| 聚二烯丙基乙基苄基氯化铵的合成及溶液性质 |
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| 引用本文： | 刘立华,曹菁,令玉林,周智华. 聚二烯丙基乙基苄基氯化铵的合成及溶液性质[J]. 医学教育探索, 2011, 24(2) |
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| 作者姓名： | 刘立华 曹菁 令玉林 周智华 |
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| 作者单位： | 湖南科技大学化学化工学院，理论化学与分子模拟省部共建教育部重点实验室，分子构效关系湖南省普通高等学校重点实验室，湖南 湘潭 411201;湖南科技大学化学化工学院，理论化学与分子模拟省部共建教育部重点实验室，分子构效关系湖南省普通高等学校重点实验室，湖南 湘潭 411202;湖南科技大学化学化工学院，理论化学与分子模拟省部共建教育部重点实验室，分子构效关系湖南省普通高等学校重点实验室，湖南 湘潭 411203;湖南科技大学化学化工学院，理论化学与分子模拟省部共建教育部重点实验室，分子构效关系湖南省普通高等学校重点实验室，湖南 湘潭 411204 |
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| 基金项目： | 国家自然科学基金(51078141)；湖南省自然科学基金(07JJ3113) |
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| 摘 要： | 在少量水存在下，将二烯丙基乙基胺(DAEA)与氯化苄直接反应合成单体二烯丙基乙基苄基氯化铵（DAEABC）。以2,2′-偶氮（2-甲基丙基脒）二盐酸盐为引发剂，采用水溶液聚合，合成了聚二烯丙基乙基苄基氯化铵(PDAEABC)。采用FT-IR、1H-NMR和元素分析对PDAEABC的结构进行表征，并考察了其在氯化钠、氯化钾、溴化钾、碘化钾、硫酸镁和硫酸钠溶液中的黏度行为。结果表明，当V(H2O)∶V(DAEA)为0.01~0.02时，能获得高纯的DAEABC晶体，收率达94%以上。PDAEABC的比浓黏度随
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| 关 键 词： | 聚二烯丙基乙基苄基氯化铵；溶液性质；比浓黏度；黏度行为；屏蔽作用 |
Synthesis and Solution Properties of Poly(diallylethylbenzylammonium chloride) |
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| LIU Li-hu,CAO Jing,LING Yu-lin and ZHOU Zhi-hua. Synthesis and Solution Properties of Poly(diallylethylbenzylammonium chloride)[J]. Researches in Medical Education, 2011, 24(2) |
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| Authors: | LIU Li-hu CAO Jing LING Yu-lin ZHOU Zhi-hua |
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| Affiliation: | Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education and Hunan Province, Hunan Province college Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xi;Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education and Hunan Province, Hunan Province college Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xi;Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education and Hunan Province, Hunan Province college Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xi;Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education and Hunan Province, Hunan Province college Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xi |
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| Abstract: | |
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| Keywords: | poly(diallylethylbenzylammonium chloride) solution properties reduced viscosity viscosity behavior shielding effect |
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