NaV6O15 microflowers as a stable cathode material for high-performance aqueous zinc-ion batteries

Reversible aqueous zinc-ion batteries (ZIBs) have great potential for large-scale energy storage owing to their low cost and safety. However, the lack of long-lifetime positive materials severely restricts the development of ZIBs. Herein, we report NaV₆O₁₅ microflowers as a cathode material for ZIBs with excellent electrochemical performance, including a high specific capacity of ∼300 mA h g⁻¹ at 100 mA g⁻¹ and 141 mA h g⁻¹ maintained after 2000 cycles at 5 A g⁻¹ with a capacity retention of ∼107%. The high diffusion coefficient and stable tunneled structure of NaV₆O₁₅ facilitate Zn²⁺ intercalation/extraction and long-term cycle stability.

NaV₆O₁₅ microflowers were synthesized as a stable cathode material for aqueous zinc ion batteries, which show a high specific capacity and excellent long-term cycling performance.     

Design and synthesis of hierarchical NiO/Ni3V2O8 nanoplatelet arrays with enhanced lithium storage properties

Hierarchical NiO/Ni₃V₂O₈ nanoplatelet arrays (NPAs) grown on Ti foil were prepared as free-standing anodes for Li-ion batteries (LIBs) via a simple one-step hydrothermal approach followed by thermal treatment to enhance Li storage performance. Compared to the bare NiO, the fabricated NiO/Ni₃V₂O₈ NPAs exhibited significantly enhanced electrochemical performances with superior discharge capacity (1169.3 mA h g⁻¹ at 200 mA g⁻¹), excellent cycling stability (570.1 mA h g⁻¹ after 600 cycles at current density of 1000 mA g⁻¹) and remarkable rate capability (427.5 mA h g⁻¹ even at rate of 8000 mA g⁻¹). The excellent electrochemical performances of the NiO/Ni₃V₂O₈ NPAs were mainly attributed to their unique composition and hierarchical structural features, which not only could offer fast Li⁺ diffusion, high surface area and good electrolyte penetration, but also could withstand the volume change. The ex situ XRD analysis revealed that the charge/discharge mechanism of the NiO/Ni₃V₂O₈ NPAs included conversion and intercalation reaction. Such NiO/Ni₃V₂O₈ NPAs manifest great potential as anode materials for LIBs with the advantages of a facile, low-cost approach and outstanding electrochemical performances.

Hierarchical NiO/Ni₃V₂O₈ nanoplatelet arrays (NPAs) grown on Ti foil were prepared as free-standing anodes for Li-ion batteries (LIBs) via a simple one-step hydrothermal approach followed by thermal treatment to enhance Li storage performance.     

Preparation and electrochemical performance of VO2(A) hollow spheres as a cathode for aqueous zinc ion batteries

Rechargeable aqueous zinc ion batteries (ZIBs), owing to their low-cost zinc metal, high safety and nontoxic aqueous electrolyte, have the potential to accelerate the development of large-scale energy storage applications. However, the desired development is significantly restricted by cathode materials, which are hampered by the intense charge repulsion of bivalent Zn²⁺. Herein, the as-prepared VO₂(A) hollow spheres via a feasible hydrothermal reaction exhibit superior zinc ion storage performance, large reversible capacity of 357 mA h g⁻¹ at 0.1 A g⁻¹, high rate capability of 165 mA h g⁻¹ at 10 A g⁻¹ and good cycling stability with a capacity retention of 76% over 500 cycles at 5 A g⁻¹. Our study not only provides the possibility of the practical application of ZIBs, but also brings a new prospect of designing high-performance cathode materials.

VO₂(A) hollow spheres exhibit superior zinc ion storage performance, large reversible capacity of 357 mA h g⁻¹ at 0.1 A g⁻¹, and good cycling stability with a capacity retention of 76% over 500 cycles at 5 A g⁻¹     

Controllable synthesis of nanostructured ZnCo2O4 as high-performance anode materials for lithium-ion batteries

Nanostructured ZnCo₂O₄ anode materials for lithium-ion batteries (LIBs) have been successfully prepared by a two-step process, combining facile and concise electrospinning and simple post-treatment techniques. Three different structured ZnCo₂O₄ anodes (nanoparticles, nanotubes and nanowires) can be prepared by simply adjusting the ratio of metallic salt and PVP in the precursor solutions. Charge–discharge tests and cyclic voltammetry (CV) have been conducted to evaluate the lithium storage performances of ZnCo₂O₄ anodes, particularly for ZnCo₂O₄ nanotubes obtained from a weight ratio 2 : 4 of metallic salt and PVP polymer in the precursor solution. Remarkably, ZnCo₂O₄ nanotubes exhibit high specific capacity, good rate property, and long cycling stability. Reversible capacity is still maintained at 1180.8 mA h g⁻¹ after 275 cycles at a current density of 200 mA g⁻¹. In case of rate capability, even after cycling at the 2000 mA g⁻¹ current density, the capacity could recover to 684 mA h g⁻¹. The brilliant electrochemical properties of the ZnCo₂O₄ anodes make them promising anodes for LIBs and other energy storage applications.

ZnCo₂O₄ nanoparticles, nanotubes, and nanofibers can be controllably prepared by simply tuning the weight ratios of metallic salts and PVP polymer in the precursor solution.     

A comparison study of MnO2 and Mn2O3 as zinc-ion battery cathodes: an experimental and computational investigation

The high specific capacity, low cost and environmental friendliness make manganese dioxide materials promising cathode materials for zinc-ion batteries (ZIBs). In order to understand the difference between the electrochemical behavior of manganese dioxide materials with different valence states, i.e., Mn(iii) and Mn(iv), we investigated and compared the electrochemical properties of pure MnO₂ and Mn₂O₃ as ZIB cathodes via a combined experimental and computational approach. The MnO₂ electrode showed a higher discharging capacity (270.4 mA h g⁻¹ at 0.1 A g⁻¹) and a superior rate performance (125.7 mA h g⁻¹ at 3 A g⁻¹) than the Mn₂O₃ electrode (188.2 mA h g⁻¹ at 0.1 A g⁻¹ and 87 mA h g⁻¹ at 3 A g⁻¹, respectively). The superior performance of the MnO₂ electrode was ascribed to its higher specific surface area, higher electronic conductivity and lower diffusion barrier of Zn²⁺ compared to the Mn₂O₃ electrode. This study provides a detailed picture of the diversity of manganese dioxide electrodes as ZIB cathodes.

MnO₂ and Mn₂O₃ cathodes for zinc ion batteries were experimentally and computationally explored.     

Surface phosphation of 3D mesoporous NiCo2O4 nanowire arrays as bifunctional anodes for lithium and sodium ion batteries

A novel surface phosphate strategy was adopted to dramatically improve the charge transport, ion diffusion, electroactive sites, and cycle stability of mesoporous NiCo₂O₄ nanowire arrays (NWAs), drastically boosting their electrochemical properties. Consequently, the as-prepared phosphated NiCo₂O₄ NWA (P-NiCo₂O₄ NWA) electrode achieved excellent energy storage performance as a bifunctional anode material for both lithium ion batteries (LIBs) and sodium ion batteries (SIBs). When evaluated as an anode for LIBs, this P-NiCo₂O₄ NWA electrode showed a high reversible capacity up to 1156 mA h g⁻¹ for 1500 cycles at 200 mA g⁻¹ without appreciable capacity attenuation, while in SIBs, the electrode could also deliver an admirable initial capacity as high as 687 mA h g⁻¹ and maintained 83.5% of this after 500 cycles at the same current density. Most important, when the current density increased from 100 to 1000 mA g⁻¹, the capacity retention was about 63% in LIBs and 54% in SIBs. This work may shed light on the engineering of efficient electrodes for multifunctional flexible energy storage device applications.

A novel surface phosphate strategy was adopted to dramatically improve the charge transport, ion diffusion, electroactive sites, and cycle stability of mesoporous NiCo₂O₄ nanowire arrays (NWAs), drastically boosting their electrochemical properties.     

Electrochemical performance of CoSe2 with mixed phases decorated with N-doped rGO in potassium-ion batteries

Potassium-ion batteries (PIBs) have received much attention as next-generation energy storage systems because of their abundance, low cost, and slightly lower standard redox potential than lithium-ion batteries (LIBs). Nevertheless, they still face great challenges in the design of the best electrode materials for applications. Herein, we have successfully synthesized nano-sized CoSe₂ encapsulated by N-doped reduced graphene oxide (denoted as CoSe₂@N-rGO) by a direct one-step hydrothermal method, including both orthorhombic and cubic CoSe₂ phases. The CoSe₂@N-rGO anodes exhibit a high reversible capacity of 599.3 mA h g⁻¹ at 0.05 A g⁻¹ in the initial cycle, and in particular, they also exhibit a cycling stability of 421 mA h g⁻¹ after 100 cycles at 0.2 A g⁻¹. Density functional theory (DFT) calculations show that CoSe₂ with N-doped carbon can greatly accelerate electron transfer and enhance the rate performance. In addition, the intrinsic causes of the higher electrochemical performance of orthorhombic CoSe₂ than that of cubic CoSe₂ are also discussed.

Potassium-ion batteries (PIBs) have received much attention as next-generation energy storage systems because of their abundance, low cost, and slightly lower standard redox potential than lithium-ion batteries (LIBs).     

Highly conductive locust bean gum bio-electrolyte for superior long-life quasi-solid-state zinc-ion batteries

Rechargeable aqueous zinc-ion batteries (ZIBs) are promising wearable electronic power sources. However, solid-state electrolytes with high ionic conductivities and long-term stabilities are still challenging to fabricate for high-performance ZIBs. Herein, locust bean gum (LBG) was used as a natural bio-polymer to prepare a free-standing quasi-solid-state ZnSO₄/MnSO₄ electrolyte. The as-obtained LBG electrolyte showed high ionic conductivity reaching 33.57 mS cm⁻¹ at room temperature. This value is so far the highest among the reported quasi-solid-state electrolytes. Besides, the as-obtained LBG electrolyte displayed excellent long-term stability toward a Zn anode. The application of the optimized LBG electrolyte in Zn–MnO₂ batteries achieved a high specific capacity reaching up to 339.4 mA h g⁻¹ at 0.15 A g⁻¹, a superior rate performance of 143.3 mA h g⁻¹ at 6 A g⁻¹, an excellent capacity retention of 100% over 3300 cycles and 93% over 4000 cycles combined with a wide working temperature range (0–40 °C) and good mechanical flexibility (capacity retention of 80.74% after 1000 bending cycles at a bending angle of 90°). In sum, the proposed ZIBs-based LBG electrolyte with high electrochemical performance looks promising for the future development of bio-compatible and environmentally friendly solid-state energy storage devices.

Locust bean gum was utilized to prepare a free-standing quasi-solid-state ZnSO₄/MnSO₄ electrolyte. Zinc-ion batteries with locust bean gum electrolyte achieved high energy density and superior lifetime.     

Surface modified Li4Ti5O12 by paper templated approach for enhanced interfacial Li+ charge transfer in Li-ion batteries

The Li₄Ti₅O₁₂ (LTO) and lithium silicate (LS) surface modified LTO have been demonstrated by a unique paper templated method. Comparative study of structural characterization with electrochemical analysis was demonstrated for pristine and modified Li₄Ti₅O₁₂. Structural and morphological study shows the existence of the cubic spinel structure with highly crystalline 250–300 nm size particles. The LS modified LTO shows the deposition of 10–20 nm sized LS nanoparticles on cuboidal LTO. Further, X-ray photoelectron spectroscopy (XPS) confirms the existence of Li₂SiO₃ (LS) in the modified LTO. The electrochemical performance was investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge–discharge. The modified LTO with 2% LS (LTS2) exhibited excellent rate capability compare to pristine LTO i.e. 182 mA h g⁻¹ specific capacity at a current rate, 50 mA g⁻¹ with remarkable cycling stability up to 1100 cycles at a current rate of 800 mA g⁻¹. The lithium ion full cell of modified LTO with LS as an anode and LiCoO₂ as a cathode exhibited a remarkably reversible specific capacity i.e. 110 mA h g⁻¹. Both electronic and ionic conductivities of pristine LTO are observed to be enhanced by incorporation of appropriate amount of LS in LTO due to a larger surface contact at the interface of electrode and electrolyte. More significantly, the versatile paper templated synthesis approach of modified LTO with LS provides densely packed highly crystalline particles. Additionally, it exhibits lower Warburg coefficient and higher Li ion diffusion coefficient which in turn accelerate the interfacial charge transfer process, which is responsible for enhanced stable electrochemical performance. The detailed mechanism is expressed and elaborated for better understanding of enhanced electrochemical performance due to the surface modification.

The versatile paper template synthesis of LTO has been demonstrated with an interconnected nanoparticles network. The system exhibits accelerated interfacial charge transfer which in turn confers enhanced stable electrochemical performance in LIBs.     

Self-assembled hierarchical porous NiMn2O4 microspheres as high performance Li-ion battery anodes

Hierarchical structured porous NiMn₂O₄ microspheres assembled with nanorods are synthesized through a simple hydrothermal method followed by calcination in air. As anode materials for lithium ion batteries (LIBs), the NiMn₂O₄ microspheres exhibit a high specific capacity. The initial discharge capacity is 1126 mA h g⁻¹. After 1000 cycles, the NiMn₂O₄ demonstrates a reversible capacity of 900 mA h g⁻¹ at a current density of 500 mA g⁻¹. In particular, the porous NiMn₂O₄ microspheres still could deliver a remarkable discharge capacity of 490 mA h g⁻¹ even at a high current density of 2 A g⁻¹, indicating their potential application in Li-ion batteries. This excellent electrochemical performance is ascribed to the unique hierarchical porous structure which can provide sufficient contact for the transfer of Li⁺ ion and area for the volume change of the electrolyte leading to enhanced Li⁺ mobility.

Hierarchical structured porous NiMn₂O₄ microspheres assembled with nanorods are synthesized through a simple hydrothermal method followed by calcination in air.     

Three-dimensional clusters of peony-shaped CuO nanosheets as a high-rate anode for Li-ion batteries

Copper oxide (CuO) has emerged as a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity, low cost and low toxicity to the natural environment. However, the low electronic/ionic conductivity and the imponderable volume expansion problem during the charge and discharge process hinder its practical applications. Herein, we introduced three-dimensional clusters of peony-shaped CuO nanosheets (TCP-CuO) to tackle these problems by increasing the surface of the active material. The unique three-dimensional peony-liked structure not only alleviates the volume expansion problem, but also enhances the electron/ion conductivity. As a result, the TCP-CuO electrode possesses a reversible high capacity of 641.1 mA h g⁻¹ at 0.1 A g⁻¹ after 80 cycles as well as an outstanding rate performance of 531.6 mA h g⁻¹ at a rate of 5C (1C = 674 mA g⁻¹) and excellent cycling durability of 441.1 mA h g⁻¹ at 1 A g⁻¹ after 100 cycles. This work demonstrated a novel strategy for the construction of a well-designed structure for other advanced energy-storage technologies.

TCP-CuO possesses a unique three-dimensional peony-liked architecture which not only alleviates volume expansion problem, but also enhances electron/ion conductivity. As an anode in LIBs, TCP-CuO delivers excellent electrochemical performances.     

Silicon micron cages derived from a halloysite nanotube precursor and aluminum sacrificial template in molten AlCl3 as an anode for lithium-ion batteries

Porous nanostructures have been proposed a promising strategy to improve the electrochemical performance of Si materials as anodes of lithium-ion batteries (LIBs). However, expensive raw materials and the tedious preparation processes hinder their widespread adoption. In this work, silicon micron cages (SMCs) have been synthesized in molten AlCl₃ through using spherical aluminum particles as a sacrificial template, and the earth-abundant and low-cost natural halloysite clay as a precursor. The aluminum spheres (1–3 μm) not only act as a sacrificial template but also facilitate the formation of silicon branches, which connect together to form SMCs. As anodes for LIBs, the SMC electrode exhibits a high reversible capacity of 1977.5 mA h g⁻¹ after 50 cycles at a current density of 0.2 A g⁻¹, and 1035.1 mA h g⁻¹ after 300 cycles at a current density of 1.0 A g⁻¹. The improved electrochemical performance of SMCs could be ascribed to the micron cage structure, providing abundant buffering space and mesopores for Si expansion. This promising method is expected to offer a pathway towards the scalable application of Si-based anode materials in the next-generation LIB technology.

(1) Silicon micron cages (SMCs) was synthesized using natural halloysite as precursor. (2) The electrochemical performance of SMCs as anode materials of lithium-ion batteries can be improved for the micron cage structure.     

Preparation of Sn-aminoclay (SnAC)-templated Fe3O4 nanoparticles as an anode material for lithium-ion batteries

Sn-aminoclay (SnAC)-templated Fe₃O₄ nanocomposites (SnAC–Fe₃O₄) were prepared through a facile approach. The morphology and macro-architecture of the fabricated SnAC–Fe₃O₄ nanocomposites were characterized by different techniques. A constructed meso/macro-porous structure arising from the homogeneous dispersion of Fe₃O₄ NPs on the SnAC surface owing to inherent NH₃⁺ functional groups provides new conductive channels for high-efficiency electron transport and ion diffusion. After annealing under argon (Ar) gas, most of SnAC layered structure can be converted to SnO₂; this carbonization allows for formation of a protective shell preventing direct interaction of the inner SnO₂ and Fe₃O₄ NPs with the electrolyte. Additionally, the post-annealing formation of Fe–O–C and Sn–O–C bonds enhances the connection of Fe₃O₄ NPs and SnAC, resulting in improved electrical conductivity, specific capacities, capacity retention, and long-term stability of the nanocomposites. Resultantly, electrochemical measurement exhibits high initial discharge/charge capacities of 980 mA h g⁻¹ and 830 mA h g⁻¹ at 100 mA g⁻¹ in the first cycle and maintains 710 mA h g⁻¹ after 100 cycles, which corresponds to a capacity retention of ∼89%. The cycling performance at 100 mA g⁻¹ is remarkably improved when compared with control SnAC. These outstanding results represent a new direction for development of anode materials without any binder or additive.

Sn-aminoclay (SnAC)/Fe₃O₄ NPs – a promising hybrid electrode to offer great electrochemical performance with a high initial discharge of 980 mA h g⁻¹ and good capacity retention of 89% after 100 cycles.     

Dunaliella Salinas based Sn–carbon anode for high-performance Li-ion batteries

Long life, high capacity, environmental friendliness and good rate performance are the most important elements in the research of lithium ion batteries (LIBs). In this paper, Sn–carbon composite electrode materials are prepared using Dunaliella Salinas based carbon (amorphous carbon) as an amorphous carbon precursor combined with tin. Hence, an amorphous carbon template enwrapped by Sn particles forms a core–shell structure (Sn–carbon composite), the annealed Dunaliella Salinas based carbon makes up the carbon core, and Sn particles form the shell of the material. The components of the materials, microstructure and electrochemical properties of LIBs were characterized and tested. The results show that the prepared Sn–carbon composite electrode materials have high purity and combine with amorphous carbon uniformly. The Sn–carbon composite exhibits excellent performance as a LIB anode, its discharge capacities of the 1st, 2nd, and 4th cycles are 1777.39, 944.15 and 722.46 mA h g⁻¹ at a current density of 100 mA g⁻¹, and the capacity is 619.09 mA h g⁻¹ after stable cycling at a current density of 200 mA g⁻¹. The capacity continues to rise at a high current density of 1000 mA g⁻¹ and is 574.97 mA h g⁻¹ at its maximum, demonstrating the excellent performance of the electrode.

Long life, high capacity, environmental friendliness and good rate performance are the most important elements in the research of lithium ion batteries (LIBs).     

Role of polyvinylpyrrolidone in the electrochemical performance of Li2MnO3 cathode for lithium-ion batteries

While Li₂MnO₃ as an over-lithiated layered oxide (OLO) shows a significantly high reversible capacity of 250 mA h g⁻¹ in lithium-ion batteries (LIBs), it has critical issues of poor cycling performance and deteriorated high rate performance. In this study, modified OLO cathode materials for improved LIB performance were obtained by heating the as-prepared OLO at different temperatures (400, 500, and 600 °C) in the presence of polyvinylpyrrolidone (PVP) under an N₂ atmosphere. Compared to the as-prepared OLO, the OLO sample heated at 500 °C with PVP exhibited a high initial discharge capacity of 206 mA h g⁻¹ and high rate capability of 111 mA h g⁻¹ at 100 mA g⁻¹. The superior performance of the OLO sample heated at 500 °C with PVP is attributed to an improved electronic conductivity and Li⁺ ionic motion, resulting from the formation of the graphitic carbon structure and increased Mn³⁺ ratio during the decomposition of PVP.

The modified OLO cathode materials for improved LIB performance were obtained by heating the as-prepared OLO in the presence of polyvinylpyrrolidone (PVP) under an N₂ atmosphere.     

K-doped Li2ZnTi3O8/C as an efficient anode material with high performance for Li-ion batteries

Li₂ZnTi₃O₈/C and Li_1.9K_0.1ZnTi₃O₈/C were successfully synthesized using the sol–gel method. Doping K apparently yielded a wider tunnel, helpful for increasing the rate of transport of lithium ions, and furthermore yielded excellent electrochemical properties. The first discharge capacity for Li_1.9K_0.1ZnTi₃O₈/C was 352.9 mA h g⁻¹ at a current density of 200 mA g⁻¹. Li_1.9K_0.1ZnTi₃O₈/C also performed stably, retaining a capacity of 323.7 mA h g⁻¹ at the 100th cycle, indicative of its excellent cycling properties. In the rate performance test, Li_1.9K_0.1ZnTi₃O₈/C showed at the first cycle a high discharge capacity of 379.5 mA h g⁻¹ for a current density of 50 mA g⁻¹ and a capacity of 258.9 mA h g⁻¹ at 1000 mA g⁻¹. The results indicated that K-doping should be considered a useful method for improving electrochemical performances.

(A and B) CV curves of (A) Li₂ZnTi₃O₈/C and (B) Li_1.9K_0.1ZnTi₃O₈/C, (C) Initial charge–discharge curves and (D) cycling capacity and (E) rate performances of Li₂ZnTi₃O₈/C and Li_1.9K_0.1ZnTi₃O₈/C. (F) The composition of the CR2032 cell.     

Nanostructured diatom earth SiO2 negative electrodes with superior electrochemical performance for lithium ion batteries

Diatomaceous earth (DE) is a naturally occurring silica source constituted by fossilized remains of diatoms, a type of hard-shelled algae, which exhibits a complex hierarchically nanostructured porous silica network. In this work, we analyze the positive effects of reducing DE SiO₂ particles to the sub-micrometer level and implementing an optimized carbon coating treatment to obtain DE SiO₂ anodes with superior electrochemical performance for Li-ion batteries. Pristine DE with an average particle size of 17 μm is able to deliver a specific capacity of 575 mA h g⁻¹ after 100 cycles at a constant current of 100 mA g⁻¹, and reducing the particle size to 470 nm enhanced the reversible specific capacity to 740 mA h g⁻¹. Ball-milled DE particles were later subjected to a carbon coating treatment involving the thermal decomposition of a carbohydrate precursor at the surface of the particles. Coated ball-milled silica particles reached stable specific capacities of 840 mA h g⁻¹ after 100 cycles and displayed significantly improved rate capability, with discharge specific capacities increasing from 220 mA h g⁻¹ (uncoated ball-milled SiO₂) to 450 mA h g⁻¹ (carbon coated ball-milled SiO₂) at 2 A g⁻¹. In order to trigger SiO₂ reactivity towards lithium, all samples were subjected to an electrochemical activation procedure prior to electrochemical testing. XRD measurements on the activated electrodes revealed that the initial crystalline silica was completely converted to amorphous phases with short range ordering, therefore evidencing the effective role of the activation procedure.

Diatomaceous earth SiO₂ anodes with superior electrochemical performance are obtained by ball milling, carbon coating and electrochemical activation of SiO₂ particles.     

Metal–organic framework derived hollow porous CuO–CuCo2O4 dodecahedrons as a cathode catalyst for Li–O2 batteries

Herein, hollow porous CuO–CuCo₂O₄ dodecahedrons are synthesized by using a simple self-sacrificial metal–organic framework (MOF) template, which resulted in dodecahedron morphology with hierarchically porous architecture. When evaluated as a cathodic electrocatalyst in lithium–oxygen batteries, the CuO–CuCo₂O₄ composite exhibits a significantly enhanced electrochemical performance, delivering an initial capacity of 6844 mA h g⁻¹ with a remarkably decreased discharge/charge overpotential to 1.15 V (vs. Li/Li⁺) at a current density of 100 mA g⁻¹ and showing excellent cyclic stability up to 111 charge/discharge cycles under a cut-off capacity of 1000 mA h g⁻¹ at 400 mA g⁻¹. The outstanding electrochemical performance of CuO–CuCo₂O₄ composite can be owing to the intrinsic catalytic activity, unique porous structure and the presence of substantial electrocatalytic sites. The ex situ XRD and SEM are also carried out to reveal the charge/discharge behavior and demonstrate the excellent reversibility of the CuO–CuCo₂O₄ based electrode.

Metal–organic framework derived porous CuO–CuCo₂O₄ dodecahedrons as a cathode catalyst for Li–O₂ batteries with significantly enhanced rate and cyclic performance.     

The study of zirconium vanadate as a cathode material for lithium ion batteries

The electrochemical properties of ZrV₂O₇ (ZVO) and ZVO@C were investigated in lithium ion batteries. The first charge (or discharge) specific capacity of ZVO and ZVO@C are 279 mA h g⁻¹, 392 mA h g⁻¹, 208 mA h g⁻¹ and 180 mA h g⁻¹ for 0%, 3%, 5% and 9% of carbon, respectively. The capacity retention rates (with 0% 3%, 5% and 9% carbon content) are 33.0%, 52.5%, 56.4% and 76.1% after ten cycles, respectively. The low inner resistance relates to the good contact of the electrode rather than the high content of carbon, and the specific capacity retention rate increases with the increase of the carbon content.

The carbon content in the electrode is not the only factor that determines the internal resistance. The high capacity of lithium ion batteries is related to high conductivity. The lattice is stable (expect for shrinkage) when Li ions insert into ZVO.     

ZnSe nanoparticles dispersed in reduced graphene oxides with enhanced electrochemical properties in lithium/sodium ion batteries

A ZnSe-reduced graphene oxide (ZnSe-rGO) nanocomposite with ZnSe dispersed in rGO is prepared via a one-step hydrothermal method and applied as the anode materials for both lithium and sodium ion batteries (LIBs/SIBs). The as-prepared composite exhibits greatly enhanced reversible capacity, excellent cycling stability and rate capability (530 mA h g⁻¹ after 100 cycles at 500 mA g⁻¹ in LIBs, 259.5 mA h g⁻¹ after 50 cycles at the current density of 100 mA g⁻¹ in SIBs) compared with bare ZnSe in both lithium and sodium storage. The rGO plays an influential role in enhancing the conductivity of the nanocomposites, buffering the volume change and preventing the aggregation of ZnSe particles during the cycling process, thus securing the high structure stability and reversibility of the electrode.

ZnSe-rGO nanocomposite with ZnSe dispersed in reduced graphene oxides is studied as an anode for lithium and sodium ion batteries (LIBs/SIBs).