| 柴胡皂甙m和柴胡皂甙n的结构鉴定 |
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| 引用本文： | 张如意,陈喜奎,杨宪斌,谭利,贺文义. 柴胡皂甙m和柴胡皂甙n的结构鉴定[J]. 药学学报, 1994, 29(9): 684-688 |
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| 作者姓名： | 张如意 陈喜奎 杨宪斌 谭利 贺文义 |
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| 作者单位： | 北京医科大学药学院，中国医学科学院中国协和医科大学药物研究所 |
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| 摘 要： | 从黑柴胡(Bupleurum smithii Wolff)根中分得二个新三萜皂甙。根据理化性质和波谱数据,分别鉴定为3β,23,28-三羟基齐墩果烷-11,13(18)-二烯-3-O-β-D-吡喃葡萄糖基-(1→3)-β-D-吡喃呋糖甙,命名为柴胡皂甙m(saikosaponin m,IV),和3β,16β,23,28-四羟基齐墩果烷-11,13(18)-二烯-3-O-β-D-吡喃葡萄糖基-(1→6)-[α-L-吡喃鼠李糖基-(1→4)]-β-D-吡喃葡萄糖甙,命名为柴胡皂甙n(saikos-aponinn,IX)。
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| 关 键 词： | 黑柴胡 三萜皂甙 柴胡皂甙m 柴胡皂甙n |
| 收稿时间： | 1993-04-29 |
THE STRUCTURES OF SAIKOSAPONIN M AND N FROM BUPLEURUM SMITHII WOLFF |
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| RY Zhang,XK Chen,XB Yang,WY Heand L Tan. THE STRUCTURES OF SAIKOSAPONIN M AND N FROM BUPLEURUM SMITHII WOLFF[J]. Acta pharmaceutica Sinica, 1994, 29(9): 684-688 |
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| Authors: | RY Zhang XK Chen XB Yang WY Heand L Tan |
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| Abstract: | From the roots of Bupleurum Smithii Wolff, collected in Minhe County,Qinghai,China,two new saikosaponins were isolated and their structures were elucidated on the basis of spectralanalysis of UV,IR,1HNMR,13CNMR and FAB-MS.The two new saponins named as saikosaponinm and saikosaponin n,were identified as 3β,23,28-trihydroxyoleana-11,13(18)-dien-3-O-β-D-glu-copyranosyl-(1→3)-β-D-fucopyranoside and 3β,16β,23,28-tetrahydroxyoleana-11, 13(18)-dien-3-O-β-D-glucopyranosyl-(1→6)-[α-L-rhamnopyranosyl(1→4)]-β-D-glucopyranoside,respectively. |
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| Keywords: | Bupleurum smithii Wolff Saikosaponin m Saikosaponin n Triterpenoidal saponin. |
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