Adsorption characteristics and inhibition effect of two Schiff base compounds on corrosion of mild steel in 0.5 M HCl solution: experimental,DFT studies,and Monte Carlo simulation

In this work, we report the synthesis of two Schiff bases of substituted gallic acid derivatives via amidation reaction and their characterization using ¹H-NMR spectroscopy to study their inhibition performance on the aggressive attack of HCl on mild steel (MS). The inhibitive performance was examined using chemical (weight loss) and electrochemical (Tafel and EIS) test methods. The results indicate that these derivatives significantly suppress the dissolution rate of mild steel via adsorption phenomena, which correlates to the Langmuir adsorption model. Tafel data display the mixed-type properties of these compounds and EIS results show that increasing Schiff base concentration not only leads to delaying the charge transfer (R_ct) of iron from 26.4 ohm cm⁻² to 227.7 ohm cm⁻² but also decreases the capacitance of the adsorbed double layer (C_dl) from 8.58 (F cm⁻²) × 10⁻⁵ to 2.55 (F cm⁻²) × 10⁻⁵. The inhibition efficiency percentage reaches the peak (90%) at optimum concentration of 250 ppm. The Monte Carlo simulations confirm the adsorption ability of the as-prepared compounds on the Fe (1 1 0) crystal. The SEM/EDX results revealed the presence of a protective film on the mild steel sample.

Structures of the synthesized Schiff bases inhibitor.     

Chromeno-carbonitriles as corrosion inhibitors for mild steel in acidic solution: electrochemical,surface and computational studies

Three novel N-hydrospiro-chromeno-carbonitriles namely, 2-amino-7,7-dimethyl-1′,3′,5-trioxo-1′,3′,5,6,7,8-hexahydrospiro[chromene-4,2′-indene]-3-carbonitrile (INH-1), 3-amino-7,7-dimethyl-2′,5-dioxo-5,6,7,8-tetrahydrospiro[chromene-4,3′-indoline]-2-carbonitrile (INH-2) and 3′-amino-7′,7′-dimethyl-2,5′-dioxo-5′,6′,7′,8′-tetrahydro-2H-spiro[acenaphthylene-1,4′-chromene]-2′-carbonitrile (INH-3) were synthesized using the principles of green chemistry and applied as corrosion inhibitors for mild steel in acidic medium using computational simulations and experimental methods. Experimental and computational studies revealed that inhibition effectiveness of the INHs followed the sequence: INH-3 (95.32%) > INH-2 (93.02%) > INH-1 (89.16%). The investigated compounds exhibit mixed-type corrosion inhibition characteristics by blocking the active sites on the surface of mild steel. EIS study revealed that the INHs behave as interface-type corrosion inhibitors. EDX analyses supported the adsorption mechanism of corrosion inhibition. A DFT study carried out for gaseous and aqueous forms of inhibitor molecules indicated that interactions of INHs with the mild steel surface involve charge transfer phenomenon or donor–acceptor interactions. A Monte Carlo (MC) simulation study revealed that only a fractional segment of the molecule lies parallel to the steel surface, since the INH molecules are not completely planar. The results of computational studies and experimental analyses were in good agreement.

Three novel N-hydrospiro-chromeno-carbonitriles, INH-1, INH-2 and INH-3 were synthesized using the principles of green chemistry and applied as corrosion inhibitors for mild steel in acidic medium using computational simulations and experimental methods.     

Effectiveness of some novel heterocyclic compounds as corrosion inhibitors for carbon steel in 1 M HCl using practical and theoretical methods

Corrosion of carbon steel is a major problem that destroys assists of industries and world steel installations; the importance of this work is to introduce new heterocyclic compounds as effective and low-cost corrosion inhibitors. Three compounds of carbohydrazide derivatives, namely: 5-amino-N′-((2-methoxynaphthalen-1-yl)methylene)isoxazole-4-carbohydrazide (H4), 2,4-diamino-N′-((2-methoxy-naphthalene-1-yl)methylene) pyrimidine-5-carbohydrazide (H5) and N′-((2-methoxynaphthalen-1-yl)methylene)-7,7-dimethyl-2,5-dioxo-4a,5,6,7,8,8a-hexahydro-2H-chromene-3-carbohydrazide (H6) were used to examine the efficacy of corrosion of carbon steel in 1 M hydrochloric acid solution. This corrosion efficacy was detected by utilizing various methods including electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), weight loss measurements (WL), surface morphology analyses by atomic force microscopy (AFM), quantum chemical computations based on density functional theory (DFT) and molecular dynamics (MD) simulation. The results indicated that these compounds act as mixed type inhibitors i.e. reduce the corrosion rate of carbon steel due to the formation of a stable protective film on the metal surface and reduce the cathodic hydrogen evolution reaction. As confirmed from impedance, carbohydrazide derivatives molecules are adsorbed physically on metal surface with higher corrosion efficacy reached to (81.5–95.2%) at 20 × 10⁻⁶ M concentration at room temperature. Temkin isotherm model is the most acceptable one to describe the carbohydrazide derivative molecules adsorption on the surface of carbon steel. Protection mechanism was supported by quantum chemical analyses and Monte Carlo modeling techniques. The theoretical calculations support the experimental results obtained. This proves the use of carbohydrazide derivatives as a very effective inhibitors against the corrosion of carbon steel in acidic media.

Corrosion of carbon steel is a major problem that destroys assists of industries and world steel installations; the importance of this work is to introduce new heterocyclic compounds as effective and low-cost corrosion inhibitors.     

Inhibition performance of halogen-substituted benzaldehyde thiosemicarbazones as corrosion inhibitors for mild steel in hydrochloric acid solution

Halogen-substituted benzaldehyde thiosemicarbazone derivatives were synthesized and their inhibition performance for mild steel in hydrochloric acid solution were investigated systematically using weight loss measurements, electrochemical techniques, scanning electron microscopy and quantum chemical calculations. Results of weight loss measurements indicated that all these compounds exhibited excellent inhibition performance and the inhibition efficiency increased with increasing inhibitor concentrations. Polarization results revealed that the synthesized benzaldehyde thiosemicarbazone derivatives were mixed-type inhibitors. Adsorption of these compounds onto a mild steel surface was mainly chemisorption and complied with the Langmuir adsorption isotherms. Both theoretical calculations and experimental measurements suggested that the inhibition efficiency of these compounds followed the order of Br-BT > Cl-BT > F-BT > H-BT.

Halogen-substituted benzaldehyde thiosemicarbazone derivatives were synthesized and applied as corrosion inhibitors for mild steel in 1 M HCl using experimental and computational methods.     

Experimental and theoretical investigations of four amine derivatives as effective corrosion inhibitors for mild steel in HCl medium

Four amine derivative compounds were synthesized: 2-[(phenylamino)methyl]phenol, 2-{[(4-hydroxyphenyl)amino]methyl}phenol, 2-[(2-hydroxybenzyl)amino]benzonitrile and 2-{[(3-chlorophenyl)amino]methyl}phenol. The structure of the organic molecules was confirmed by FT-IR, ¹³C NMR and ¹H NMR spectroscopy analyses. Their corrosion inhibition performances on mild steel in 1 M HCl were investigated using electrochemical measurements and surface analysis. Scanning electron microscopy analysis confirms the presence on the mild steel surface of a protective film of the as-prepared organic compounds, which depends on the substituent groups. Moreover, density functional theory and molecular dynamics simulation were employed in order to determine the adsorption mechanism and the position of amine derivative molecules towards the mild steel surface in an aggressive solution and to confirm the electrochemical results. The inhibition efficiency (IE) decreases with a decrease in concentration and the adsorption obeyed the Langmuir isotherm. The substitution of the OH group on the aromatic ring by Cl or CN increases IE to 90.23 and 92.56%, respectively. Molecular dynamics simulations attested that the four molecules were adsorbed on the Fe (110) surface in a flat position in the presence of water and HCl with high interaction between the different groups of the inhibitors and mild steel surface.

Four amine derivative compounds were synthesized and used as organic corrosion inhibitors.     

Synthesis,characterization and electrochemical analysis of cysteine modified polymers for corrosion inhibition of mild steel in aqueous 1 M HCl

Butler''s cyclopolymerization protocol was used to synthesize homo and copolymers of cysteine residues and diallyldimethylammonium chloride (DADMAC) using water as a solvent and excellent yields were obtained. The structural composition of the polymers was determined using nuclear magnetic resonance (NMR) and Fourier-transform infrared (FT-IR) spectroscopies. The thermal stability of the synthesized polymers was determined using thermogravimetric analysis (TGA). The corrosion efficiencies and adsorption characteristics of these polymers on mild steel were evaluated using gravimetric weight loss and potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The copolymers of cysteine residues and DADMAC exhibited excellent inhibition efficiencies in arresting mild steel corrosion in 1 M hydrochloric acid (HCl) at 60 °C. The best fitted Langmuir, Temkin and Freundlich adsorption isotherms suggested that the adsorption process occurs through chemisorption and physisorption. The surface morphology of mild steel in the presence or absence of polymers was determined using atomic force microscopy (AFM), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS). This systematic study might provide a way to design new inhibitor compounds that could be beneficial in the field of biomedical science as well as for anti-corrosion applications.

Mild steel framework embedded in corrosion inhibiting structural motifs.     

Isoxazolidine derivatives as corrosion inhibitors for low carbon steel in HCl solution: experimental,theoretical and effect of KI studies

Two isoxazolidine derivatives namely 5-(benzo[d][1,3]dioxol-5-ylmethyl)-2-tetradecyl isoxazolidine (BDMTI) and 5-(4-hydroxy-3-methoxybenzyl)-2-tetradecyl isoxazolidine (HMBTI) were synthesized and characterized using FTIR, C-NMR, H-NMR, and elemental analysis. The synthesized compounds were evaluated as corrosion inhibitors for API 5L X60 steel in 1 M HCl in the temperature range of 25–60 °C using gravimetric and electrochemical (Electrochemical Impedance Spectroscopy (EIS), Potentiodynamic Polarization (PDP) and Linear Polarization Resistance (LPR)) techniques. The effect of addition of a small amount of iodide ions on the corrosion inhibition performance of the compounds was also assessed. In addition, quantum chemical calculations and Monte Carlo simulations were employed to correlate the electronic properties of the compounds with the corrosion inhibition effect as well as to evaluate the adsorption/binding of the inhibitor molecules on the steel surface. Experimental results show that the two compounds inhibited the corrosion of carbon steel in an acid environment with HMBTI showing superior performance. The corrosion inhibition effect was found to be dependent on the inhibitors'' concentration and temperature. Addition of iodide ions improves the inhibition efficiency considerably due to co-adsorption of the iodide ions and the inhibitors on the steel surface which was competitive in nature as confirmed from the synergistic parameter (S₁) which was less than unity at higher temperature. Experimental and theoretical results are in good agreement.

Two isoxazolidine derivatives (BDMTI and HMBTI) were synthesized and characterized using FTIR, C-NMR, H-NMR and elemental analysis and evaluated as corrosion inhibitors for X60 steel in 1 M HCl solution.     

Rheological,electrochemical, surface,DFT and molecular dynamics simulation studies on the anticorrosive properties of new epoxy monomer compound for steel in 1 M HCl solution

A new epoxy monomer, namely, tetraglycidyl-1,2-aminobenzamide (ER), was synthesized by condensation of the amines with epichlorohydrin in a basic medium. The obtained epoxy monomer was characterized by FT-IR and ¹H NMR spectroscopy. Rheological properties of this monomer were determined using an advanced rheometer. Subsequently, the synthesized ER monomer was investigated as corrosion inhibitor for carbon steel in 1 M HCl solution. The adsorption properties of ER were analyzed by electrochemical, surface investigation and theoretical computational studies using DFT and molecular dynamics (MD). Results showed a high dependence of the viscosity of ER on temperature and concentration, and also, that ER has better inhibition performance. A good agreement between the results derived from computational (MD and DFT) and experimental methods was observed. The thermodynamic parameters, along with the kinetic parameters, showed that the adsorption of ER molecules onto carbon steel surface obeyed the Langmuir isotherm model, and the adsorption at metal–electrolyte interfaces involved both chemical and physical adsorption, but predominantly chemisorption mechanism.

A new epoxy monomer, namely, tetraglycidyl-1,2-aminobenzamide (ER), was synthesized by condensation of the amines with epichlorohydrin in a basic medium.     

Nitrogen and sulfur Co-doped carbon dots as ecofriendly and effective corrosion inhibitors for Q235 carbon steel in 1 M HCl solution

Novel nitrogen and sulfur co-doped carbon dots (N,S-CDs) were synthesized via a hydrothermal procedure using citric acid (CA) and thiourea (TU) as precursors, and the corresponding corrosion protection performance was first investigated for Q235 carbon steel in 1 M HCl solution. Experimental results indicated that N,S-CDs as mixed-type corrosion inhibitors could effectively prevent Q235 carbon steel from corrosion in 1 M HCl solution, and the corrosion inhibition efficiency was improved with the increase in N,S-CD concentration. The maximum value was achieved at 400 ppm of N,S-CDs at 25 °C, which was approximately 96.6%, 94.6% and 90.55%, according to the potentiodynamic polarization curves, EIS results and weight loss measurement, respectively. Additionally, with the temperature ranging from 25 to 55 °C, the inhibition efficiency obtained from the weight loss measurement was enhanced from 90.55% to 94.04%. Such superior inhibition effect was assigned to the physisorption and chemisorption of N,S-CDs on the Q235 carbon steel surface, which was also be confirmed by XPS analysis. The adsorption of N,S-CDs onto a steel substrate conformed to the Langmuir adsorption isotherm.

N,S-CDs as ecofriendly inhibitors effectively inhibit the acid corrosion of carbon steel with an inhibition efficiency of 96.6%.     

Experimental and DFT studies on the ultrasonic energy-assisted extraction of the phytochemicals of Catharanthus roseus as green corrosion inhibitors for mild steel in NaCl medium

Catharanthus roseus (Apocynaceae family) extract is rich in organic phytochemicals such as alkaloids, polyphenolic compounds, and flavonoids. It contains several functional entities such as fused heterocycles, and hydroxyl and carbonyl groups, which could be useful for corrosion inhibition of mild steel in NaCl environments. In the present work, ultrasonic energy was used to obtain the ethanolic extracts of root and stem which were then tested as corrosion inhibitors for mild steel in the presence of 3.5% NaCl. The corrosion inhibition process was studied by UV-visible spectroscopy, Fourier transform infrared spectroscopy, atomic force microscopy, weight loss, and electrochemical methods. After immersing in the corrosive medium, the microstructures of mild steel were investigated by scanning electron microscopy, X-ray diffraction, and ellipsometry. The extract of C. roseus showed excellent adsorption on mild steel surface as confirmed by DFT calculations. The results indicate that the extract of C. roseus acts as a mixed type corrosion inhibitor, where the stem extract is the most efficient inhibitor in 3.5% NaCl solution possibly due to the higher active area of stem phytochemicals.

C. roseus phytochemicals are physisorbed on the 111 Fe surface, and the oxygen non-bonding electron chemisorbed on the polarized state 111 Fe surface.     

The performance of three novel Gemini surfactants as inhibitors for acid steel corrosion: experimental and theoretical studies

Adipic acid was used to synthesize three nonionic Gemini surfactants containing different numbers of propylene oxide units in their structures. The produced surfactants have been characterized employing FTIR and 1H-NMR spectra. Some of the physical properties of them, namely, surface tension, maximum surface excess concentration, surface pressure, critical micelle concentration, and the minimal area of the surface taken by a single molecule, were computed. The inhibitory effect of the synthesized surfactants on the corrosion of C-steel (C45) in 1.0 M HCl solution was studied. Gravimetric and electrochemical methods were used for corrosion rate measurements. The outcomes acquired from the used methods showed that every one of the three surfactants works as a strong inhibitor for steel acidic corrosion. By raising surfactant concentration and exposure time, the inhibition proficiency improves. The inhibition efficiency exceeded 90% for the three compounds. The higher the propylene oxide units contained in the surfactant molecule the higher is its inhibition efficiency. Based on the findings, a mechanism for inhibitory action was proposed. Moreover, the density functional theory (DFT) and molecular electrostatic potential (MEP) were investigated for the three inhibitors. The calculated parameters were correlated with the inhibition efficiency.

Adipic acid was used to synthesize three nonionic Gemini surfactants containing different numbers of propylene oxide units in their structures.     

Experimental and theoretical investigations of benzoic acid derivatives as corrosion inhibitors for AISI 316 stainless steel in hydrochloric acid medium: DFT and Monte Carlo simulations on the Fe (110) surface

The inhibition efficiency of benzoic acid (C1), para-hydroxybenzoic acid (C2), and 3,4-dihydroxybenzoic acid (C3) towards enhancing the corrosion resistance of austenitic AISI 316 stainless steel (SS) has been evaluated in 0.5 M HCl using weight loss (WL), open circuit potential (OCP), potentiodynamic polarization method, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM) analysis. The results obtained from the different experimental techniques were consistent and showed that the inhibition efficiency of these inhibitors increased with the increase in concentration in this order C3 > C2 > C1. In addition, the results of the weight loss measurements showed that these inhibitors followed the Villamil isotherm. Quantum chemical calculations and Monte Carlo simulations have also been used for further insight into the adsorption mechanism of the inhibitor molecules on Fe (110). The quantum chemical parameters have been calculated by density functional theory (DFT) at the B3LYP level of theory with 6-31G+(2d,p) and 6-31G++(2d,p) basis sets in gas and aqueous phase. Parameters such as the lowest unoccupied (E_LUMO) and highest occupied (E_HOMO) molecular orbital energies, energy gap (ΔE), chemical hardness (η), softness (σ), electronegativity (χ), electrophilicity (ω), and nucleophilicity (ε) were calculated and showed the anti-corrosive properties of C1, C2 and C3. Moreover, theoretical vibrational spectra were calculated to exhibit the functional hydroxyl groups (OH) in the studied compounds. In agreement with the experimental data, the theoretical results showed that the order of inhibition efficiency was C3 > C2 > C1.

The corrosion inhibition efficiencies of benzoic acid (C1), para-hydroxybenzoic acid (C2), and 3,4-dihydroxybenzoic acid (C3) have been evaluated in 0.5 M HCl toward protecting AISI 316 stainless steel (SS).     

Natural parsley oil as a green and safe inhibitor for corrosion of X80 carbon steel in 0.5 M H2SO4 solution: a chemical,electrochemical, DFT and MC simulation approach

This work focuses on the use of natural parsley oil as a safe, eco-friendly and cost-effective inhibitor for dissolution of X80 carbon steel (X80CS) in 0.5 M H₂SO₄ solution. Electrochemical and chemical measurements and theoretical studies were utilized to determine the inhibitory vigor of parsley oil. The inhibition efficacy increases with an increase in the parsley oil concentration and a decrease in temperature. It reached 95.68% at 450 ppm of parsley oil. The inhibition process is explained by spontaneous adsorption of the oil on the X80CS. Adsorption is described by the Langmuir isotherm model. The polarization data demonstrate that parsley oil is categorized as a mixed inhibitor with a dominant control of the cathodic reaction. Parsley oil inhibits the pitting corrosion of X80CS in the presence of NaCl solution by moving the pitting potential to a more positive mode indicating protection against pitting attack. The thermodynamic parameters for activation and adsorption were computed and interpreted. The four chemical components in natural parsley oil were examined using density functional theory (DFT). Monte Carlo (MC) simulation was performed to study the adsorption of parsley oil on the X80CS surface. The outcomes confirmed that the Apiole molecule is the most effective in the inhibition process.

This work focuses on the use of natural parsley oil as a safe, eco-friendly and cost-effective inhibitor for dissolution of X80 carbon steel (X80CS) in 0.5 M H₂SO₄ solution.     

Adsorption and anti-corrosion characteristics of vanillin Schiff bases on mild steel in 1 M HCl: experimental and theoretical study

Herein, two Schiff base derivatives of vanillin and divanillin with 2-picolylamine, namely, 2-methoxy-4-((pyridin-2-ylmethylimino)methyl)phenol (compound A) and 3,3′-dimethoxy-5,5′-bis-((pyridin-2-ylmethylimino)methyl)-[1,1′-biphenyl]-2,2′-diol (compound B), respectively, were synthesized. Additionally, their adsorption characteristics and corrosion inhibition behavior were compared for mild steel in 1 M HCl using electrochemical impedance spectroscopy, potentiodynamic polarization and weight loss methods. Compound B was found to impart a better anti-corrosive effect (around 95% inhibition efficiency at 313 K) than compound A. The inhibitors act as effective mixed-type inhibitors and exhibit Langmuir-type adsorption behaviour. The kinetic–thermodynamic parameters together with the data obtained from density functional theory (DFT) and molecular dynamics (MD) simulations illustrate the mechanism of corrosion and mode of adsorption of both inhibitors on the metal surface. The better corrosion mitigation propensity of the dimeric form of the inhibitor (compound B) over the monomeric form (compound A) was tested experimentally and explained according to the theoretical data.

Two Schiff base derivatives of vanillin and divanillin with 2-picolylamine are synthesized and their anti-corrosive propensity for mild steel in aqueous HCl are compared.     

Novel adamantyl clubbed iminothiazolidinones as promising elastase inhibitors: design,synthesis, molecular docking,ADMET and DFT studies

Porcine Pancreatic Elastase (PPE) is a serine protease that is homologous to trypsin and chymotrypsin that are involved in various pathologies like inflammatory disease, Chronic Obstructive Pulmonary Disease (COPD), acute respiratory distress syndrome, cystic fibrosis, and atherosclerosis. PPE if remained uninhibited would lead to digestion of important connective tissue. We developed new structurally diverse series of adamantyl-iminothiazolidinone hybrids to divulge elastase inhibition assay. To identify potent derivatives, in silico screening was conducted and in vitro studies disclosed that the compounds 5a, 5f, 5g, and 5h showed excellent binding energies and low IC₅₀ values. In silico studies including molecular docking, DFT studies (using the B3LYP/SVP basis set in the gas phase) drug likeness scores and molecular dynamic simulation studies were conducted to evaluate protein–ligand interactions and to determine the stability of top ranked conformation. In silico studies further supported the results of in vitro experiments and suggest these derivatives as novel inhibitors of elastase enzyme.

Structurally diverse adamantyl-iminothiazolidinone conjugates were synthesized, evaluated for elastase inhibition, and subjected to in silico ADMET prediction. The inhibition studies revealed compounds 5a, 5f, 5g, and 5h to show significant activity.     

Functional polyaspartic acid derivatives as eco-friendly corrosion inhibitors for mild steel in 0.5 M H2SO4 solution

To improve the corrosion inhibition efficiency of eco-friendly polyaspartic acid (PASP) for mild steel in acidic solutions, PASP/N-(3-aminopropyl)imidazole (PD-1) and PASP/N-(3-aminopropyl)-imidazole-co-n-dodecylamine (PD-2) were chemically synthesized by the facile ring-opening reaction of polysuccinimide. Inhibition efficiencies of PD-1 and PD-2 for mild steel in a 0.5 M H₂SO₄ solution were investigated by electrochemical measurements (electrochemical impedance and polarization) and the weight loss method. In comparison with PASP, PD-1 and PD-2 show improved inhibition efficiencies due to the functional groups. In particular, PD-2 shows superior corrosion inhibition capacity, and the efficiency is up to 94% at a relatively low concentration of 100 mg L⁻¹ at 298 K, as determined by potentiodynamic polarization measurements. Surface analysis of mild steel with PD-2 as an inhibitor clearly indicates that the inhibitor molecules adsorb on the steel surface and efficiently inhibit the corrosion of mild steel. The present work provides very meaningful results in designing and preparing new polymer inhibitors with high inhibition efficiency.

To improve the corrosion inhibition efficiency of polyaspartic acid (PASP) for mild steel in acidic solutions, PASP/N-(3-aminopropyl)imidazole (PD-1) and PASP/N-(3-aminopropyl)-imidazole-co-n-dodecylamine (PD-2) were synthesized.     

Bis-Schiff bases of 2,2′-dibromobenzidine as efficient corrosion inhibitors for mild steel in acidic medium

In this work, three new bis-Schiff bases, namely 1,1′-(2,2′-dibromo-[1,1′-biphenyl]-4,4′-diyl)bis(N-phenylmethanimine) (BNSB01), 1,1′-(2,2′-dibromo-[1,1′-biphenyl]-4,4′-diyl)bis(N-(4-bromophenyl)methanimine) (BNSB02) and 4,4′-(((2,2′-dibromo-[1,1′-biphenyl]-4,4′-diyl)bis(methanylylidene))bis(azanylylidene))diphenol (BNSB03), were synthesized. These Schiff bases were evaluated for their corrosion inhibition ability on mild steel specimens in 0.5 M HCl by using electrochemical and weight loss techniques. The inhibition performance was found to increase with an increase in the inhibitor concentration and decrease with an increase in temperature. The results revealed that the synthesized compounds followed the Langmuir isotherm model and were efficient mixed-type inhibitors. The electrochemical impedance studies also indicated that with a rise in the concentration of inhibitors, the charge transfer resistance increased. The surface morphology of the inhibited and uninhibited specimens was examined using scanning electron microscopy (SEM). The efficiency of the compounds was in the order BNSB02 > BNSB03 > BNSB01. All the results obtained were in good correlation with each other.

The inhibitory effect of three new bis-Schiff bases on mild steel corrosion in 0.5 M HCl was studied by the weight loss method and the electrochemical method.     

Synthesis and characterization of novel dicarbohydrazide derivatives with electrochemical and theoretical approaches as potential corrosion inhibitors for N80 steel in a 3.5% NaCl solution

Two novel ethanoanthracene-11,12-dicarbohydrazide derivatives N′¹¹,N′¹²-bis((Z)-4-hydroxybenzylidene)-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarbohydrazide (H₂HEH) and N′¹¹,N′¹²-bis((Z)-4-methoxybenzylidene)-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarbohydrazide (H₂MEH) were synthesized and characterized by FT-IR spectroscopy, electronic spectra, and NMR spectroscopy. These two derivatives as novel anticorrosion inhibitors for N80 steel in a 3.5% NaCl solution were studied using electrochemical techniques including potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS), and electrochemical frequency modulation (EFM). Corrosion parameters and adsorption isotherms were determined from current–potential diagrams (i.e., Tafel slopes). The impact of temperature and inhibitor concentration on the corrosion performance was studied using the PP method. The PP results suggested mixed-type inhibitors. The inhibition prohibition increased and decreased when the dose was increased and the temperature was increased, respectively. The adsorption of the hydrazides on the N80 exterior followed the Langmuir isotherm. The maximum inhibition proficiency for H₂MEH and H₂HEH were 93.3% and 92.2%, respectively, at 1 × 10⁻⁴ M. Moreover, the investigated surface was studied with the synthesized compounds through X-ray photoelectron spectroscopy (XPS) to confirm the construction of an adsorbed shielding barrier. An evident association was established between the corrosion inhibition proficiency and theoretical variables acquired using the density functional theory (DFT) method and Monte Carlo (MC) simulations. The experimental data were in good agreement with the theoretical results.

Two novel dicarbohydrazide derivatives (H₂HEH) and (H₂MEH) were synthesized and tested as corrosion inhibitors for N80 steel in 3.5% NaCl solution via electrochemical and theoretical approaches.