Structures et propriétés diélectriques des poly(α-acétoxystyréne)s parasubstitués |
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Authors: | Jean-Pierre Monthard Marcel Camps Ahmed Belfkira Michel Chatzopoulos Robert Granger Luc Jorat Grard Noyel |
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Institution: | Jean-Pierre Monthéard,Marcel Camps,Ahmed Belfkira,Michel Chatzopoulos,Robert Granger,Luc Jorat,Gérard Noyel |
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Abstract: | The relations between structure and isothermal, dielectric properties of poly(α-acetoxystyrene)s substituted in para position by ? OCOCH3 ( 1a ), ? OCOCH2CH3 ( 1b ), ? OCOCH2CH2CH3 ( 1c ), ? OCOC6H5 ( 1d ), ? OCOCH2CH2Cl ( 1f ) and ? OCOOCH3 ( 1g ) were studied. The dielectric constants, at 105 Hz and 20 ± 2°C, were found to be: 3,79 ( 1a ), 3,36 ( 1b ), 3,18 ( 1c ), 3,51 ( 1d ), 3,36 ( 1e ), 3,65 ( 1f ) and 3,07 ( 1g ). The polymers 1a – 1g do not show any α- or β-transition. Increasing bulkiness of the para substituent gives rise to a decreasing dielectric constant due to an increase of the degree of syndiotacticity, as determined from 1H and 13C NMR spectra. |
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