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自动电位滴定法测定水中总硬度的应用研究
引用本文:张文改,黄丽,杨敏,尹艳梅,林春明. 自动电位滴定法测定水中总硬度的应用研究[J]. 中国卫生检验杂志, 2008, 18(12): 2589-2590,2674
作者姓名:张文改  黄丽  杨敏  尹艳梅  林春明
作者单位:1. 广东省东莞市疾病预防控制中心,广东东莞,523016
2. 广东医学院,广东东莞,523808
摘    要:目的:建立自动电位滴定法测定水中总硬度。方法:50 ml水样经处理后进行在线动态滴定。结果:不同水样中10 mg/L和25 mg/L的加标回收率为99.02%~100.68%;相对标准偏差为0.13%~2.93%(n=6);对24份水样品进行测定,自动电位滴定法与人工滴定法的结果无显著性差异(P>0.05)。结论:自动电位滴定法操作简单、快速,自动化程度高,测定总硬度时准确度和重复性均好,适用于水中总硬度的常规分析。

关 键 词:总硬度  自动电位滴定法  生活饮用水

Applied study of automatic potentiometric titration on determination of total hardness in water
Zhang Wen-gai,Huang Li,Yang Min,Yin Yan-mei,Lin Chun-ming. Applied study of automatic potentiometric titration on determination of total hardness in water[J]. Chinses Journal of Health Laboratory Technology, 2008, 18(12): 2589-2590,2674
Authors:Zhang Wen-gai  Huang Li  Yang Min  Yin Yan-mei  Lin Chun-ming
Affiliation:Zhang Wen-gai1,Huang Li1,Yang Min1,Yin Yan-mei1,Lin Chun-ming2
Abstract:Objective:To establish a method for determination of total hardness in drinking water by automatic potentiometric titration.Methods:The 50 ml sample was titrated on line through automatic potentiometric titration after treatment.Results:The recovery rate of total hardness(10 mg/L and 25 mg/L) in different kinds of water was 99.02%~100.68%.The RSD was 0.13%~2.93%(n=6).It was shown that there was no significant difference between automatic potentiometric titration and national method by applying 24 water-samples(P>0.05).Conclusion:Automatic potentiometric titration is simple,rapid and automatic.It has good accuracy,reproducibility and is suitable for routine analysis of total hardness in drinking water.
Keywords:Automatic potentiometric titration  Total hardness  Drinking water
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