Electrochemical adsorption studies of urea on copper surface in alkaline medium |
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Authors: | Fouzia Altaf Rumana QureshiSafeer Ahmed Athar Y KhanAmtul Naseer |
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Institution: | Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan |
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Abstract: | The inhibitive action of urea on the corrosion behavior of copper was investigated in borate buffer pH (8.4) by means of cyclic voltammetry and electrochemical impedance spectroscopy (EIS). A consistent trend of increase in inhibition efficiency was observed as a function of concentration of urea. The adsorption of urea on copper surface was found to obey the Langmuir adsorption isotherm with ΔG = −35.2 kJ/mole and adsorption constant K = 2.7 × 104 dm3/mole. Impedance spectroscopic measurements confirmed that charge transfer resistance increases in presence of urea upon increasing its concentration. |
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Keywords: | Copper Cyclic voltammetry EIS Adsorption |
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