Stereokontrolle. III. Geschwindigkeitskonstanten der iso- und syndiotaktischen anlagerung

The rate constants of isotactic and syndiotactic addition can be calculated from the rate constant k_w of the propagation reaction and the fractions of isotactic and syndiotactic dyads and triads. Corresponding equations are given for BERNOULLI trials and MARKOV trials of first order with respect to monomer dyads. The temperature dependence of dyad formation is discussed for MARKOV trials.