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New dibenz[b, f]oxepins from Cercis chinensis Bunge
Authors:LI-HUA Mu  JIAN-BEI Li  JING-ZHI Yang  DONG-MING Zhang
Institution:  a Key Laboratory of Bioactive Substances and Resources Utilization of Chinese Herbal Medicine, Ministry of Education, Institute of Materia Medica, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing, China
Abstract:Three new dibenzb,f]oxepins: 6-methoxy-7-methyl-8-hydroxydibenzb, f]oxepin (1), 1,8-dimethoxy-6-hydroxy-7-methyldibenzb, f]oxepin (2), and 1-hydroxy-6,8-dimethoxy-7-methyldibenzb,f]oxepin (3), along with two known dibenzb,f]oxepins pacharin (4) and bauhiniastatin 4 (5), were isolated from Cercis chinensis Bunge (Leguminosae). Their structures were elucidated on the basis of spectroscopic evidence (EI-MS, UV, IR, 1H, 13C and 2D NMR). Compounds 1-5 were isolated from the Cercis genus for the first time.
Keywords:Cercis chinensis Bunge  Leguminosae  Dibenz[b  f]oxepins
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