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热溶对红柳林煤低温热解行为的影响
引用本文:石策,黄胜,吴诗勇,吴幼青,高晋生. 热溶对红柳林煤低温热解行为的影响[J]. 医学教育探索, 2017, 43(4): 474-480
作者姓名:石策  黄胜  吴诗勇  吴幼青  高晋生
作者单位:华东理工大学 能源化工系, 上海 200237,华东理工大学 能源化工系, 上海 200237;华东理工大学 煤气化及能源化工教育部重点实验室, 上海 200237,华东理工大学 能源化工系, 上海 200237;华东理工大学 煤气化及能源化工教育部重点实验室, 上海 200237,华东理工大学 能源化工系, 上海 200237;华东理工大学 煤气化及能源化工教育部重点实验室, 上海 200237,华东理工大学 能源化工系, 上海 200237;华东理工大学 煤气化及能源化工教育部重点实验室, 上海 200237
基金项目:国家自然科学基金(21506060)
摘    要:以正己烷为溶剂,考察了热溶温度对红柳林煤(HL)热溶行为的影响,并研究了不同热溶温度下残渣的热解特性。结果表明:随着热溶温度从260℃升高至340℃,热溶萃取的小分子化合物(包括焦油和水的液相产物以及气相产物)的产率逐渐从7.10%增加至11.96%。热溶处理对原煤热解行为的影响显著,经过热溶处理后原煤热解析出的挥发分的产率则从28.02%降至10.49%~21.38%。随着热溶温度从260℃升高至340℃,热溶残渣热解过程中析出物质的产率从21.38%降至10.49%,液相产物的产率从12.01%降至3.72%,气相产物的产率稍有降低。煤中的小分子化合物是煤低温热解过程的"活性"物质,它不仅是化合物热解液相产物的组成部分,还可为煤的主体结构热解供氢,促进煤热解向焦油和气体的转化。

关 键 词:热解  热溶  焦油  小分子化合物
收稿时间:2016-12-14

Effect of Thermal Dissolution on Low Temperature Pyrolysis Performance of Hongliulin Coal
SHI Ce,HUANG Sheng,WU Shi-yong,WU You-qing and GAO Jin-sheng. Effect of Thermal Dissolution on Low Temperature Pyrolysis Performance of Hongliulin Coal[J]. Researches in Medical Education, 2017, 43(4): 474-480
Authors:SHI Ce  HUANG Sheng  WU Shi-yong  WU You-qing  GAO Jin-sheng
Affiliation:Department of Energy Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China,Department of Energy Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China,Department of Energy Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China,Department of Energy Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China and Department of Energy Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
Abstract:
Keywords:pyrolysis  thermal dissolution  tar  small molecular compounds
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