Application of Activated Carbon Banana Peel Coated with Al2O3-Chitosan for the Adsorptive Removal of Lead and Cadmium from Wastewater

This study was aimed at evaluating the adsorption capacity of novel banana peel activated carbon (BPAC) modified with Al₃O₂@chitosan for the removal of cadmium (Cd²⁺) and lead (Pb²⁺) from wastewater. Characterization techniques such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transformed infrared (FTIR) spectroscopy, and Brunauer–Emmett–Teller analysis confirmed the synthesized BPAC@Al₃O₂@chitosan composite material. The univariate approach was used to study the influence of different experimental parameters (such as adsorbent mass, sample pH, and contact time) that affects simultaneous removal of Cd²⁺ and Pb²⁺ ions. Kinetic results showed that adsorption favored the pseudo-second-order kinetic model, whereas the adsorption of Cd²⁺ and Pb²⁺ was best described by the Langmuir model and the adsorption capacity for Cd²⁺ and Pb²⁺ was 46.9 mg g⁻¹ and 57.1 mg g⁻¹, respectively, for monolayer adsorption. It was shown the BPAC composite can be re-used until the third cycle of adsorption–desorption (% Re > 80). Based on the obtained results, it can be concluded that the prepared BPAC@Al₃O₂@chitosan composite material is cost effective, as it is generated from waste banana peels and can be re-used. In addition, the prepared material was able to remove Cd²⁺ and Pb²⁺ up to 99.9%.     

Adsorption of Heavy Metals Ions from Mining Metallurgical Tailings Leachate Using a Shell-Based Adsorbent: Characterization,Kinetics and Isotherm Studies

This study defines the optimal parameters that allow the use of waste mollusk shells (WS) to remove heavy metals from three mining and metallurgical leachates. First, the influence of parameters such as pH, contact time, initial metal concentration, adsorbent dose and the presence of co-ions in Cu²⁺, Cd²⁺, Zn²⁺ and Ni²⁺ adsorption was investigated in synthetic solutions. Metal uptake was found to be dependent on the initial pH of the solution, the removal rate increasing with the increase in pH, showing the highest affinity at pH 5–6. The removal efficiency at lower concentrations was greater than at higher values. The competitive adsorption results on bimetallic solutions showed that the adsorption capacity of the sorbent was restricted by the presence of other ions and suppressed the uptake of heavy metals compared to the single adsorption. Cu²⁺ was the metal that most inhibited the removal of Cd²⁺, Zn²⁺ and Ni²⁺. The Langmuir isotherm provided the best fit to the experimental data for Cu²⁺, Cd²⁺ and Zn²⁺ and the Freundlich isotherm, for Ni²⁺. The data showed that the maximum adsorption capacity a_max for Zn²⁺, Cd²⁺ and Cu²⁺, was 526.32 mg g⁻¹, 555.56 mg g⁻¹ and 769.23 mg g⁻¹, respectively. Sorption kinetics data best fit the pseudo-second-order kinetic model. The results obtained in the tests with three mining and metallurgical leachates showed that WS were effective in simultaneously removing several heavy metals ions such as Cu, Ni, Zn, Cd, Ni, As and Se.     

Recycling of Waste Toner Powder as Adsorbent to Remove Aqueous Heavy Metals

The removal of Cd²⁺, Zn²⁺ and Ni²⁺ from metal solutions onto waste toner power (WTP) was investigated. The influence of parameters such as pH, contact time, initial metal concentration and adsorbent dosage was studied in batch adsorption experiments. Batch equilibrium experiments showed that the highest removal efficiency for Zn²⁺ and Cd²⁺ occurs at pH 7, while pH 5 is the most suitable for Ni²⁺ removal. The amount of metal removed (mg/g) improved when increasing the initial concentration, and sorption of heavy metals reached equilibrium in 24 h. Metals’ uptake increased with increasing adsorbent dosage. The adsorption isotherms of Zn²⁺, Cd²⁺ and Ni²⁺ onto WTP fit the Langmuir better than the Freundlich model with correlation coefficient R² values ranging from 0.998 to 0.968 and 0.989 to 0.881, respectively. The data showed that the maximum adsorption capacity of heavy metals, a_max, ranged from 2.42 to 1.61 mg/g, from 6.22 to 2.01 mg/g and from 3.49 to 2.56 mg/g for Ni²⁺, Zn²⁺ and Cd²⁺, respectively, with the three WTPs used in this study. This adsorbent can potentially be used to remove metal ions from wastewater.     

Kinetics and Thermodynamics Studies for Cadmium (II) Adsorption onto Functionalized Chitosan with Hexa-Decyl-Trimethyl-Ammonium Chloride

A new adsorbent material was obtained by functionalization of chitosan with hexa-decyl-trimethyl-ammonium chloride and tested as an adsorbent for Cd(II) ions. Functionalization is due to the desire to improve the adsorbent properties of the biopolymer used for removal of metallic ions. Obtained material was characterized by FTIR (Fourier Transform InfraRed spectroscopy), SEM (Scanning Electron Microscopy) and EDX (Energy dispersive X-ray Spectroscopy). To prove the Cd(II) adsorption mechanism, we performed adsorption tests determining influence of biopolymer ratio, pH, contact time, temperature and Cd(II) initial concentration. Obtained experimental data were modeled using two kinetics models: pseudo-first-order and pseudo-second-order models. Cd(II) adsorption kinetics was better described by pseudo-second-order model. Further, experimental data were fitted using three different adsorption isotherms: Langmuir, Freundlich and Sips. The studied adsorption process is well described by the Sips adsorption isotherm, when the maximum adsorption capacity value is near the experimental one. Likewise, we evaluated the values of thermodynamic parameters which indicate that the studied process is an endothermic and spontaneous one, being a physical adsorption. Prepared adsorbent materials have a maximum adsorption capacity of 204.3 mg Cd²⁺ per gram at pH > 4.0 and 298 K. In addition, this material was reused for Cd²⁺ recovery for 20 times.     

Effects of Electronegativity and Hydration Energy on the Selective Adsorption of Heavy Metal Ions by Synthetic NaX Zeolite

The adsorption capacity of synthetic NaX zeolite for Pb²⁺, Cd²⁺, Cu²⁺ and Zn²⁺ in single and multi-component systems were investigated. The effects of electronegativity and hydration energy on the selective adsorption, as well as potential selective adsorption mechanism of the NaX zeolite for Pb²⁺, Cd²⁺, Cu²⁺ and Zn²⁺ were also discussed. The maximum adsorption capacity order of the heavy metals in the single system was Pb²⁺ > Cd²⁺ > Cu²⁺ > Zn²⁺, and this could be related to their hydration energy and electronegativity. The values of the separation factors (α) and affinity constant (K_EL) in different binary systems indicated that Pb²⁺ was preferentially adsorbed, and Zn²⁺ presented the lowest affinity for NaX zeolite. The selective adsorption capacities of the metals were in the order, Pb²⁺ > Cd²⁺ ≈ Cu²⁺ > Zn²⁺. The trend for the selective adsorption of NaX zeolite in ternary and quaternary systems was consistent with that in the binary systems. Pb²⁺ and Cu²⁺ reduced the stability of the Si-O-Al bonds and the double six-membered rings in the NaX framework, due to the high electronegativity of Pb²⁺ and Cu²⁺ than that of Al³⁺. The selective adsorption mechanism of NaX zeolite for the high electronegative metal ions could mainly result from the negatively charged O in the Si-O-Al structure of the NaX zeolite, hence heavy metal ions with high electronegativity display a strong affinity for the electron cloud of the oxygen atoms in the Si-O-Al. This study could evaluate the application and efficiency of zeolite in separating and recovering certain metal ions from industrial wastewater.     

Synthesis and Characterization of Biopolymeric Chitosan Derived from Land Snail Shells and Its Potential for Pb2+ Removal from Aqueous Solution

Pb²⁺ is considered to be a very toxic pollutant in the aquatic environmental media. Biopolymeric chitosan synthesized from snail shell has been studied for its potential to remove heavy metals from aqueous solution. The experiments were conducted in the range of 1–50 mg/L initial Pb²⁺ concentration at 298 K. The effects of pH, adsorbent dosage and contact time on the adsorptive property of the adsorbent were investigated and optimized. The derived chitosan was characterized using Fourier transform infrared spectrometer (FT-IR) and X-ray florescence (XRF). The experimental data obtained were analysed using the Langmuir and Freundlich adsorption isotherm models. The Langmuir model and pseudo second order kinetic model suitably described the adsorption and kinetics of the process with regression coefficients of 0.99 and 1.00, respectively. Sodium hydroxide was a better desorbing agent than hydrochloric acid and de-ionized water. From the results obtained, it is concluded that synthesized biopolymers from land snail shells has the potential for the removal of Pb²⁺ from aqueous solutions.     

Preparation of a Novel Millet Straw Biochar-Bentonite Composite and Its Adsorption Property of Hg2+ in Aqueous Solution

The remediation of mercury (Hg) contaminated soil and water requires the continuous development of efficient pollutant removal technologies. To solve this problem, a biochar–bentonite composite (CB) was prepared from local millet straw and bentonite using the solution intercalation-composite heating method, and its physical and chemical properties and micromorphology were then studied. The prepared CB and MB (modified biochar) had a maximum adsorption capacity for Hg²⁺ of 11.722 and 9.152 mg·g⁻¹, respectively, far exceeding the corresponding adsorption value of biochar and bentonite (6.541 and 2.013 mg·g⁻¹, respectively).The adsorption of Hg²⁺ on the CB was characterized using a kinetic model and an isothermal adsorption line, which revealed that the pseudo-second-order kinetic model and Langmuir isothermal model well represented the adsorption of Hg²⁺ on the CB, indicating that the adsorption was mainly chemical adsorption of the monolayer. Thermodynamic experiments confirmed that the adsorption process of Hg²⁺ by the CB was spontaneous and endothermic. Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and a thermogravimetric analysis (TGA) showed that after Hg²⁺ was adsorbed by CB, functional groups, such as the –OH group (or C=O, COO–, C=C) on the CB, induced complexation between Hg and –O–, and part of Hg (ii) was reduced Hg (i), resulting in the formation of single or double tooth complexes of Hg–O– (or Hg–O–Hg). Therefore, the prepared composite (CB) showed potential application as an excellent adsorbent for removing heavy metal Hg²⁺ from polluted water compared with using any one material alone.     

Green Synthesis of Zinc Oxide Nanoparticles Using Red Seaweed for the Elimination of Organic Toxic Dye from an Aqueous Solution

This study aims to produce green zinc oxide nanoparticles (ZnO-NPs) derived from red seaweed (Pterocladia Capillacea) and evaluate their potential to absorb Ismate violet 2R (IV2R) ions from an aqueous solution. UV-vis spectrophotometry, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), and a Brunauer–Emmett–Teller surface area analysis (BET) were used to analyze the structural, morphological, and optical features of the synthesized nanoparticles. The change in color of the chemical solution revealed the formation of zinc oxide nanoparticles. The FTIR examination confirmed the synthesis of both Zn and ZnO nanoparticle powder, with a BET surface area of 113.751 m² g⁻¹ and an average pore size of 2.527 nm for the synthesized adsorbent. Furthermore, the maximum removal effectiveness of IV2R was 99% when 0.08 g ZnO-NPs was applied at a pH of 6, a temperature of 55 °C, and a contact time of 120 min. The dye adsorption capacity of the ZnO-NPs was 72.24 mg g⁻¹. The adsorption process was also controlled by the Freundlich adsorption model and pseudo-second-order reaction kinetics. The adsorption of IV2R ions onto the ZnO-NPs could be represented as a nonideal and reversible sorption process of a nonuniform surface, according to Freundlich adsorption isotherms. In addition, the constant values of the model parameters were determined using various nonlinear regression error functions. Moreover, thermodynamic parameters such as entropy change, enthalpy change, and free energy change were investigated; the adsorption process was spontaneous and endothermic. The high capacity of the ZnO-NPs synthesized by red seaweed promotes them as promising substances for applications in water treatment for the removal of IV2R dye from aqueous systems.     

Bismuth/Porous Graphene Heterostructures for Ultrasensitive Detection of Cd (II)

Heavy metals pollution is one of the key problems of environment protection. Electrochemical methods, particularly anodic stripping voltammetry, have been proven a powerful tool for rapid detection of heavy metal ions. In the present work, a bismuth modified porous graphene (Bi@PG) electrode as an electrochemical sensor was adopted for the detection of heavy metal Cd²⁺ in an aqueous solution. Combining excellent electronic properties in sensitivity, peak resolution, and high hydrogen over-potential of bi-continuous porous Bi with the large surface-area and high conductivity on PG, the Bi@PG electrode exhibited excellent sensing ability. The square wave anodic stripping voltammetry response showed a perfect liner range of 10⁻⁹–10⁻⁸ M with a correlation coefficient of 0.9969. The limit of detection (LOD) and the limit of quantitation (LOQ) are calculated to be 0.1 and 0.34 nM with a sensitivity of 19.05 μA·nM⁻¹, which is relatively excellent compared to other carbon-based electrodes. Meanwhile, the Bi@PG electrode showed tremendous potential in composite detection of multifold heavy metals (such as Pb²⁺ and Cd²⁺) and wider linear range.     

Simultaneous Removal of Pb2+ and Zn2+ Heavy Metals Using Fly Ash Na-X Zeolite and Its Carbon Na-X(C) Composite

Pure zeolite (Na-X) and a zeolite–carbon composite (Na-X(C)) were investigated as adsorbents of heavy metals—Pb²⁺ and Zn²⁺ from an aqueous solution. These materials were synthesized from fly ash—a waste from conventional hard coal combustion. Both solids were characterized using XRD, SEM-EDS, nitrogen adsorption/desorption, particle size and elemental composition analyses. The adsorption study was performed at pH 5 in the systems containing one or two adsorbates simultaneously. The obtained results showed that the pure zeolite was characterized by a more developed surface area (728 m²/g) than its carbon composite (272 m²/g), and the mean pore diameters were equal to 1.73 and 2.56 nm, respectively. The pure Na-X zeolite showed better adsorption properties towards heavy metals than its Na-X(C) composite, and Zn²⁺ adsorbed amounts were significantly higher than the Pb²⁺ ones (the highest experimental adsorption levels were: for Zn²⁺—656 and 600 mg/g, and for Pb²⁺—575 and 314 mg/g, on the Na-X and Na-X(C) surfaces, respectively). The zinc ions are exchanged with the cations inside the zeolite materials structure more effectively than lead ions with a considerably larger size. In the mixed systems, the competition between both heavy metals for access to the active sites on the adsorbent surface leads to the noticeable reduction in their adsorbed amounts. Moreover, the hydrochloric acid was a better desorbing agent for both heavy metals, especially Pb²⁺ one (desorption reached 78%), than sodium base (maximal desorption 25%).     

Snail Based Carbonated-Hydroxyapatite Material as Adsorbents for Water Iron (II)

Carbonated hydroxyapatite (CHAp) adsorbent material was prepared from Achatina achatina snail shells and phosphate-containing solution using a wet chemical deposition method. The CHAp adsorbent material was investigated to adsorb aqua Fe(II) complex; [Fe(H₂O)₆]²⁺ from simulated iron contaminated water for potential iron remediation application. The CHAp was characterized before and after adsorption using infrared (IR) and Raman spectroscopy. The IR and the Raman data revealed that the carbonate functional groups of the CHAp adsorbent material through asymmetric orientation in water bonded strongly to the aqua Fe(II) complex adsorbate. The adsorption behaviour of the adsorbate onto the CHAp adsorbent correlated well to pseudo-second-order kinetics model, non-linear Langmuir and Freundlich model at room temperature of a concentration (20–100 mg L⁻¹) and contact time of 180 min. The Langmuir model estimated the maximum adsorption capacity to be 45.87 mg g⁻¹ whereas Freundlich model indicated an S-type isotherm curvature which supported the spectroscopy revelation.     

A Review of Adsorbents for Heavy Metal Decontamination: Growing Approach to Wastewater Treatment

Heavy metal is released from many industries into water. Before the industrial wastewater is discharged, the contamination level should be reduced to meet the recommended level as prescribed by the local laws of a country. They may be poisonous or cancerous in origin. Their presence does not only damage people, but also animals and vegetation because of their mobility, toxicity, and non-biodegradability into aquatic ecosystems. The review comprehensively discusses the progress made by various adsorbents such as natural materials, synthetic, agricultural, biopolymers, and commercial for extraction of the metal ions such as Ni²⁺, Cu²⁺, Pb²⁺, Cd²⁺, As²⁺ and Zn²⁺ along with their adsorption mechanisms. The adsorption isotherm indicates the relation between the amount adsorbed by the adsorbent and the concentration. The Freundlich isotherm explains the effective physical adsorption of the solute particle from the solution on the adsorbent and Langmuir isotherm gives an idea about the effect of various factors on the adsorption process. The adsorption kinetics data provide valuable insights into the reaction pathways, the mechanism of the sorption reaction, and solute uptake. The pseudo-first-order and pseudo-second-order models were applied to describe the sorption kinetics. The presented information can be used for the development of bio-based water treatment strategies.     

Fly Ash Coated with Magnetic Materials: Improved Adsorbent for Cu (II) Removal from Wastewater

Fly ash/magnetite material was used for the adsorption of copper ions from synthetic wastewater. The obtained material was characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET) surface area, and vibrating sample magnetometer (VSM). Batch adsorption experiments were employed in order to investigate the effects of adsorbent dose, initial Cu (II) concentration and contact time over adsorption efficiency. The experimental isotherms were modeled using Langmuir (four types of its linearization), Freundlich, Temkin, and Harkins–Jura isotherm models. The fits of the results are estimated according to the Langmuir isotherm, with a maximum adsorption capacity of 17.39 mg/g. The pseudo-second-order model was able to describe kinetic results. The data obtained throughout the study prove that this novel material represents a potential low-cost adsorbent for copper adsorption with improved adsorption capacity and magnetic separation capability compared with raw fly ash.     

The plant cDNA LCT1 mediates the uptake of calcium and cadmium in yeast

Nonessential metal ions such as cadmium are most likely transported across plant membranes via transporters for essential cations. To identify possible pathways for Cd²⁺ transport we tested putative plant cation transporters for Cd²⁺ uptake activity by expressing cDNAs in Saccharomyces cerevisiae and found that expression of one clone, LCT1, renders the growth of yeast more sensitive to cadmium. Ion flux assays showed that Cd²⁺ sensitivity is correlated with an increase in Cd²⁺ uptake. LCT1-dependent Cd²⁺ uptake is saturable, lies in the high-affinity range (apparent K_M for Cd²⁺ = 33 μM) and is sensitive to block by La³⁺ and Ca²⁺. Growth assays demonstrated a sensitivity of LCT1-expressing yeast cells to extracellular millimolar Ca²⁺ concentrations. LCT1-dependent increase in Ca²⁺ uptake correlated with the observed phenotype. Furthermore, LCT1 complements a yeast disruption mutant in the MID1 gene, a non-LCT1-homologous yeast gene encoding a membrane Ca²⁺ influx system required for recovery from the mating response. We conclude that LCT1 mediates the uptake of Ca²⁺ and Cd²⁺ in yeast and may therefore represent a first plant cDNA encoding a plant Ca²⁺ uptake or an organellar Ca²⁺ transport pathway in plants and may contribute to transport of the toxic metal Cd²⁺ across plant membranes.     

Effect of cadmium ions on dioxygen affinity and polyphosphate activity of human red blood cells

Summary The effect of cadmium ions on the dioxygen affinity, the time-dependent depletion of intracellular polyphosphates, and the elongation of human red blood cells (RBC's) was examined. The incubation of RBC's in the presence of 1 mM Cd²⁺ at 37°C for more than one hour results in a decrease of the p₅₀ value by 2.5–3.0 mmHg in comparison to controls. The p₅₀ of stripped (phosphate-free) hemoglobin is not affected by the presence of 1 mM Cd²⁺ (p₅₀=4.8 mmHg at pH 7.2 and 37°C). Experiments with RBC cryolysates demonstrate an apparently competitive effect of 2.3-bisphosphoglycerate (DPG) with cadmium ions on the dioxygen affinity. From ³¹P NMR spectra, ³¹P T₁ relaxation, and ³¹P T₂ relaxation behavior a more direct evidence for DPG-Cd²⁺ complexation is obtained. ³¹P NMR spectra of RBC cryolysates also indicate DPG-Cd²⁺ complexation. The hydrolysis of free polyphosphates in RBC's incubated at 37°C as monitored by ³¹P NMR spectra can be noticed after a three-hour lag phase (constant polyphosphate level). This lag phase is lengthened from three hours to four hours in the presence of Cd²⁺ ions. RBC elongation, as a measure of deformability, decreases slightly upon incubation with 1 mM Cd²⁺.     

Potential Applications of Arthrospira platensis Lipid-Free Biomass in Bioremediation of Organic Dye from Industrial Textile Effluents and Its Influence on Marine Rotifer (Brachionus plicatilis)

Arthrospira platensis is one of the most important cultured microalgal species in the world. Arthrospira complete dry biomass (ACDB) has been reported as an interesting feedstock for many industries, including biodiesel production. The A. platensis by-product of biodiesel production (lipid-free biomass; LFB) is a source of proteins, functional molecules, and carbohydrates, and can also be reused in several applications. The current study investigated the efficiency of ACDB and LFB in bioremediation of dye (Ismate violet 2R, IV2R) from textile effluents. In addition, the potential of ACDB and LFB loaded by IV2R as a feed for Rotifer, Brachionus plicatilis, was examined. The surface of the adsorbents was characterized by SEM, FTIR, and Raman analysis to understand the adsorption mechanism. The batch sorption method was examined as a function of adsorbent dose (0.02–0.01 g L⁻¹), solution initial concentration (10–100 mg L⁻¹), pH (2–10), and contact time (15–180 min). The kinetic studies and adsorption isotherm models (Freundlich, Langmuir, Tempkin, and Halsey) were used to describe the interaction between dye and adsorbents. The results concluded that the adsorption process increased with increasing ACDB and LFB dose, contact time (120 min), initial IV2R concentration (10 mg L⁻¹), and acidity pH (2 and 6, respectively). For the elimination of industrial textile wastewater, the ACDB and LFB sorbents have good elimination ability of a dye solution by 75.7% and 61.11%, respectively. The kinetic interaction between dye and adsorbents fitted well to Langmuir, Freundlish, and Halsey models for LFB, and Langmuir for ACDB at optimum conditions with R² > 0.9. In addition, based on the bioassay study, the ACDB and LFB loaded by IV2R up to 0.02 g L⁻¹ may be used as feed for the marine Rotifer B. plicatilis.     

Removal of Heavy Metal Ions from One- and Two-Component Solutions via Adsorption on N-Doped Activated Carbon

This paper deals with the adsorption of heavy metal ions (Cu²⁺ and Zn²⁺) on the carbonaceous materials obtained by chemical activation and ammoxidation of Polish brown coal. The effects of phase contact time, initial metal ion concentration, solution pH, and temperature, as well as the presence of competitive ions in solution, on the adsorption capacity of activated carbons were examined. It has been shown that the sample modified by introduction of nitrogen functional groups into carbon structure exhibits a greater ability to uptake heavy metals than unmodified activated carbon. It has also been found that the adsorption capacity increases with the increasing initial concentration of the solution and the phase contact time. The maximum adsorption was found at pH = 8.0 for Cu(II) and pH = 6.0 for Zn(II). For all samples, better fit to the experimental data was obtained with a Langmuir isotherm than a Freundlich one. A better fit of the kinetic data was achieved using the pseudo-second order model.     

Differential effects of metal ions on type a and type B monoamine oxidase activities in rat brain and liver mitochondria

To investigate the hypothesis that neurotoxic metals can exert their toxicity through the direct inhibition of monoamine oxidases (MAOs), the effects of several neurotoxic metal ions on type A (MAO-A) and type B (MAO-B) monoamine oxidase activities in rat forebrain nonsynaptic mitochondria and rat liver mitochondria were studied. At pathophysiological levels (10–100 M), Cu²⁺ and Cd²⁺ are good inhibitors of brain mitochondrial MAO-A and, to a lesser extent, liver mitochondrial MAO-A. The inhibition of MAO-B activities in brain and liver mitochondria by Cu²⁺ and Cd²⁺ is only detected at the higher end of the concentration range (i.e., 50–100 M). At the pathophysiological level of 0.5 mM, Al³⁺ only inhibits brain mitochondrial MAO-A but at the higher level of 2.5 mM, it inhibits both forms of MAO in brain as well as liver mitochondria. Even at toxic levels (e.g., 5 mM), neither Mn²⁺ nor Li⁺ inhibits the activities of MAO-A and MAO-B in brain and liver mitochondria. Our results are consistent with the hypothesis that some neurotoxic metals can exert their toxicity through the direct inhibition of the isoforms of MAO. Our data also suggest that the selective inhibition of brain MAO-A by Cu²⁺ and Cd²⁺ may assume pathophysiological importance in the neurotoxicity of copper and cadmium.     

Enhanced Defluoridation of Water Using Zirconium—Coated Pumice in Fixed-Bed Adsorption Columns

Millions of people across the globe suffer from health issues related to high fluoride levels in drinking water. The purpose of this study was to test modified pumice as an adsorbent for the purification of fluoride-containing waters. The adsorption of fluoride onto zirconium-coated pumice (Zr–Pu) adsorbent was examined in fixed-bed adsorption columns. The coating of zirconium on the surface of VPum was revealed by X-ray diffractometer (XRD), Inductively coupled plasma-optical emission spectroscopy (ICP-EOS), and X-ray fluorescence (XRF) techniques. The degree of surface modification with the enhanced porosity of Zr–Pu was evident from the recorded scanning electron microscope (SEM) micrographs. The Brunauer-Emmett-Teller (BET) analysis confirmed the enhancement of the specific surface area of VPum after modification. The Fourier transform infrared (FTIR) examinations of VPum and Zr–Pu before and after adsorption did not reveal any significant spectrum changes. The pH drift method showed that VPum and Zr–Pu have positive charges at pH_PZC lower than 7.3 and 6.5, respectively. Zr–Pu yielded a higher adsorption capacity of 225 mg/kg (2.05 times the adsorption capacity of VPum: 110 mg/kg), at pH = 2 and volumetric flow rate (Q_O) of 1.25 mL/min. Breakthrough time increases with decreasing pH and flow rate. The experimental adsorption data was well-matched by the Thomas and Adams-Bohart models with correlation coefficients (R²) of ≥ 0.980 (Zr–Pu) and ≥ 0.897 (VPum), confirming that both models are suitable tools to design fixed-bed column systems using volcanic rock materials. Overall, coating pumice with zirconium improved the defluoridation capacity of pumice; hence, a Zr–Pu-packed fixed-bed can be applied for defluoridation of excess fluoride from groundwater. However, additional investigations on, for instance, the influences of competing ions are advisable to draw explicit conclusions.     

Effect of Aluminium Powder on Kaolin-Based Geopolymer Characteristic and Removal of Cu2+

This current work focuses on the synthesis of geopolymer-based adsorbent which uses kaolin as a source material, mixed with alkali solution consisting of 10 M NaOH and Na₂SiO₃ as well as aluminium powder as a foaming agent. The experimental range for the aluminium powder was between 0.6, 0.8, 1.0 and 1.2wt%. The structure, properties and characterization of the geopolymer were examined using X-Ray Diffraction (XRD), Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). Adsorption capacity and porosity were analysed based on various percentages of aluminium powder added. The results indicate that the use of aluminium powder exhibited a better pore size distribution and higher porosity, suggesting a better heavy metal removal. The maximum adsorption capacity of Cu²⁺ approached approximately 98%. The findings indicate that 0.8% aluminium powder was the optimal aluminium powder content for geopolymer adsorbent. The removal efficiency was affected by pH, adsorbent dosage and contact time. The optimum removal capacity of Cu²⁺ was obtained at pH 6 with 1.5 g geopolymer adsorbent and 4 h contact time. Therefore, it can be concluded that the increase in porosity increases the adsorption of Cu²⁺.