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1.
The poly(lactic acid) (PLA) biodegradable polymer, as well as natural, siliceous reinforcement in the form of diatomaceous earth, fit perfectly into the circular economy trend. In this study, various kinds of commercial PLA have been reinforced with diatomaceous earth (DE) to prepare biodegradable composites via the extrusion process. The structure of the manufactured composites as well as adhesion between the matrix and the filler were investigated using scanning electron microscopy (SEM). Differential scanning calorimetry (DSC) analyses were carried out to determine crystallinity of PLA matrix as function of DE additions. Additionally, the effect of the ceramic-based reinforcement on the mechanical properties (Young’s modulus, elongation to failure, ultimate tensile strength) of PLA has been investigated. The results are discussed in terms of possible applications of PLA + DE composites.  相似文献   

2.
Biodegradable polymer materials are increasingly used in the packaging industry due to their good properties and low environmental impact. Therefore, the work was performed on the injection molding of the bio-based composites of polylactide (PLA) and polyhydroxyalcanates (PHI) modified with two phases: reinforcing (walnut shell flour and cellulose) and coloring (beta carotene and anthocyanin). The produced materials were subjected to wide mechanical characteristics—tensile, flexural, and fatigue tests. Additionally, the influence of photo and hydrodegradation on the change of the surface structure and mechanical properties of the composites was assessed. The addition of natural fillers contributed to the improvement of the stiffness of the tested composites. PHI composites withstood a higher number of cycles during cyclic loading, but the stress values obtained in the static tensile test were higher for PLA composites. Moreover, a clear change of color was observed after both the photo and hydrodegradation process for all tested materials; however, after the degradation processes, the filler-modified materials underwent greater discoloration. For the composites based on PHI, the type of degradation did not affect the mechanical properties. On the other hand, for PLA composites, hydrolytic degradation contributed to a higher decrease in properties—the decrease in tensile strength for unmodified PLA after photodegradation was 4%, while after hydrodegradation it was 24%.  相似文献   

3.
Catalysis has been a key way of improving the efficiency-to-cost ratio of chemical and electrochemical processes. There have been recent developments in catalyst materials that enable the development of novel and more sophisticated devices that, for example, can be used in applications, such as membranes, batteries or fuel cells. Since catalytic reactions occur on the surface, most catalyst materials are based on open porous structures, which facilitates the transport of fluids (gas or liquid) and chemical (or electrochemical) specific surface activity, thus determining the overall efficiency of the device. Noble metals are typically used for low temperature catalysis, whereas lower cost materials, such as nickel, are used for catalysis at elevated temperatures. 3D printing has the potential to produce a more sophisticated fit for purpose catalyst material. This article presents the development, fabrication and performance comparison of three thermoplastic composites where PLA (polylactic acid), PVB (polyvinyl butyral) or ABS (acrylonitrile butadiene styrene) were used as the matrix, and nickel particles were used as filler with various volume fractions, from 5 to 25 vol%. The polymer–metal composites were extruded in the form of filaments and then used for 3D FDM (Fused Deposition Modeling) printing. The 3D printed composites were heat treated to remove the polymer and sinter the nickel particles. 3D printed composites were also prepared using nickel foam as a substrate to increase the final porosity and mechanical strength of the material. The result of the study demonstrates the ability of the optimized filament materials to be used in the fabrication of high open porosity (over 60%) structures that could be used in high-temperature catalysis and/or electrocatalysis.  相似文献   

4.
This review article focuses on the aluminum-based metal matrix composites (Al-based MMCs). Studies or investigations of their mechanical and tribological properties performed by researchers worldwide in the past are presented in detail. The processing techniques and applications for Al-based MMCs are also documented here. A brief background on the composite materials, their constituents, and their classification, as well as the different matrix materials and particulates used in Al-based MMCs, can be found in this review. Then, an overview of dual-particle-size reinforced composites, heat treatment of Al alloys, and temper designations used in heat treatment are also included. In addition, the factors influencing the mechanical and wear properties of Al-based MMCs are discussed. The primary objective is that both present and future researchers and investigators will be assisted by the comprehensive knowledge compiled in this article to further explore and work towards the betterment of society in general.  相似文献   

5.
Lichao Feng  Ning Xie  Jing Zhong 《Materials》2014,7(5):3919-3945
Carbon nanofiber (CNF), as one of the most important members of carbon fibers, has been investigated in both fundamental scientific research and practical applications. CNF composites are able to be applied as promising materials in many fields, such as electrical devices, electrode materials for batteries and supercapacitors and as sensors. In these applications, the electrical conductivity is always the first priority need to be considered. In fact, the electrical property of CNF composites largely counts on the dispersion and percolation status of CNFs in matrix materials. In this review, the electrical transport phenomenon of CNF composites is systematically summarized based on percolation theory. The effects of the aspect ratio, percolation backbone structure and fractal characteristics of CNFs and the non-universality of the percolation critical exponents on the electrical properties are systematically reviewed. Apart from the electrical property, the thermal conductivity and mechanical properties of CNF composites are briefly reviewed, as well. In addition, the preparation methods of CNFs, including catalytic chemical vapor deposition growth and electrospinning, and the preparation methods of CNF composites, including the melt mixing and solution process, are briefly introduced. Finally, their applications as sensors and electrode materials are described in this review article.  相似文献   

6.
In the concrete industry, various R&D efforts have been devoted to self-healing technology, which can maintain the long-term performance of concrete structures, which is important in terms of sustainable development. Cracks in cement composites occur and propagate because of various internal and external factors, reducing the composite’s stability. Interest in “self-healing” materials that can repair cracks has led researchers to embed self-healing capsules in cement composites. Overcoming the limitations of polymer capsules produced by chemical manufacturing methods, three-dimensional (3D) printing can produce capsules quickly and accurately and offers advantages such as high material strength, low cost, and the ability to fabricate capsules with complex geometries. We performed structural analysis simulations, experimentally evaluated the mechanical properties and solubility of poly(lactic acid) (PLA) capsules, and examined the effect of the capsule wall thickness and printing direction on cement composites embedded with these capsules. Thicker capsules withstood larger bursting loads, and the capsule rupture characteristics varied with the printing angle. Thus, the capsule design parameters must be optimized for different environments. Although the embedded capsules slightly reduced the compressive strength of the cement composites, the benefit of the encapsulated self-healing agent is expected to overcome this disadvantage.  相似文献   

7.
In this study, the influence of carbonate lake sediments (Polylactide/Carbonate Lake Sediments–PLA/CLS) on the mechanical and structural properties of polylactide matrix composites was investigated. Two fractions of sediments originating from 3–8 and 8–12 m were analysed for differences in particle size by distribution (Dynamic Light Scattering–DLS), phase composition (X-ray Diffraction–XRD), the presence of surface functional groups (Fourier Transform-Infrared–FT-IR), and thermal stability (Thermogravimetric Analysis–TGA). Microscopic observations of the composite fractures were also performed. The effect of the precipitate fraction on the mechanical properties of the composites before and after conditioning in the weathering chamber was verified through peel strength, flexural strength, and impact strength tests. A melt flow rate study was performed to evaluate the effect of sediment on the processing properties of the PLA/CLS composite. Hydrophobic-hydrophilic properties were also investigated, and fracture analysis was performed by optical and electron microscopy. The addition of carbon lake sediments to PLA allows for the obtention of composites resistant to environmental factors such as elevated temperature or humidity. Moreover, PLA/CLS composites show a higher flow rate and higher surface hydrophobicity in comparison with unmodified PLA.  相似文献   

8.
Many investigators have become interested in nanostructures due to their outstanding mechanical, chemical, and electrical properties. Two-dimensional nanoplates with higher mechanical properties compared with traditional structural applications are a common structure of nanosystems. Nanoplates have a wide range of uses in various sectors due to their unique properties. This paper focused on the static analysis of functionally graded (FG) nanoplates with porosities. The nonlocal strain gradient theory is combined with four-variable shear deformation theory to model the nanoplate. The proposed model captures both nonlocal and strain gradient impacts on FG nanoplate structures by incorporating the nonlocal and strain gradient factors into the FG plate’s elastic constants. Two different templates of porosity distributions are taken into account. The FG porous nanoplate solutions are compared with previously published ones. The impact of nonlocal and strain gradient parameters, side-to-thickness ratio, aspect ratio, and porosity parameter, are analyzed in detail numerically. This paper presents benchmark solutions for the bending analysis of FG porous nanoplates. Moreover, the current combination of the nonlocal strain gradient theory and the four-variable shear deformation theory can be adapted for various nanostructured materials such as anisotropic, laminated composites, FG carbon nanotube reinforced composites, and so on.  相似文献   

9.
To find out whether Al2O3 nanofiller is effective in improving the characteristics of polymer composites, composite polymer films based on biodegradable polylactide and epoxidized aluminum oxide nanofibers were obtained by solution casting. Surface morphology, mechanical and thermal properties of composites were studied by SEM, IR-Fourier spectroscopy, DSC and DMA. It was shown that, below and above the percolation threshold, the properties of the films differ significantly. The inclusion of alumina nanoparticles up to 0.2% leads to a plasticizing effect, a decrease in the crystallization temperature and the melting enthalpy and an increase in the tensile stress. An increase in the content of alumina nanoparticles in films above the percolation threshold (0.5%) leads to a decrease in the crystallinity of the films, an increase in stiffness and a drop in elasticity. Finding the percolation threshold of alumina nanoparticles in PLA films makes it possible to control their properties and create materials for various applications. The results of this study may have major significance for the commercial use of aluminum oxide nanofibers and can broaden the research field of composites.  相似文献   

10.
The present study investigated the effect of biochar (BC) addition on mechanical, thermal, and water resistance properties of PLA and hemp-PLA-based composites. BC was combined with variable concentration to PLA (5 wt%, 10 wt%, and 20 wt%) and hemp (30 wt%)-PLA (5 wt% and 10 wt%); then, composites were blended and injection molded. Samples were characterized by color measurements, tensile tests, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and water contact angle analysis. Experimental results showed that adding 5 wt% of BC enhanced the composite’s tensile modulus of elasticity and strength. Hence, the use of optimized loading of BC improved the mechanical strength of the composites. However, after BC addition, thermal stability slightly decreased compared with that of neat PLA due to the catalytic effect of BC particles. Moreover, the water-repelling ability decreased as BC content increased due to the specific hydrophilic characteristics of the BC used and its great porosity.  相似文献   

11.
The presented study focuses on the development of flax fiber (FF) reinforced composites prepared with the use of poly(lactic acid)/poly(butylene adipate-co-terephthalate)—PLA/PBAT blend system. This type of modification was aimed to increase impact properties of PLA-based composites, which are usually characterized by high brittleness. The PLA/PBAT blends preparation was carried out using melt blending technique, while part of the samples was prepared by reactive extrusion process with the addition of chain extender (CE) in the form of epoxy-functionalized oligomer. The properties of unreinforced blends was evaluated using injection molded samples. The composite samples were prepared by compression molding technique, while flax fibers reinforcement was in the form of plain fabric. The properties of the laminated sheets were investigated during mechanical test measurements (tensile, flexural, impact). Differential scanning calorimetry (DSC) analysis was used to determine the thermal properties, while dynamic mechanical thermal analysis (DMTA) and heat deflection temperature (HDT) measurements were conducted in order to measure the thermomechanical properties. Research procedure was supplemented with structure evaluation using scanning electron microscopy (SEM) analysis. The comparative study reveals that the properties of PLA/PBAT-based composites were more favorable, especially in the context of impact resistance improvement. However, for CE modified samples also the modulus and strength was improved. Structural observations after the impact tests confirmed the presence of the plastic deformation of PLA/PBAT matrix, which confirmed the favorable properties of the developed materials. The use of PBAT phase as the impact modifier strongly reduced the PLA brittleness, while the reactive extrusion process improves the fiber-matrix interactions leading to higher stiffness and strength.  相似文献   

12.
Legislative restrictions and the needs of consumers have created a demand for sustainable materials. Polylactide (PLA) is a biodegradable polyester with advantageous mechanical properties, however, due to its low crystallization rate, it also has low thermomechanical stability. Its range of application temperatures can be widened using nucleating agents and fillers including basalt powder (BP), a waste product from the mining industry. This study analyzed the possibility of enhancing the properties of a PLA-BP composite by chemically treating the filler. Basalt powder was subjected to silanization with 3-aminopropyltriethoxysilane or γ-glycidoxypropyltrimethoxysilane and mixed with PLA at 5–20 wt%. The nucleating effect of a potassium salt of 3,5-bis(methoxycarbonyl) (LAK-301) in the silanized composite was also evaluated. The properties of the materials with silanized BP were compared with the unmodified basalt powder. The miscibility of the filler and the polymer was assessed by oscillatory rheometry. The structure of the composites was studied using scanning electron microscopy and their thermomechanical properties were analyzed using dynamic mechanical thermal analysis. Mechanical properties such as tensile strength, hardness and impact strength, and heat deflection temperature of the materials were also determined. It was concluded that BP-filled nucleated PLA composites presented satisfactory thermomechanical stability without silanization, but chemical treatment could improve the matrix–filler interactions.  相似文献   

13.
Despite the knowledge gained in recent years regarding the use of acoustic emissions (AEs) in ecologically friendly, natural fiber-reinforced composites (including certain composites with bio-sourced matrices), there is still a knowledge gap in the understanding of the difference in damage behavior between green and biocomposites. Thus, this article investigates the behavior of two comparable green and biocomposites with tests that better reflect real-life applications, i.e., load-unloading and creep testing, to determine the evolution of the damage process. Comparing the mechanical results with the AE, it can be concluded that the addition of a coupling agent (CA) markedly reduced the ratio of AE damage to mechanical damage. CA had an extremely beneficial effect on green composites because the Kaiser effect was dominant during cyclic testing. During the creep tests, the use of a CA also avoided the transition to new damaging phases in both composites. The long-term applications of PE green material must be chosen carefully because bio and green composites with similar properties exhibited different damage processes in tests such as cycling and creep that could not be previously understood using only monotonic testing.  相似文献   

14.
This paper presents results of a study on the effect of filler size in the form of 15 wt% corn stalk (CS) fibers on the mechanical and thermomechanical properties of polylactide (PLA) matrix composites. In the test, polylactidic acid (PLA) is filled with four types of length of corn stalk fibers with a diameter of 1 mm, 1.6 mm, 2 mm and 4 mm. The composites were composed by single screw extrusion and then samples were prepared by injection molding. The mechanical properties of the composites were determined by static tensile test, static bending test and Charpy impact test while the thermo-mechanical properties were determined by dynamic mechanical thermal analysis (DMTA). The composite structures were also observed using X-ray microcomputed tomography and scanning electron microscopy. In the PLA/CS composites, as the filler fiber diameter increased, the degradation of mechanical properties relative to the matrix was observed including tensile strength (decrease 22.9–51.1%), bending strength (decrease 18.9–36.6%) and impact energy absorption (decrease 58.8–69.8%). On the basis of 3D images of the composite structures for the filler particles larger than 2 mm a weak dispersion with the filler was observed, which is reflected in a significant deterioration of the mechanical and thermomechanical properties of the composite. The best mechanical and thermomechanical properties were found in the composite with filler fiber of 1 mm diameter. Processing resulted in a more than 6-fold decrease in filler fiber length from 719 ± 190 µm, 893 ± 291 µm, 1073 ± 219 µm, and 1698 ± 636 µm for CS1, CS1.6, CS2, and CS4 fractions, respectively, to 104 ± 43 µm, 123 ± 60 µm, 173 ± 60 µm, and 227 ± 89 µm. The fabricated green composites with 1 to 2 mm corn stalk fiber filler are an alternative to traditional plastic based materials in some applications.  相似文献   

15.
Sustainable fibre reinforced polymer composites have drawn significant attention in many industrial sectors as a means for overcoming issues with end-of-life regulations and other environmental concerns. Plant based natural fibres are considered to be the most suitable reinforcement for sustainable composites since they are typically from renewable resources, are cheap, and are biodegradable. In this study, a number of plant based natural fibres-curaua, flax, and jute fibres-are used to reinforce epoxy, poly(lactic acid) (PLA), and polypropylene (PP) matrices to form aligned discontinuous natural fibre reinforced composites (ADNFRC). The novel HiPerDiF (high performance discontinuous fibre) method is used to produce high performance ADNFRC. The tensile mechanical, fracture, and physical (density, porosity, water absorption, and fibre volume fraction) properties of these composites are reported. In terms of stiffness, epoxy and PP ADNFRC exhibit similar properties, but epoxy ADNFRC shows increased strength compared to PP ADNFRC. It was found that PLA ADNFRC had the poorest mechanical performance of the composites tested, due principally to the limits of the polymer matrix. Moreover, curaua, flax (French origin), and jute fibres are found to be promising reinforcements owing to their mechanical performance in epoxy and PP ADNFRC. However, only flax fibre with desirable fibre length is considered to be the best reinforcement constituent for future sustainable ADNFRC studies in terms of mechanical performance and current availability on the market, particularly for the UK and EU.  相似文献   

16.
The objective of this work was to obtain cement composites with low percolation thresholds, which would reduce the cost of graphite and maintain good mechanical properties. For this purpose, exfoliated graphite was used as a conductive additive, which was obtained by exfoliating the expanded graphite via ultrasonic irradiation in a water bath with surfactant. To obtain evenly distributed graphite particles, the exfoliated graphite was incorporated with the remaining surfactant into the matrix. This study is limited to investigating the influence of exfoliated graphite on the electrical and mechanical properties of cement mortars. The electrical conductivity of the composites was investigated to determine the percolation threshold. The flexural and compressive strength was tested to assess the mechanical properties. In terms of the practical applications of these composites, the piezoresistive, temperature–resistivity, and thermoelectric properties were studied. The results showed that the incorporation of exfoliated graphite with surfactant is an effective way to obtain a composite with a percolation threshold as low as 0.96% (total volume of the composite). In addition, the mechanical properties of the composites are satisfactory for practical application. These composites also have good properties in terms of practical applications. As a result, the exfoliated graphite used can significantly facilitate the practical use of smart composites.  相似文献   

17.
The most active research area is nanotechnology in cementitious composites, which has a wide range of applications and has achieved popularity over the last three decades. Nanoparticles (NPs) have emerged as possible materials to be used in the field of civil engineering. Previous research has concentrated on evaluating the effect of different NPs in cementitious materials to alter material characteristics. In order to provide a broad understanding of how nanomaterials (NMs) can be used, this paper critically evaluates previous research on the influence of rheology, mechanical properties, durability, 3D printing, and microstructural performance on cementitious materials. The flow properties of fresh cementitious composites can be measured using rheology and slump. Mechanical properties such as compressive, flexural, and split tensile strength reveal hardened properties. The necessary tests for determining a NM’s durability in concrete are shrinkage, pore structure and porosity, and permeability. The advent of modern 3D printing technologies is suitable for structural printing, such as contour crafting and binder jetting. Three-dimensional (3D) printing has opened up new avenues for the building and construction industry to become more digital. Regardless of the material science, a range of problems must be tackled, including developing smart cementitious composites suitable for 3D structural printing. According to the scanning electron microscopy results, the addition of NMs to cementitious materials results in a denser and improved microstructure with more hydration products. This paper provides valuable information and details about the rheology, mechanical properties, durability, 3D printing, and microstructural performance of cementitious materials with NMs and encourages further research.  相似文献   

18.
This paper presents the properties of the wood-resin composites. For improving their antibacterial character, silver nanoparticles were incorporated into their structures. The properties of the obtained materials were analyzed in vitro for their anti-biofilm potency in contact with aerobic Gram-positive Staphylococcus aureus and Staphylococcus epidermidis; and aerobic Gram-negative Escherichia coli and Pseudomonas aeruginosa. These pathogens are responsible for various infections, including those associated with healthcare. The effect of silver nanoparticles incorporation on mechanical and thermomechanical properties as well as gloss were investigated for the samples of composites before and after accelerating aging tests. The results show that bacteria can colonize in various wrinkles and cracks on the composites with wood flour but also the surface of the cross-linked unsaturated polyester resin. The addition of nanosilver causes the death of bacteria. It also positively influences mechanical and thermomechanical properties as well as gloss of the resin.  相似文献   

19.
The aim of the research was to obtain intelligent and eco-friendly packaging materials by incorporating innovative additives of plant origin. For this purpose, natural substances, including green tea extract (polyphenon 60) and caffeic acid, were added to two types of biodegradable thermoplastics (Ingeo™ Biopolymer PLA 4043D and Bioplast GS 2189). The main techniques used to assess the impact of phytocompounds on materials’ thermal properties were differential scanning calorimetry (DSC) and thermogravimetry (TGA), which confirmed the improved resistance to thermo-oxidation. Moreover, in order to assess the activity of applied antioxidants, the samples were aged using a UV aging chamber and a weathering device, then retested in terms of dynamic mechanical properties (DMA), colour changing, Vicat softening temperature, and chemical structure, as studied using FT-IR spectra analysis. The results revealed that different types of aging did not cause significant differences in thermo-mechanical properties and chemical structure of the samples with natural antioxidants but induced colour changing. The obtained results indicate that polylactide (PLA) and Bioplast GS 2189, the plasticizer free thermoplastic biomaterial containing polylactide and starch (referred to as sPLA in the present article), both with added caffeic acid and green tea extract, can be applied as smart and eco-friendly packaging materials. The composites reveal better thermo-oxidative stability with reference to pure materials and are able to change colour as a result of the oxidation process, especially after UV exposure, providing information about the degree of material degradation.  相似文献   

20.
Composite materials are a combination of two or more types of materials used to enhance the mechanical and structural properties of engineering products. When fibers are mixed in the polymeric matrix, the composite material is known as fiber-reinforced polymer (FRP). FRP materials are widely used in structural applications related to defense, automotive, aerospace, and sports-based industries. These materials are used in producing lightweight components with high tensile strength and rigidity. The fiber component in fiber-reinforced polymers provides the desired strength-to-weight ratio; however, the polymer portion costs less, and the process of making the matrix is quite straightforward. There is a high demand in industrial sectors, such as defense and military, aerospace, automotive, biomedical and sports, to manufacture these fiber-reinforced polymers using 3D printing and additive manufacturing technologies. FRP composites are used in diversified applications such as military vehicles, shelters, war fighting safety equipment, fighter aircrafts, naval ships, and submarine structures. Techniques to fabricate composite materials, degrade the weight-to-strength ratio and the tensile strength of the components, and they can play a critical role towards the service life of the components. Fused deposition modeling (FDM) is a technique for 3D printing that allows layered fabrication of parts using thermoplastic composites. Complex shape and geometry with enhanced mechanical properties can be obtained using this technique. This paper highlights the limitations in the development of FRPs and challenges associated with their mechanical properties. The future prospects of carbon fiber (CF) and polymeric matrixes are also mentioned in this study. The study also highlights different areas requiring further investigation in FDM-assisted 3D printing. The available literature on FRP composites is focused only on describing the properties of the product and the potential applications for it. It has been observed that scientific knowledge has gaps when it comes to predicting the performance of FRP composite parts fabricated under 3D printing (FDM) techniques. The mechanical properties of 3D-printed FRPs were studied so that a correlation between the 3D printing method could be established. This review paper will be helpful for researchers, scientists, manufacturers, etc., working in the area of FDM-assisted 3D printing of FRPs.  相似文献   

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