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Variously Prepared Zeolite Y as a Modifier of ANFO
Authors:Ł  ukasz Kuterasiń  ski,Agnieszka M. Wojtkiewicz,Marta Sadowska,Paulina Ż  eliszewska,Bogna D. Napruszewska,Mał  gorzata Zimowska,Mateusz Pytlik,Andrzej Biessikirski
Affiliation:1.Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, 8 Niezapominajek Street, 30-239 Krakow, Poland;2.Conformity Assessment Body, Central Mining Institute, 1 Gwarków Square, 40-166 Katowice, Poland;3.Faculty of Civil Engineering and Resource Management, AGH University of Science and Technology, 30 Mickiewicz Avenue, 30-059 Krakow, Poland
Abstract:In the presented research, we investigated Ammonium Nitrate Fuel Oil (ANFO), with the addition of variously modified zeolite Y as an attractive explosive. Analysis of both blasting tests and thermodynamic models of blasting properties led to the conclusion that the addition of zeolite Y enhanced the detonation properties of such prepared ANFO via the growth of the detonation pressure, temperature, compression energy, and heat of the explosion. Generally, the modification of ANFO with variously prepared zeolite Y also reduced the volume of (COx + NOx) post-blast fumes. Furthermore, it was found that the ANFO’s velocity of detonation (VOD) could be controlled by the choice of the way of zeolite Y modification. Namely, for zeolite Y without Mg, as well as Mg-Y prepared via the impregnation method, the VOD rose. The opposite effect was observed when ANFO was modified with Mg-Y, obtained from the deposition of Mg over zeolite Y via the ultrasonic-assisted procedure.
Keywords:zeolite Y   ANFO   modifier   detonation   post-blast fumes
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