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11.
Stanislav S. Shcherbakov Artyom Yu. Magometov Viktoriia Yu. Shcherbakova Alexander V. Aksenov Dmitriy A. Domenyuk Vladimir A. Zelensky Michael Rubin 《RSC advances》2020,10(17):10315
A new synthetic protocol for preparation of medicinally important 4-aryl-5-alkynylpyrimidines is described. The featured approach involves a sequence of chemo- and regioselective Brønsted acid-catalyzed electrophilic alkylation of arenes with 5-bromopyrimidine, followed by oxidative re-aromatization of the formed dihydropyrimidine ring. Finally, palladium-catalyzed Sonogashira cross-coupling reaction provided an end-game strategy.Efficient assembly of 4-aryl-5-alkynylpyrimidines is described featuring novel Brønsted acid-catalyzed electrophilic alkylation of arenes with 5-bromopyrimidine as a key step. 相似文献
12.
Viktoriia Fedorenko Roman Viter Radosaw Mrwczyski Daina Damberga Emerson Coy Igor Iatsunskyi 《RSC advances》2020,10(50):29751
In the present work, we report on the modelling of processes at the zinc oxide and polydopamine (ZnO/PDA) interface. The PDA layer was deposited onto ZnO nanorods (NRs) via chemical bath deposition. The defect concentrations in ZnO before and after PDA deposition were calculated and analysed. The ZnONRs/PDA core–shell nanostructures were studied by transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman and Fourier-transform infrared (FTIR) spectroscopy, photoluminescence (PL) measurements, and diffuse reflectance spectroscopy. The TEM and electron energy loss spectroscopy (EELS) measurements confirmed the conformal coating of PDA, while the PL emission from ZnO and ZnONRs/PDA samples showed a reduction of intensity after the PDA deposition. The decrease of defect concentration participating in PL and quantum efficiency explains the PL reduction. Finally, the observed decrease of activation energies and a shift of the PL peaks are attributed to the formation of an additional local electrical field between the PDA and ZnO nanostructures.The results shown in this study provide a unique insight into the optical and electronic processes of the ZnO/PDA interface. 相似文献
13.
Olga Fursa Joanne Reekie Ihor Kuzin Larysa Hetman Alina Kryshchuk Olena Starychenko Nana Hrytsaiuk Inna Khodus Alla Nyzhnyk Viktoriia Rakhuba Maryna Kovalevska Tetiana Maistat Iryna Pryhoda Marianna Ahieieva Olena Varvarovska Olena Valdenmaiier Jens Lundgren Lars Peters the CARE study group 《Journal of the International AIDS Society》2023,26(9):e26166