In situ microwave-assisted solvothermal synthesis via morphological transformation of ZnCo2O4 3D nanoflowers and nanopetals to 1D nanowires for hybrid supercapacitors

Over recent decades, the conversion of energy and its storage have been in the lime light due to the depletion of fossil resources. The electrochemical energy storage devices like supercapacitors and batteries, and their materials and fabrication methods have been extensively evaluated, which is the best solution for the energy crisis. Herein, zinc cobaltite (ZnCo₂O₄; ZCO) nanostructures grown on nickel (Ni) foam by microwave-assisted solvothermal fabrication for hybrid supercapacitors are reported. Two different structures/samples, ZCO-15/Ni (nanoflowers) and ZCO-30/Ni (nanowires), were obtained by simply adjusting the reaction time. The electrochemical and physicochemical properties of the as-prepared samples were systematically determined. Particularly, ZCO-15/Ni exhibits excellent structural stability due to its dual morphologies: nanoflowers and nanopetals, and exhibits a large electroactive surface area (25.61 m² g⁻¹), pore diameter (48.38 nm), and robust adhesion to Ni foam, enabling ion and electron transport. ZCO-15/Ni foam electrode delivers an excellent specific capacity of 650.27 C g⁻¹ at 0.5 A g⁻¹ and admirable cyclic performance of 91% capacitance retention after 5000 cycles compared to ZCO-30/Ni electrode. The excellent electrochemical performance of ZCO makes them promising electrode materials for batteries, hybrid supercapacitors, and other alternative energy storage applications.

Microwave-assisted solvothermal fabrication of ZnCo₂O₄ nanostructures for energy storage applications like supercapacitors and batteries.     

Anchoring carbon layers and oxygen vacancies endow WO3−x/C electrode with high specific capacity and rate performance for supercapacitors

Herein, novel hierarchical carbon layer-anchored WO_3−x/C ultra-long nanowires were developed via a facile solvent-thermal treatment and a subsequent rapid carbonization process. The inner anchored carbon layers and abundant oxygen vacancies endowed the WO_3−x/C nanowire electrode with high conductivity, as measured with a single nanowire, which greatly enhanced the redox reaction active sites and rate performance. Surprisingly, the WO_3−x/C electrode exhibited outstanding specific capacitance of 1032.16 F g⁻¹ at the current density of 1 A g⁻¹ in a 2 M H₂SO₄ electrolyte and maintained the specific capacitance of 660 F g⁻¹ when the current density increased to 50 A g⁻¹. Significantly, the constructed WO_3−x/C//WO_3−x/C symmetric supercapacitors achieved specific capacitance of 243.84 F g⁻¹ at the current density of 0.5 A g⁻¹ and maintained the capacitance retention of 94.29% after 5000 charging/discharging cycles at the current density of 4 A g⁻¹. These excellent electrochemical performances resulted from the fascinating structure of the WO_3−x/C nanowires, showing a great potential for future energy storage applications.

A high-performance supercapacitor electrode comprising hierarchical carbon layer-anchored WO_3−x/C nanowires with inner abundant redox reaction active sites and numerous oxygen vacancies is presented.     

“Water-in-salt” electrolyte enhanced high voltage aqueous supercapacitor with carbon electrodes derived from biomass waste-ground grain hulls

To design high specific surface area and optimize the pore size distribution of materials, we employ a combination of carbonization and KOH activation to prepare activated carbon derived from ground grain hulls. The resulting carbon material at lower temperature (800, BSAC-A-800) exhibits a porous structure with a high specific surface area of 1037.6 m² g⁻¹ and a pore volume of 0.57 m³ g⁻¹. Due to the synergistic structural characteristics, BSAC-A-800 reveals preferable capacitive performance, showing a specific capacitance as high as 313.3 F g⁻¹ at 0.5 A g⁻¹, good rate performance (above 73%), and particularly stable cycling performance (99.1% capacitance retention after 10 000 cycles at a current density of 10 A g⁻¹). More importantly, the assembled symmetric supercapacitor using a water-in-salt electrolyte (17 m NaClO₄) with high discharge specific capacitance (59 F g⁻¹ at 0.5 A g⁻¹), high energy density (47.2 W h kg⁻¹) and high voltage (2.4 V) represents significant progress towards performance comparable to that of commercial salt-in-water electrolyte supercapacitors (with discharge specific capacitance of 50 F g⁻¹, energy densities of ∼28.1 W h kg⁻¹ and voltages of 2.0 V).

To design high specific surface area and optimize the pore size distribution of materials, we employ a combination of carbonization and KOH activation to prepare activated carbon derived from ground grain hulls.     

Fabrication of composite material of RuCo2O4 and graphene on nickel foam for supercapacitor electrodes

Supercapacitors are energy storage devices with the advantage of rapid charging and discharging, which need a higher specific capacitance and superior cycling stability. Hence, a composite material consisting of RuCo₂O₄ and reduced graphene oxide with a nanowire network structure was synthesized on nickel foam using a one-step hydrothermal method and annealing process. The nanowire network structure consists of nanowires with gaps that provide more active sites for electrochemical reactions and shorten the diffusion path of electrolyte ions. The prepared electrodes exhibit outstanding electrochemical performance with 2283 F g⁻¹ at 1 A g⁻¹. When the current density is 10 A g⁻¹, the specific capacitance of the electrodes is 1850 F g⁻¹, which maintains 81% of the initial specific capacitance. In addition, the prepared electrodes have a long-term cycling life with capacitance retention of 92.60% after 3000 cycles under the current density of 10 A g⁻¹. The composite material is a promising electrode material for high-performance supercapacitors.

The RuCo₂O₄/rGO@NF composite electrode has been prepared by a one-step hydrothermal method and annealing process, with high specific capacitance and excellent cycle stability.     

Facile preparation of partially reduced graphite oxide nanosheets as a binder-free electrode for supercapacitors

Preparation of graphene (GR) based electrode materials with excellent capacitive properties is of great importance to supercapacitors. Herein, we report a facile approach to prepare partially reduced graphite oxide (PRG) nanosheets by reducing graphite oxide (GO) using commercial Cu₂O powder as a reduction agent, moreover, we demonstrate that the PRG nanosheets can act as building blocks for assembling hydrogels (PRGH) and flexible film (PRGF). The obtained PRGH and PRGF can be directly used as binder-free electrodes for supercapacitors and give high specific capacitance (292 and 273 F g⁻¹ at a current density of 0.5 A g⁻¹ in a three-electrode system, respectively) due to the existence of oxygen-containing functional groups in PRG nanosheets. PRG also gives excellent rate ability and cycle stability. This study suggests a facile pathway to produce GR-based materials with excellent capacitive properties and is meaningful for flexible supercapacitors.

Partial reduced graphite oxide nanosheets with excellent capacitive property have been prepared using commercial Cu₂O powders as reduction agent.     

Enhanced capacitive performance by improving the graphitized structure in carbon aerogel microspheres

Herein, good electrical conductivity and high specific surface area carbon aerogel (CA) microspheres were synthesized by a facile and economical route using a high temperature carbonization and CO₂ activation method. The electroconductive graphitized structure of the CA microspheres could be easily improved by increasing the carbonization temperature. Then the CA microspheres were activated with CO₂ to increase the specific surface area of the electrode material for electric double layer capacitors (EDLC). The sample carbonized at 1500 °C for 0.5 h and CO₂ activated at 950 °C for 8 h showed an acceptable specific surface area and excellent cycle performance and rate capability for EDLC: 98% of the initial value of the capacitance was retained after 10 000 cycles, a specific capacitance of 121 F g⁻¹ at 0.2 A g⁻¹ and 101 F g⁻¹ at 2 A g⁻¹.

Carbon aerogels (CAs) microspheres with good electrical conductivity and high specific surface area were synthesized by high temperature carbonization and CO₂ activation method, which exhibit an enhanced capacitive performance in supercapacitors.     

One-pot synthesis of CoFe2O4/rGO hybrid hydrogels with 3D networks for high capacity electrochemical energy storage devices

CoFe₂O₄/reduced graphene oxide (CoFe₂O₄/rGO) hydrogel was synthesized in situ via a facile one-pot solvothermal approach. The three-dimensional (3D) network structure consists of well-dispersed CoFe₂O₄ nanoparticles on the surfaces of graphene sheets. As a binder-free electrode material for supercapacitors, the electrochemical properties of the CoFe₂O₄/rGO hybrid hydrogel can be easily adjusted by changing the concentration of the graphene oxide (GO) precursor solution. The results indicate that the hybrid material made using 3.5 mg mL⁻¹ GO solution exhibits an outstanding specific capacitance of 356 F g⁻¹ at 0.5 A g⁻¹, 68% higher than the pure CoFe₂O₄ counterpart (111 F g⁻¹ at 0.5 A g⁻¹), owing to the large specific surface area and good electric conductivity. Additionally, an electrochemical energy storage device based on CoFe₂O₄/rGO and rGO was assembled, which exhibits a high energy density of 17.84 W h kg⁻¹ at a power density of 650 W kg⁻¹ and an excellent cycling stability with 87% capacitance retention at 5 A g⁻¹ after 4000 cycles. This work takes one step further towards the development of 3D hybrid hydrogel supercapacitors and highlights their potential application in energy storage devices.

CoFe₂O₄/reduced graphene oxide (CoFe₂O₄/rGO) hydrogel was synthesized in situ via a facile one-pot solvothermal approach.     

Disodium citrate-assisted hydrothermal synthesis of V2O5 nanowires for high performance supercapacitors

Orthorhombic vanadium pentoxide (V₂O₅) nanowires with uniform morphology were successfully fabricated via a facile hydrothermal process. The effect of disodium citrate dosage on the crystallinity, morphology and electrochemical properties of the products was analyzed. Experimental results indicate that orthorhombic V₂O₅ nanowires with high crystallinity and diameter of about 20 nm can be obtained at 180 °C for 24 h when the dosage of disodium citrate is 0.236 g. Furthermore, the prepared V₂O₅ nanowires demonstrate a high specific capacitance of 528.2 F g⁻¹ at 0.5 A g⁻¹ and capacitance retention of 85% after 1000 galvanostatic charge/discharge cycles at 1 A g⁻¹ when used as supercapacitors electrode in 0.5 M K₂SO₄.

Orthorhombic vanadium pentoxide (V₂O₅) nanowires with uniform morphology were successfully fabricated via a facile hydrothermal process.     

N/S co-doped coal-based porous carbon spheres as electrode materials for high performance supercapacitors

N/S co-doped porous carbon spheres (NSPCSs) were prepared by a simple ultrasonic spray pyrolysis (USP) using the mixed solution of coal oxide and l-cysteine, and without a subsequent activation process. The surface properties of carbon materials have been successfully modified by the concurrent incorporation of N and S. So the capacitive performance of NSPCSs was greatly enhanced. It is used as a supercapacitor electrode to achieve a high specific capacitance of 308 F g⁻¹ at a current density of 1 A g⁻¹ and 90.2% capacitance retention even after 10 000 cycles at 5 A g⁻¹. These numerical results show that the supercapacitors based on coal-based carbon materials have great potential in high performance electrochemical energy storage.

N/S co-doped porous carbon spheres were prepared using one step strategy for high performance supercapacitors.     

Ionic-liquid-assisted one-pot synthesis of Cu2O nanoparticles/multi-walled carbon nanotube nanocomposite for high-performance asymmetric supercapacitors

Finding earth-abundant and high-performance electrode materials for supercapacitors is a demanding challenge in the energy storage field. Cuprous oxide (Cu₂O) has attracted increasing attention due to its theoretically high specific capacitance, however, the development of Cu₂O-based electrodes with superior capacitive performance is still challenging. We herein report a simple and effective ionic-liquid-assisted sputtering approach to synthesizing the Cu₂O nanoparticles/multi-walled carbon nanotubes (Cu₂O/MWCNTs) nanocomposite for high-performance asymmetric supercapacitors. The Cu₂O/MWCNTs nanocomposite delivers a high specific capacitance of 357 F g⁻¹, good rate capability and excellent capacitance retention of about 89% after 20 000 cycles at a current density of 10 A g⁻¹. The high performance is attributed to the uniform dispersion of small-sized Cu₂O nanoparticles on conductive MWCNTs, which offers plenty of redox active sites and thus improve the electron transfer efficiency. Oxygen vacancies are further introduced into Cu₂O by the NaBH₄ treatment, providing the oxygen-deficient Cu₂O/MWCNTs (r-Cu₂O/MWCNTs) nanocomposite with significantly improved specific capacitance (790 F g⁻¹) and cycling stability (∼93% after 20 000 cycles). The assembled asymmetric supercapacitor based on the r-Cu₂O/MWCNTs//activated carbon (AC) structure achieves a high energy density of 64.2 W h kg⁻¹ at 825.3 W kg⁻¹, and long cycling life. This work may form a foundation for the development of both high capacity and high energy density supercapacitors by showcasing the great potential of earth-abundant Cu-based electrode materials.

A one-pot room-temperature-ionic-liquid-assisted sputtering approach is designed to synthesize Cu₂O/MWCNTs nanocomposite with high capacitance and long cycling life due to synergistic effects of oxygen-deficient Cu₂O and conductive MWCNTs.     

NH4V4O10 nanobelts vertically grown on 3D TiN nanotube arrays as high-performance electrode materials of supercapacitors

High performance supercapacitor without binders has attracted wide attention as an energy storage device. In this work, novel NH₄V₄O₁₀ nanobelts were successfully synthesized and decorated into TiN nanotube arrays by a simple hydrothermal method. The as-prepared no-binder electrode hybrids exhibited excellent electrochemical performances with a specific capacitance of 749.0 F g⁻¹ at 5 mV s⁻¹ and a capacity retention of 85.7% after 200 cycles, which makes it an appealing candidate for electrode materials of supercapacitors.

NH₄V₄O₁₀ nanobelts were synthesized and decorated into TiN nanotube arrays as supercapacitor electrode with a specific capacitance of 749.0 F g⁻¹ at 5 mV s⁻¹ and a capacity retention of 85.7% after 200 cycles.     

Dual-doped hierarchical porous carbon derived from biomass for advanced supercapacitors and lithium ion batteries

Nowadays, designing heteroatom-doped porous carbons from inexpensive biomass raw materials is a very attractive topic. Herein, we propose a simple approach to prepare heteroatom-doped porous carbons by using nettle leaves as the precursor and KOH as the activating agent. The nettle leaf derived porous carbons possess high specific surface area (up to 1951 m² g⁻¹), large total pore volume (up to 1.374 cm³ g⁻¹), and high content of nitrogen and oxygen heteroatom doping (up to 17.85 at% combined). The obtained carbon as an electrode for symmetric supercapacitors with an ionic liquid electrolyte can offer a superior specific capacitance of 163 F g⁻¹ at 0.5 A g⁻¹ with a capacitance retention ratio as high as 67.5% at 100 A g⁻¹, and a low capacitance loss of 8% after 10 000 cycles. Besides, the as-built supercapacitor demonstrates a high specific energy of 50 W h kg⁻¹ at a specific power of 372 W kg⁻¹, and maintains 21 W h kg⁻¹ at the high power of 40 kW kg⁻¹. Moreover, the resultant carbon as a Li-ion battery anode delivers a high reversible capacity of 1262 mA h g⁻¹ at 0.1 A g⁻¹ and 730 mA h g⁻¹ at 0.5 A g⁻¹, and maintains a high capacity of 439 mA h g⁻¹ after 500 cycles at 1 A g⁻¹. These results demonstrate that the nettle leaf derived porous carbons offer great potential as electrodes for advanced supercapacitors and lithium ion batteries.

Nettle leaf derived nitrogen and oxygen dual-doped porous carbons exhibit great potential as anodes for high performance supercapacitors and lithium ion batteries.     

Diaminopyrene modified reduced graphene oxide as a novel electrode material for excellent performance supercapacitors

In this paper, novel reduced graphene oxide (rGO) composites (DAPrGOs) modified by diaminopyrene (DAP) were successfully synthesized via a facile solvothermal reaction method and used for supercapacitors. Compared with the pristine rGO, the DAPrGO1 electrode showed distinctly better performance (397.63 F g⁻¹vs. 80.29 F g⁻¹ of pristine rGO at 0.5 A g⁻¹) with small charge transfer resistance. When a symmetric device was fabricated using DAPrGO1 as the active material, it also exhibited a high capacitance of 82.70 F g⁻¹ at 0.5 A g⁻¹ with an energy density of 25.84 W h kg⁻¹ at a power density of 375 W kg⁻¹, and even offered a high power density of 7500 W kg⁻¹ (18.71 W h kg⁻¹) at 10 A g⁻¹. Moreover, the device possessed good electrochemical stability up to 20 000 cycles, implying promising applications in energy storage fields.

Schematic illustration of the facile synthesis process of DAPrGOs nanocomposites, Ragone plots and the superior cyclic stability of the assembled DAPrGO1//DAPrGO1 SSS.     

Hexadecyl trimethyl ammonium bromide assisted growth of NiCo2O4@reduced graphene oxide/ nickel foam nanoneedle arrays with enhanced performance for supercapacitor electrodes

NiCo₂O₄@reduced graphene oxide (rGO)/nickel foam (NF) composites were prepared via a hydrothermal method followed by annealing assisted by hexadecyl trimethyl ammonium bromide (CTAB). NiCo₂O₄@rGO/NF nanoneedle arrays grew directly on Ni foam (NF) without using a binder. The effect of graphene oxide (GO) concentration on the electrochemical properties of the composite was studied. When the GO concentration was 5 mg L⁻¹, the as-prepared NiCo₂O₄@rGO/NF reaches the highest specific capacitance of 1644 F g⁻¹ at a current density of 1 A g⁻¹. Even at 15 A g⁻¹, the specific capacitance is still 1167 F g⁻¹ and the capacitance retention rate is 89% after 10 000 cycles at 10 A g⁻¹. Furthermore, a NiCo₂O₄@rGO/NF//graphene hydrogel (GH) asymmetric supercapacitor cell (ASC) device was assembled and exhibits a high specific capacitance of 84.13 F g⁻¹ at 1 A g⁻¹ and excellent cycle stability (113% capacitance retention) after 10 000 charge/discharge cycles at 10 A g⁻¹. This provides potential for application in the field of supercapacitors due to the outstanding specific capacitance, rate performance and cycle stability of NiCo₂O₄@rGO/NF.

Anisotropic NiCo₂O₄ nanoneedle arrays grew directly on Ni foam in the presence of rGO via the hydrothermal method followed by annealing assisted by hexadecyl trimethyl ammonium bromide (CTAB).     

Facile synthesis of a two-dimensional layered Ni-MOF electrode material for high performance supercapacitors

Recently, various metal–organic framework (MOF)-based supercapacitors (SCs) have received much attention due to their porosity and well-defined structures. Yet poor conductivity and low capacitance in most MOF-based devices limit their wide application. As an electrode material, 2D MOFs exhibit a rapid electron transfer rate and high specific surface area due to their unique structures. In this work, a 2D layered Ni-MOF is synthesized through a simple solvothermal method and serves as an electrode material for SCs. Electrochemical studies show that the Ni-MOF exhibits low charge transfer resistance, excellent specific capacitance of 1668.7 F g⁻¹ at 2 A g⁻¹ and capacitance retention of 90.3% after 5000 cycles at 5 A g⁻¹. Moreover, Ni-MOF//AC asymmetric SCs are assembled. The device exhibits high specific capacitance of 161 F g⁻¹ at 0.2 A g⁻¹ and the energy density reached 57.29 W h kg⁻¹ at a power density of 160 W kg⁻¹. The high electrochemical performance can be ascribed to the inherent porosity of MOFs and the 2D layered structure.

A 2D Ni-MOF was synthesized by a hydrothermal method and used as an electrode for SCs.     

Oxygen functional groups improve the energy storage performances of graphene electrochemical supercapacitors

Graphene is a promising electrode material for supercapacitors due to its superior physical and chemical properties, but the influence of its oxygen functional groups on capacitive performance still remains somewhat uncertain. In this work, graphene sheets with different oxygen content have been prepared through thermal reduction in argon. Furthermore, oxidation and pore-forming treatment of graphene annealed at 800 °C are also performed to explore the important effect of oxygen functional groups. The effects of disorder degree, surface area and oxygen functional groups on the specific capacitance were explored systematically. The content and species of oxygen functional groups are found to be significant factors influencing the electrochemical supercapacitor performance of graphene electrodes. The specific capacitances of graphene annealed at 200, 400 and 800 °C are 201, 153 and 34 F g⁻¹, respectively. However, the specific capacitance of graphene reduced at 800 °C can be increased to 137 F g⁻¹ after nitric acid oxidation treatment, and is only 39 F g⁻¹ after pore forming on graphene surface, demonstrating that the oxygen functional groups can improve the capacitive performances of graphene electrochemical supercapacitors.

The content and species of oxygen functional groups are significant factors influencing the electrochemical supercapacitor performance of graphene electrodes.     

Advanced binder-free electrodes based on CoMn2O4@Co3O4 core/shell nanostructures for high-performance supercapacitors

Three-dimensional (3D) hierarchical CoMn₂O₄@Co₃O₄ core/shell nanoneedle/nanosheet arrays for high-performance supercapacitors were designed and synthesized on Ni foam by a two-step hydrothermal route. The hybrid nanostructure exhibits much more excellent capacitive behavior compared with either the pristine CoMn₂O₄ nanoneedle arrays alone or Co₃O₄ nanosheets alone. The formation of an interconnected pore hybrid system is quite beneficial for the facile electrolyte penetration and fast electron transport. The CoMn₂O₄@Co₃O₄ electrode can achieve a high specific capacitance of 1627 F g⁻¹ at 1 A g⁻¹ and 1376 F g⁻¹ at 10 A g⁻¹. In addition, an asymmetric supercapacitor (ASC) was assembled by using the CoMn₂O₄@Co₃O₄ core/shell hybrid nanostructure arrays on Ni foam as a positive electrode and activated carbon as a negative electrode in an aqueous 3 M KOH electrolyte. A specific capacitance of 125.8 F g⁻¹ at 1 A g⁻¹ (89.2% retention after 5000 charge/discharge cycles at a current density of 2 A g⁻¹) and a high energy density of 44.8 W h kg⁻¹ was obtained. The results indicate that the obtained unique integrated CoMn₂O₄@Co₃O₄ nanoarchitecture may show great promise as ASC electrodes for potential applications in energy storage.

CoMn₂O₄@Co₃O₄ core/shell arrays on Ni foam exhibit outstanding electrochemical performance for asymmetric supercapacitors with respect to high specific capacitance and high cycling stability.     

A general method to fabricate MoO3/C composites and porous C for asymmetric solid-state supercapacitors

MoO₃ is one of the most promising electrodes for high energy density supercapacitors due to its layered structure, which facilitates the insertion/removal of small ions. However, the commercial recognition of MoO₃-based electrodes has been hampered by their low electronic conductivity, poor structural stability and narrow working potential window. A MoO₃/C composite (MCs) has been synthesized by a polymerization method followed by calcination of the obtained hydrogel. The obtained MCs electrode exhibits remarkable electrochemical performance in both aqueous (432.5 F g⁻¹ at a current density of 0.5 A g⁻¹, 100% capacity retention after 10 000 cycles) and all-solid (220.5 F g⁻¹ at 0.5 A g⁻¹) systems with porous C as the positive electrode, demonstrating its potential in commercial utilization.

The obtained MCs electrode exhibits remarkable electrochemical performance in both aqueous and all-solid systems (220.5 F g⁻¹ at 0.5 A g⁻¹ with porous C as the positive electrode), certifying its excellent potential in supercapacitors.     

Nitrogen-doped hierarchical porous carbon derived from a chitosan/polyethylene glycol blend for high performance supercapacitors

Nitrogen-doped hierarchical porous carbon (NHPC) materials were synthesized by using a chitosan/polyethylene glycol (PEG) blend as raw material through a facile carbonization–activation process. In this method, chitosan was used as a nitrogen-containing carbon precursor, low cost and large-scale commercial PEG was employed as a porogen. The physical and electrochemical properties of the resultant NHPC were affected by the ratio of chitosan and PEG. The sample obtained by the ratio of 3 : 2 exhibits a high specific surface area (2269 m² g⁻¹), moderate nitrogen doping (3.22 at%) and optimized pore structure. It exhibits a high specific capacitance of 356 F g⁻¹ in 1 M H₂SO₄ and 271 F g⁻¹ in 2 M KOH at a current density of 1 A g⁻¹, and over 230 F g⁻¹ can be still retained at a high current density of 20 A g⁻¹ in both electrolytes. Additionally, the assembled symmetric supercapacitors show an excellent cycling stability with 94% (in 1 M H₂SO₄) and 97% (in 2 M KOH) retention after 10 000 cycles at 1 A g⁻¹. These results indicate that the chitosan/PEG blend can act as a novel and appropriate precursor to prepare low-cost NHPC materials for high-performance supercapacitors.

NHPC was prepared from a low cost chitosan/PEG blend by a facile method for high performance supercapacitors.     

Facile preparation of 3D porous agar-based heteroatom-doped carbon aerogels for high-energy density supercapacitors

The fabrication of heteroatom-doped porous carbon materials with high electrical conductivity and large specific surface area via an environmentally friendly route is critical and challenging. Herein, nitrogen and oxygen co-doped agar porous carbon (APC) was developed for supercapacitors via a one-step carbonization method with agar as the raw material and ammonia as the activator and nitrogen source. APC outperformed pectin porous carbon, tamarind porous carbon, and the previously reported carbon-based supercapacitors with a high capacitance retention of 72% even from 0.5 A g⁻¹ to 20 A g⁻¹ and excellent cycling stability in 6 M KOH solution (retained after 10 000 cycles) with a rate of over 98.5%. Furthermore, the APC electrode-based symmetric device exhibited an impressive energy density of 20.4 W h kg⁻¹ and an ultra-high power density of 449 W kg⁻¹ in 1 M Na₂SO₄ electrolyte together with excellent cycling stability (103.2% primary capacitance retentivity after 10 000 cycles). This study offers a novel method for the synthesis of nitrogen heteroatom-doped hierarchical porous carbon materials for performance-enhanced energy storage devices.

N and O co-doped agar porous carbon (APC) as electrode materials exhibit excellent performance. A respectable energy density of 20.4 W h kg⁻¹ and an ultra-high power density of 449 W kg⁻¹, as well as excellent cycle stability in 1 M Na₂SO₄ electrolyte.