A novel triterpenoid saponin from Polygala tenuifolia Willd |
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Authors: | Xu Tun-Hai Lv Gang Xu Ya-Juan Xie Sheng-Xiu Zhao Hong-Feng Han Dong Si Yun-Shan Li Yu Niu Jian-Zhao Xu Dong-Ming |
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Institution: | Department of Traditional Chinese Medicine Chemistry, School of Traditional Chinese Medicine, Beijing University of Chinese Medicine, Beijing, China. |
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Abstract: | A new triterpenoid saponin, tenuifoside A, was isolated together with three known triterpenoid saponins 2, 3, and 4 from the roots of Polygala tenuifolia Willd. With the help of chemical and spectral analyses (IR, MS, 1D-NMR, and 2D-NMR), the structure of the new saponin was elucidated as 3-O-beta-d-glucopyranosyl presenegenin 28-O-beta-d-xylopyranosyl-(1 --> 3)-beta-d-xylopyranosyl-(1 --> 4)-beta-D-apiofuranosyl-(1 --> 3)]-alpha-L-rhamnopyranosyl-(1 --> 2)-4-O-p-methoxycinnamoyl]-alpha-l-rhamnopyranosyl-(1 --> 3)]-beta-d-fucopyranosyl ester (1). Three known triterpenoid saponins (2-4) were identified on the basis of spectroscopic data. |
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