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Reactive Coatings in Glass Capillaries: Preparation of Temperature‐ and Light‐Responsive Surfaces and Accurate Determination of Wettability Switching
Authors:Natalie Wagner  Daniel Kessler  Patrick Theato
Institution:1. Institute for Technical and Macromolecular Chemistry, University of Hamburg, Hamburg, Germany;2. Institute of Organic Chemistry, Johannes Gutenberg University Mainz, Mainz, Germany
Abstract:The inner walls of thin glass capillaries are coated with a reactive precursor coating that can be converted into different temperature‐ and light‐responsive coatings. The switching range of wettability can be determined by measuring the meniscus height of water inside these capillaries at different temperatures and upon UV‐light irradiation. In comparison with the sessile drop measurement, very accurate equilibrium contact angles are obtained by this method.
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Keywords:capillary rise  contact angle  organic–  inorganic hybrids  switching of wettability  temperature‐responsive coatings
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