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Synthesis and Characterization of New Acrylate and Methacrylate Monomers with Pendant Pyridine Groups
Authors:Li Cui  Günter Lattermann
Abstract:To overcome some drawbacks of polyvinylpyridines, new monomers of acrylate and methacrylate type with pendant pyridine groups i.e., 4‐(3‐methacryloylpropyl)pyridine 1a and 4‐(3‐acryloylpropyl)pyridine 1b were successfully prepared, although it turned out to be challenging work to synthesize the acrylate monomer 1b . First polymerization studies showed that the new monomers could be polymerized easily by atom transfer radical polymerization (ATRP). The new polymers show excellent characteristics, such as very good solubility, low glass‐transition temperature, and easy quaternization.
image

Design and structure of new monomers 1a and 1b .

Keywords:atom transfer radical polymerization (ATRP)  monomers  polyacrylates  polycations  polymethacrylates  synthesis
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