High-Temperature Effect on the Tensile Mechanical Properties of Unidirectional Carbon Fiber-Reinforced Polymer Plates

Carbon fiber-reinforced polymer (CFRP) has the advantages of a high strength-weight ratio and excellent fatigue resistance and has been widely used in aerospace, automotive, civil infrastructure, and other fields. The properties of CFRP materials under high temperatures are a key design issue. This paper presents the quasi-static tensile mechanical properties of unidirectional CFRP plates at temperatures ranging from 20 to 600 °C experimentally. The laser displacement transducer was adopted to capture the in situ displacement of the tested specimen. The results showed that the tensile strength of the CFRP specimen was affected by the high-temperature effect significantly, which dropped 68% and 16% for the 200 and 600 °C, respectively, compared with that of the room temperature. The degradation measured by the laser transducer system was more intensive compared with previous studies. The elastic modulus decreased to about 29% of the room temperature value at 200 °C. With the evaporation of the resin, the failure modes of the CFRP experienced brittle fracture to pullout of the fiber tow. The study provides accurate tensile performance of the CFRP plate under high-temperature exposure, which is helpful for the engineering application.     

Effects of High Temperatures on the Performance of Carbon Fiber Reinforced Polymer (CFRP) Composite Cables Protected with Fire-Retardant Materials

In this study, the safe critical temperature that can be tolerated by CFRP tendons under normal working conditions was derived through tensile tests at room and high temperatures. Next, the times required to reach a safe critical temperature for CFRP cables protected with different types of fire-retardant materials of various thicknesses were determined through fire resistance tests, Finally, fitting the surface of the finite element simulation results allowed the establishment of the temperature rise calculation model of CFRP tendons under the protection of fire-retardant materials. The results showed that 300 °C can be regarded as the safe critical temperature. Both high-silica needled felt and ceramic fiber felt exhibited high fireproof performance. With an increase in the thickness of the fire-retardant material, the time for the CFRP tendon to reach the inflection point of the heating rate increased, and the safe fire resistance time increased exponentially. According to the HC temperature rise curve, the fire resistance time of CFRP tendons protected by 24 mm thick high-silica needled felt was 45 min, and that for CFRP tendons protected by 24 mm thick ceramic fiber felt was 39.5 min. Under the action of fire corresponding to the hydrocarbon temperature rise model, the safe fire resistance time of CFRP tendons protected by 45 mm high-silica needled felt or 50 mm ceramic fiber felt was more than 2 h, sufficient to meet the specification. The proposed model of fire resistance performance enables the determination of the thickness of the fire resistance material required to obtain different degrees of fire resistance for CFRP cables for structural use.     

Temperature Influence on Additive Manufactured Carbon Fiber Reinforced Polymer Composites

The popular applications of Additive Manufactured (AM) polymer materials in engineering, medical, and industrial fields have been widely recognized due to their high-speed production despite their complex design shapes. Fused Deposition Modeling (FDM) is the technique that has become the most renowned AM process due to its simplicity and because it is the cheapest method. The main objective of this research is to perform a numerical simulation of the thermo-mechanical behaviour of AM polymer with continuous carbon fibre reinforcement exposed to elevated temperatures. The influence of global thermal loads on AM material was focused on mechanical property changes at the microscale (level of fiber–matrix interaction). The mechanical response (strain/stress distribution) of the AM material on the temperature loading was modelled using the finite element method (FEM). The coupled thermal-displacement analysis was used during the numerical calculations. The strain in the sample due to its exposition on elevated temperature was measured using fibre Bragg grating (FBG) sensors. The numerical results were compared with the experimental results achieved for the sample exposure to the same thermal conditions showing good agreement. A strong influence of the temperature on the matrix structure and the condition of bondings between fibres and matrix was observed.     

Bond Relationship of Carbon Fiber-Reinforced Polymer (CFRP) Strengthened Steel Plates Exposed to Service Temperature

Emerging as a new technology, carbon fiber-reinforced polymer (CFRP) has been introduced to rehabilitate and strengthen steel structures using an adhesive agent. However, the outdoor service temperature is potentially degrading to the mechanical strength of the adhesive, as well as affecting the bonding of the strengthened steel structure. Therefore, this paper aims to investigate the bond relationship of CFRP-strengthened steel plates exposed to service temperatures. Two types of experiments were conducted to determine the tensile and flexural performance of CFRP-strengthened steel plates. The experiments were designed using a Box–Behnken design (BBD) and response surface methodology (RSM) by considering three parameters: service temperature (25 °C, 45 °C and 70 °C), number of CFRP layers (one, three and five layers) and bond length (40, 80 and 120 mm). The findings show the dominant failure mode transformed from adhesion failure between steel and adhesive interfaces to adhesion failure between CFRP and adhesive interfaces as the service temperature increased. The tensile strength improved by 25.62% when the service temperature increased. Field emission scanning electron microscope (FESEM) analysis proved that the strength enhancement is due to the densification and reduction of the adhesive particle microstructure gaps through the softening effect at service temperature. However, service temperature is found to have less impact on flexural strength. Incorporating the experimental results in RSM, two quadratic equations were developed to estimate the tensile and flexural strength of CFRP-strengthened steel plates. The high coefficient of determination, R2, yields at 0.9936 and 0.9846 indicate the high reliability of the models. Hence, it can be used as an estimation tool in the design stage.     

Modeling Evolution of Cutting Force in Ultrasonically Assisted Drilling of Carbon Fiber Reinforced Plastics

In this study, the effects of process parameters (feed rate, spindle speed, and ultrasonic power level) on the cutting force and delamination in the ultrasonic vibration-assisted drilling of carbon fiber-reinforced plastics (CFRPs) have been investigated. A series of drilling tests under various conditions defined by the design of experiment technique were conducted. The evolution of the cutting force during drilling cycles was measured and analyzed. Experimental analysis results based on the Taguchi method and analysis of variance show that the spindle speed is an influential factor affecting the cutting force with a contribution of 75.36%, and the feed rate significantly affects the delamination damage with a contribution of 46.57%. In addition, the cutting force was found to increase with drilling cycles at different rates, which depends on the process parameters used in drilling. The evolution behavior of cutting force was well fitted based on the process parameters by proposed regression models. Experimental validation indicates that the predicted forces show reasonable agreement with measured values under different conditions and reveal good prediction performances, with a root mean square error of 5.6 and a mean absolute percentage error of 5.8%. In drilling tests with variable cutting conditions, the evolution of the cutting forces predicted based on the selected parameters was successfully verified when compared with the measured results, with RMSE and MAPE values of 7.55 and 5.61%, respectively. As a conclusion, this predictive model provides an effective basis for selecting appropriate drilling parameters to suppress the cutting force on CFRP composites.     

Effect of Different Lubricating Environment on the Tribological Performance of CNT Filled Glass Reinforced Polymer Composite

In recent years, the engineering implications of carbon nanotubes (CNTs) have progressed enormously due to their versatile characteristics. In particular, the role of CNTs in improving the tribological performances of various engineering materials is well documented in the literature. In this work, an investigation has been conducted to study the tribological behaviour of CNTs filled with glass-reinforced polymer (GFRP) composites in dry sliding, oil-lubricated, and gaseous (argon) environments in comparison to unfilled GFRP composites. The tribological study has been conducted on hardened steel surfaces at different loading conditions. Further, the worn surfaces have been examined for a particular rate of wear. Field-emission scanning electron (FESEM) microscopy was used to observe wear behaviours. The results of this study explicitly demonstrate that adding CNTs to GFRP composites increases wear resistance while lowering friction coefficient in all sliding environments. This has also been due to the beneficial strengthening and self-lubrication properties caused by CNTs on GFRP composites, according to FESEM research.     

Effect of Temperature on the Complex Modulus of Mg-Based Unidirectionally Aligned Carbon Fiber Composites

Composite materials based on magnesium–lithium (MgLi) and magnesium–yttrium (MgY) matrices reinforced with unidirectional carbon fibers were prepared using the gas pressure infiltration method. Two types of carbon fibers were used, high-strength PAN-based T300 fibers and high-modulus pitch-based Granoc fibers. The PAN-based carbon fibers have an internal turbostratic structure composed of crystallites. The pitch-based carbon fibers have a longitudinally aligned graphite crystal structure. The internal carbon fiber structure is crucial in the context of the interfacial reaction with the alloying element. There are various mechanisms of bonding to carbon fibers in the case of magnesium–lithium and magnesium–yttrium alloys. This paper presents the use of the DMA method for the characterization of the role of alloying elements in the quality of interfacial bonding and the influence on the complex modulus at increasingly elevated temperatures (50–250 °C). The complex modulus values of the composites with T300 fibers were in the range of 118–136 GPa. The complex modulus values of the composites with Granoc fibers were in the range of 198–236 GPa. The damping capacity of magnesium-based unidirectionally aligned carbon fiber composites is related to the quality of the interfacial bonding.     

Effect of Nanofiller on the Mechanical Properties of Carbon Fiber/Epoxy Composites under Different Aging Conditions

In this study, carbon fiber-reinforced epoxy composites (CFRPs) containing multi-walled carbon nanotube (MWCNT) and halloysite nanoclay were fabricated. The effects of these nanofillers (MWCNT and nanoclay) on the tensile and flexural properties of the CFRPs under different aging conditions were studied. These aging conditions included water soaking, acid soaking, alkali soaking, and thermal shock cycling. The experimental results showed that, after accelerated aging, the mechanical performance of the CFRPs decreased. The performance degradation in the soaking environment depends on the immersion temperature and immersion medium. High-temperature accelerated the aging behavior of the CFRPs, resulting in low strength and modulus. The CFRPs were more vulnerable to acid soaking and alkali soaking than water soaking. The MWCNT and halloysite nanoclay are beneficial to improve the immersion aging resistance of the CFRPs, and the additions of nanofillers delayed the performance degradation under immersion aging conditions. However, nanofillers hardly improve the aging resistance of the CFRPs under thermal shock cycling condition. The fracture morphologies were observed by scanning electron microscopy (SEM) to reflect the failure modes of the CFRPs under various aging conditions. Differential scanning calorimeter (DSC) and fourier transform infrared (FTIR) spectroscopy tests were used to estimate the changes in the chemical structures and properties of epoxy resin and its composites under different conditions.     

Natural Cellulosic Fiber Reinforced Concrete: Influence of Fiber Type and Loading Percentage on Mechanical and Water Absorption Performance

The paper reports experimental research regarding the mechanical characteristics of concrete reinforced with natural cellulosic fibers like jute, sisal, sugarcane, and coconut. Each type of natural fiber, with an average of 30 mm length, was mixed with a concrete matrix in varying proportions of 0.5% to 3% mass. The tensile and compressive strength of the developed concrete samples with cellulosic fiber reinforcement gradually increased with the increasing proportion of natural cellulosic fibers up to 2%. A further increase in fiber loading fraction results in deterioration of the mechanical properties. By using jute and sisal fiber reinforcement, about 11.6% to 20.2% improvement in tensile and compressive strength, respectively, was observed compared to plain concrete, just by adding 2% of fibers in the concrete mix. Bending strength increased for the natural fiber-based concrete with up to 1.5% fiber loading. However, a decrease in bending strength was observed beyond 1.5% loading due to cracks at fiber−concrete interface. The impact performance showed gradual improvement with natural fiber loading of up to 2%. The water absorption capacity of natural cellulosic fiber reinforced concrete decreased substantially; however, it increased with the loading percent of fibers. The natural fiber reinforced concrete can be commercially used for interior or exterior pavements and flooring slabs as a sustainable construction material for the future.     

Effect of Fiber Content and Alignment on the Mechanical Properties of 3D Printing Cementitious Composites

This paper studies aligned glass fiber-reinforced composites for printing. To determine the influence of fiber content and alignment on the mechanical properties of this novel material, a large number of standard test specimens were prepared, which included samples fabricated by mold-casting, randomly dispersed fiber reinforced mixtures and aligned fiber cement composites containing 10 types of fiber volume ratios manufactured by nozzle sizes ranging of 24 and 10 mm (fiber length = 12 mm). Mechanical properties and failure modes of the specimens under compression and flexural tests were studied experimentally. The anisotropic behaviors of printed samples were analyzed by different loading directions. As a result, the compressive and flexural strength of printed samples showed obvious anisotropy. With the increase of fiber volume ratio, flexural strength of the fiber reinforced composite was elevated tremendously but its compression strength reduced slightly. Moreover, fiber alignment also had a significant influence on the mechanical properties of the fiber reinforced composite. The composite cement-based material with 1 vol.-% aligned fiber exhibited an excellent flexural strength of 9.38 MPa, which increased by 483% in comparison to that of the plain cement paste.     

Influence of Laser Treatment on End Notched Flexure Bonded Joints in Carbon Fiber Reinforced Polymer: Experimental and Numerical Results

Surface pretreatment for bonding is one of the most important steps for the manufacturing of a reliable bonded joint. In this paper, the effectiveness of an innovative pretreatment by CO₂ pulsed laser for bonding Carbon Fiber Reinforced Polymer (CFRP) was investigated. End Notched Flexure (ENF) specimens were made with different densities of laser treatment, and the respective fracture toughness was obtained through the Compliance-Based Beam Method (CBBM). Furthermore, a cohesive model for simulating debonding processes was illustrated, and the cohesive parameters were obtained by an inverse method. The achieved results represent a fundamental step for the development of a numerical model useful for the determination of laser texturing as a function of the applied local stress into the bonded joint.     

Comparison of the Influence of Two Types of Plasma Treatment of Short Carbon Fibers on Mechanical Properties of Epoxy Composites Filled with These Treated Fibers

The interfacial interface between fibers and matrix plays a key role for epoxy matrix composites and short recycled randomly arranged fibers. This study used short recycled carbon fiber (RCF) as a filler. Plasma treatment was used for carbon fiber surface treatment. This treatment was performed using radio (RF) and microwave (MW) frequencies at the same pressure and atmosphere. Appropriate chemical modification of the fiber surfaces helps to improve the wettability of the carbon fibers and, at the same time, allows the necessary covalent bonds to form between fibers and the epoxy matrix. The effect of the plasma treatment was analyzed and confirmed by X-ray photoelectron spectroscopy, Raman microscopy, scanning electron microscopy, transmission electron microscopy and wettability measurements. Composite samples filled with recycled carbon fibers with low concentrations (1 wt%, 2.5 wt% and 5 wt%) and high concentrations (20 wt% and 30 wt%) were made from selected treated fibers. The mechanical properties (impact toughness, 3PB) were analyzed on these samples. It was found that the modulus of elasticity and bending stress increase with the increasing content of recycled carbon fibers. A more significant change in impact strength occurred in samples with low concentration.     

Thermal Ablation Damage Analysis of CFRP Suffering from Lightning Based on Principles of Tomography

Coupled electrical–thermal finite element analysis (FEA) models are widely adopted to analyze the thermal ablation damage of carbon fiber reinforced polymer (CFRP) caused by lightning, but it is still difficult to analyze the ablation due to its complex space geometry. According to the principle of computerized tomography (CT), tomographic images of FEA models’ temperature fields with different thicknesses were obtained to calculate the mass loss and compare the damage morphology. The four areas including Area 0, Area I, Area II, and Area III; were separated from the temperature fields in terms of different vaporization and pyrolysis temperature ranges of carbon fiber (CF) and resin matrix. Ablation mass losses were calculated by pixel statistics and tomographic intervals, which were consistent with the experimental results. The maximum ablation area of unprotected CFRP was found on the tomography images of 50 μm rather than the surface by comparing tomographic images with different thickness due to the influence of the thermal radiation, but this effect was not found in CFRP protected by copper mesh. Some other phenomena, including continuous evolutions of ablation areas and the influence of the intersection angle on the direction of the ablation extension, were also discovered.     

Fatigue Damage Evaluation of Short Carbon Fiber Reinforced Plastics Based on Thermoelastic Temperature Change and Second Harmonic Components of Thermal Signal

Short fiber reinforced plastics (SFRPs) have excellent moldability and productivity compared to continuous fiber composites. In this study, thermoelastic stress analysis (TSA) was applied to detect delamination defects in short carbon fiber reinforced plastics (SCFRPs). The thermoelastic temperature change ΔT_E, phase of thermal signal θ_E, and second harmonic temperature component ΔT_D were measured. In the fatigue test of SCFRP, it was confirmed that changes in ΔT_E, θ_E, and ΔT_D appeared in the damaged regions. A staircase-like stress level test for a SCFRP specimen was conducted to investigate the generation mechanism of the ΔT_D. The distortion of the temperature change appeared at the maximum tension stress of the sinusoidal load—and when the stress level decreased, the temperature change returned to the original sinusoidal waveform. ΔT_D changed according to the change in the maximum stress during the staircase-like stress level test, and a large value of ΔT_D was observed in the final ruptured region. A distortion of the temperature change and ΔT_D was considered to be caused by the change in stress sharing condition between the fiber and resin due to delamination damage. Therefore, ΔT_D can be applied to the detection of delamination defects and the evaluation of damage propagation.     

Effect of Hemp Fiber Surface Treatment on the Moisture/Water Resistance and Reaction to Fire of Reinforced PLA Composites

The effects of surface pretreatment (water and alkali) and modification with silane on moisture sorption, water resistance, and reaction to fire of hemp fiber reinforced polylactic acid (PLA) composites at two fiber loading contents (30 and 50 wt.%) are investigated in this work. Moisture adsorption was evaluated at 30, 50, 75 and 95% relative humidity, and water resistance was determined after a 28-day immersion period. The cone calorimetry technique was used to investigate response to fire. The fiber surface treatment resulted in the removal of cell wall components, which increased fiber individualization and homogeneity as shown in scanning microscopic pictures of the composite cross-section. Although the improved fiber/matrix bonding increased the composite’s water resistance, the different fiber treatments generated equal moisture adsorption results for the 30 wt.% reinforced composites. Overall, increasing the fiber amount from 30 to 50 wt.% increased the composite sensitivity to moisture/water, mainly due to the availability of more hydroxyl groups and to the development of a higher pore volume, but fire protection improved due to a reduction in the rate of thermal degradation induced by the reduced PLA content. The new Oswin’s model predicted the composite adsorption isotherm well. The 30 wt.% alkali and silane treated hemp fiber composite had the lowest overall adsorption (9%) while the 50 wt.% variant produced the highest ignition temperature (181 ± 18 °C).     

Influence of Fiber Addition on the Properties of High-Performance Concrete

High performance fiber-reinforced concrete (HPFRC) has been frequently investigated in recent years. Plenty of studies have focused on different materials and types of fibers in combination with the concrete matrix. Experimental tests show that fiber dosage improves the energy absorption capacity of concrete and enhances the robustness of concrete elements. Fiber reinforced concrete has also been illustrated to be a material for developing infrastructure sustainability in RC elements like façade plates, columns, beams, or walls. Due to increasing costs of the produced fiber reinforced concrete and to ensure the serviceability limit state of construction elements, there is a demand to analyze the necessary fiber dosage in the concrete composition. It is expected that the surface and length of used fiber in combination with their dosage influence the structure of fresh and hardened concrete. This work presents an investigation of the mechanical parameters of HPFRC with different polymer fiber dosage. Tests were carried out on a mixture with polypropylene and polyvinyl alcohol fiber with dosages of 15, 25, and 35 kg/m³ as well as with control concrete without fiber. Differences were observed in the compressive strength and in the modulus of elasticity as well as in the flexural and splitting tensile strength. The flexural tensile strength test was conducted on two different element shapes: square panel and beam samples. These mechanical properties could lead to recommendations for designers of façade elements made of HPFRC.     

Infill Density Influence on Mechanical and Thermal Properties of Short Carbon Fiber-Reinforced Polyamide Composites Manufactured by FFF Process

In three-dimensional (3D) printing, one of the main parameters influencing the properties of 3D-printed materials is the infill density (ID). This paper presents the influence of ID on the microstructure, mechanical, and thermal properties of carbon fiber-reinforced composites, commercially available, manufactured by the Fused Filament Fabrication (FFF) process. The samples were manufactured using FFF by varying the infill density (25%, 50%, 75%, and 100%) and were subjected to tensile tests, three-point bending, and thermal analyses by Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). It was shown that the samples with 100% ID had the highest values of both tensile, 90.8 MPa, and flexural strengths, 114 MPa, while those with 25% ID had the lowest values of 56.4 MPa and 62.2 MPa, respectively. For samples with infill densities of 25% and 50%, the differences between the maximum tensile and flexural strengths were small; therefore, if the operating conditions of the components allow, a 25% infill density could be used instead of 50%. After DSC analysis, it was found that the variation in the ID percentage determined the change in the glass transition temperature from 49.6 °C, for the samples with 25% ID, to 32.9 °C, for those with 100% ID. TGA results showed that the samples with IDs of 75% and 100% recorded lower temperatures of onset degradation (approximately 344.75 °C) than those with infill densities of 25% and 50% (348.5 °C, and 349.6 °C, respectively).     

Study on Correlation of Mechanical and Thermal Properties of Coal-Based Carbon Foam with the Weight Loss Rate after Oxidation

With the increasing demand for high temperature-resistant heat insulation materials for hypersonic vehicles, carbon foam has been studied extensively, and its mechanical and thermal properties have been fully researched, but the oxidation behavior of carbon foams during service and the change in their properties after oxidation are rarely studied. This paper studied the relationship between both mechanical and thermal properties and oxidation degree of two kinds of foams, coal-based carbon foam and antioxidant coal-based carbon foam with chemical vapor deposition of SiC particles. The variation trend for the two kinds of foam was the same. When the oxidation degree was less than 15%, the compression modulus and strength weakened with the increase in weight loss rate, but the thermal conductivity decreased with the increase in weight loss rate, which was a favorable influence for the thermal protection system. The mechanical and thermal properties had a linear relationship with the weight loss rate, but the slope was different between 0% to 10% and 10% to 15%. The microscopic mechanism of these changes was also analyzed.     

Effects of Basalt and Carbon Fillers on Fire Hazard,Thermal, and Mechanical Properties of EPDM Rubber Composites

Due to growing restrictions on the use of halogenated flame retardant compounds, there is great research interest in the development of fillers that do not emit toxic compounds during thermal decomposition. Polymeric composite materials with reduced flammability are increasingly in demand. Here, we demonstrate that unmodified graphene and carbon nanotubes as well as basalt fibers or flakes can act as effective flame retardants in polymer composites. We also investigate the effects of mixtures of these carbon and mineral fillers on the thermal, mechanical, and rheological properties of EPDM rubber composites. The thermal properties of the EPDM vulcanizates were analyzed using the thermogravimetric method. Flammability was determined by pyrolysis combustion flow calorimetry (PCFC) and cone calorimetry.     

Effect of Superabsorbent Polymer on the Mechanical Performance and Microstructure of Concrete

The internally cured material known as superabsorbent polymer (SAP) is an important innovation in concrete engineering technology. This paper investigates the effect of adding a polymer with superabsorbent capabilities on the physical and mechanical performance of concrete. The microstructure of the new hybrid concrete was also studied, and the influence of the polymer particle size and volume on the mechanical durability was evaluated. The mechanical properties of the new hybrid concrete, such as compressive strength, flexural strength, elastic modulus, and splitting tensile strength, were measured through laboratory experiments. The microstructure characteristics of the concrete were also investigated by scanning electron microscopy (SEM). The results show that shrinkage was reduced, while the volume stability of the concrete improved. Moreover, we found that cracking was reduced, while issues such as chloride penetration and freeze-thaw resistance were also improved. In addition, the SAP could effectively improve the microstructure of the concrete and refine the pore structure, as seen in the microscopic test. This paper helps to promote the development of internally cured material and improve technology for the prevention of concrete construction cracks.