Efficiency of Soil Amendments for Copper Removal and Brassica Juncea (L.) Growth in Wastewater Irrigated Agricultural Soil

Wastewater irrigation is becoming a massive challenge for sustainable agriculture. Particularly, copper (Cu) presence in wastewater poses a great threat to the food chain quality. Thus, scientists need to address this issue by using chemical and organic soil amendments to restore the soil ecosystem. Therefore, this study aims to examine the efficacy of sulphur, compost, acidified animal manure and sesame straw biochar for Cu immobilization, adsorption and Brassica growth in wastewater irrigated soil. The current findings presented that all the soil amendments prominently improved brassica yield and significantly minimized the Cu uptake by Brassica shoots and roots in sesame straw biochar (SB) (64.2% and 50.2%), compost (CP) (48% and 32.5%), acidified manure (AM) (37% and 23.2%) and Sulphur (SP) (16% and 3.1%) respectively relative to untreated soil. In addition, Cu bioavailability was reduced by 51%, 34%, 16.6%, and 7.4% when SB, CP, AM, and SP were incorporated in wastewater irrigated polluted soil. The Cu adsorption isotherm results also revealed that SB treated soil has great potential to increase Cu adsorption capacity by 223 mg g^??1 over control 89 mg g^??1. Among all the treatments, SB and CP were considered suitable candidates for the restoration of Cu polluted alkaline nature soil.

     

Phenolic water toxins: redox mechanism and method of their detection in water and wastewater

Phenolic pollutants are highly toxic and persistent in the environment. Their efficient detection is a pressing social demand. In this regard we introduce a novel ultrasensitive electroanalytical platform for the individual and synchronized detection of three phenolic isomers commonly known as hydroquinone (HQ), resorcinol (RC), and catechol (CC). The sensing device consists of a glassy carbon electrode (GCE) modified with functionalized carbon nanotubes (fCNTs) and gold–silver (Au–Ag NPs) bimetallic nanoparticles. The sandwiched scaffold represented as fCNTs/Au–Ag NPs/fCNTs/GCE efficiently senses HQ, RC, and CC with detection limits of 28.6 fM, 36.5 fM and 42.8 fM respectively. The designed sensor is more promising than reported sensors for phenolic toxins in the context of high sensitivity, selectivity, and rapid responsiveness. The designed sensor also shows the qualities of stability, reproducibility, reliability, and selective recognition capacity for target analytes in multiple real water samples. Moreover, computational calculations explain the function of the electrode modifier in facilitating charge transfer between the transducer and analytes.

Phenolic pollutants are highly toxic and persistent in the environment.