The Effect of Antimony (III) Oxide on the Necessary Amount of Precursors Used in Laser-Activated Coatings Intended for Electroless Metallization

The article presents research on the potential use of organometallic compounds with the addition of antimony (III) oxide Sb₂O₃ as a coating additive that will make coatings susceptible to electroless metallization after prior surface irradiation with 193 nm wavelength laser radiation and a different number of laser pulses. The surface modification and activation effects were assessed by optical-imagining as well as by scanning electron microscopy (SEM) with energy dispersive analysis (EDX). It was found that the presence of Sb₂O₃ in the coating made it possible to reduce the content of the copper complex, causing an intensive surface ablation, resulting in the formation of a conical structure with a higher content of metallic copper nuclei.     

Oxazoline scaffold in synthesis of benzosiloxaboroles and related ring-expanded heterocycles: diverse reactivity,structural peculiarities and antimicrobial activity

Two isomeric benzosiloxaborole derivatives 3a and 5a bearing fluorine and 4,4-dimethyl-2-oxazolin-2-yl substituents attached to the aromatic rings were obtained. Both compounds were prone to hydrolytic cleavage of the oxazoline ring after initial protonation or methylation of the nitrogen atom. The derivative 3c featuring N-methylammoniumalkyl ester functionality was successfully subjected to N-sulfonylation and N-acylation reactions to give respective derivatives which demonstrates its potential for modular synthesis of structurally extended benzosiloxaboroles. Compound 5c bearing N-ammoniumalkyl ester underwent conversion to a unique macrocyclic dimer due to siloxaborole ring opening. Furthermore, an unexpected 4-electron reduction of the oxazoline ring occurred during an attempted synthesis of 5a. The reaction gave rise to an unprecedented 7-membered heterocyclic system 4a comprising a relatively stable B–O–B–O–Si linkage and stabilized by an intramolecular N–B coordination. It could be cleaved to derivative 4c bearing BOH and SiMe₂OH groups which acts as a pseudo-diol as demonstrated by formation of an adduct with Tavaborole. Apart from the multinuclear NMR spectroscopy characterization, crystal structures of the obtained products were determined in many cases by X-ray diffraction. Investigation of biological activity of the obtained compounds revealed that derivatives 3e and 3f with pendant N-methyl arylsulfonamide groups exhibit high activity against Gram-positive cocci such as methicillin-sensitive Staphylococcus aureus ATCC 6538P, methicillin-resistant S. aureus (MRSA) ATCC 43300 as well as the MRSA clinical strains, with MIC values in the range of 3.12–6.25 mg L⁻¹. These two compounds also showed activity against Enterococcus faecalis ATCC 29212 and Enterococcus faecium ATCC 6057 (with MICs of 25–50 mg L⁻¹). The results of the antimicrobial activity and cytotoxicity studies indicate that 3e and 3f can be considered as potential antibacterial agents, especially against S. aureus MRSA.

Transformations of oxazoline–benzosiloxaborole conjugates gave rise to novel boracyclic systems as well as functionalized derivatives featuring antibacterial activity.     

Detection and monitoring toxigenicity of cyanobacteria by application of molecular methods

The aim of this study was early genetic identification of microcystin-producing cyanobacteria and monitoring their toxigenicity by determining toxin concentrations in three Polish lakes throughout the summer of 2004. The assessment of cyanobacterial blooms was carried out in shallow, eutrophic water bodies: Lake Jeziorak, Lake Bninskie, and Sulejow Reservoir. Samples for DNA, phycological, and toxin analyses were collected from July till October. Molecular analysis of the 16S rRNA region was used to detect cyanobacteria in water samples. The microscopic analysis was performed to investigate seasonal variation of phytoplankton. Cyanobacteria, with domination by Microcystis, Planktothrix, and Planktolyngbya were detected during the whole monitoring period in Sulejow Reservoir, Lake Bninskie, and Lake Jeziorak, respectively. The presence and identification of toxic strains in water bodies was studied by PCR amplification of mcy genes in the microcystis synthesis pathway. The presence of the mcyA, mcyB, mcyD, and mcyE genes in water samples indicated the genetic potential to produce microcystins. Toxicity of water samples and microcystin concentrations were established by PPIA and HPLC, respectively. The maximum concentration of microcystins was 11.13 microg/L and 4.67 microg/L in samples dominated by P. agardhii and M. aeruginosa, respectively. Molecular analysis showed that toxigenic strains of cyanobacteria occurred in the three lakes throughout the summer season.     

Photogrammetry-Based Volume Measurement Framework for the Particle Density Estimation of LECA

This paper presents a photogrammetry-based volume measurement framework for the particle density estimation of Lightweight expanded clay aggregate (LECA). The results are compared with computed tomography (CT) and Archimedes’ method measurements. All of the steps required in order to apply the proposed approach are explained. Next, we discuss how the interpretation of open pores affects the results of volume measurements. We propose to process the shapes obtained from different methods by applying an Ambient Occlusion algorithm with the same threshold, t = 0.175. The difference between the CT and SfM methods is less than 0.006 g/cm³, proving that the photogrammetry-based approach is accurate enough. The Archimedes’ method significantly overestimates the density of the particles. Nevertheless, its accuracy is acceptable for most engineering purposes. Additionally, we evaluate the accuracy of shape reconstruction (in terms of the Hausdorff distance). For 95% of the grain’s surface, the maximum error is between 0.073 mm and 0.129 mm (depending on the grain shape). The presented approach is helpful for measuring the particle density of porous aggregates. The proposed methodology can be utilized in order to estimate intergranular porosity, which is valuable information for the calibration of DEM models.     

Polyaniline and Polyaniline-Based Materials as Sorbents in Solid-Phase Extraction Techniques

Polyaniline (PANI) is one of the best known and widely studied conducting polymers with multiple applications and unique physicochemical properties. Due to its porous structure and relatively high surface area as well as the affinity toward many analytes related to the ability to establish different types of interactions, PANI has a great potential as a sorbent in sample pretreatment before instrumental analyses. This study provides an overview of the applications of polyaniline and polyaniline composites as sorbents in sample preparation techniques based on solid-phase extraction, including conventional solid-phase extraction (SPE) and its modifications, solid-phase microextraction (SPME), dispersive solid-phase extraction (dSPE), magnetic solid-phase extraction (MSPE) and stir-bar sorptive extraction (SBSE). The utility of PANI-based sorbents in chromatography was also summarized. It has been shown that polyaniline is willingly combined with other components and PANI-based materials may be formed in a variety of shapes. Polyaniline alone and PANI-based composites were successfully applied for sample preparation before determination of various analytes, both metal ions and organic compounds, in different matrices such as environmental samples, food, human plasma, urine, and blood.     

Determination of Two-Stage Heat Treatment Parameters in Industrial Conditions in Order to Obtain a TRIP Structure in Low-Alloy Carbon Steel Wires

The research presented in this article aimed to obtain a semi-finished product in the form of TRIP wires, which in further research will be used to produce fasteners in the form of KPS-6 screws used in the construction industry. At present, the process of manufacturing this type of fastener (from wire rod to the finished product) involves two technological lines: one for carrying out the drawing process and obtaining a semi-finished product in the form of a wire with appropriate properties, and the other for the production of fasteners. Semi-finished product wires with a ferritic-perlitic structure obtained after the drawing process are the starting product for the production of fasteners, the tensile strength of which is approximately 450 MPa. In order to be able to obtain fasteners characterized by an increased level of properties in 8.8 grade, after the screw manufacturing process, heat treatment should be carried out by hardening and tempering. The new technology proposed in the article includes: a drawing wire rod with a semi-finished product diameter, two-stage heat treatment on the line for pass-through heating and cooling, ensuring the obtaining of a TRIP-type structure in drawn wires, and calibration drawing. The product of this process was a wire whose tensile strength was in the range of 700–800 MPa with a TRIP structure. Thanks to obtaining a TRIP-type structure with the assumed amount of retained austenite, we obtained wires with higher strength properties and very high plasticity in relation to wires with the same chemical composition and ferritic and perlitic structure. The research carried out in the article also allowed us to obtain, in the semi-finished product wires, a favourable relationship between the strength properties and plasticity of the material, expressed by the value of the R_e/R_m coefficient (yield strength/tensile strength) and the so-called yield ratio, which determines the material′s susceptibility to cold deformation; the smaller these coefficients, the greater the yield strength. The subsequent stages of the research will include the development of forming fasteners in the form of KPS-6 screws used in the steel construction industry with TRIP structures, with increased properties of products in the 8.8 property class, without conducting heat treatment by hardening and tempering. It is assumed that the resulting product will have an additional usable feature: preserving a certain amount of retained austenite in the structure of the finished fasteners, which will be transformed into martensite during operation, and thus affect the longevity of the fasteners.     

Simplified Modelling of the Edge Crush Resistance of Multi-Layered Corrugated Board: Experimental and Computational Study

The edge crush test is the most popular laboratory test in the corrugated packaging industry. It measures the edge crush resistance of a sample in the cross-fiber direction (CD), also known as the ECT index. This parameter is widely used for the specification of the board by its producers. It is also utilized in most analytical formulas describing the load capacity of the packaging. On the other hand, the ECT value can be estimated from both analytical and numerical models based on the basic parameters of each constituent paper. Knowing the compressive strength in CD (commonly known as SCT) and the elastic properties of the individual layers, the sample geometry (i.e., the period and height of the corrugated layer), as well as the boundary conditions, the ECT value can be calculated. This is very useful as new boards can be virtually analyzed before being manufactured. In this work, both detailed numerical models based on finite elements (FE) methods and very simple analytical (engineering) models were used for the ECT calculations. All presented models were validated with experimental data. The surprising consistency and high precision of the results obtained with the simplest approach was additionally analyzed in the study.     

Tests of Dental Properties of Composite Materials Containing Nanohybrid Filler

Complex composite materials are used in many areas of dentistry. Initially, chemically hardened materials were also used, and in this group nanohybrid composites are highly valued. They are often used today, mainly for the direct reconstruction of damaged hard tooth tissue materials for rebuilding damaged tissues using indirect adhesive techniques. The research was conducted to determine the mechanical properties of materials with nanofillers. The article focuses on methods of important test methods for dental prosthetics: resilience, abrasion, wear test, impact strength, hardness, SEM, and chemical analysis. As part of this work, five different series of hybrid composites with nano-fillers were tested. The mechanical properties of composites, such as compressive strength, microhardness, flexural strength, and modulus of elasticity, depend mainly on the type, particle size, and amount of filler introduced. The obtained test results showed that the type and amount of nanofiller have a significant influence on the mechanical and tribological properties. The introduction of nanofillers allowed us to obtain higher mechanical properties compared to classic materials discussed by other researchers. The study observed a change in vibrations in the IR spectrum, which allowed a comparison of the organic structures of the studied preparations.