Biodegradation of [14C] Ring-Labeled Nonylphenol Ethoxylate |
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Authors: | C G Naylor C A Staples G M Klecka J B Williams P T Varineau C Cady |
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Institution: | (1) Huntsman Corporation, 8103 Forest Mesa Drive, Austin, TX 78759, USA;(2) Assessment Technologies, Inc., Spotsylvania, Virginia;(3) The Dow Chemical Company, Midland, Michigan;(4) The Dow Chemical Company, South Charleston, West Virginia;(5) ABC Labs, Columbia, Missouri |
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Abstract: | Nonylphenol (NP) and the 9-mole ethoxylate of nonylphenol (NPE9) were synthesized with a uniform radioactive 14C label in the aromatic ring. The 14C]NP isomer distribution and 14C]NPE9 oligomer distribution closely matched that of commercial NPE9. Biodegradation of 14C]NPE9 was examined under conditions simulating a river water environment, and changes in the oligomer distribution and mineralization
to 14CO2 were monitored for 128 days. Over 40% of the 14C]NPE aromatic ring carbon was converted to 14CO2 and another 21% was incorporated into the biomass. Primary degradation of NPE (conversion to metabolites other than NP, NPE
ethoxylates, and NPE carboxylates) was estimated to be 87–97%. NP was a minor metabolite, accounting for less than 0.4% of
the initial NPE. These studies demonstrate that the phenolic ring of NPE is opened, metabolized, and mineralized in the aquatic
environment. |
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