External Condensation of HFE 7000 and HFE 7100 Refrigerants in Shell and Tube Heat Exchangers

The paper describes the results of experimental studies of media as an intermediary in heat exchange taking place in low volume conditions. Their properties predestine them both as a future-proof for transporting and storing heat materials. The paper concerns the current topic related to the miniaturization of cooling heat exchangers. There are many studies in the literature on the phase transition of refrigerants in the flow in pipe minichannels. However, there is a lack of studies devoted to the condensation process in a small volume on the surface of pipe minichannels. The authors proposed a design of a small heat exchanger with a shell-and-tube structure, where the refrigerant condenses on the outer surface of the pipe minichannels cooled from the inside with water. It is a response to the global trend of building highly efficient, miniaturized structures for cooling and air conditioning heat exchangers. Two future-proof, ecological replacements of the CFC refrigerants still present in the installations were used for the experimental research. These are low-pressure fluids HFE 7000 and HFE 7100. The tests were carried out in a wide range of changes in thermal-flow parameters: G = 20–700 kg·m⁻²s⁻¹, q = 3000–60,000 W·m⁻², t_s = 40–80 °C.     

Study on X-ray Emission Using Ultrashort Pulsed Lasers in Materials Processing

The interaction of ultrashort pulsed laser radiation with intensities of 10¹³ W cm⁻² and above with materials often results in an unexpected high X-ray photon flux. It has been shown so far, on the one hand, that X-ray photon emissions increase proportionally with higher laser power and the accumulated X-ray dose rates can cause serious health risks for the laser operators. On the other hand, there is clear evidence that little variations of the operational conditions can considerably affect the spectral X-ray photon flux and X-ray emissions dose. In order to enhance the knowledge in this field, four ultrashort pulse laser systems for providing different complementary beam characteristics were employed in this study on laser-induced X-ray emissions, including peak intensities between 8 × 10¹² W∙cm⁻² < I₀ < 5.2 × 10¹⁶ W∙cm⁻², up to 72.2 W average laser power as well as burst/bi-burst processing mode. By the example of AISI 304 stainless steel, it was verified that X-ray emission dose rates as high as H˙′(0.07) > 45 mSv h⁻¹ can be produced when low-intensity ultrashort pulses irradiate at a small 1 µm intra-line pulse distance during laser beam scanning and megahertz pulse repetition frequencies. For burst and bi-burst pulses, the second intra-burst pulse was found to significantly enhance the X-ray emission potentially induced by laser pulse and plasma interaction.     

A Low-Temperature Heat Output Photoactive Material-Based High-Performance Thermal Energy Storage Closed System

Designing and synthesizing photothermal conversion materials with better storage capacity, long-term stability as well as low temperature energy output capability is still a huge challenge in the area of photothermal storage. In this work, we report a brand new photothermal conversion material obtained by attaching trifluoromethylated azobenzene (Azo_F) to reduced graphene oxide (rGO). Azo_F-rGO exhibits outstanding heat storage density and power density up to 386.1 kJ·kg⁻¹ and 890.6 W·kg⁻¹, respectively, with a long half-life (87.7 h) because of the H-bonds based on high attachment density. Azo_F-rGO also exhibits excellent cycling stability and is equipped with low-temperature energy output capability, which achieves the reversible cycle of photothermal conversion within a closed system. This novel Azo_F-rGO complex, which on the one hand exhibits remarkable energy storage performance as well as excellent storage life span, and on the other hand is equipped with the ability to release heat at low temperatures, shows broad prospects in the practical application of actual photothermal storage.     

Effect of Fiber Shape on the Tribological,Mechanical, and Morphological Behaviors of Sisal Fiber-Reinforced Resin-Based Friction Materials: Helical,Undulated, and Straight Shapes

In this paper, we aim to evaluate the tribological, mechanical, and morphological performance of resin-based friction composites reinforced by sisal fibers with different shapes, namely helical, undulated, and straight shapes. The experimental results show that the shape of the sisal fibers exerts a significant effect on the impact property of the composite materials but no obvious influence on the density and hardness. The friction composite containing the helical-shaped sisal fibers exhibits the best overall tribological behaviors, with a relatively low fade (9.26%), high recovery (98.65%), and good wear resistance (2.061 × 10⁻⁷ cm³∙N⁻¹∙m⁻¹) compared with the other two composites containing undulated-shaped fibers and straight-shaped fibers. The impact fracture surfaces and worn surfaces of the composite materials were inspected by scanning electron microscopy, and we demonstrate that adding helical-shaped sisal fibers into the polymer composites provides an enhanced fiber–matrix interface adhesion condition and reduces the extent of fiber debonding and pullout, effectively facilitating the presence of more secondary plateaus on the friction surface, which are responsible for the enhanced tribological and mechanical properties. The outcome of this study reveals that sisal fibers with a helical shape could be a promising candidate as a reinforcement material for resin-based brake friction composite applications.     

The Effect of Heat Flux to the Fire-Technical and Chemical Properties of Spruce Wood (Picea abies L.)

The paper assesses the influence of the heat flux on spruce wood (Picea abies L.) behavior. The heat flux was performed at 15, 20, 25, and 30 kW·m⁻². The fire-technical properties, such as the mass burning rate, charring thickness, charring rate, as well as the chemical composition (contents of the extractives, lignin, cellulose, holocellulose), of wood were determined. The highest burning rate of spruce wood of 0.32%·s⁻¹ was reached at the heat flux of 30 kW·m⁻². The charring rate ranged from 1.004 mm·min⁻¹ (15 kW·m⁻²) to 2.016 mm·min⁻¹ (30 kW·m⁻²). The proposed model of the charring process of spruce wood in time and appropriate thickness as a selected parameter is applicable in validation of the results of computer fire models in the design of fire protection of wooden buildings. The decrease in the holocellulose content mostly caused by the degradation of hemicelluloses was observed during thermal loading. The biggest decrease in hemicelluloses (24.94%) was recorded in samples loaded at 30 kW·m⁻². The contents of cellulose increased due to the structural changes (carbonization and crosslinking), the content of lignin increased as well due to its higher thermal stability compared to saccharides, as well as the resulting lignin condensation.     

Influence of Orientation and Radiative Heat Transfer on Aluminum Foams in Buoyancy-Induced Convection

Two differently-produced open-cell aluminum foams were compared to a commercially available finned heat sink. Further, an aluminum plate and block were tested as a reference. All heat sinks have the same base plate dimensions of four by six inches. The first foam was made by investment casting of a polyurethane preform and has a porosity of 0.946 and a pore density of 10 pores per linear inch. The second foam is manufactured by casting over a solvable core and has a porosity of 0.85 and a pore density of 2.5 pores per linear inch. The effects of orientation and radiative heat transfer are experimentally investigated. The heat sinks are tested in a vertical and horizontal orientation. The effect of radiative heat transfer is investigated by comparing a painted/anodized heat sink with an untreated one. The heat flux through the heat sink for a certain temperature difference between the environment and the heat sink’s base plate is used as the performance indicator. For temperature differences larger than 30 ^°C, the finned heat sink outperforms the in-house-made aluminum foam heat sink on average by 17%. Furthermore, the in-house-made aluminum foam dissipates on average 12% less heat than the other aluminum foam for a temperature difference larger than 40 ^°C. By painting/anodizing the heat sinks, the heat transfer rate increased on average by 10% to 50%. Finally, the thermal performance of the horizontal in-house-made aluminum foam heat sink is up to 18% larger than the one of the vertical aluminum foam heat sink.     

Wear Behavior of a Heat-Treatable Al-3.5Cu-1.5Mg-1Si Alloy Manufactured by Selective Laser Melting

In this study, the wear behavior of a heat-treatable Al-7Si-0.5Mg-0.5Cu alloy fabricated by selective laser melting was investigated systematically. Compared with the commercial homogenized AA2024 alloy, the fine secondary phase of the SLM Al-Cu-Mg-Si alloy leads to a low specific wear rate (1.8 ± 0.11 × 10⁻⁴ mm³(Nm)⁻¹) and a low average coefficient of friction (0.40 ± 0.01). After the T6 heat treatment, the SLM Al-Cu-Mg-Si alloy exhibits a lower specific wear rate (1.48 ± 0.02 × 10⁻⁴ mm³(Nm)⁻¹), but a similar average coefficient of friction (0.34 ± 0.01) as the heat-treated AA2024 alloy. Altogether, the SLM Al-3.5Cu-1.5Mg-1Si alloy is suitable for the achievement of not only superior mechanical performance, but also improved tribological properties.     

Heat transport in bubbling turbulent convection

Boiling is an extremely effective way to promote heat transfer from a hot surface to a liquid due to numerous mechanisms, many of which are not understood in quantitative detail. An important component of the overall process is that the buoyancy of the bubble compounds with that of the liquid to give rise to a much-enhanced natural convection. In this article, we focus specifically on this enhancement and present a numerical study of the resulting two-phase Rayleigh–Bénard convection process in a cylindrical cell with a diameter equal to its height. We make no attempt to model other aspects of the boiling process such as bubble nucleation and detachment. The cell base and top are held at temperatures above and below the boiling point of the liquid, respectively. By keeping this difference constant, we study the effect of the liquid superheat in a Rayleigh number range that, in the absence of boiling, would be between 2 × 10⁶ and 5 × 10⁹. We find a considerable enhancement of the heat transfer and study its dependence on the number of bubbles, the degree of superheat of the hot cell bottom, and the Rayleigh number. The increased buoyancy provided by the bubbles leads to more energetic hot plumes detaching from the cell bottom, and the strength of the circulation in the cell is significantly increased. Our results are in general agreement with recent experiments on boiling Rayleigh–Bénard convection.     

Effect of Ga on the Oxide Film Structure and Oxidation Resistance of Sn–Bi–Zn Alloys as Heat Transfer Fluids

The effect of gallium on the oxide film structure and overall oxidation resistance of low melting point Sn–Bi–Zn alloys was investigated under air atmosphere using thermogravimetric analyses. The liquid alloys studied had a Ga content of 1–7 wt.%. The results showed that the growth rates of the surface scale formed on the Sn–Bi–Zn–Ga alloys conformed to the parabolic law. The oxidation resistance of Sn–Bi–Zn alloys was improved by Ga addition and the activation energies increased from 12.05 kJ∙mol⁻¹ to 22.20 kJ∙mol⁻¹. The structure and elemental distribution of the oxide film surface and cross-section were found to become more complicated and denser with Ga addition. Further, the results of X-ray photoelectron spectroscopy and X-ray diffraction show that Ga elements accumulate on the surface of the liquid metal to form oxides, which significantly slowed the oxidation of the surface of the liquid alloy.     

Influence of Ti-Si-N Nanocomposite Coating on Heat Radiation Resistance of Fireproof Fabrics

Fireproof fabrics are commonly used for protection of fireguards. Such materials must be characterized by improved heat resistance, especially to radiation and flame. In this paper, fireproof fabric (NATAN and PROTON—trademark names) was covered with Ti-Si-N nanocomposite reflective coating using magnetron sputtering. The fabrics were subjected to heat radiation of heat flux density from 0.615 to 2.525 kW/m². A testing stage equipped with a heat source, thermal imaging camera and thermocouples was used. Two variants of the coatings were studied: Ti-Si and (Ti,Si)N considering different thicknesses of layers. The temperature increment and time to reach the pain threshold (60 °C) which corresponds approximately to a 2nd-degree burn according to Henriques criterion were analyzed. In addition, the microstructural analysis of the samples using a scanning electron microscope (SEM) equipped with energy dispersive spectroscopy (EDS) system was performed. The improvement of heat resistance showed for Ti-Si-coated PROTON and NATAN for all tested heat flux densities. Time to reach 60 °C for PROTON fabric increased maximally from 11.23 s (without coating) to 13.13 s (Ti-Si coating) for heat flux density of 0.615 kW/m² and for NATAN—maximally from 7.76 s (without coating) to 11.30 s (Ti-Si coating) for the same heat flux density.     

Selective Laser Melting of Stainless Steel 316L with Face-Centered-Cubic-Based Lattice Structures to Produce Rib Implants

Selective laser melting has a great potential to manufacture biocompatible metal alloy scaffolds or implants with a regulated porosity structure. This study uses five face-centered cubic (FCC) lattice structures, including FCC, FCC-Z, S-FCC, S-FCC-Z, and FCC-XYZ. Specimens with different lattice structures are fabricated using two laser energy densities, 71 J/mm³ and 125 J/mm³. Density, tensile, compressive and flexural test results exhibit the effect of laser parameters and lattice structure geometries on mechanical properties. The higher laser energy density of 125 J/mm³ results in higher properties such as density, strength, and Young’s modulus than the laser energy density of 71 J/mm³. The S-FCC lattice has the lowest density among all lattices. The mechanical tests result show specimen with FCC-XYZ lattice structures fabricated using a laser energy density of 125 J/mm³ meet the tensile properties requirement for human ribs. This structure also meets the requirement in flexural strength performance, but its stiffness is over that of human ribs. The compression test results of lattices are still incomparable due to unavailable compression data of the human ribs. In short, The FCC-XYZ lattice design fabricated by the 125 J/mm³ laser energy density parameter can be used to manufacture customized rib implants.     

Preparation and Properties of Electrodeposited Ni-B-Graphene Oxide Composite Coatings

With the rapid development of modern industries, the surface quality and performance of metals need to be improved. Composite electrodeposition (co-deposition) has evolved as an important technique for improving the surface performance of metal materials. Herein, a new type of graphene oxide (GO)-reinforced nickel–boron (Ni-B) composite coating was successfully prepared on a 7075 aluminum (Al) alloy by co-deposition. Characterization revealed a significant improvement in the mechanical and anti-corrosion properties of the composite with the incorporation of GOs. The composite showed a rougher, compact, cauliflower-like morphology with finer grains, a higher hardness (1532 HV), a lower rate of wear (5.20 × 10⁻⁵ mm³∙N⁻¹∙m⁻¹), and a lower corrosion rate (33.66 × 10⁻³ mm∙y⁻¹) compared with the Ni-B alloy deposit (878 HV, 9.64 × 10⁻⁵ mm³∙N⁻¹∙m⁻¹, and 116.64 × 10⁻³ mm∙y⁻¹, respectively). The mechanism by which GOs strengthen the Ni-B matrix is discussed.     

From the Cover: Superconducting characteristics of 4-? carbon nanotube–zeolite composite

We have fabricated nanocomposites consisting of 4-Å carbon nanotubes embedded in the 0.7-nm pores of aluminophosphate-five (AFI) zeolite that display a superconducting specific heat transition at 15 K. MicroRaman spectra of the samples show strong and spatially uniform radial breathing mode (RBM) signals at 510 cm⁻¹ and 550 cm⁻¹, characteristic of the (4, 2) and (5, 0) nanotubes, respectively. The specific heat transition is suppressed at >2 T, with a temperature dependence characteristic of finite-size effects. Comparison with theory shows the behavior to be consistent with that of a type II BCS superconductor, characterized by a coherence length of 14 ± 2 nm and a magnetic penetration length of 1.5 ± 0.7 μm. Four probe and differential resistance measurements have also indicated a superconducting transition initiating at 15 K, but the magnetoresistance data indicate the superconducting network to be inhomogeneous, with a component being susceptible to magnetic fields below 3 T and other parts capable of withstanding a magnetic field of 5 T or beyond.     

Influence of Mineralogical Structure of Mold Flux Film on Heat Transfer in Mold during Continuous Casting of Peritectic Steel

The mineralogical structure of flux films is a critical factor in controlling heat transfer in the mold and avoiding the longitudinal cracking of slabs during the continuous casting of peritectic steel. In this study, the layered structure, crystallization ratio, mineralogical species, and morphology features of flux films were characterized by optical microscopy, X-ray diffraction, and electron-probe microanalysis. Microstructural observation revealed that the normal flux films for peritectic steels present a multilayered structure and high crystallization ratio (60~90 vol%), mainly composed of well-developed crystalline akermanite and cuspidine. In contrast, the films with outstanding flux characteristics with abundant longitudinal cracks on the slab surface have a low crystallization ratio (<50 vol%) or vast crystallite content (>80 vol%). Furthermore, heat transfer analysis showed that the low crystallization ratio and the vast crystallite content of flux films worsen the heat transfer rate or uniformity in the mold, whereas the appropriate thickness and cuspidine content of flux films can improve the heat transfer performance. From the above results, it is concluded that using strong crystalline flux to obtain the ideal mineral phase structure of flux film is one of the important measures for reducing longitudinal cracks during continuous casting of peritectic steel slabs.     

Cooling Subgrade Effectiveness by L-Shaped Two-Phase Closed Thermosyphons with Different Inclination Angles and XPS Insulation Boards in Permafrost Regions

This study focused on the coupling heat transfer mechanism and the cooling efficiency of L-shaped two-phase closed thermosyphons (L-shaped TPCTs) in the wide subgrade of permafrost regions. Considering the fact that time–space dynamics change the effects of the air temperature, wind speed, and geotemperature, a coupled air temperature–L-shaped TPCT–subgrade soil heat transfer model was established using the ANSYS 15.0 software platform, and the rationality of the model was verified through measured data. The heat-transfer characteristics of the L-shaped TPCTs and the long-term thermal stability of the subgrade were studied under different inclination angles of the evaporator (α = 15°, 30°, 50°, 70°, and 90°). Then, the cooling effectiveness of a composite subgrade with TPCTs and an XPS insulation board was numerically calculated. The results show that the heat flux of the L-shaped TPCT was the greatest when α = 50°, and the heat flux reached the maximum value of 165.7 W·m⁻² in January. The L-shaped TPCT had a relatively good cooling effect on the subgrade as a whole when α = 50° and 70°, but the thawing depth at the center of the subgrade with L-shaped TPCTs reached 9.0 m below the ground surface in the 30th year. The composite subgrade with L-shaped TPCTs/vertical TPCT/XPS insulation board is an effective method to protect the permafrost foundation and improve the long-term thermal stability of the wide subgrade. The maximum heat flux of evaporation section of the L-shaped TPCT is 18.8% higher than that of the vertical TPCT during the working period of the TPCTs of the composite subgrade.     

Two-Dimensional Heterostructure of PPy/CNT–E. coli for High-Performance Supercapacitor Electrodes

The nano-biocomposite electrodes composed of carbon nanotube (CNT), polypyrrole (PPy), and E. coli-bacteria were investigated for electrochemical supercapacitors. For this purpose, PPy/CNT–E. coli was successfully synthesized through oxidative polymerization. The PPy/CNT–E. coli electrode exhibited a high specific capacitance of 173 F∙g⁻¹ at the current density of 0.2 A∙g⁻¹, which is much higher than that (37 F∙g⁻¹) of CNT. Furthermore, it displayed sufficient stability after 1000 charge/discharge cycles. The CNT, PPy/CNT, and PPy/CNT–E. coli composites were characterized by x-ray diffraction, scanning electron microscopy, and surface analyzer (Brunauer–Emmett–Teller, BET). In particular, the pyrrole monomers were easily adsorbed and polymerized on the surface of CNT materials, as well as E. coli bacteria enhanced the surface area and porous structure of the PPy/CNT–E. coli composite electrode resulting in high performance of devices.     

Recycling Black Tea Waste Biomass as Activated Porous Carbon for Long Life Cycle Supercapacitor Electrodes

Value creation through waste recycling is important for a sustainable society and future. In particular, biomass, which is based on crops, is a great recyclable resource that can be converted into useful materials. Black tea is one of the most cultivated agricultural products in the world and is mostly discarded after brewing. Herein, we report the application of black tea waste biomass as electrode material for supercapacitors through the activation of biomass hydrochar under various conditions. Raw black tea was converted into hydrochar via a hydrothermal carbonization process and then activated with potassium hydroxide (KOH) to provide a large surface area and porous structure. The activation temperature and ratio of KOH were controlled to synthesize the optimal black tea carbon (BTC) with a large surface area and porosity suitable for use as electrode material. This method suggests a direction in which the enormous amount of biomass, which is simply discarded, can be utilized in the energy storage system. The synthesized optimal BTC has a large surface area of 1062 m² and specific capacitance up to 200 F∙g⁻¹ at 1 mV∙s⁻¹. Moreover, it has 98.8% retention of charge–discharge capacitance after 2000 cycles at the current density of 5 A∙g⁻¹.     

Laser Boronizing of Additively Manufactured 18Ni-300 Maraging Steel Part Surface

The problem of insufficient wear resistance of maraging steels (MSt) has so far been solved mainly by the use of the thermochemical nitriding process, which has a number of limitations and disadvantages. In the present work, for MSt parts manufactured by laser powder bed fusion (LPBF), a more flexible laser alloying process was suggested as an alternative surface hardening process. The purpose of the present work is to give a better understanding on the possible hardening effect obtainable when amorphous boron is used as an alloying additive in relation with microstructural evolution and specific process parameters and to promote further development of this technology. For the alloying, a one kilowatt CO₂ laser was applied at 0.5–4.0 mm laser spot and 250–1500 mm/min laser operating speed, providing 50,955–796 W∙cm⁻² power density and 24.0–4.0 J∙mm⁻¹ heat input. Before laser processing, surfaces were covered with amorphous boron. The appropriate melt pool geometry was obtained at 0.5 mm laser spot, for which XPS analysis revealed an increase in boron concentration from ~3.1 to ~5.7 wt.% with a laser speed increase from 500 to 1500 mm/min. XRD analysis revealed domination of Fe₃B type borides along with the presence of FeB, Fe₂B, Ni₄B₃ borides, austenitic and martensitic phases. The microstructure of modified layers exhibited evolution from hypoeutectic microstructure, having ~630–780 HK0.5 hardness, to superfine lamellar nanoeutectic (~1000–1030 HK0.2) and further to submicron-sized dendritic boride structure (~1770 HK0.2). Aging of laser-boronized layers resulted in the change of phase composition and microstructure, which is mainly expressed in a plenty precipitation of Mo₂B₅ borides and leads to a reduction in hardness—more significant (by ~200–300 HK0.2) for hypoeutectic and hypereutectic layers and insignificant (by ~50 HK0.2) for near-eutectic. With the application of the laser boronizing technique, the hardness of MSt parts surface was increased up to ~three times before aging and up to ~2.3 times after aging, as compared with the hardness of aged MST part.     

Effect of Metal Foam Insert Configurations on Flow Boiling Heat Transfer and Pressure Drop in a Rectangular Channel

Heat transfer under flow boiling is better in a rectangular channel filled with open-cell metal foam than in an empty channel, but the high pressure drop is a drawback of the empty channel method. In this study, various types of metal foam insert configurations were tested to reduce the pressure drop while maintaining high heat transfer. Specifically, we measured the boiling heat transfer and pressure drop of a two-phase vertical upward flow of R245fa inside a channel. To measure the pressure and temperature differences of the metal foam, differential pressure transducers and T-type thermocouples were used at both ends of the test section. While the saturation pressure was kept constant at 5.9 bar, the steam quality at the inlet of the test section was changed from 0.05 to 0.99. The channel height, moreover, was 3 mm, and the mass flux ranged from 133 to 300 kg/m²s. The two-phase flow characteristics were observed through a high-speed visualization experiment. Heat transfer tended to increase with the mean vapor quality, and, as expected, the fully filled metal foam channel offered the highest thermal performance. The streamwise insert pattern model had the lowest heat transfer at a low mass flux. However, at a higher mass flux, the three different insert models presented almost the same heat transfer coefficients. We found that the streamwise pattern model had a very low pressure drop compared to that of the spanwise pattern models. The goodness factors of the flow area and the core volume of the streamwise patterned model were higher than those of the full-filled metal foam channel.