On the mechanism of the carbon dioxide/propylene oxide alternating copolymerization in the presence of organozinc catalysts |
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| Authors: | Witold Kuran,Stanis&#x aw Pasynkiewicz,Jadwiga Skupi&#x ska |
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| Affiliation: | Witold Kuran,Stanisław Pasynkiewicz,Jadwiga Skupińska |
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| Abstract: | Carbon dioxide and propylene oxide were copolymerized in the presence of the catalytic systems diethylzinc/polyhydric phenols modified by pretreatment with one of the monomers. The mechanisms of initiation, propagation, termination, and chain-transfer reaction in the copolymerization are suggested and discussed. |
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