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1.
Image analysis techniques are gaining popularity in the studies of civil engineering materials. However, the current established image analysis methods often require advanced machinery and strict image acquisition procedures which may be challenging in actual construction practices. In this study, we develop a simplified image analysis technique that uses images with only a digital camera and does not have a strict image acquisition regime. Mortar with 10%, 20%, 30%, and 40% pozzolanic material as cement replacement are prepared for the study. The properties of mortar are evaluated with flow table test, compressive strength test, water absorption test, and surface porosity based on the proposed image analysis technique. The experimental results show that mortar specimens with 20% processed spent bleaching earth (PSBE) achieve the highest 28-day compressive strength and lowest water absorption. The quantified image analysis results show accurate representation of mortar quality with 20% PSBE mortar having the lowest porosity. The regression analysis found strong correlations between all experimental data and the compressive strength. Hence, the developed technique is verified to be feasible as supplementary mortar properties for the study of mortar with pozzolanic material.  相似文献   

2.
In this study, the compressive strength and water contact angle of mortar specimens prepared by mixing two types of water repellent with ordinary Portland cement (OPC) and rapid-hardening cement mortar were measured before and after surface abrasion. In addition, the hydration products and chemical bonding of cement mortar with the repellents were examined using X-ray diffraction (XRD), thermogravimetry-differential thermal analysis (TG-DTA), and Fourier-transform infrared spectroscopy (FT-IR) to evaluate the performance of these cement mortar mixtures as repair materials. We found that the fast-hardening cement mortar mixture containing the oligomer water repellent showed the best performance with a high compressive strength and large water contact angle. With the oligomer water repellent, the rapid-hardening cement mortar mixture showed contact angles of 131° and 126° even after a 2 mm abrasion, thereby confirming that the water repellent secured hydrophobicity through strong bonding with the entire cement mortar as well as its surface. The compressive strengths were found to be 34.5 MPa at 3 h and 54.8 MPa at 28 days, confirming that hydration occurred well despite the addition of water repellent.  相似文献   

3.
In the concrete industry, various R&D efforts have been devoted to self-healing technology, which can maintain the long-term performance of concrete structures, which is important in terms of sustainable development. Cracks in cement composites occur and propagate because of various internal and external factors, reducing the composite’s stability. Interest in “self-healing” materials that can repair cracks has led researchers to embed self-healing capsules in cement composites. Overcoming the limitations of polymer capsules produced by chemical manufacturing methods, three-dimensional (3D) printing can produce capsules quickly and accurately and offers advantages such as high material strength, low cost, and the ability to fabricate capsules with complex geometries. We performed structural analysis simulations, experimentally evaluated the mechanical properties and solubility of poly(lactic acid) (PLA) capsules, and examined the effect of the capsule wall thickness and printing direction on cement composites embedded with these capsules. Thicker capsules withstood larger bursting loads, and the capsule rupture characteristics varied with the printing angle. Thus, the capsule design parameters must be optimized for different environments. Although the embedded capsules slightly reduced the compressive strength of the cement composites, the benefit of the encapsulated self-healing agent is expected to overcome this disadvantage.  相似文献   

4.
Hydration characteristics and mechanical properties of calcium sulphoaluminate (CSA) cement with different contents of CaCO3 and gypsum under NaCl solutions were studied, using the testing methods of isothermal calorimetry, X-ray diffraction (XRD), mercury intrusion porosimetry (MIP), linear shrinkage, and compressive strength. Results show that CaCO3 can promote hydration and reduce the hydration heat of CSA cement. The reaction between gypsum and C4A3S- releases a large quantity of heat in the initial hydration period; however, over 3 days of accumulation, the level of hydration heat is reduced. Under NaCl solutions, the aluminate phase has difficulty reacting with CaCO3 to form carbonate phase but combines with chloride ions to form Friedel’s salt. On the contrary, gypsum reduces aluminate phase, and the content of Friedel’s salt is also reduced. Furthermore, CaCO3 and gypsum both increase the total porosity of the CSA cement paste under NaCl solutions during the early curing phase, and over the long-term, pore structure is also optimized. CaCO3 and gypsum reduce the linear shrinkage of CSA cement paste under NaCl solutions. Overall, the compressive strength of CSA cement is reduced with the addition of CaCO3, and the trend will be sharper with the increase in CaCO3. However, when it comes to gypsum, the compressive strength is almost the same during early curing, but in the long-term, compressive strength improves. Essentially, the compressive strength of CSA cement mortar with CaCO3 and gypsum will improve under NaCl solutions.  相似文献   

5.
Comparing with the traditional construction process, 3D printing technology used in construction offers many advantages due to the elimination of formwork. Currently, 3D printing technology used in the construction field is widely studied, however, limited studies are available on the dynamic properties of 3D printed materials. In this study, the effects of sand to binder ratios and printing directions on the fractal characteristics, dynamic compressive strength, and energy dissipation density of 3D printed cement mortar (3DPCM) are explored. The experiment results indicate that the printing direction has a more significant influence on the fractal dimension compared with the sand to binder ratio (S/B). The increasing S/B first causes an increase and then results in a decline in the dynamic compressive strength and energy dissipation of different printing directions. The anisotropic coefficient of 3DPCM first is decreased by 20.67%, then is increased by 10.56% as the S/B increases from 0.8 to 1.4, showing that the anisotropy is first mitigated, then increased. For the same case of S/B, the dynamic compressive strength and energy dissipation are strongly dependent on the printing direction, which are the largest printing in the Y-direction and the smallest printing in the X-direction. Moreover, the fractal dimension has certain relationships with the dynamic compressive strength and energy dissipation density. When the fractal dimension changes from 2.0 to 2.4, it shows a quadratic relationship with the dynamic compressive strength and a logarithmic relationship with the energy dissipation density in different printing directions. Finally, the printing mortar with an S/B = 1.1 is proved to have the best dynamic properties, and is selected for the 3D printing of the designed field barrack model.  相似文献   

6.
Polyvinyl alcohol (PVA) and calcium sulphoaluminate (CSA) cement were used to prepare repair mortar for the restoration of the walls of a building built with bricks. The preparation, hydration, and properties of the PVA-modified CSA cement repair mortar were studied. Besides this, the mechanism by which PVA improves the bonding strength is also discussed. The results demonstrate that PVA prolongs the setting time of CSA cement, which is ascribed to PVA inhibiting the dissolution of C4A3$ (4CaO·3Al2O3·SO3) and the precipitation of AFt (3CaO·Al2O3·3CaSO4·26H2O) within the hydration age of 0~60 min. PVA lowers the mechanical strength of CSA cement repair mortar at the hydration age of 6 h. After 6 h, the mechanical strength is improved. PVA could also improve the bonding strength between CSA repair mortar and bricks. This is mainly ascribed to the Al ions in both the hydration products of CSA cement and the clay bricks reacting with the hydroxyl group of PVA and forming the chemical bond C-O-Al. Therefore, a tighter combination between CSA cement repair mortar and the clay bricks forms, thereby improving the bonding strength.  相似文献   

7.
For brittle and quasi-brittle materials such as rock and concrete, the impact-resistance characteristics of the corresponding engineering structures are key to successful application under complex service environments. Modeling of concrete-like slab fractures under impact loading is helpful to analyze the failure mechanism of an engineering structure. In this paper, simulation models of impact tests of a cement mortar slab were developed, and a continuum–discontinuum element method (CDEM) was used for dynamic analysis. Concretely, the cracking simulations of a mortar slab when considering the hammer shape and impact velocity were conducted, and the impact process and failure results of the slab structure were analyzed. The results showed that the top fracture area of the mortar slab was significantly smaller than that of slab bottom under impact loadings of the drop hammer. The impact velocity was an important factor that affected the mortar slab’s cracking. With the increase in the initial impact velocity, the effective fracture area of the slab structure increased significantly; the impact force and rupture degree of the mortar slab also showed a linear growth trend. The shapes of the impact hammerhead also had a significant effect on the crack model of the mortar slab. The effective fracture zones of slab structures were close under circular and square hammers, while the effective fracture zone was significantly larger under a rectangular hammer impact. The peak value (45.5 KN) of the impact force under a circular hammer was significantly smaller than the peak value (48.7 KN) of the impact force under the rectangular hammer. When considering the influence of the stress concentration of the impact hammerhead, the maximum impact stress of the rectangular hammer was 147.3 MPa, which was significantly greater than that of the circular hammer impact (maximum stress of 87.5 MPa). This may have meant that the slab structures were prone to a directional rupture that mainly propagated along the long axis of the rectangular hammerhead. This impact mode is therefore more suitable for rehabilitation and reconstruction projects of slab structures.  相似文献   

8.
Ecological concrete could reduce the environment impacts of the tremendous construction of infrastructures due to its favorability to plant growth. Nonetheless, the alkalinity of the ecological concrete is usually too high when using ordinary Portland cement (OPC). To solve this problem, the magnesium ammonium phosphate cement (MPC) was used to prepare a novel porous ecological concrete instead of OPC. The pH value and compressive strength of MPC were analyzed and the pore structure was evaluated. The chemical composition and morphology were investigated by an X-ray diffraction test and scanning electron microscope observation. In addition, the void ratio, compressive strength and planting-growing characteristic of MPC-based porous ecological concrete were also studied. The pH value of the MPC suspension ranged from 6.8 to 8.5, which was much lower than that of OPC. The pH value of MPC gradually increased with the increment of phosphorus/magnesium molar ratio (P/M) and the compressive strength reached a maximum value of 49.2 MPa when the P/M value was 1/4. Fly ash (FA) and ground blast furnace slag (GBFS) could improve the pore structure and compressive strength; however, the pH value was slightly increased. As the paste-to-aggregate ratio increased, the void ratio of concrete gradually decreased, while the compressive strength gradually increased. The meadow grass was planted in the MPC-based ecological concrete, and the seeds germinated in one week and showed a better growth status than those planted in the OPC-based ecological concrete.  相似文献   

9.
This work aims to investigate the effects of multi-walled carbon nanotubes (MWCNTs) on the strength and electrical properties of cement mortar. MWCNTs were added to cement mortar in four different concentrations: 0.00 wt.%, 0.01 wt.%, 0.015 wt.%, and 0.02 wt.% by the mass of cement. The consistency, density, setting time and compressive and flexural strength of mixes were tested and analyzed at 28 and 90 days curing time. Mechanical performance tests confirm an increase of 25% and 20% in the ultimate compressive and flexural strength respectively, which results from MWCNT 0.02 wt.% loading at 90 days curing time. The resistivity measurements in mortars with 0.01 and 0.015 wt.% MWCNT loading result up to 10% decrement at both 28 and 90 days curing. Activation energy calculations show fully accordance with these statements, resuming that 0.01 wt.% MWCNT appears to be the most effective loading scheme to produce certain conductivity enhancement in cement mortar.  相似文献   

10.
In this article, the effect of cement type on selected properties of plastering mortars containing a cellulose ether admixture was studied. In the research, commercial CEM I Portland cement, CEM II and CEM III, differing in the type and amount of mineral additives, and cement class, were used as binders. Tests of consistency, bulk density, water retention value (WRV), mechanical properties and calorimetric tests were performed. It was proved that the type of cement had no effect on water retention, which is regulated by the cellulose ether. All mortars modified with the admixture were characterized by WRV of about 99%. High water retention is closely related to the action of the cellulose ether admixture. As a result of the research, the possibility of using cement with additives as components of plasters was confirmed. However, attention should be paid to the consistency, mechanical properties of the tested mortars and changes in the pastes during the hydration process. Different effects of additives resulted from increasing or decreasing the consistency of mortars; the flow was in the range from 155 mm to 169 mm. Considering the compressive strength, all plasters can be classified as category III or IV, because the mortars attained the strength required by the standard, of at least 3.5 MPa. The processes of hydration of pastes were carried out with different intensity. In conclusion, the obtained results indicate the possibility of using CEM II and CEM III cements to produce plastering mortars, without changing the effect of water retention.  相似文献   

11.
There have been numerous recent studies on improving the mechanical properties and durability of cement composites by mixing them with functional polymers. However, research into applying modified biopolymer such as catechol-functionalized chitosan to cement mortar or concrete is rare to the best of our knowledge. In this study, catechol-functionalized chitosan (Cat-Chit), a well-known bioinspired polymer that imitates the basic structures and functions of living organisms and biological materials in nature, was synthesized and combined with cement mortar in various proportions. The compressive strength, tensile strength, drying shrinkage, accelerated carbonation depth, and chloride-ion penetrability of these mixes were then evaluated. In the ultraviolet–visible spectra, a maximum absorption peak appeared at 280 nm, corresponding to catechol conjugation. The sample containing 7.5% Cat-Chit polymer in water (CPW) exhibited the highest compressive strength, and its 28-day compressive strength was ~20.2% higher than that of a control sample with no added polymer. The tensile strength of the samples containing 5% or more CPW was ~2.3–11.5% higher than that of the control sample. Additionally, all the Cat-Chit polymer mixtures exhibited lower carbonation depths than compared to the control sample. The total charge passing through the samples decreased as the amount of CPW increased. Thus, incorporating this polymer effectively improved the mechanical properties, carbonation resistance, and chloride-ion penetration resistance of cement mortar.  相似文献   

12.
The growth of the construction industry has led to the greater consumption of natural resources, which has a direct or indirect negative impact on the environment. To mitigate this, recycled or waste materials are being used as a partial substitute in the manufacture of concrete. Among these waste materials is cement kiln dust (CKD), which is produced during cement production. This study investigated the potential benefits of replacing part of the cement with CKD in two construction applications, i.e., plain concrete and cement blocks. This reflects positively on cost, energy, and the environment, since putting CKD in a landfill damages agricultural soil and plant respiration. In this study, an experimental program was carried out to study how replacing various percentages of ordinary portland cement (OPC) with CKD affected the compressive strengths, the tensile strengths, and the air contents of concrete and cement blocks. Although the results showed that the compressive and tensile strengths decreased as the amount of CKD increased, the air content of the concrete increased, which showed that 5% CKD was suitable for such applications. The results were used to propose two equations that approximate the concrete and cement block compressive strengths according to the CKD replacement percentage.  相似文献   

13.
Hydraulic fracturing may be induced easily in a cement-based structure in a sulfate-rich environment, which threatens engineering safety. In order to investigate the evolution of critical water pressure, a series of hydraulic fracturing tests and splitting tensile strength tests on the cement mortar under different sulfate-exposure periods are performed. The critical water pressure of the cement mortar under sulfate attack experiences an initial increase stage and a subsequent decrease stage. A stress intensity factor is modified by two proposed damage variables which are crack length and fracture stress. Then, the relationship between the critical water pressure and the tensile strength is established. Moreover, an evolution model of the critical water pressure is proposed, which reveals that the matrix tensile strength and porosity of cement mortar strongly affect the critical water pressure evolution. Additionally, an empirical formula is suggested to describe the critical water pressure evolution of the cement mortar under sulfate attack, and its validity is verified by experimental results.  相似文献   

14.
This paper presents workability, compressive strength and microstructure for geopolymer pastes and mortars made of class C fly ash at mass ratios of water-to-fly ash from 0.30 to 0.35. Fluidity was in the range of 145–173 mm for pastes and 131–136 mm for mortars. The highest strengths of paste and mortar were 58 MPa and 85 MPa when they were cured at 70 °C for 24 h. In XRD patterns, unreacted quartz and some reacted product were observed. SEM examination indicated that reacted product has formed and covered the unreacted particles in the paste and mortar that were consistent with their high strength.  相似文献   

15.
In order to solve the problem of lack of natural river sand, crushed waste oyster shells (WOS) were used to replace river sand. By replacing 20% river sand, WOS mortar with different particle sizes of WOS were made for the experiment. Through experimental observation, the initial slump and slump flow loss rate were studied. The effects of different particle sizes and curing times on the compressive strength, flexural strength, static elastic modulus, and dry shrinkage of WOS mortar were analyzed. The relationship formulas between the compressive strength, flexural strength, particle size, and curing age were proposed. The results showed that the setting time and slump flow decreased with a decrease in the particle size of WOS. It was also found that the mortar with fine crushed WOS had high compressive strength, flexural strength, and static elastic modulus at both early and long-term curing age. A formula was proposed to describe the development of the compressive strength with the particle size of WOS and curing time, and the relations among these mechanical properties were discussed. Furthermore, drying shrinkage increased when WOS was used and could not satisfy the standard requirement of 0.075%. In contrast, the addition of fine WOS and double-dose sulfonated naphthalene-formaldehyde superplasticizer (SNF SP) reduced the shrinkage rate of the mortar by 8.35% and provided better workability and mechanical properties for mortar.  相似文献   

16.
The continuous growth of the concrete industry requires an increased quantity of cement and natural aggregates year after year, and it is responsible for a major part of the global CO2 emissions. These aspects led to rigorous research for suitable raw materials. Taking into account that these raw materials must have a sustainable character and also a low impact on environmental pollution, the replacement of the conventional components of concrete by residual waste can lead to these targets. This paper’s aim is to analyze the density, compressive strength and the thermal conductivity of nine concrete compositions with various rates of waste: four mixes with 10%, 20%, 40% and 60% chopped PET bottles aggregates and 10% fly ash as cement partial substitution; a mix with 60% waste polystyrene of 4–8 mm and 10% fly ash; a mix with 20% waste polystyrene of 4–8 mm, 10% waste polystyrene of 0–4 mm and 10% fly ash; a mix with 50% waste polystyrene of 4–8 mm, 20% waste polystyrene of 0–4 mm and 20% fly ash two mixes with 10% fly ash and 10% and 40% waste sawdust, respectively. Using 60% PET aggregates, 60% polystyrene granules of 4–8 mm, or 20% polystyrene of 0–4 mm together with 50% polystyrene of 4–8 mm led to the obtainment of lightweight concrete, with a density lower than 2000 kg/m3. These mixes also registered the best results from a thermal conductivity point of view, after the concrete mix with 40% saw dust. Regarding compressive strength, the mix with 10% PET obtained a result very close to the reference mix, while those with 20% PET, 40% PET, 30% polystyrene, and 10% saw dust, respectively, registered values between 22 MPa and 25 MPa, values appropriate for structural uses.  相似文献   

17.
In this paper, the traditional, silicate-based Portland cement (PC) was employed as the control to explore the impact of adding varying amounts of metakaolin (MK) on the mechanical properties of cement mortar. In fact, as a mineral admixture, metakaolin (MK) has the ability to significantly improve the early strength and sulfate resistance of cement mortar in traditional, silicate-based Portland cement (PC). In addition to this, the performance of Portland cement mortar is greatly affected by the curing mode. The previous research mainly stays in the intermittent curing and alkaline excitation mode, and there are few studies on the influence of relatively humidity on it. Moreover, the paper investigated the impact of four different curing methods about humidity on the mechanical properties and sulfate resistance. The results show that the best content of metakaolin in Portland cement is 10% (M10), and the best curing method is 95% humidity in the first three days followed by 60% humidity in the later period (3#). Based on previous literature that suggests that adding MK thickens water film layer on the surface of mortar, the mechanism of MK increasing the early strength of cement was analyzed. The compressive strength of the Portland cement containing 10% MK (M10) after 1 day curing is 3.18 times that of pristine PC mortar, and is comparable if PC is cured for three days under the same curing conditions. The traditional PC mortar is highly dependent on the wet curing time, and normally requires a curing time of at least seven days. However, the incorporation of MK can greatly reduce the sensitivity of Portland cement to water; MK cement mortar with only three days wet curing (3#M10) can reach 49.12 MPa after 28 days, which can greatly shorten the otherwise lengthy wet curing time. Lastly, the cement specimens with MK also demonstrated excellent resistance against sulfate corrosion. The work will provide a strong theoretical basis for the early demolding of cement products in construction projects. At the same time, this study can also provide a theoretical reference for the construction of climate drought and saline land areas, which has great reference value.  相似文献   

18.
In this study, the effect of waste glass on the mechanical properties of concrete was examined by conducting a series of compressive strength, splitting tensile strength and flexural strength tests. According to this aim, waste glass powder (WGP) was first used as a partial replacement for cement and six different ratios of WGP were utilized in concrete production: 0%, 10%, 20%, 30%, 40%, and 50%. To examine the combined effect of different ratios of WGP on concrete performance, mixed samples (10%, 20%, 30%) were then prepared by replacing cement, and fine and coarse aggregates with both WGP and crashed glass particles. Workability and slump values of concrete produced with different amounts of waste glass were determined on the fresh state of concrete, and these properties were compared with those of plain concrete. For the hardened concrete, 150 mm × 150 mm × 150 mm cubic specimens and cylindrical specimens with a diameter of 100 mm and a height of 200 mm were tested to identify the compressive strength and splitting tensile strength of the concrete produced with waste glass. Next, a three-point bending test was carried out on samples with dimensions of 100 × 100 × 400 mm, and a span length of 300 mm to obtain the flexure behavior of different mixtures. According to the results obtained, a 20% substitution of WGP as cement can be considered the optimum dose. On the other hand, for concrete produced with combined WGP and crashed glass particles, mechanical properties increased up to a certain limit and then decreased owing to poor workability. Thus, 10% can be considered the optimum replacement level, as combined waste glass shows considerably higher strength and better workability properties. Furthermore, scanning electron microscope (SEM) analysis was performed to investigate the microstructure of the composition. Good adhesion was observed between the waste glass and cementitious concrete. Lastly, practical empirical equations have been developed to determine the compressive strength, splitting tensile strength, and flexure strength of concrete with different amounts of waste glass. Instead of conducting an experiment, these strength values of the concrete produced with glass powder can be easily estimated at the design stage with the help of proposed expressions.  相似文献   

19.
Cement-based lightweight materials have received much attention recently in embankment backfill applications, the boundary of which is more close to a plane strain condition. To study the influence of plane strain condition on the behavior and void structure of cement-based lightweight material under cyclic loading, this paper conducted a series of compression tests on foamed cement pastes with densities of 700 and 900 kg/m3 subjected to static and cyclic loading under plane strain conditions. The X-CT technique was adopted to obtain the three-dimensional (3-D) void structures of the specimens before and after the loading tests. The results showed that the plane strain conditions yielded specimen compression strengths 30–50% higher than the unconfined conditions. The specimen integrity endured under load levels of less than 0.5, but failed after approximately 1000 cycles under a load level of 0.8, indicating that cyclic loading could accelerate the degradation of the specimena. The void structures of the specimens showed that the void volumes were featured bfatured an unimodal distribution with unimodal positions in a range of 0.1–0.2 mm3. The unimodal position became higher with the increasing cyclic load level. Slices of the specimens after static and cyclic loading tests suggested that cyclic load could easily lead to the rupture of voids that then merge into bigger voids and the connection of voids forming cracks.  相似文献   

20.
This article presents a study of the effect of water glass and its introduction on the hydration of Portland cement and its properties in plastic and solid states. The introduction of sodium water glass into the mixing water extends the setting time of Portland cement by 35%, while introduction into the cement paste reduces it by 24.4%; for potassium water glass, the respective values are 10.8% and 10.8%. The introduction of sodium water glass into the mixing water decreases its consistency by 17.6%; its introduction into the cement paste reduces its consistency by 97%. Based on microcalorimetric studies and using the modelling method, mechanisms of the processes occurring in the cement paste, for various methods of introducing water glass admixtures, and their influence on the properties of cement are proposed. The important implications of the obtained results are that, using various methods for introducing admixtures of water glass, it is possible to regulate the setting of cement slurries within significant limits that are important during their transportation.  相似文献   

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