Interlaminar Fracture Behavior of Carbon Fiber/Polyimide Composites Toughened by Interleaving Thermoplastic Polyimide Fiber Veils

Carbon fiber reinforced thermosetting polyimide (CF/TSPI) composites were interleaved with thermally stable thermoplastic polyimide (TPPI) fiber veils in order to improve the interlaminar fracture toughness without sacrificing the heat resistance. Both of the mode I and mode II interlaminar fracture toughness (G_IC and G_IIC) for the untoughened laminate and TPPI fiber veils interleaved laminates were characterized by the double cantilever beam (DCB) test and end notch flexure (ENF) test, respectively. It is found that the TPPI fiber veils interleaved laminates exhibit extremely increased fracture toughness than the untoughened one. Moreover, the areal density of TPPI greatly affected the fracture toughness of laminates. A maximum improvement up to 179% and 132% on G_IC and G_IIC is obtained for 15 gsm fiber veils interleaved laminate, which contributes to the existence of bicontinuous TPPI/TSPI structure in the interlayer according to the fractography analysis. The interlaminar fracture behavior at elevated temperatures for 15 gsm fiber veils interleaved laminate were also investigated. The results indicated that the introduction of thermally stable TPPI fiber veils could enhance the fracture toughness of CF/TSPI composites by exceeding 200% as compared to the untoughened one even as tested at 250 °C.     

Experimental Investigation of Delamination in Composite Continuous Fiber-Reinforced Plastic Laminates with Elastic Couplings

This paper presents an experimental evaluation of influence of the elastic couplings on the fracture toughness as well as on delamination initiation and propagation in carbon/epoxy composite laminates. For this purpose the mode I double cantilever beam (DCB) tests according to the American Society for Testing and Materials (ASTM) D5528 Standard were performed on specimens with different delamination interfaces and specific lay-ups composition exhibiting the bending-twisting (BT) and the bending-extension (BE) couplings. The critical strain energy release rates (mode I c-SERR, G_IC) were calculated by using the classical methods, namely: the modified beam theory (MBT), the compliance calibration (CCM) and the modified compliance calibration (MCC). In order to evaluate an accuracy of the different methods, the values of c-SERR obtained by using standardized data reduction schemes were compared with values calculated by using the compliance based beam method (CBBM). All the methods give rise to comparable values of the G_IC, which makes the CBBM an appealing choice, since it does not depend on crack length monitoring during the test. Initiation and propagation of delamination were investigated by using the acoustic emission (AE) technique. Moreover, the scanning electron microscope (SEM) analysis were performed after the experimental tests in order to investigate a fracture surface at delamination plane.     

The Curing Kinetics of E-Glass Fiber/Epoxy Resin Prepreg and the Bending Properties of Its Products

The curing kinetics can influence the final macroscopic properties, particularly the three-point bending of the fiber-reinforced composite materials. In this research, the curing kinetics of commercially available glass fiber/epoxy resin prepregs were studied by non-isothermal differential scanning calorimetry (DSC). The curing kinetic parameters were obtained by fitting and the apparent activation energy E_a of the prepreg, the pre-exponent factor, and the reaction order value obtained. A phenomenological nth-order curing reaction kinetic model was established according to Kissinger equation and Crane equation. Furthermore, the optimal curing temperature of the prepregs was obtained by the T-β extrapolation method. A vacuum hot pressing technique was applied to prepare composite laminates. The pre-curing, curing, and post-curing temperatures were 116, 130, and 153 °C respectively. In addition, three-point bending was used to test the specimens’ fracture behavior, and the surface morphology was analyzed. The results show that the differences in the mechanical properties of the samples are relatively small, indicating that the process settings are reasonable.     

Improved Strength and Toughness of Carbon Woven Fabric Composites with Functionalized MWCNTs

This investigation examines the role of carboxyl functionalized multi-walled carbon nanotubes (COOH-MWCNTs) in the on- and off-axis flexure and the shear responses of thin carbon woven fabric composite plates. The chemically functionalized COOH-MWCNTs were used to fabricate epoxy nanocomposites and, subsequently, carbon woven fabric plates to be tested on flexure and shear. In addition to the neat epoxy, three loadings of COOH-MWCNTs were examined: 0.5 wt%, 1.0 wt% and 1.5 wt% of epoxy. While no significant statistical difference in the flexure response of the on-axis specimens was observed, significant increases in the flexure strength, modulus and toughness of the off-axis specimens were observed. The average increase in flexure strength and flexure modulus with the addition of 1.5 wt% COOH-MWCNTs improved by 28% and 19%, respectively. Finite element modeling is used to demonstrate fiber domination in on-axis flexure behavior and matrix domination in off-axis flexure behavior. Furthermore, the 1.5 wt% COOH-MWCNTs increased the toughness of carbon woven composites tested on shear by 33%. Microstructural investigation using Fourier Transform Infrared Spectroscopy (FTIR) proves the existence of chemical bonds between the COOH-MWCNTs and the epoxy matrix.     

Experimental Investigation on the Influence of Fiber Path Curvature on the Mechanical Properties of Composites

Automated fiber placement (AFP) has been widely used as an advanced manufacturing technology for large and complex composite parts and the trajectory planning of the laying path is the primary task of AFP technology. Proposed in this paper is an experimental study on the effect of several different path planning placements on the mechanical behavior of laminated materials. The prepreg selected for the experiment was high-strength toughened epoxy resin T300 carbon fiber prepreg UH3033-150. The composite laminates with variable angles were prepared by an eight-tow seven-axis linkage laying machine. After the curing process, the composite laminates were conducted by tensile and bending test separately. The test results show that there exists an optimal planning path among these for which the tensile strength of the laminated specimens decreases slightly by only 3.889%, while the bending strength increases greatly by 16.68%. It can be found that for the specific planning path placement, the bending strength of the composite laminates is significantly improved regardless of the little difference in tensile strength, which shows the importance of path planning and this may be used as a guideline for future AFP process.     

Research on the Fracture Behavior of Steel-Fiber-Reinforced High-Strength Concrete

The behavior of steel fiber concrete, which is the most widely used building material, has been widely examined. However, methods for calculating Fracture parameters differ by fracture behavior of SFHSC with different strengths. In this study, the fracture behavior of steel-fiber-reinforced high-strength concrete (SFHSC) was -investigated using three-point bending tests. A total of 144 notched concrete beams with a size of 100 mm × 100 mm × 515 mm were tested for three-point bending in 26 groups. The effects of the steel fiber volume ratio, steel fiber type, and relative notch depth on the fracture toughness (K_IC) and fracture energy (G_F) of SFHSC specimens were studied. The results show that an increase in the volume fraction of steel fiber (ρ_f) added to high-strength concrete (HSC) significantly improves the fracture behavior of HSC. As compared to milled and sheared corrugated steel fibers, cut bow steel fibers significantly improve the fracture behavior of SFHSC. The effect of incision depth changes on the K_IC and G_F of SFHSC and HSC for the comparison group has no common characteristics. With an increase in incision depth, the values of K_IC of the SFHSC specimens decrease slightly. The G_F0.5/G_F0.4 of the SFHSC specimens show a decreasing trend with an increase in ρ_f. According to the test results, we propose calculation models for the fracture behavior of SFHSC with different strengths. Thus, we present a convenient and accurate method to calculate fracture parameters, which lays a foundation for subsequent research.     

Flexural and Impact Behaviors of Mortar Composite Including Carbon Fibers

This study investigated the flexural and impact performances of mortar composite made with carbon fibers (MCCF). Four mortar composites (MCCF1, MCCF2, MCCF3, and MCCF4) were produced, using 1%, 2%, 3%, and 4% carbon fibers by volume, respectively. Another mortar composite without any carbon fibers (MCCF0) was prepared for its use as a control mix. The freshly mixed mortar composites were tested for inverted slump cone flow time to ensure they had an adequate workability to cast test specimens under vibration. In addition, all fresh mortar composites were examined for density and air content. The hardened mortar composites were tested for their first-crack flexural strength, ultimate flexural strength, first-crack impact resistance, and ultimate impact resistance. Moreover, the first-crack flexural toughness, ultimate flexural toughness, first-crack impact toughness, and ultimate impact toughness were determined for all hardened mortar composites. The correlations among the hardened properties of the mortar composites were also sought. Finally, the optimum fiber content was defined from the overall test results and considering the costs of the mortar composites. The test results showed that the workability and density of the fresh mortar composite decreased, whereas its air content increased due to the inclusion of carbon fibers. However, MCCF3 possessed the highest density and lowest air content among all MCCF mixes. It also had a higher workability than MCCF4. In the hardened state, the first-crack flexural strength and impact resistance, as well as the ultimate flexural strength and impact resistance of mortar composite, increased significantly with the increasing volume content of carbon fibers. In addition, the first-crack flexural toughness, ultimate flexural toughness, first-crack impact toughness, and ultimate impact toughness increased greatly with the higher volume content of carbon fibers. Strong correlations between the flexural strength and impact resistance, and between the flexural toughness and impact toughness of the mortar composites, were observed. Above all, excellent flexural strength, flexural toughness, impact resistance, and impact toughness values were observed for MCCF4 (4% carbon fibers). The 28-day ultimate flexural strength and impact resistance of MCCF4 increased by 4.6 MPa and 134 blows, respectively, as compared to MCCF0. Moreover, the 28-day ultimate flexural toughness and ultimate impact toughness values of MCCF4 were higher than that of MCCF0, by 3739.7 N-mm and 2703.3 J, respectively. However, MCCF3 (3% carbon fibers) also exhibited a good performance under flexural and impact loadings. Based on the costs of all mortar composites and their performances in both fresh and hardened states, MCCF3 was derived as the best mortar mix. This implies that 3% carbon fibers can be defined as the optimum fiber content in the context of the present study.     

Mechanical Properties of Flax Tape-Reinforced Thermoset Composites

Three thermoset resin systems—bio-epoxy, epoxy, and polyester-with 30 v% flax fiber reinforcement have been studied to identify the optimal fiber–resin combination in a typical composite structure. Tensile, interface and interlaminar shear strength together with flexural and impact damage tolerance were compared in this study. The results revealed that mechanical and interfacial properties were not significantly affected by the different resin systems. Microscopy studies reveal that epoxy laminates predominantly fail by fibre linear breakage, polyester laminates by fiber pull-out, and bio-epoxy laminates by a combination of the two. The higher failure strains and pull-out mechanism may explain the better impact damage tolerance of polyester composites. Flow experiments were also conducted, revealing faster impregnation and lower void content with polyester resin, followed by bio-epoxy, due to their lower viscosities. Overall, bio-epoxy resin demonstrates comparable performance to epoxy and polyester resins for use in (semi-)structural bio-composites.     

Electrical Conductivity of Glass Fiber-Reinforced Plastic with Nanomodified Matrix for Damage Diagnostic

The electrical conductivity of glass fiber-reinforced plastic (GFRP) with epoxy matrix modified by multiwall carbon nanotubes (MWCNT) was studied. The electrical conductivity of nanomodified lamina and multi-layered GFRP was investigated on several levels using a structural approach. Components of the electrical conductivity tensor for unidirectional-reinforced monolayer were calculated similarly as in micromechanics using the conductivity of the nanomodified matrix. The electrical conductivity of multilayer composite was calculated using laminate theory and compared with values measured experimentally for various fiber orientation angles. Calculated and experimental data were in good agreement. The voltage distribution measured throughout the laminate allowed detecting the damage in its volume. The electrode network located on the laminate surface could determine the location, quantification, and geometry of the damage in the GFRP lamina modified with MWCNT. Experimental and calculated electrical resistance data for GFRP double-cantilever beam specimens were investigated in Mode I interlaminar fracture toughness test. Results demonstrate that electrical resistance could be successfully used for the diagnostic of the crack propagation during interlaminar fracture of the MWCNT-modified GFRP.     

Enhanced Thermal Stability,Mechanical Properties and Structural Integrity of MWCNT Filled Bamboo/Kenaf Hybrid Polymer Nanocomposites

Recently, there has been an inclination towards natural fibre reinforced polymer composites owing to their merits such as environmental friendliness, light weight and excellent strength. In the present study, six laminates were fabricated consisting of natural fibres such as Kenaf fibre (Hibiscus cannabinus L.) and Bamboo fibre, together with multi-walled carbon nanotubes (MWCNTs) as reinforcing fillers in the epoxy matrix. Mechanical testing revealed that hybridization of natural fibres was capable of yielding composites with enhanced tensile properties. Additionally, impact testing showed a maximum improvement of ≈80.6% with the inclusion of MWCNTs as nanofiller in the composites with very high energy absorption characteristics, which were attributed to the high specific energy absorption of carbon nanotubes. The viscoelastic behaviour of hybridised composites reinforced with MWCNTs also showed promising results with a significant improvement in the glass transition temperature (Tg) and 41% improvement in storage modulus. It is worth noting that treatment of the fibres in NaOH solution prior to composite fabrication was effective in improving the interfacial bonding with the epoxy matrix, which, in turn, resulted in improved mechanical properties.     

Experimental and Numerical Study of Low-Velocity Impact and Tensile after Impact for CFRP Laminates Single-Lap Joints Adhesively Bonded Structure

To investigate the mechanical behavior of the single-lap joints (SLJs) adhesively bonded structure of carbon fiber reinforced polymer (CFRP) laminates under the low-velocity impact (LVI) and tensile-after impact (TAI), tests and simulations were carried out. A finite element model (FEM) was established based on the cohesive zone model (CZM) and Hashin criterion to predict the damage evolution process of adhesive film, intra- and inter-laminar of the SLJs of CFRP laminates, and its effectiveness was verified by experiments. Moreover, three different overlap lengths (20 mm, 30 mm, and 40 mm) and four different impact energies (Intact joint, 10 J, 20 J, and 30 J) are considered in the present study. Finally, the effects of different impact energies and overlap lengths on the residual strength of SLJs after impact were discussed. The results divulged that numerical results of impact and TAI processes of SLJs were in good agreement with experiment results. During the impact process, the damage of the laminates was primarily fiber and matrix tensile damage, whereas the adhesive film was damaged cohesively; the areas of damage increased with the increase of impact energy, and the normal stress of the adhesive film expanded from the edge to the middle region with the increase of impact force. The influence of LVI on SLJs adhesively bonded structures was very significant, and it is not effective to obtain a higher impact resistance by increasing the overlap length. For the tensile process, the failure mode of TAI of the SLJs was interface failure, the surplus strength of the SLJs gradually decreased with the increase of the impact energy because of the smaller overlap length, the overlap length more than 30 mm, and the low energy impact has almost no effect on the residual strength of the SLJs.     

Bionic Design and 3D Printing of Continuous Carbon Fiber-Reinforced Polylactic Acid Composite with Barbicel Structure of Eagle-Owl Feather

Inspired by eagle-owl feather with characteristics of light weight and high strength, the bionic continuous carbon fiber-reinforced polylactic acid composite with barbicel structure was successfully 3D printed. Under the action of external load, angles between barbicels and rachis structure of eagle-owl feather decreased, which consumed a part of energy and built structure base of bionic feather structure model with a certain arrangement angle of continuous carbon fiber. Variation of bionic structure model design parameters significantly affected the mechanical properties of the 3D printing bionic composites. The relatively low continuous carbon fiber content on tensile force direction restricted enhancement of tensile strength of bionic composite. However, attributed to different angle arrangement of continuous carbon fiber, the propagation of cracks in bionic composite was hindered, exhibiting high impact resistance. The effective and feasible bionic feather design and 3D printing of continuous carbon fiber-reinforced polylactic acid composite extended the corresponding application in the areas with high impact loads.     

Effect of Fiber Content and Alignment on the Mechanical Properties of 3D Printing Cementitious Composites

This paper studies aligned glass fiber-reinforced composites for printing. To determine the influence of fiber content and alignment on the mechanical properties of this novel material, a large number of standard test specimens were prepared, which included samples fabricated by mold-casting, randomly dispersed fiber reinforced mixtures and aligned fiber cement composites containing 10 types of fiber volume ratios manufactured by nozzle sizes ranging of 24 and 10 mm (fiber length = 12 mm). Mechanical properties and failure modes of the specimens under compression and flexural tests were studied experimentally. The anisotropic behaviors of printed samples were analyzed by different loading directions. As a result, the compressive and flexural strength of printed samples showed obvious anisotropy. With the increase of fiber volume ratio, flexural strength of the fiber reinforced composite was elevated tremendously but its compression strength reduced slightly. Moreover, fiber alignment also had a significant influence on the mechanical properties of the fiber reinforced composite. The composite cement-based material with 1 vol.-% aligned fiber exhibited an excellent flexural strength of 9.38 MPa, which increased by 483% in comparison to that of the plain cement paste.     

Transparent Fiber-Reinforced Composites Based on a Thermoset Resin Using Liquid Composite Molding (LCM) Techniques

In this study, optically transparent glass fiber-reinforced polymers (tGFRPs) were produced using a thermoset matrix and an E-glass fabric. In situ polymerization was combined with liquid composite molding (LCM) techniques both in a resin transfer molding (RTM) mold and a lite-RTM (L-RTM) setup between two glass plates. The RTM specimens were used for mechanical characterization while the L-RTM samples were used for transmittance measurements. Optimization in terms of the number of glass fabric layers, the overall degree of transparency of the composite, and the mechanical properties was carried out and allowed for the realization of high mechanical strength and high-transparency tGFRPs. An outstanding degree of infiltration was achieved maintaining up to 75% transmittance even when using 29 layers of E-glass fabric, corresponding to 50 v.% fiber, using an L-RTM setup. RTM specimens with 44 v.% fiber yielded a tensile strength of 435.2 ± 17.6 MPa, and an E-Modulus of 24.3 ± 0.7 GPa.     

Synthesis,Characterization, and Modeling of Aligned ZnO Nanowire-Enhanced Carbon-Fiber-Reinforced Composites

This paper presents the synthesis, characterization, and multiscale modeling of hybrid composites with enhanced interfacial properties consisting of aligned zinc oxide (ZnO) nanowires and continuous carbon fibers. The atomic layer deposition method was employed to uniformly synthesize nanoscale ZnO seeds on carbon fibers. Vertically aligned ZnO nanowires were grown from the deposited nanoscale seeds using the low-temperature hydrothermal method. Morphology and chemical compositions of ZnO nanowires were characterized to evaluate the quality of synthesized ZnO nanowires in hybrid fiber-reinforced composites. Single fiber fragmentation tests reveal that the interfacial shear strength (IFSS) in epoxy composites improved by 286%. Additionally, a multiscale modeling framework was developed to investigate the IFSS of hybrid composites with radially aligned ZnO nanowires. The cohesive zone model (CZM) was implemented to model the interface between fiber and matrix. The damage behavior of fiber was simulated using the ABAQUS user subroutine to define a material’s mechanical behavior (UMAT). Both experimental and analytical results indicate that the hierarchical carbon fibers enhanced by aligned ZnO nanowires are effective in improving the key mechanical properties of hybrid fiber-reinforced composites.     

Mechanical Properties of Aramid/Carbon Hybrid Fiber-Reinforced Concrete

In this study, aramid fiber (Kevlar^® 29 fiber) and carbon fiber were added into concrete in a hybrid manner to enhance the static and impact mechanical properties. The coupling agent presence on the surface of carbon fibers was spotted in Scanning Electron Microscope (SEM) and energy-dispersive X-ray spectroscopy (EDS) graphs. The carbon fiber with a coupling agent affected the mechanical strength of the reinforced concrete. At 1% fiber/cement weight percentage, the hybrid fiber-reinforced concrete (HFRC) prepared using Kevlar fiber and carbon fiber of 12 and 24 mm in length under different mix proportions was investigated to determine the maximum mechanical strengths. From the test results, the mechanical strength of the HFRC attained better performance than that of the concrete with only Kevlar or carbon fibers. Foremost, the mix proportion of Kevlar/carbon fiber (50–50%) significantly improved the compressive, flexural, and splitting tensile strengths. Under different impact energies, the impact resistance of the HFRC specimen was much higher than that of the benchmark specimen, and the damage of the HFRC specimens was examined with an optical microscope to identify slippage or rupture failure of the fiber in concrete.     

The Thickness Effect of PSF Nanofibrous Mat on Fracture Toughness of Carbon/Epoxy Laminates

The geometrical features of nanofibers, such as nanomat thickness and the diameter of nanofibers, have a significant influence on the toughening behavior of composite laminates. In this study, carbon/epoxy laminates were interleaved with polysulfone (PSF) nanofibrous mats and the effect of the PSF nanomat thickness on the fracture toughness was considered for the first time. For this goal, the nanofibers were first produced by the electrospinning method. Then, double cantilever beam (DCB) specimens were manufactured, and mode-I fracture tests were conducted. The results showed that enhancing the mat thickness could increase the fracture toughness considerably (to about 87% with the maximum thickness). The toughening mechanism was also considered by presenting a schematic picture. Micrographs were taken using a scanning electron microscope (SEM).     

Experimental and Numerical Comparison of Impact Behavior between Thermoplastic and Thermoset Composite for Wind Turbine Blades

Damage generated due to low velocity impact in composite plates was evaluated focusing on the design and structural integrity of wind turbine blades. Impact properties of composite plates manufactured with thermoplastic and thermoset resins for different energy levels were measured and compared. Specimens were fabricated using VARTM (vacuum assisted resin transfer molding), using both matrix systems in conjunction with carbon, glass and carbon/glass hybrid fibers in the NCF (non-crimp fabric) architecture. Resin systems used were ELIUM 188O (thermoplastic) from Arkema Co., Ltd. and a standard epoxy reference, EPR-L20 from Hexion Co., Ltd. (thermoset). Auxiliary numerical finite element analyses were performed to better understand the tests physics. These models were then compared with the experimental results to verify their predictive capacity, given the intrinsic limitations due to their simplicity. Based in the presented results, it is possible to observe that ELIUM is capable to replace a conventional thermoset matrix. The thermoplastic panels presented similar results compared to its thermoset counterparts, with even a trend of less impact damage. Additionally, for both thermoplastic and thermoset resin systems, glass layups showed the lowest levels of damage while carbon panels presented the highest damage levels. Hybrid laminates can be applied as a compromise solution.     

Strengthening Effect of Short Carbon Fiber Content and Length on Mechanical Properties of Extrusion-Based Printed Alumina Ceramics

Extrusion-based ceramic printing is fast and convenient, but the green body strength is too low, and the application prospect is not high. An extrusion-based printing method of alumina ceramics toughened by short carbon fiber is reported in this paper. The bending strength and fracture toughness of 3D-printed alumina ceramics were improved by adding short carbon fiber. The toughening effects of four carbon fiber lengths (100 μm, 300 μm, 700 μm, and 1000 μm) and six carbon fiber contents (1, 2, 3, 4, 5, and 6 wt%) on ceramics were compared. The experimental results show that when the length of carbon fiber is 700 μm, and carbon fiber is 5 wt%, the toughening effect of fiber is the best, and the uniform distribution of fiber is an effective toughening method. Its bending strength reaches 33.426 ± 1.027 MPa, and its fracture toughness reaches 4.53 ± 0.46 MPa·m^1/2. Compared with extrusion-based printed alumina ceramics without fiber, the bending strength and fracture toughness increase by 55.38% and 47.56%, respectively.     

Synergistical Performance Modification of Epoxy Resin by Nanofillers and Carboxyl-Terminated Liquid Nitrile–Butadiene Rubber

Epoxy composite materials are widely used in power equipment. As the voltage level increases, the requirement of material properties, including electrical, thermal, and mechanical, has also increased. Introducing thermally conductive nanofiller to the epoxy/liquid rubber composites system is an effective approach to improve heat performance, but the effects of thermally conductive nanofillers on relaxation characteristics remain unclarified. In this paper, nano-alumina (nano-Al₂O₃) and nano-boron nitride (nano-BN) have been employed to modify the epoxy/carboxyl-terminated liquid nitrile–butadiene rubber (epoxy/CTBN) composites system. The thermal conductivity and glass transition temperature of different formula systems have been measured. The effect of the nanofillers on the relaxation behaviors of the resin matrix has been investigated. Results show that the different kinds of nanofillers will introduce different relaxation processes into the matrix and increase the conductivity at the same time. This study can provide a theoretical basis for the synergistic improvement of multiple properties of epoxy resin composites.