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Efficient Sensitized Photoluminescence from Erbium Chloride Silicate via Interparticle Energy Transfer
Authors:Hao Shen  Huabao Shang  Yuhan Gao  Deren Yang  Dongsheng Li
Affiliation:1.State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China; (H.S.); (H.S.); (Y.G.); (D.Y.);2.Institute of Fluid Physics, China Academy of Engineering Physics, Mianshan Road 64#, Mianyang 621900, China
Abstract:In this study, we prepare Erbium compound nanocrystals and Si nanocrystal (Si NC) co-embedded silica film by the sol-gel method. Dual phases of Si and Er chloride silicate (ECS) nanocrystals were coprecipitated within amorphous silica. Effective sensitized emission of Er chloride silicate nanocrystals was realized via interparticle energy transfer between silicon nanocrystal and Er chloride silicate nanocrystals. The influence of density and the distribution of sensitizers and Er compounds on interparticle energy transfer efficiency was discussed. The interparticle energy transfer between the semiconductor and erbium compound nanocrystals offers some important insights into the realization of efficient light emission for silicon-based integrated photonics.
Keywords:interparticle energy transfer   erbium chloride silicate   sensitized emission
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