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Radiochemical separation of carrier-free 204,206 Bi from alpha-irradiated thallium oxide target.
Authors:Dalia Nayak  Susanta Lahiri  Kamalika Roy  S Basu  A Ramaswami
Affiliation:Chemical Sciences Division, Saha Institute of Nuclear Physics, 1/AF Bidhannagar, 700 064, Kolkata, India.
Abstract:Alpha activation of Tl(2)O(3) target results in the formation of carrier-free 204,206 Bi. Two different radiochemical methods were used for the separation of bismuth radionuclides from the target matrix. A very high separation factor was achieved using liquid-liquid extraction (LLX) method with methyl isobutyl ketone (MIBK)-HCl system. Solid-liquid exchange adsorption was carried out using a novel inorganic ion exchanger, zirconium vanadate from HCl medium. The separation was found to be maximum around pH 2.
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