A Comparative Study of the Mechanical Properties of FDM 3D Prints Made of PLA and Carbon Fiber-Reinforced PLA for Thin-Walled Applications

This study focused on the analysis of the mechanical properties of thin-walled specimens fabricated by fused deposition modelling (FDM). Two materials were considered, i.e., polylactide (PLA) and polylactide with carbon fiber (PLA-CF). The article describes how the specimens with different thicknesses and printing orientations were designed, printed, measured to assess their geometric and dimensional accuracy, subjected to tensile testing, and examined using scanning electron microscopy. The data provided here can be used for further research aimed at improving filament deposition and modifying the base material by combining it with different components, for example carbon fiber. The investigations revealed that the properties of thin-walled elements produced by FDM varied significantly depending on the thickness. So far, this problem has not been investigated extensively. Research by analyzing the key parameter, which is the direction of printing that is important for thin-walled models, provides a lot of new information for designers and technologists and opens the way to further extended scientific research in the field of the strength analysis of thin-walled models produced by 3D printing, which is very applicable to structure optimization in the era of the industrial revolution 4.0 and progress in the LEAN manufacturing process.     

Compression Strength of PLA Bolts Produced via FDM

The aim of this research was to define the compression strength of polylactic acid bolts produced using the fused deposition modelling method. In accomplishing this, static and cyclic compression tests for different metric thread sizes were carried out in accordance with ISO 4014. Tests were conducted on M42, M48, M56, M60, and M64 threads, while samples with three different types of pitch—one nominal and two fine threads—were prepared for each diameter. Standard ISO 604 for defining the compression modulus Ec was implemented as the test basis. Accordingly, the mean compression modulus value Ec for all measurements was 917.79 ± 184.99 MPa. Cyclic compression tests were then carried out on samples with the M64 × 4 thread. Fifty thread loading cycles were carried out for each variant to obtained different strain amplitude values and strain frequencies. Our work indicated that the values of the storage modulus defined in cyclic tests E′ increased, while the values of the loss modulus E″ decreased when the value of the strain frequency increased. We found it not possible to determine the nature of the changes in the value of the storage modulus E′ in the function of the strain amplitude. We did, however, observe an increase in the value of the loss modulus E″, together with the increase in the tested range of the strain amplitude. The determined mechanical values can be therefore be used for designing threaded connections made of polylactic acid using the fused deposition modelling method.     

The Influence of 3D Printing Parameters on Adhesion between Polylactic Acid (PLA) and Thermoplastic Polyurethane (TPU)

A 3D printer in FDM technology allows printing with two nozzles, which creates an opportunity to produce multi-material elements. Printing from two materials requires special consideration of the interface zone generated between their geometrical boundaries. This article aims to present the possibility of printing with PLA and TPU using commercially available filaments and software to obtain the best possible bond strength between two different polymers with respect to printing parameters, surface pattern (due to the material contact surface’s roughness), and the order of layer application. The interaction at the interface of two surfaces of two different filaments (PLA-TPU and TPU-PLA) and six combinations of patterns were tested by printing seven replicas for each. A total of 12 combinations were obtained. By analyzing pairs of samples (the same patterns, different order of materials), the results for the TPU/PLA samples were better or very close to the results for PLA/TPU. The best variants of pattern combinations were distinguished. Well-chosen printing parameters can prevent a drop in parts efficiency compared to component materials (depending on the materials combination).     

Rheological Characterization and Printability of Polylactide (PLA)-Alumina (Al2O3) Filaments for Fused Deposition Modeling (FDM)

This article presents the study of the rheological properties and the printability of produced ceramic-polymer filaments using fused deposition method (FDM) 3D printing technology. Powder mixtures with an alumina content of 50 to 70 vol.% were fabricated by a wet processing route. A series of rheological experiments of the obtained mixtures were conducted in the temperature range from 200 to 220 °C for the commercial polylactide (PLA) powder and from 200 to 240 °C for ceramic-polymer, which corresponds to the recommended temperatures for 3D printing of commercial PLA filaments. The composition with the maximum content of alumina leads to a powdery material in which the molten polymer is insufficient to measure the rheological properties. In spite of this, the filaments were prepared from all the obtained mixtures with a tabletop single-screw extruder, the diameter and surface profile of which were analyzed. As the ceramic content increased, the diameter and surface roughness of the filaments increased. Therefore, it was only possible to print an object from a filament with the lowest ceramic content. However, the print quality of the 3D printed objects from the fabricated ceramic-polymer filament is worse (imperfect form, defects between layers) compared to the commercial PLA filament. To eliminate such defects in the future, it is necessary to conduct additional research on the development of printing modes and possibly modify the software and components of the 3D printer.     

A Comparative Analysis of Selected Methods for Determining Young’s Modulus in Polylactic Acid Samples Manufactured with the FDM Method

The objective of this study was to compare three methods for determining the Young’s modulus of polylactic acid (PLA) and acrylonitrile-butadiene-styrene (ABS) samples. The samples were manufactured viathe fused filament fabrication/fused deposition modeling (FFF/FDM) 3D printing technique. Samples for analysis were obtained at processing temperatures of 180 °C to 230 °C. Measurements were performed with the use of two nondestructive techniques: the impulse excitation technique (IET) and the ultrasonic (US) method. The results were compared with values obtained in static tensile tests (STT), which ranged from 2.06 ± 0.03 to 2.15 ± 0.05 GPa. Similar changes in Young’s modulus were observed in response to the processing temperatures of the compared methods. The values generated by the US method were closer to the results of the STT, but still diverged considerably, and the error exceeded 10% in all cases. Based on the present findings, it might be concluded that the results of destructive and nondestructive tests differ by approximately 1 GPa.     

Investigation of Tensile Properties of Different Infill Pattern Structures of 3D-Printed PLA Polymers: Analysis and Validation Using Finite Element Analysis in ANSYS

The advancement of 3D-printing technology has ushered in a new era in the production of machine components, building materials, prototypes, and so on. In 3D-printing techniques, the infill reduces the amount of material used, thereby reducing the printing time and sustaining the aesthetics of the products. Infill patterns play a significant role in the property of the material. In this research, the mechanical properties of specimens are investigated for gyroid, rhombile, circular, truncated octahedron, and honeycomb infill structures (hexagonal). Additionally, the tensile properties of PLA 3D-printed objects concerning their infill pattern are demonstrated. The specimens were prepared with various infill patterns to determine the tensile properties. The fracture of the specimen was simulated and the maximum yield strengths for different infill structures and infill densities were determined. The results show the hexagonal pattern of infill holds remarkable mechanical properties compared with the other infill structures. Through the variation of infill density, the desired tensile strength of PLA can be obtained based on the applications and the optimal weight of the printed parts.     

Preliminary Study on Mechanical Aspects of 3D-Printed PLA-TPU Composites

Additive technologies using Fused Deposition Modeling (FDM) technology are currently a promising tool for the production of polymeric multicomposites. This paper presents the results of a static 3-point bending test carried out on 3D printed samples of the PLA-TPU composite. The article also discusses initial vibrodiagnostic research and Finite Element Method (FEM) analysis of the 3D-printed composite bushings. The data obtained from FEM analysis served as input data for motion simulation analysis, where the influence of the stiffness of the suspension on the trajectory has been verified.     

Deviations of the SLM Produced Lattice Structures and Their Influence on Mechanical Properties

Selective laser melting (SLM) is an additive manufacturing technology suitable for producing cellular lattice structures using fine metal powder and a laser beam. However, the shape and dimensional deviations occur on the thin struts during manufacturing, influencing the mechanical properties of the structure. There are attempts in the literature to describe the actual shape of the struts’ geometry, however, on a smaller data sample only, and there is a lack of a universal FEA material model applicable to a wider range of lattice structure diameters. To describe the actual dimensions of the struts, a set of lattice structures, with diameters ranging from 0.6 to 3.0 mm, were manufactured using SLM. These samples were digitized using micro-computed tomography (μCT) and fully analyzed for shape and dimensions. The results show large deviations in diameters of inscribed and circumscribed cylinders, indicating an elliptical shape of the struts. With increasing lattice structure diameter, the deviations decreased. In terms of the effect of the shape and dimensions on the mechanical properties, the Gaussian cylinder was found to describe struts in the diameter range of 1.5 to 3.0 mm sufficiently well. For smaller diameters, it is appropriate to represent the actual cross-section by an ellipse. The use of substitute ellipses, in combination with the compression test results, has resulted in FEA material model that can be used for the 0.6 to 3.0 mm struts’ diameter range. The model has fixed Young’s and tangential modules for these diameters and is controlled only by the yield strength parameter (YST).     

Influence of Layer Thickness and Raster Angle on the Mechanical Properties of 3D-Printed PEEK and a Comparative Mechanical Study between PEEK and ABS

Fused deposition modeling (FDM) is a rapidly growing 3D printing technology. However, printing materials are restricted to acrylonitrile butadiene styrene (ABS) or poly (lactic acid) (PLA) in most Fused deposition modeling (FDM) equipment. Here, we report on a new high-performance printing material, polyether-ether-ketone (PEEK), which could surmount these shortcomings. This paper is devoted to studying the influence of layer thickness and raster angle on the mechanical properties of 3D-printed PEEK. Samples with three different layer thicknesses (200, 300 and 400 μm) and raster angles (0°, 30° and 45°) were built using a polyether-ether-ketone (PEEK) 3D printing system and their tensile, compressive and bending strengths were tested. The optimal mechanical properties of polyether-ether-ketone (PEEK) samples were found at a layer thickness of 300 μm and a raster angle of 0°. To evaluate the printing performance of polyether-ether-ketone (PEEK) samples, a comparison was made between the mechanical properties of 3D-printed polyether-ether-ketone (PEEK) and acrylonitrile butadiene styrene (ABS) parts. The results suggest that the average tensile strengths of polyether-ether-ketone (PEEK) parts were 108% higher than those for acrylonitrile butadiene styrene (ABS), and compressive strengths were 114% and bending strengths were 115%. However, the modulus of elasticity for both materials was similar. These results indicate that the mechanical properties of 3D-printed polyether-ether-ketone (PEEK) are superior to 3D-printed ABS.     

Fabrication of PLA/PCL/Graphene Nanoplatelet (GNP) Electrically Conductive Circuit Using the Fused Filament Fabrication (FFF) 3D Printing Technique

For the purpose of fabricating electrically conductive composites via the fused filament fabrication (FFF) technique whose properties were compared with injection-moulded properties, poly(lactic acid) (PLA) and polycaprolactone (PCL) were mixed with different contents of graphene nanoplatelets (GNP). The wettability, morphological, rheological, thermal, mechanical, and electrical properties of the 3D-printed samples were investigated. The microstructural images showed the selective localization of the GNPs in the PCL nodules that are dispersed in the PLA phase. The electrical resistivity results using the four-probes method revealed that the injection-moulded samples are insulators, whereas the 3D-printed samples featuring the same graphene content are semiconductors. Varying the printing raster angles also exerted an influence on the electrical conductivity results. The electrical percolation threshold was found to be lower than 15 wt.%, whereas the rheological percolation threshold was found to be lower than 10 wt.%. Furthermore, the 20 wt.% and 25 wt.% GNP composites were able to connect an electrical circuit. An increase in the Young’s modulus was shown with the percentage of graphene. As a result, this work exhibited the potential of the FFF technique to fabricate biodegradable electrically conductive PLA-PCL-GNP composites that can be applicable in the electronic domain.     

The Mechanical Properties of Fiber Metal Laminates Based on 3D Printed Composites

The production and mechanical properties of fiber metal laminates (FMLs) based on 3D printed composites have been investigated in this study. FMLs are structures constituting an alternating arrangement of metal and composite materials that are used in the aerospace sector due to their unique mechanical performance. 3D printing technology in FMLs could allow the production of structures with customized configuration and performance. A series of continuous carbon fiber reinforced composites were printed on a Markforged system and placed between layers of aluminum alloy to manufacture a novel breed of FMLs in this study. These laminates were subjected to tensile, low velocity and high velocity impact tests. The results show that the tensile strength of the FMLs falls between the strength of their constituent materials, while the low and high velocity impact performance of the FMLs is superior to those observed for the plain aluminum and the composite material. This mechanism is related to the energy absorption process displayed by the plastic deformation, and interfacial delamination within the laminates. The present work expects to provide an initial research platform for considering 3D printing in the manufacturing process of hybrid laminates.     

Influence of UV Ageing on Properties of Printed PLA Containing Graphene Nanopowder

The present paper analyses the properties of printed polylactic acid (PLA) samples with admixtures of graphene nanopowder (GNP) at wt. 1%, 2% and 4%. The pure polylactide and admixed polylactide printed samples were examined to determine their chemical-physical properties, stiffness, and strength parameters. The tests of tensile, dynamic mechanical analysis (DMA), difference thermogravimetric (TG), and differential scanning calorimetry (DSC) were executed before and after UV (ultraviolet) treatment. The first part of the paper shows the process of manufacturing granulates and filaments mixed with graphene. The second part of the paper concerns the results of the tests made on printed samples. The analysed samples were printed using a Prusa i3 MK3 printer. It transpired that the content of graphene at 1% improved the mechanical parameters of the printed composite by organising its structure. Increasing the amount of graphene caused the values of the measured parameters to drop. This research indicates how important it is to determine the optimal values of nanoadditives in biopolymers.     

New Organophilic Montmorillonites with Lactic Acid Oligomers and Other Environmentally Friendly Compounds and Their Effect on Mechanical Properties of Polylactide (PLA)

New organophilic montmorillonites with oligomers of lactic acid and other compounds such as citric acid, stearic acid, maleic anhydride, pentaerythritol and ε-caprolactone were synthesized. They were characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), elemental analysis and swelling capacity in water. In all tested composites, an increase in the montmorillonite interlayer distance resulting from intercalation of the modifying substance in the montmorillonite was found by means of XRD. Elemental analysis and FTIR showed that all of the tested samples contained an organic segment in the montmorillonite structure. TGA studies revealed that composites modified with lactic acid oligomers, stearic acid or ε-caprolactone had the highest thermal stability. They also exhibited the lowest swelling capacity which was 2–3 times lower than that for unmodified sodium montmorillonite. Some preliminary studies on the mechanical properties of PLA/modified montmorillonite are also presented and discussed.     

Impact of Particle Size of Ceramic Granule Blends on Mechanical Strength and Porosity of 3D Printed Scaffolds

3D printing is a promising method for the fabrication of scaffolds in the field of bone tissue engineering. To date, the mechanical strength of 3D printed ceramic scaffolds is not sufficient for a variety of applications in the reconstructive surgery. Mechanical strength is directly in relation with the porosity of the 3D printed scaffolds. The porosity is directly influenced by particle size and particle-size distribution of the raw material. To investigate this impact, a hydroxyapatite granule blend with a wide particle size distribution was fractioned by sieving. The specific fractions and bimodal mixtures of the sieved granule blend were used to 3D print specimens. It has been shown that an optimized arrangement of fractions with large and small particles can provide 3D printed specimens with good mechanical strength due to a higher packing density. An increase of mechanical strength can possibly expand the application area of 3D printed hydroxyapatite scaffolds.     

Influence of the AlSi7Mg0.6 Aluminium Alloy Powder Reuse on the Quality and Mechanical Properties of LPBF Samples

Additive manufacturing (AM) is dynamically developing and finding applications in different industries. The quality of input material is a part of the process and of the final product quality. That is why understanding the influence of powder reuse on the properties of bulk specimens is crucial for ensuring the repeatable AM process chain. The presented study investigated the possibility of continuous reuse of AlSi7Mg0.6 powder in the laser powder bed fusion process (LPBF). To date, there is no study of AlSi7Mg0.6 powder reuse in the LPBF process to be found in the literature. This study aims to respond to this gap. The five batches of AlSi7Mg0.6 powder and five bulk LPBF samples series were characterised using different techniques. The following characteristics of powders were analysed: the powder size distribution (PSD), the morphology (scanning electron microscopy—SEM), the flowability (rotating drum analysis), and laser light absorption (spectrophotometry). Bulk samples were characterised for microstructure (SEM), chemical composition (X-ray fluorescence spectrometry—XRF), porosity (computed tomography—CT) and mechanical properties (tensile, hardness). The powder was reused in subsequent processes without adding (recycling/rejuvenation) virgin powder (collective ageing powder reuse strategy). All tested powders (powders P0–P4) and bulk samples (series S0–S3) show repeatable properties, with changes observed within error limits. Samples manufactured within the fifth reuse cycle (series S4) showed some mean value changes of measured characteristics indicating initial degradation. However, these changes also mostly fit within error limits. Therefore, the collective ageing powder reuse strategy is considered to give repeatable LPBF process results and is recommended for the AlSi7Mg0.6 alloy within at least five consecutive LPBF processes.     

Microwave Absorption Properties of Carbon Black-Carbonyl Iron/Polylactic Acid Composite Filament for Fused Deposition Modeling

A single microwave absorbent and simple coating structure cannot meet the increasing requirements for broadband and strong absorption. Three-dimensional printing is an effective way to prepare multi-component complex structure metamaterial absorbers, and the key is to prepare raw materials with excellent absorption properties, suitable for 3D printing. In this paper, CB-CIP/PLA composite filament was prepared via a high-energy mixer and twin-screw extruder by compounding the dielectric loss material carbon black (CB) and the magnetic loss material carbonyl iron powder (CIP) with polylactic acid (PLA) as the matrix. The coaxial ring test piece was printed by FDM technology, and the microstructure of the composites was observed and analyzed by SEM. Meanwhile, the electromagnetic parameters of the composites were examined by a vector network analyzer, mainly studying the influence of the CB and CIP content and thickness on the microwave absorbing properties of the composite material. The results show that when the CB content is 20% and the CIP content is 30%, the CB-CIP/PLA composite has excellent microwave absorption and broad bandwidth. When the matching thickness is 1.6 mm, the minimum reflection loss (RL) reaches −51.10 dB; when the thickness is 1.7 mm, the effective absorption bandwidth (RL < −10 dB) is 5.04 GHz (12.96–18 GHz), nearly covering the whole Ku band. This work provides an efficient formulation and process to prepare an absorbing composite filament for FDM.     

Construction and Validation of Simulation Models of Samples Made from 316L Steel by Applying Additive Technique

The main aim of the study includes research concerning the strength of samples printed out of 316L steel in the form of laminates and the creation of reflective simulation models with regard to the results obtained during the research. In addition, the tests addressed the effect of the arrangement of the printed layers on the final strength of the object. Static tensile tests allowed the material constants of 316L steel in the form of dimensionally printed laminate to be determined. Tests were conducted on samples with different printed angles. The tests also covered the impact of the printing envelope on samples with the printing angles. Based on the determined material constants, simulation models for calculations using the finite element method were created. Furthermore, the study includes analytical and simulation calculations of plain laminate in order to verify the accuracy of the Composite Layup module in Abaqus CAE software. The study was summarized by compiling and commenting on the results obtained from the conducted research. Tests showed that there is a possibility of simulating the strength of the printouts from 316L steel using the FEM calculations. It was shown that the FEM model results are similar to those obtained in the tests. The calculated errors were from 3.6 to 14.4%. The linear model describes well the first part of the stress–strain curve, but in further research, it is strongly recommended that a proper and checked nonlinear anisotropic one is presented.     

Improvement of the Thermal Conductivity and Mechanical Properties of 3D-Printed Polyurethane Composites by Incorporating Hydroxylated Boron Nitride Functional Fillers

Recently, the use of fused deposition modeling (FDM) in the three-dimensional (3D) printing of thermal interface materials (TIMs) has garnered increasing attention. Because fillers orient themselves along the direction of the melt flow during printing, this method could effectively enhance the thermal conductivity of existing composite materials. However, the poor compatibility and intensive aggregation of h-BN fillers in polymer composites are still detrimental to their practical application in thermally conductive materials. In this study, hydroxyl-functionalized boron nitride (OH-BN) particles were prepared by chemical modification and ultrasonic-assisted liquid-phase exfoliation to explore their impact on the surface compatibility, mechanical properties and the final anisotropic thermal conductivity of thermoplastic polyurethane (TPU) composites fabricated by FDM printing. The results show that the surface-functionalized OH-BN fillers are homogeneously dispersed in the TPU matrix via hydrogen bonding interactions, which improve the interfacial adhesion between the filler and matrix. For the same concentration of loaded filler, the OH-BN/TPU composites exhibit better mechanical properties and thermal conductivities than composites incorporating non-modified h-BN. These composites also show higher heat conduction along the stand-vertical direction, while simultaneously exhibiting a low dielectric constant and dielectric loss. This work therefore provides a possible strategy for the fabrication of thermal management polymers using 3D-printing methods.     

Modulation of the PLLA Morphology through Racemic Nucleation to Reach Functional Properties Required by 3D Printed Durable Applications

This paper presents an alternative for enhancing the durability of poly (L-lactide) (PLLA) by racemic nucleation following stereo-complexation with a selected poly (D-lactide) (PLDA). The compounds are obtained by melt blending of a PLLA grade, previously designed for 3D printing but with a low heat deflection temperature and impact resistance, with grades of PLDA differing in their molecular weight (Mw), D-lactide content (DS) and concentration. Our method considered how to reveal the racemic nucleation caused by stereo-complexation and its influence on functional properties. The FTIR study we performed showed that, depending on Mw, DS and concentration of the stereo-complexer (PDLA) used, bigger or smaller spectral changes can occur. The stereo-complexation was confirmed by the DSC analysis and, for the selected compound, by the POM, SEM, AFM microscopies, functional property and shapeability as 3D printing filaments. All the obtained results sustain the idea that, if a PLLA with M_w of 4.5 × 10⁴ g·mol⁻¹ is modified with PDLA with a medium M_w of 11.6 × 10⁴ g·mol⁻¹, medium DS of 4% and 1% concentration, a racemic nucleation is possible. It produces a racemic polylactic acid (PDLLA) with improved durability and good shapeability as 3D printing filaments. These results are explicable if the dependence of the intermolecular interactions appears between the PLLA and stereo-complexer PDLA. To enlarge the durable applicability of racemic polylactic acid (PDLLA), future research should identify other parameters controling the PLA stereo-complexing as the intensifying the mobility of the macromolecules, the finding of the optimal recemic cristalization window.     

The Effect of Binder Loading on the Pore Size of 3D Printed PMMA

Binder jetting is known to produce porous objects by depositing the binder selectively layer by layer on a powder bed. In this study, the pore size of printed parts and the correlating mechanical properties are investigated on a commercially available PMMA powder binder system. Pore sizes are measured via capillary flow porometry and mechanical properties via tensile tests. Porometry indicates that the pore size stays at a constant level of 22 µm at 5 to 10 wt% binder loading before decreasing to 6 µm at loadings of 30 wt% or higher. The results were compared with the mechanical testing and related to the agglomerate strength model of Rumpf. The highlights of the article are the application of a binder jetted part as a filter and the identification of a close relationship between porosity and mechanical strength, similar to phenomena in agglomeration science.