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国产沉香化学成分的研究——Ⅲ.异白木香醇的结构测定和低沸点成分的分离与鉴定
引用本文:杨峻山,王玉兰,苏亚伦,贺存恒,郑启泰,杨晶. 国产沉香化学成分的研究——Ⅲ.异白木香醇的结构测定和低沸点成分的分离与鉴定[J]. 药学学报, 1989, 24(4): 264-268
作者姓名:杨峻山  王玉兰  苏亚伦  贺存恒  郑启泰  杨晶
作者单位:中国医学科学院药物研究所,北京100050
摘    要:自国产沉香(Aquilaria sinensis)[瑞香科(Thymeleaceae)植物]的挥发油中,经硅胶柱层析和离心薄层层析分离得到一新的倍半萜,命名为异白木香醇(isobaimuxinol),根据光谱(IR,1HNMR,13CNMR,2 D-NMR和MS)分析确定其结构式为(Ⅰ)所示,并用X-光衍射晶体解析进一步确定了其立体化学。同时,也从该植物挥发油的低沸点部分分离得到四个已知化合物:苄基丙酮,对甲氧基苄基丙酮,茴香酸和β-沉香呋喃。这些化合物均为首次从该植物中得到。

关 键 词:沉香  瑞香科  挥发油  倍半萜  异白木香醇
收稿时间:1988-01-29

Studies on the chemical constituents of Aquilaria sinensis (Lour) Gilg. III. Elucidation of the structure of isobaimuxinol and isolation and identification of the constituents of lower boiling fraction of the volatile oil
JS Yang,YL Wang,YL Su,CH He,QT Zheng and J Yang. Studies on the chemical constituents of Aquilaria sinensis (Lour) Gilg. III. Elucidation of the structure of isobaimuxinol and isolation and identification of the constituents of lower boiling fraction of the volatile oil[J]. Acta pharmaceutica Sinica, 1989, 24(4): 264-268
Authors:JS Yang  YL Wang  YL Su  CH He  QT Zheng  J Yang
Abstract:A new sesquiterpenoid, named isobaimuxinol, C15H26O2, mp 73-75 degrees C, [a]D12-68(0) (c 0.10, CHCl3), was isolated from the volatile oil of Aquilaria sinensis (Lour), Gilg. (Thymeleaceae). Based on spectral (IR, 1H-NMR, 13C-NMR and 2D-NMR as well as MS) analysis its structure was identified as isobaimuxinol. The relative stereochemistry of isobaimuxinol was determined by X-ray crystallograhy. In addition, four known compounds, benzylacetone, p-methoxybenzylacetone, anisic acid and beta-agarofuran were isolated and identified from the lower boiling fraction of the volatile oil of this plant. These compounds were obtained for the first time from this plant.
Keywords:Thymeleaceae  Volatile oil  Sesquiterpenoids  Isobaimuxinol  Aquilaria sininsis (Lour.) Gilg.
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