Application of hyperspectral imaging for spatial prediction of soluble solid content in sweet potato

Visible and near infrared (Vis-NIR) hyperspectral imaging was used for fast detection and visualization of soluble solid content (SSC) in ‘Beijing 553’ and ‘Red Banana’ sweet potatoes. Hyperspectral images were acquired from 420 ROIs of each cultivar of sliced sweet potatoes. There were 8 and 10 outliers removed from ‘Beijing 553’ and ‘Red Banana’ sweet potatoes by Monte Carlo partial least squares (MCPLS). The optimal spectral pretreatments were determined to enhance the performance of the prediction model. Successive projections algorithm (SPA) and competitive adaptive reweighted sampling (CARS) were employed to select characteristic wavelengths. SSC prediction models were developed using partial least squares regression (PLSR), support vector regression (SVR) and multivariate linear regression (MLR). The more effective prediction performances emerged from the SPA–SVR model with R_p² of 0.8581, RMSEP of 0.2951 and RPD_p of 2.56 for ‘Beijing 553’ sweet potato, and the CARS–MLR model with R_p² of 0.8153, RMSEP of 0.2744 and RPD_p of 2.09 for ‘Red Banana’ sweet potato. Spatial distribution maps of SSC were obtained in a pixel-wise manner using SPA–SVR and CARS–MLR models for quantifying the SSC level in a simple way. The overall results illustrated that Vis-NIR hyperspectral imaging was a powerful tool for spatial prediction of SSC in sweet potatoes.

Visible and near infrared (Vis-NIR) hyperspectral imaging was used for fast detection and visualization of soluble solid content (SSC) in ‘Beijing 553’ and ‘Red Banana’ sweet potatoes.     

Two 3D Mn-based coordination polymers: synthesis,structure and magnetocaloric effect

Two three-dimensional (3D) coordination polymers, namely Mn^II₆(CH₃COO)₂(HCOO)₂(IN)₈(C₄H₈O)₂(H₂O) and Mn^III₆Mn^II₁₂(μ₃-O)₆(CH₃COO)₁₂(IN)₁₈(H₂O)_7.5 (abbreviated as Mn^II₆ and Mn^II₁₂Mn^III₆ respectively; HIN = isonicotinic acid), were synthesized by the reaction of Mn(CH₃COO)₂·4H₂O and isonicotinic acid under solvothermal conditions. Magnetic studies revealed that antiferromagnetic interactions may be present in compounds Mn^II₆ and Mn^II₁₂Mn^III₆. Moreover, the values of −ΔS_m (26.27 (Mn^II₆) and 37.69 (Mn^II₁₂Mn^III₆) J kg⁻¹ K⁻¹ at ΔH = 7 T) are relatively larger than those of the reported Mn-based coordination polymers. This work provides a great scope in the magnetocaloric effect (MCE) of pure 3d-type systems.

Two 3D coordination polymers (Mn^II₆ and Mn^II₁₂Mn^III₆) were synthesized. Magnetic studies revealed that they are potential magnetic materials.     

Synthesis of MOFs/GO composite for corrosion resistance application on carbon steel

Two unreported metal–organic frameworks [Cu(6-Me-2,3-pydc)(1,10-phen)·7H₂O]_n (namely Cu-MOF) and [Mn₂(2,2′-bca)₂(H₂O)₂]_n (namely Mn-MOF) were synthesized by a solvothermal method and their structures were characterized and confirmed by elemental analysis, X-ray single crystal diffraction, Fourier infrared spectroscopy and thermogravimetric analysis. Cu-MOF/graphene (Cu-MOF/GR), Cu-MOF/graphene oxide (Cu-MOF/GO), Mn-MOF/graphene (Mn-MOF/GR) and Mn-MOF/graphene oxide (Mn-MOF/GO) composite materials were successfully synthesized by a solvothermal method and characterized and analyzed by PXRD, SEM and TEM. In order to study the corrosion inhibition properties of the Cu-MOF/GR, Cu-MOF/GO, Mn-MOF/GR and Mn-MOF/GO composite materials on carbon steel, they were mixed with waterborne acrylic varnish to prepare a series of composite coatings to explore in 3.5 wt% NaCl solution by electrochemical measurements and results showed that the total polarization resistance of the 3% Cu-MOF/GO and 3% Mn-MOF/GO composite coatings on the carbon steel surface were relatively large, and were 55 097 and 55 729 Ω cm², respectively, which could effectively protect the carbon steel from corrosion. After immersion for 30 days, the 3% Mn-MOF/GO composite still maintained high corrosion resistance, the |Z| values were still as high as 23 804 Ω cm². Therefore, MOFs compounded with GO can produce a synergistic corrosion inhibition effect and improve the corrosion resistance of the coating; this conclusion is well confirmed by the adhesion capability test.

Two unreported metal–organic frameworks [Cu(6-Me-2,3-pydc)(1,10-phen)·7H₂O]_n (namely Cu-MOF) and [Mn₂(2,2′-bca)₂(H₂O)₂]_n (namely Mn-MOF) were synthesized and characterized. Cu-MOF and Mn-MOF all can form a three-dimensional structure.     

Green and facile edge-oxidation of multi-layer graphene by sodium persulfate activated with ferrous ions

Effective edge oxidation of graphene with high structural integrity is highly desirable yet technically challenging for most practical applications. In this work, we have developed a green and facile strategy to obtain edge-oxidized graphene with good dispersion stability and high electrical conductivity by exploiting high edge reactivity of highly conductive multi-layer graphene and oxidizing radicals (SO₄⁻˙) generated from sodium persulfate (Na₂S₂O₈) with ferrous ion (Fe²⁺) activation. Owing to high structural integrity of pristine graphene and effective edge oxidation, the obtained edge-oxidized graphene exhibited excellent dispersion stability and satisfactory electrical conductivity (i.e. ≥240 S cm⁻¹). Moreover, the oxidation degree of pristine graphene can be well controlled by adjusting treatment time. The obtained edge-oxidized graphene is expected to find a variety of applications in many fields of anti-static films, energy storage materials, flexible sensors and high-performance nanocomposites.

A green and facile strategy is represented to obtain edge-oxidized graphene by exploiting sulfate radicals generated from Na₂S₂O₈ with Fe²⁺ activation.     

Prevalence and associated factors of periodontal conditions among 55- to 74-year-old adults in China: results from the 4th National Oral Health Survey

Clinical Oral Investigations - The purpose of this study was to assess periodontal health conditions among 55- to 74-year-old Chinese people and to analyze the factors associated with periodontal...