The Durability of Mortar Containing Alkali Activated Fly Ash-Based Lightweight Aggregate

Beneficiating fly ash as valuable construction material such as artificial lightweight aggregate (LWA) could be an alternative solution to increase the utilization of the industrial by-product. However, generally, LWA is characterized by high porosity and a related high water absorption, which on the one hand allows production of lightweight mortar, but on the other hand can affect its performance. Thus, in this research, the durability performance of mortar composed with alkali-activated fly ash-based LWA, and commercial expanded clay (EC) LWA was investigated. The fly ash LWA was prepared in a pan granulator, with a 6-molar solution of NaOH mixed with Na₂SiO₃ in a Na₂SiO₃/NaOH weight ratio of 1.5 being used as activator (FA 6M LWA). The results revealed that mortar containing FA 6M LWA had equivalent mechanical strength with mortar containing EC LWA. The mortar containing FA 6M LWA had comparable capillary water uptake and chloride migration resistance with the reference and EC LWA mortar. Furthermore, the addition of FA 6M LWA was proven to enhance the carbonation resistance in the resulting mortar, due to the denser interfacial transition zone (ITZ) of mortar with LWA.     

Life Cycle Assessment and Impact Correlation Analysis of Fly Ash Geopolymer Concrete

Geopolymer concrete (GPC) has drawn widespread attention as a universally accepted ideal green material to improve environmental conditions in recent years. The present study systematically quantifies and compares the environmental impact of fly ash GPC and ordinary Portland cement (OPC) concrete under different strength grades by conducting life cycle assessment (LCA). The alkali activator solution to fly ash ratio (S/F), sodium hydroxide concentration (C_NaOH), and sodium silicate to sodium hydroxide ratio (SS/SH) were further used as three key parameters to consider their sensitivity to strength and CO₂ emissions. The correlation and influence rules were analyzed by Multivariate Analysis of Variance (MANOVA) and Gray Relational Analysis (GRA). The results indicated that the CO₂ emission of GPC can be reduced by 62.73%, and the correlation between CO₂ emission and compressive strength is not significant for GPC. The degree of influence of the three factors on the compressive strength is C_NaOH (66.5%) > SS/SH (20.7%) > S/F (9%) and on CO₂ emissions is S/F (87.2%) > SS/SH (10.3%) > C_NaOH (2.4%). Fly ash GPC effectively controls the environmental deterioration without compromising its compressive strength; in fact, it even in favor.     

Characterization and Comparison of Corrosion Layer Microstructure between Cement Mortar and Alkali-Activated Fly Ash/Slag Mortar Exposed to Sulfuric Acid and Acetic Acid

In this study, we investigated the formation and evolution of the corrosion layers in alkali-activated mortar and ordinary Portland cement mortar exposed to sulfuric acid and acetic acid environments with different pH values, and explored the differences in the deterioration mechanisms. The experimental results indicated that ordinary Portland cement (OPC) mortars experienced more severe deterioration in terms of appearance, mass loss, and strength loss as compared with alkali-activated mortars exposed to an acetic acid environment, but their neutralization depths were smaller. Alkali-activated fly ash (AAF) mortar had a the relatively intact appearance but the greatest neutralization depth, which was due to its stable three-dimensional network but highly porous structure. To sum up, alkali-activated fly ash/slag (AFS) mortar had the best resistance to acid attack. In addition, the mortars exposed to acetic acid suffered greater deterioration than those exposed to sulfuric acid with the same pH values, which was mainly due to the highly porous corrosion layer formed in acetic acid, whereas crystallization of gypsum in sulfuric acid had a pore filling effect. However, for alkali-activated slag (AAS) and OPC mortars exposed to a sulfuric acid environment, extensive gypsum resulted in the formation of micro-cracks, and the corrosion layer of OPC mortar was more prone to fall off. OPC mortar also had the greatest resistance difference values of the continuously connected micro-pores before and after acid corrosion, followed by AAS, AAF, and AFS mortars, and these values for all the specimens were smaller in sulfuric acid. Furthermore, the gaps between acetic and sulfuric acid attacks increased with increased calcium content in binders, which were 7%, 13%, 21%, and 29% for AAF, AFS, AAS, and OPC mortars, respectively. Thus, it can be inferred that an appropriate amount of gypsum existed in the corrosion layer which could act as a barrier to some extent ina sulfuric acid environment.     

Process Development of Fly Ash-Based Geopolymer Mortars in View of the Mechanical Characteristics

This study aimed to determine the effects of design parameters, including the liquid/solid ratio (L/S), Na₂SiO₃/NaOH weight ratio, and curing temperature, on class F fly ash-based geopolymer composites. For this purpose, two disparate sources of fly ash were supplied from Çatalağzı (FA) and İsken Sugözü (FB) Thermal Power Plants in Turkey. Two different L/S ratios of 0.2 and 0.4 were used. The Na₂SiO₃/NaOH ratios in the alkaline solutions were 1, 1.5, 2, 2.5, and 3 by weight for each type of geopolymer mixture. Then, 40 different mixes were cured at two specific temperatures (70 °C and 100 °C) for 24 h and then preserved at room temperature until testing. Thereafter, the physical water absorption properties, apparent porosity, and bulk density were examined at 28 days on the hardened mortars. Additionally, compressive and flexural tests were applied to the geopolymers at 7, 28, and 90 days. It was found that the highest compressive strength was 60.1 MPa for the geopolymer manufactured with an L/S of 0.2 and Na₂SiO₃/NaOH ratio of 2. Moreover, the best thermal curing temperature for obtaining optimal strength characteristics was 100 °C for the FB.     

Durability of Mortars with Fly Ash Subject to Freezing and Thawing Cycles and Sulfate Attack

Destruction of cement composites occurs due to the alternate or simultaneous effects of aggressive media, resulting in the destruction of concrete under the influence of chemical and physical factors. This article presents the results of changes in the measurement of linear strains of samples and changes in the microstructure of cement after 30 freezing and thawing cycles and immersed in 5% sodium sulfate solution. The compressive strengths ratios were carried out at the moment when the samples were moved to the sulfate solution after 30 cycles and at the end of the study when the samples showed visual signs of damage caused by the effect of 5% Na₂SO₄. The composition of the mixtures was selected based on the Gibbs triangle covering the area up to 40% replacement of Portland cement with low and high-calcium fly ashes or their mixture. Air-entrained and non-air entrained mortars were made of OPC, in which 20%, 26.6%, and 40% of Portland cement were replaced with low and/or high-calcium fly ash. Initial, freezing and thawing cycles accelerated the destruction of non- air-entrained cement mortars immersed in 5% sodium sulfate solution. The sulfate resistance, after the preceding frost damage, decreased along with the increase in the amount of replaced fly ash in the binder. Air-entrained mortars in which 20% of cement was replaced with high-calcium fly ash showed the best resistance to the action of sodium sulfate after 30 freezing and thawing cycles.     

Effect of Slag on the Strength and Shrinkage Properties of Metakaolin-Based Geopolymers

Metakaolin-based geopolymers possess excellent corrosion and high-temperature resistance, which are advantageous compared to ordinary Portland cement. The addition of slag in metakaolin-based geopolymers is a promising approach to improve their mechanical properties. Thus, this study investigated the effect of slag content on the strength and shrinkage properties of metakaolin-based geopolymers. Increasing the slag content and Na₂O content was beneficial to the reaction of alkali-activated metakaolin-based geopolymers, thereby improving their compressive strength and density. After 56 days of aging, a maximum compressive strength of 86.1 MPa was achieved for a metakaolin-based geopolymer with a slag content of 50 mass%. When the Na₂O content was 12%, the compressive strength of the metakaolin geopolymers with a slag content of 30% was 42.36% higher than those with a Na₂O content of 8%. However, as the slag and alkali contents increased, the reaction rate of the metakaolin-based geopolymers increased, which significantly decreased the porosity, increased the shrinkage, and decreased the volumetric stability of the system. In this paper, in-depth study of the volume stability of alkali-activated metakaolin-based geopolymers plays an important role in further understanding, controlling, and utilizing the deformation behavior of geopolymers.     

Use of Gypsum as a Preventive Measure for Strength Deterioration during Curing in Class F Fly Ash Geopolymer System

This study discusses strength deterioration during the curing process of fly ash geopolymer and the use of CaSO₄·2H₂O (gypsum) as a deterioration remedy when the ash was synthesized using a 10M NaOH and Na-silicate solution. The strength decline was mainly due to the widespread formation of nanometer-sized cracks that were related to excessive Na and Si concentrations at an early age. Use of 2 wt% CaSO₄·2H₂O resulted in the best measured strength by temporarily reducing Na and Si concentrations; Na was absorbed by SO₄²⁻, up to 11% in the matrix within one day, and formed Na₂SO₄ (thenardite), which gradually dissolved over time, slowly releasing Na ions. However, more than 4% gypsum suppressed overall strength development because too many Na ions were locked into Na₂SO₄ and could not participate in geopolymerization. The addition of gypsum impeded glass dissolution and even halted the process when more than 4% gypsum was used.     

Mechanical and Durability Analysis of Fly Ash Based Geopolymer with Various Compositions for Rigid Pavement Applications

Ordinary Portland cement (OPC) is a conventional material used to construct rigid pavement that emits large amounts of carbon dioxide (CO₂) during its manufacturing process, which is bad for the environment. It is also claimed that OPC is susceptible to acid attack, which increases the maintenance cost of rigid pavement. Therefore, a fly ash based geopolymer is proposed as a material for rigid pavement application as it releases lesser amounts of CO₂ during the synthesis process and has higher acid resistance compared to OPC. This current study optimizes the formulation to produce fly ash based geopolymer with the highest compressive strength. In addition, the durability of fly ash based geopolymer concrete and OPC concrete in an acidic environment is also determined and compared. The results show that the optimum value of sodium hydroxide concentration, the ratio of sodium silicate to sodium hydroxide, and the ratio of solid-to-liquid for fly ash based geopolymer are 10 M, 2.0, and 2.5, respectively, with a maximum compressive strength of 47 MPa. The results also highlight that the durability of fly ash based geopolymer is higher than that of OPC concrete, indicating that fly ash based geopolymer is a better material for rigid pavement applications, with a percentage of compressive strength loss of 7.38% to 21.94% for OPC concrete. This current study contributes to the field of knowledge by providing a reference for future development of fly ash based geopolymer for rigid pavement applications.     

An Investigation of the Ground Walnut Shells’ Addition Effect on the Properties of the Fly Ash-Based Geopolymer

The development of geopolymers is in line with the requirements of sustainable development. Creating a new type of material from various industrial and bio-based wastes and by-products can lead to reduced energy consumption, reduced waste generation, reduced global CO₂ emissions, as well as reduced resource extraction of natural resources. In this study, geopolymer composites based on class F fly ash with the addition of fine quartz sand and ground walnut shells used as a substitute for sand were examined. The study focused on investigating the effects of different weight percentages of ground walnut shells and quartz sand on the density and strength properties, including compressive and flexural strength, thermal conductivity, efflorescence formation, and water absorption of the fly ash-based geopolymer composites. The microstructure of the studied geopolymers was also analyzed using a scanning electron microscope (SEM). It was observed that the addition of ground walnut shells contributes to the decrease in density and mechanical properties, increase in absorption properties, and decrease in porosity of fly ash-based geopolymers. Furthermore, the addition of ground walnut shells allows for a significant reduction in efflorescence on the surface of the tested geopolymer composites. Moreover, partial or complete replacement of sand by ground walnut shells in geopolymer composites based on fly ash allows for a significant reduction in their thermal conductivity, which makes it possible to use these composites as insulation materials.     

The Effect of Stray Current on Calcium Leaching of Cement-Based Materials

The metro engineering is in an environment rich in stray current and groundwater, which will accelerate concrete corrosion. In this study, the corrosion of cement-based materials, under stray current, consisting of direct current, was investigated, and the effects of stray current magnitude, water-binder ratio, fly ash, and silica fume on its corrosion were analyzed. The results show that, as the energisation duration of the stray current increases, the mass of the cathode side leachables increases, and the compressive strength of the cement-based materials decreases overall; at 120 d of stray current, the water-binder ratio of 0.50 shows the least reduction in strength, compared to the others; the mass of cathode side leachables decrease significantly with the increase in fly ash content; when fly ash content is 15%, the mass of cathode side leachables is the least, and the decrease in the compressive strength at 120 d of stray current is the smallest. At 10% silica fume content, the mass of the cathode side leachables is the least, and the decrease in the compressive strength of the cement-based materials at 120 d of stray current is the smallest. In general, the corrosion resistance is relatively good at 15% fly ash content and 10% silica fume content under stray current.     

Effect of Solids-To-Liquids,Na2SiO3-To-NaOH and Curing Temperature on the Palm Oil Boiler Ash (Si + Ca) Geopolymerisation System

This paper investigates the effect of the solids-to-liquids (S/L) and Na₂SiO₃/NaOH ratios on the production of palm oil boiler ash (POBA) based geopolymer. Sodium silicate and sodium hydroxide (NaOH) solution were used as alkaline activator with a NaOH concentration of 14 M. The geopolymer samples were prepared with different S/L ratios (0.5, 1.0, 1.25, 1.5, and 1.75) and Na₂SiO₃/NaOH ratios (0.5, 1.0, 1.5, 2.0, 2.5, and 3.0). The main evaluation techniques in this study were compressive strength, X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscope (SEM). The results showed that the maximum compressive strength (11.9 MPa) was obtained at a S/L ratio and Na₂SiO₃/NaOH ratio of 1.5 and 2.5 at seven days of testing.     

Evaluation on the Mechanical Properties of Ground Granulated Blast Slag (GGBS) and Fly Ash Stabilized Soil via Geopolymer Process

This study intended to address the problem of damaged (collapsed, cracked and decreased soil strength) road pavement structure built on clay soil due to clay soil properties such as low shear strength, high soil compressibility, low soil permeability, low soil strength, and high soil plasticity. Previous research reported that ground granulated blast slag (GGBS) and fly ash can be used for clay soil stabilizations, but the results of past research indicate that the road pavement construction standards remained unfulfilled, especially in terms of clay’s subgrade soil. Due to this reason, this study is carried out to further investigate soil stabilization using GGBS and fly ash-based geopolymer processes. This study investigates the effects of GGBS and ratios of fly ash (solid) to alkaline activator (liquid) of 1:1, 1.5:1, 2:1, 2.5:1, and 3:1, cured for 1 and 7 days. The molarity of sodium hydroxide (NaOH) and the ratio of sodium silicate (Na₂SiO₃) to sodium hydroxide (NaOH) was fixed at 10 molar and 2.0 weight ratio. The mechanical properties of the soil stabilization based geopolymer process were tested using an unconfined compression test, while the characterization of soil stabilization was investigated using the plastic limit test, liquid limit test, scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). The results showed that the highest strength obtained was 3.15 MPA with a GGBS to alkaline activator ratio of 1.5 and Na₂SiO₃ to NaOH ratio of 2.0 at 7 days curing time. These findings are useful in enhancing knowledge in the field of soil stabilization-based geopolymer, especially for applications in pavement construction. In addition, it can be used as a reference for academicians, civil engineers, and geotechnical engineers.     

Bayesian Regularized Artificial Neural Network Model to Predict Strength Characteristics of Fly-Ash and Bottom-Ash Based Geopolymer Concrete

Geopolymer concrete (GPC) offers a potential solution for sustainable construction by utilizing waste materials. However, the production and testing procedures for GPC are quite cumbersome and expensive, which can slow down the development of mix design and the implementation of GPC. The basic characteristics of GPC depend on numerous factors such as type of precursor material, type of alkali activators and their concentration, and liquid to solid (precursor material) ratio. To optimize time and cost, Artificial Neural Network (ANN) can be a lucrative technique for exploring and predicting GPC characteristics. In this study, the compressive strength of fly-ash based GPC with bottom ash as a replacement of fine aggregates, as well as fly ash, is predicted using a machine learning-based ANN model. The data inputs are taken from the literature as well as in-house lab scale testing of GPC. The specifications of GPC specimens act as input features of the ANN model to predict compressive strength as the output, while minimizing error. Fourteen ANN models are designed which differ in backpropagation training algorithm, number of hidden layers, and neurons in each layer. The performance analysis and comparison of these models in terms of mean squared error (MSE) and coefficient of correlation (R) resulted in a Bayesian regularized ANN (BRANN) model for effective prediction of compressive strength of fly-ash and bottom-ash based geopolymer concrete.     

Design of Fly Ash-Based Alkali-Activated Mortars,Containing Waste Glass and Recycled CDW Aggregates,for Compressive Strength Optimization

Alkali-activated mortars and concretes have been gaining increased attention due to their potential for providing a more sustainable alternative to traditional ordinary Portland cement mixtures. In addition, the inclusion of high volumes of recycled materials in these traditional mortars and concretes has been shown to be particularly challenging. The compositions of the mixtures present in this paper were designed to make use of a hybrid alkali-activation model, as they were mostly composed of class F fly ash and calcium-rich precursors, namely, ordinary Portland cement and calcium hydroxide. Moreover, the viability of the addition of fine milled glass wastes and fine limestone powder, as a source of soluble silicates and as a filler, respectively, was also investigated. The optimization criterium for the design of fly ash-based alkali-activated mortar compositions was the maximization of both the compressive strength and environmental performance of the mortars. With this objective, two stages of optimization were conceived: one in which the inclusion of secondary precursors in ambient-cured mortar samples was implemented and, simultaneously, in which the compositions were tested for the determination of short-term compressive strength and another phase containing a deeper study on the effects of the addition of glass wastes on the compressive strength of mortar samples cured for 24 h at 80 °C and tested up to 28 days of curing. Furthermore, in both stages, the effects (on the compressive strength) of the inclusion of construction and demolition recycled aggregates were also investigated. The results show that a heat-cured fly ash-based mortar containing a 1% glass powder content (in relation to the binder weight) and a 10% replacement of natural aggregate for CDRA may display as much as a 28-day compressive strength of 31.4 MPa.     

Investigation of the Geopolymerization Potential of a Waste Silica-Rich Diabase Mud

Diabase mud (DM) is a silica-rich residue yielding from aggregate crushing and washing operations in quarries. This work focuses on identifying the geopolymerization potential of a diabase mud through characterization of its mineralogical composition, investigation of its reactivity, and assessment of the early compressive strengths of alkali activated mixtures formulated based on the mud’s dissolution results. The findings suggest that considerably low amounts of Al and Si metals were dissolved following the dissolution tests conducted on DM, however, the incorporation of small quantities of CEM I, gypsum, and metakaolin (MK) moderately at a Na₂SiO₃:NaOH ratio of 50:50 and with a molarity of NaOH of 4 M enhanced the geopolymerization compared to low L/S ratio mixtures cured at different conditions. When M was increasing, the high L/S ratio mixtures exhibited fluctuations in strengths, especially beyond a 10 M NaOH molarity. Maximum strengths of mixtures at equivalent molarity of 10 were achieved when the Na₂SiO₃:NaOH ratio reached 30:70, regardless of the ambient conditions and the presence of CEM I. The curing conditions, the ratio of Na₂SO₃:NaOH, and the presence of CEM I in the DM-based mixtures did not appear to significantly affect the mixture when NaOH concentration was between 2 M and 4 M; at higher molarities, however, these enhanced the strengths of the geopolymerized DM.     

Using Fly Ash Wastes for the Development of New Building Materials with Improved Compressive Strength

Fly ash wastes (silica, aluminum and iron-rich materials) could be smartly valorized by their incorporation in concrete formulation, partly replacing the cement. The necessary binding properties can be accomplished by a simple procedure: an alkali activation process, involving partial hydrolysis, followed by gel formation and polycondensation. The correlations between the experimental fly ash processing conditions, particle characteristics (size and morphology) and the compressive strength values of the concrete prepared using this material were investigated by performing a parametric optimization study to deduce the optimal processing set of conditions. The alkali activation procedure included the variation of the NaOH solutions concentration (8–12 M), temperature values (25–65 °C) and the liquid/solid ratio (1–3). The activation led to important modifications of the crystallography of the samples (shown by powder XRD analysis), their morphologies (seen by SEM), particle size distribution and Blaine surface values. The values of the compressive strength of concrete prepared using fly ash derivatives were between 16.8–22.6 MPa. Thus, the processed fly ash qualifies as a proper potential building material, solving disposal-associated problems, as well as saving significant amounts of cement consumed in concrete formulation.     

The Influence of Short Coir,Glass and Carbon Fibers on the Properties of Composites with Geopolymer Matrix

The aim of the article is to analyze the influence of short coir, glass and carbon fiber admixture on the mechanical properties of fly ash-based geopolymer, such as: flexural and compressive strength. Glass fiber and carbon fibers have been chosen due to their high mechanical properties. Natural fibers have been chosen because of their mechanical properties as well as for the sake of comparison between their properties and the properties of the artificial ones. Fourth series of fly ash-based geopolymers for each fiber was cast: 1, 2, and 5% by weight of fly ash and one control series without any fibers. Each series of samples were tested on flexural and compressive strength after 7, 14, and 28 days. Additionally, microstructural analysis was carried out after 28 days. The results have shown an increase in compressive strength for composites with fibers—an improvement in properties between 25.0% and 56.5% depending on the type and amount of fiber added. For bending strength, a clear increase in the strength value is visible for composites with 1 and 2% carbon fibers (62.4% and 115.6%). A slight increase in flexural strength also occurred for 1% addition of glass fiber (4.5%) and 2% addition of coconut fibers (5.4%). For the 2% addition of glass fibers, the flexural strength value did not change compared to the value obtained for the matrix material. For the remaining fiber additions, i.e., 5% glass fiber as well as 1 and 5% coconut fibers, the flexural strength values deteriorated. The results of the research are discussed in a comparative context and the properties of the obtained composites are juxtaposed with the properties of the standard materials used in the construction industry.     

Influence of Bentonite on Mechanical and Durability Properties of High-Calcium Fly Ash Geopolymer Concrete with Natural and Recycled Aggregates

In this study, bentonite (a naturally occurring pozzolana) was incorporated as a partial replacement (up to 20%) for high-calcium fly ash (HCFA)-based geopolymeric natural aggregate concrete (GNAC) and geopolymeric recycled aggregate concrete (GRAC). The mechanical (compressive strength and splitting tensile strength), durability (chloride migration coefficient, water absorption, and acid attack resistance), and rheological properties (slump test, fresh density, and workability) were investigated. The results revealed that incorporation of bentonite (10 wt % with ordinary Portland cement) showed appreciable improvement in the strength and durability of both the GNAC and GRAC, though its effect is more significant for GRAC than the GNAC.     

Influence of Silica Fume on High-Calcium Fly Ash Expansion during Hydration

The purpose of this work was to study the possibility of neutralizing high-calcium fly ash expansion during hydration. The object of the study was the fly ash of Berezovskaya GRES, which is capable of independent setting and hardening. The test in the Le Chatelier molds showed that the divergence of indicator arms was 90–100 mm 1 day after mixing with water. The expansion and cracking of the fly ash could be completely prevented by silica fume addition in an amount of 42.9% by weight of the fly ash. At the same time, the compressive strength of specimens from the fly ash–sand paste in a ratio of 1:5 at the age of 28 days was 1.47 MPa. The isothermal heat release at a temperature of 20 °C for 10 days reached 500 kJ/kg. XRF and DTA results showed that free lime in the fly ash was completely hydrated in 11 days and gave the greatest expansion in the absence of silica fume. The presence of silica fume made the lime hydration incomplete and decreased the expansion. Unslaked free lime remained in the system. Exothermic data showed that silica fume inhibited CaO hydration from the reaction start.     

Exploration of Carbon Dioxide Curing of Low Reactive Alkali-Activated Fly Ash

In this paper, the effect of carbon curing procedure on low reactive fly ash alkali-activated pastes was investigated. Specimens were cured with pure carbon dioxide (CO₂) gas for different curing times under 4 bar pressure. Chemical and physical characteristics of the geopolymer pastes were obtained from mass monitoring, titration test, XRD, FTIR and TGA-DTG analyses. Regarding the test results, after three days of CO₂ curing, the highest CO₂ uptake was obtained at 4.8 wt% of fly ash precursor, with carbon sequestration efficiency at 22.6%. The ratio of carbon dioxide absorbed as efflorescence to the total absorbed CO₂ was measured. The results show that at early age, almost 50% of carbonated products appeared as efflorescence; however, by increasing the curing time, and after 3 days of curing, about 80% of carbon dioxide was stored in the matrix. It was found that, in all cases, carbonation curing was detrimental to the geopolymerization process due to a high amount of efflorescence and led to a reduction in the compressive strength. At 24 h and 3 days, the specimens showed a lower reduction in compressive strength in comparison to CO₂ samples cured at 3 h, 6 h and 12 h. Regarding the XRD results, calcite was detected in the 24 h and 3 days specimens, which contributes to lower pore sizes due to a higher molar volume and production of silica gel that might participate in the polymerization processes and results in densified microstructures.