivostoku, Vladivostok 690022, Russian Federation. misch@piboc.dvo.ru
Abstract:Two new spinochromes, echinamines A (1) and B (2), were isolated from the sea urchin Scaphechinus mirabilis. Compounds 1 and 2 represent the first examples of natural polyhydroxynaphthazarins with a primary amine group. The structures of 1 and 2 were established by analysis of spectroscopic data and synthesis of their dimethyl ethers.
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