| Abstract: | Dinitrogen complexes of poly{1-[4-(chlorodicyclopentadienyltitanio)phenyl]ethylene-co-1-(4-bromophenyl)ethylene-co-1-phenylethylene} ( 2a – e ) were synthesized. It was found that there is an equilibrium between the mononuclear and binuclear complex. Ammonia was formed after hydrolysis of the reaction mixtures resulting from 2a – e and lithium naphthalide in a nitrogen atmosphere. The yield of ammonia increased extremely with decreasing content of titanocene in the polymer. In the system with 2a 41,7 mol ammonia were formed per 1 mol of titanium. |
