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白花丹参的化学成分研究(Ⅱ)
引用本文:曹春泉,孙隆儒,王小宁. 白花丹参的化学成分研究(Ⅱ)[J]. 中草药, 2009, 40(2): 173-175
作者姓名:曹春泉  孙隆儒  王小宁
作者单位:山东大学药学院,山东,济南,250012
摘    要:目的 研究白花丹参的化学成分.方法 采用色谱法分离,波谱学数据分析鉴定结构.结果 从白花丹参根的乙醇提取物中分离得到4个化合物,分别鉴定为8,9-dihydro-1,6-dimethylfuro[3,2-c] naphtha[2,1-e]oxepine-10,12-dione(I)、丹参二醇C(II)、鼠尾草酚酮(Ⅲ)和1,2,6,7,8,9-hexahydro-1,6,6-trimethyl-3,11-dioxanaphtho[2,1-e]azulene-10,12一dione(IV).结论 化合物I为新化合物,命名为白花丹参酮(salmilalba-none),化合物Ⅱ~Ⅳ为首次从白花丹参中分离获得.

关 键 词:白花丹参  白花丹参酮  结构鉴定
收稿时间:2008-06-21

Chemical constituents of Salvia miltiorrhiza f. alba
CAO Chun-quan,SUN Long-ru and WANG Xiao-ning. Chemical constituents of Salvia miltiorrhiza f. alba[J]. Chinese Traditional and Herbal Drugs, 2009, 40(2): 173-175
Authors:CAO Chun-quan  SUN Long-ru  WANG Xiao-ning
Affiliation:School of Pharmaceutical Sciences, Shandong University, Jinan 250012, China;School of Pharmaceutical Sciences, Shandong University, Jinan 250012, China;School of Pharmaceutical Sciences, Shandong University, Jinan 250012, China
Abstract:Objective To study the chemical constituents of Salvia rniitiorrhiza f. alba. Methods The compounds were isolated by chromatographic techniques and their structures were elucidated by spec- troscopic analysis. Results Four compounds were obtained from the plant and identified as 8, 9-dihydro- 1, 6-dimethylfuro[3, 2-c] naphtha[2, 1-e] oxepine-10, 12-dione (I), tanshindiol C (II), salviolone (Ⅲ), 1, 2, 6, 7, 8, 9-hexahydro-1, 6, 6-trimethyl-3, 11-dioxanaphtho[2, 1-e] azulene-10, 12-dione (Ⅳ). Conclusion Compound I is a new one, named salmilalbanone (8, 9-dihydro-1, 6-dimethylfuro[3, 2-c] naphtha[2, 1-e] oxepine-10, 12-dione), while compounds Ⅱ-Ⅳ are isolated from the plant for the first time.
Keywords:Salvia miltiorrhiza Bunge f.alba C.Y.Wu et H.W.Li  salmilalbanone  structural i- dentification
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