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Correction for ‘Dipyrrolyl-bis-sulfonamide chromophore based probe for anion recognition’ by Namdev V. Ghule et al., RSC Adv., 2014, 4, 27112–27115, DOI: 10.1039/C4RA04000G.The authors regret that an incorrect version of Fig. 1 was included in the original article. The correct version of Fig. 1 is presented below.Open in a separate windowFig. 1Color changes of receptor DPBS in chloroform upon addition of 5 equiv. of F−, Cl−, Br−, I−, H2PO4−, HSO4−, ClO4− and AcO− (tetrabutylammonium salts).The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers. 相似文献
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Correction for ‘Efficient removal of cobalt from aqueous solution using β-cyclodextrin modified graphene oxide’ by Wencheng Song et al., RSC Adv., 2013, 3, 9514–9521.The authors regret that Fig. 1 and and33 were incorrect in the original article. The SEM images of both GO and β-CD, and the Raman spectra of both, were confused with other samples. The correct versions of Fig. 1 and and33 are presented below.Open in a separate windowFig. 1SEM images of (a) GO and (b) β-CD-GO.Open in a separate windowFig. 2Raman spectra of GO and β-CD-GO.The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers. 相似文献
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Fei Liu Shaocan Dong Zhaoxiang Zhang Xiaqing Li Xiaodong Dai Yanping Xin Xuewu Wang Kun Liu Zhenhe Yuan Zheng Zheng 《RSC advances》2019,9(72):42438
Correction for ‘Synthesis of a well-dispersed CaFe2O4/g-C3N4/CNT composite towards the degradation of toxic water pollutants under visible light’ by Fei Liu et al., RSC Adv., 2019, 9, 25750–25761.The authors regret that mistakes were made during the preparation of Fig. 1 in the published article. In the original article, Fig. 1 presented XRD data for CaFe2O4/CNT, which inadvertently duplicated the data for CaFe2O4. In addition, the spectra in the original figure do not match with the relevant discussion of Fig. 1 (on page 25753–25754) which referred to XRD patterns for g-C3N4, CaFe2O4 and CaFe2O4/g-C3N4/CNT composite. The correct image for Fig. 1 is shown below but no changes are required to the associated discussion of Fig. 1.Open in a separate windowFig. 1XRD patterns of the as-prepared CaFe2O4 and CaFe2O4/g-C3N4/CNT composite.The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers. 相似文献
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Hong Xiang Qingkai Zhang Danqi Wang Shilin Xia Guijun Wang Guixin Zhang Hailong Chen Yingjie Wu Dong Shang 《RSC advances》2019,9(46):26548
Correction for ‘iTRAQ-based quantitative proteomic analysis for identification of biomarkers associated with emodin against severe acute pancreatitis in rats’ by Hong Xiang et al., RSC Adv., 2016, 6, 72447–72457.The authors regret that Fig. 2–4 were shown incorrectly in the original article. An incorrect section of the SAP group in the MPO-immunohistochemical staining (Fig. 2A) and HE staining (Fig. 3) experiments was used in error. In addition, Fig. 4 has been revised to show the zymogen granule, in order to better represent the ultrastructure of the pancreas. The correct versions of Fig. 2–4 are shown below.Open in a separate windowFig. 2Emodin down-regulated the MPO protein expression in pancreas of SAP rats. (A) Effect of emodin on MPO-immunopositive area (brown) staining of pancreatic tissue in SAP rats by immunohistochemical detection. (B) Effect of emodin on MPO-immunopositive area (red) staining of pancreatic tissue in SAP rats by immunofluorescence detection. Images are presented at 200× magnification. The data are presented as the mean ± SD, n = 6. **P < 0.01 versus SO; #P < 0.05 versus SAP, ##P < 0.01 versus SAP.Open in a separate windowFig. 3Emodin improved pancreatic histopathology of SAP rats. Effect of emodin on H&E staining of pancreatic tissue in SAP rats. Images are presented at 200× magnification. The data are presented as the mean ± SD, n = 6. **P < 0.01 versus SO; #P < 0.05 versus SAP, ##P < 0.01 versus SAP.Open in a separate windowFig. 4Emodin attenuated cellular structure changes in pancreas of SAP rats. Representative images of the cells’ ultrastructure in the SO (A), SAP (B), 60 mg kg−1 emodin (C), 30 mg kg−1 emodin (D) and 15 mg kg−1 emodin (E) groups. Images are presented at 25 000× magnification.The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers. 相似文献
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Correction for ‘A p-type multi-wall carbon nanotube/Te nanorod composite with enhanced thermoelectric performance’ by Dabin Park et al., RSC Adv., 2018, 8, 8739–8746.The authors regret that an incorrect version of Fig. 8 was included in the original article. The correct version of Fig. 8 is presented below.Open in a separate windowFig. 1FE-SEM images of MWCNT/Te nanorod composites with various MWCNT contents (a) 1 wt%, (b) 3 wt%, and (c) 5 wt%.The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers. 相似文献
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Formation of a new metastable fcc-MgH2 nanocrystalline phase upon mechanically-induced plastic deformation of MgH2 powders is reported. Our results have shown that cold rolling of mechanically reacted MgH2 powders for 200 passes introduced severe plastic deformation of the powders and led to formation of micro-lathes consisting of γ- and β-MgH2 phases. The cold rolled powders were subjected to different types of defects, exemplified by dislocations, stacking faults, and twinning upon high-energy ball milling. Long term ball milling (50 hours) destabilized β-MgH2 (the most stable phase) and γ-MgH2 (the metastable phase), leading to the formation of a new phase of face centered cubic structure (fcc). The lattice parameter of fcc-MgH2 phase was calculated and found to be 0.4436 nm. This discovered phase possessed high hydrogen storage capacity (6.6 wt%) and revealed excellent desorption kinetics (7 min) at 275 °C. We also demonstrated a cyclic-phase-transformation conducted between these three phases upon changing the ball milling time to 200 hours.Effect of mechanically-induced cold-rolling followed by high energy ball milling on cyclic phase transformation.The worldwide interest in MgH2 is attributed to the natural abundance of Mg metal, and its capability to store hydrogen up to 7.60 wt% (0.11 kg H2 L−1).1–3 Among the metal hydride family, MgH2 has been considered as a promising candidate for solid-state hydrogen storage.4–6 Despite the attractive properties of MgH2, and the simplicity for producing the compound on an industrial scale at ambient temperature via a reactive ball milling (RBM) technique,7,8 MgH2 is a very stable compound, and possesses slow kinetics of hydrogenation and dehydrogenation under 300 °C.9 Since the 1990s efforts have been made in order to destabilize MgH2 and improve its hydrogenation and dehydrogenation kinetics upon doping with a long list of catalysts.10–15 Most of the used catalysts showed significant enhancement of the kinetics behavior for MgH2, indexed by a decreasing decomposition temperature and a speed-up of its kinetics behavior.16–20 In spite of the beneficial effects obtained upon adding such foreign catalytic agents, they always lead to a dramatic decrease of the hydrogen storage capacity of MgH2.21,22Apart from doping MgH2 powders with catalysts, it has been experimentally demonstrated by some authors that changing the crystal structure of stable β-tetragonal MgH2 phase to a less stable phase of γ-orthorhombic MgH2 led to improve the gas uptake/release kinetics and decrease the hydrogenation temperature without drastic decreasing of the storage capacity.23–26 The β-to-γ phase transformations can be attained via severe plastic deformation (SPD)27 at ambient temperature by different approaches such as high-energy ball milling (HEBM),28 cold rolling (CRing),29 equal channel angular pressing (ECAP),30 and high pressure torsion (HPT).22,31 A common result of these employed techniques is the formation of nanocrystalline phase along with introducing high intensity defects, leading to increase of grain boundaries density. Presence of these defects in the lattice leads to create nucleation points for hydrogenation, where existence of large number of grain boundaries assists fast diffusion pathways for hydrogen.The present work has been addressed in part to study the effect of HEBM on the structure and decomposition properties of CRed MgH2 powders. Moreover, we aimed to investigate experimentally the possibility of formation a new metastable MgH2 phase rather than the reported g-phase and theoretically calculated δ and ε phases32 upon long term of milling.For the purpose of the present study, 5 g Mg (∼80 μm, 99.8 wt%) powder was balanced inside a He gas atmosphere-glove box and sealed together with fifty hardened steel-balls (11 mm in diameter), using ball-to-powder weight ratio as 40 : 1. The vial was then evacuated to the level of 10−3 bar and then filled with 50 bar of H2. The RBM process was carried out at room temperature, using planetary-type HEBM. After 25 hours (h) of RBM, the vial was open inside the glove box to discharge the powders. The powders were charged and sealed in a stainless steel (SUS304) tube (0.8 cm diameter and 20 cm length) inside the glove box. The tube contained MgH2 powders were severely CRed for different number of passes (1 to 200 passes), using two-drum type manual cold roller (11 cm wide × 5.5 cm rollers diameter). The as-CRed powders for 200 passes were then HEBMed under hydrogen gas for different milling time, in the range between 3 h to 50 h. All the samples were characterized by means of X-ray diffraction (XRD) with Cu radiation, field-emission high-resolution transmission electron microscope (FE-HRTEM) equipped with energy-dispersive X-ray spectroscopy (EDS), field emission scanning electron microscope (FE-SEM)/EDS, and differential scanning calorimeter (DSC). The absorption/desorption kinetics were investigated via Sievert''s method in different temperatures under hydrogen gas pressure in the range between 200 mbar to 8 bar.The XRD patterns of MgH2 powders obtained after 25 h of RBM is shown in Fig. 1a. Bragg peaks corresponding to starting hcp-Mg powders were hardly seen and replaced by sharp diffracted lines related to γ- and β-MgH2 phases, as elucidated in Fig. 1a. The SEM observations indicated the powders tendency to agglomerate, forming large aggregates upon CRing for 25 passes (Fig. 2a). Increasing the CRing passes to 200 times led to grain refinement, as implied by the broadening in the Bragg-peaks presented in Fig. 1b. At this stage, micro-bands with thickness of 143 μm were developed as a result of cold working generated during CRing process, as shown in Fig. 2b. The FE-HRTEM image of as-CRed powders for 200 passes indicated the development of lattice imperfections (e.g. stacking faults and deformation twins). This is implying the mechanically-induced SPD, as elucidated in ESI, Fig. S1.†Open in a separate windowFig. 1XRD patterns of MgH2 powders obtained after 25 h of RBMing (a), and then CRed for 200 passes (b). XRD pattern of CRed powders for 200 passes and then HEBMEd for 50 h is presented in (c).Open in a separate windowFig. 2FE-SEM micrographs taken at accelerated voltage of 1 kV of MgH2 powders obtained after 25 h of RBMing and then CRed for (a) 25, and (b) 200 passes.In order to study the effect of HEBM on the stability of cold-rolled MgH2 aggregates, the powders were charged into tool steel vial and ball milled under 50 bar of H2 for different milling time. The XRD pattern of CRed MgH2 powders obtained after 200 CR passes and then HEBMed for 50 h is displayed in Fig. 1c. Obviously, the Bragg peaks corresponding to γ- and β-MgH2 phases were completely vanished and replaced by new Bragg peaks of unreported phase, appeared at scattering angles (2θ) of, 35.034, 40.584, 58.758, 70.115, and 73.868 (Fig. 1c). XRD analysis indicated that this discovered MgH2 phase has face centered cubic structure (fcc) of space group, Fmm(225). The lattice parameter (ao) of this phase, calculated from (111) was 0.44361 nm. The as-synthesized fcc-MgH2 powders had fine spherical particles with sizes distributed in the range between 0.25 μm to 1 μm, as displayed in Fig. 3.Open in a separate windowFig. 3FE-SEM micrograph of MgH2 powders obtained after 25 h of RBM, CRed for 200 passes and finally HEBMed for 50 h. Peak position, 2θ (degree) Interplanar spacing, d (nm) Miller indexes (h,k,l) Lattice parameter, ao (nm) 35.034 0.25612 111 0.44361 40.584 0.22229 200 0.44458 58.758 0.15713 220 0.44443 70.115 0.13421 311 0.44512 73.868 0.12829 222 0.44441