Analysis of the Temperature Distribution on the Surface of Saddle-Shaped Briquettes Consolidated in the Roller Press

The unit pressure in the fine-grained material consolidation process in the roller press can reach over hundred MPa and is a parameter which results, among other things, from the properties of the consolidated material and the compaction unit geometry. Its value changes depending on the place on the molding surface. Generating different pressure on the surface of briquettes makes their compaction different. One’s own and other researchers’ experience shows that, in the case of exerting high pressure on the merged fine-grained material, the higher unit pressure exerted on the material, the higher temperature of the consolidated material is. The temperature distribution on the surface of the briquettes can testify the locally exerted pressure on the briquette. The stress distribution in the briquetting material is still a subject of research. The article includes thermography studies of the briquetting process of four material mixtures. Thermal images of briquettes were taken immediately after they left the compaction zone as well as forming rollers. The obtained thermograms and temperature variability at characteristic points of the surface of briquettes were analyzed. The correlation between the temperature distribution and the stress distribution in the briquettes was determined.     

Thermal and Stress Properties of Briquettes from Virginia Mallow Energetic Crops

The article discusses the influence of briquetting/compaction parameters. This includes the effects of pressure and temperature on material density and the thermal conductivity of biomass compacted into briquette samples. Plant biomass mainly consists of lignin and cellulose which breaks down into simple polymers at the elevated temperature of 200 °C. Hence, the compaction pressure, compaction temperature, density, and thermal conductivity of the tested material play crucial roles in the briquetting and the torrefaction process to transform it into charcoal with a high carbon content. The tests were realized for samples of raw biomass compacted under pressure in the range from 100 to 1000 bar and at two temperatures of 20 and 200 °C. The pressure of 200 bar was concluded as the most economically viable in briquetting technology in the tests conducted. The conducted research shows a relatively good log relationship between the density of the compacted briquette and the compaction pressure. Additionally, higher compaction pressure resulted in higher destructive force of the compacted material, which may affect the lower abrasion of the material. Regarding heat transfer throughout the sample, the average thermal conductivity for the compacted biomass was determined at a value of 0.048 ± 0.001 W/(K∙m). Finally, the described methodology for thermal conductivity determination has been found to be a reliable tool, therefore it can be proposed for other applications.     

Influence of the Die Height on the Density of the Briquette Produced from Shredded Logging Residues

An alternative to plant biomass of various origins are forest logging residues. They differ significantly from other, previously used plant materials. This difference is due to the heterogeneous composition and relatively large size of individual particles. This research on the compaction of this type of shredded material was aimed at determining the influence of the die height on the density and relaxation of briquettes. This parameter is crucial for the proper construction of compaction devices. The measurements were carried out for the same fractional composition of the shredded logging residues, with variable input parameters of the material and process. It was found that the briquette density and relaxation are influenced by the die height, as well as the material moisture content and process temperature. The highest density at maximum compaction pressure (1.40 g·cm^–3) was obtained at a moisture content of 16%, temperature of 80 °C, and the lowest die height (195 mm). In the case of the briquette density after ejection from the die, the best results were obtained at the same temperature and die height but at a moisture content of 9%. The tests confirmed that, regardless of the process temperature and material moisture, the briquette density increases as the die height is reduced. The relaxation coefficient of compacted logging residues ranges from 21.7% to 50.1% and depends mainly on the material moisture content and the temperature of the process. The lowest value of the relaxation coefficient (21.7 ± 1.61) was obtained at 9% moisture content, 60 °C temperature, and 220 mm die height.     

Modelling of the Fine-Grained Materials Briquetting Process in a Roller Press with the Discrete Element Method

By using the Altair^® EDEM™ software, which implements the discrete element method, modelling and further study of the processes occurring in the roller press’s deformation area were carried out. It was shown that the discrete element method makes it possible to accurately describe the phenomena occurring in the area of roller press deformation compared with the finite element method. Models of material compaction in a roller press are developed using calcium hydroxide (slaked lime) and copper ore concentrate. The developed model makes it possible to determine the process’s energy parameters and the material’s compaction characteristics, taking into account the characteristics of its constituent particles. It was shown that discrete element modelling could be used effectively to create roller presses that provide rational characteristics of the briquetting process, taking into account the properties of the material being briquetted and the operating modes of the equipment. The results of the studies provided the basis for the applicability of the development of the discrete element method for describing the phenomena occurring in roller presses and accelerating the design of press equipment and briquetting technological processes.     

The Analysis of the Morphology of the Saddle-Shaped Bronze Chips Briquettes Produced in the Roller Press

This paper presents the results of the investigations of the properties of saddle-shaped copper alloy chips briquettes produced in a roller press. The physical and mechanical properties of the investigated briquettes were examined on their external surfaces as well as on their cross-sections. The density, chemical composition, microstructure analysis obtained with a 3D and scanning microscope, surface roughness and hardness of the obtained briquettes were investigated. The research proved the differentiation of the physical and mechanical properties of briquettes depending on the investigated area of their surface. The analysis of changes in the porosity of briquettes on their cross-section showed zones of various densification levels. This research expands the knowledge of the processes taking place during the compaction and consolidation of granular materials in roller presses as well as the knowledge concerning designing the geometry of forming tools.     

The Wear on Roller Press Rollers Made of 20Cr4/1.7027 Steel under Conditions of Copper Concentrate Briquetting

This paper defines the wear process of rollers made of 20Cr4. Rollers with a diameter of 1000 mm were installed in a roller press used for the production of drop-shaped briquettes and the copper concentrate was briquetted for 1100 h. Three-dimensional (3D) geometry analysis, metallographic analysis, macroscopy, scanning electron microscopy, as well as hardness measurements were performed. It was observed that the working surface was non-uniformly worn. The smallest wear affects the molding cavities situated on the outermost edges of the ring. The wear increases as the center of the ring is approximated, and it reaches its maximum at the middle of the ring. The molding cavities also wear asymmetrically. For the shape considered in this study, the lower part of a cavity is subject to a higher wear rate. We found that the material of the working ring was carburized, but its hardness was significantly lower than required. The roller ring microstructure changes depended on the distance from the cavity’s face. An investigation of the wear mechanisms showed different types of abrasive wear, corrosive processes, and plastic deformation. The exact type and course of wear were described, depending on the location on the working surface.     

Dispersed Power Production in Terms of the Potential of Briquettes Made from Straw and Willow as Renewable Sources of Energy

The rapid development of agricultural technologies has triggered new possibilities of using plant waste as fuel. Briquetting plant material is one of the methods of using crop residue as permanent energy carriers. Nevertheless, to maintain the normalised properties of briquettes, their small-scale production should follow an established and well-considered deliberate technological process limiting production costs. The material to be used for energy production should, in particular, be pre-prepared in terms of crushing and moisture content to ensure the right product parameters. The article aims to provide an analysis of briquettes with varied physicochemical parameters to determine and order homogenous groups for selected parameters characteristic for briquettes made from various bioenergy materials. The specific aim of the article required a statistical analysis as a tool for separating the selected factors. An analysis of variance (ANOVA) was involved, together with a post-hoc Duncan test. The analyses demonstrated that the briquette composition, such as bulk value, moisture, and ash content can enhance the briquette quality. In discussion, the straw used was compared with other kinds of agricultural biomass samples and considerable differences were identified. The chemical analysis showed a high content of carbon (from 42.64 to 45.66%) and oxygen (from 47.60 to 49.68%). The percentage share of hydrogen in the chemical structure of the materials accounted for approximately 6%. The ash content found while investigating various straw types ranged from 3.67 to 4.26%, making it lower than reported in the literature. The study also looked at the energetic potential of straw and wood biomass. It was noticed that bioenergetic sources are much potentially higher than the materials used in the traditional power sector. Especially where it concerns an unlimited source that can be provided to the bio-energetic sector. The study is intended to focus the future energy sector on the use of bioenergy in terms of applying straw to energy production purposes.     

Influence of the Direction of Mixture Compaction on the Selected Properties of a Hemp-Lime Composite

The aim of the research presented in the article was to check the differences in the hygro-thermal and mechanical properties of hemp-lime composites with different shives fractions, depending on the direction of mixture compaction. The research part of the paper presents the preparation method and investigation on the composites. Thermal conductivity, capillary uptake, as well as flexural and compressive strengths were examined. Additionally, an analysis of the temperature distribution in the external wall insulated with the tested composites was performed. The results confirm that the direction of compaction influences the individual properties of the composites in a similar way, depending on the size of the shives. The differences are more pronounced in the case of the composite containing longer fractions of shives. Both thermal conductivity of the material and the capillary uptake ability are lower in the parallel direction of the compaction process. Composites exhibit greater stiffness, but they fail faster with increasing loads when loaded in the direction perpendicular to compaction.     

贵州省燃煤型氟中毒地区的氟源新认识

目的：调查贵州省燃煤型氟中毒地区的氟源。方法：测定3个典型氟中毒重病村的煤、拌煤粘土、煤饼、煤饼灰的含氟量；调查贵州省煤含氟量。结果：化落、马家庄、偏坡寨3个村子的煤氟分别为107．8、104．1、117．6mg/kg，拌煤粘土氟分别为6103．7、1900．5、2619．7mg/kg，煤饼氟分别为805．3、480．7、1713．6mg/kg，煤饼灰氟分别为639．6、332．5、841．7mg/kg；贵州省煤氟均值为115．5mg/kg.结论:氟源主要是拌煤粘土，其含氟量一般很高。     

The effect of Bacillus thuringiensis israelensis [H-14] on emergence of Mansonia mosquitos from natural breeding habitat

The measurement of the ultimate effects of the microbial insecticides on mosquito density is best obtained by assessment of adult populations. The main aims of this study are: (1) to assess the effect of Bacillus thuringiensis israelensis (Bti) FC Skeetal and Bactimos briquettes on the emergence rate of Mansonia bonneae developed from the introduced first-instar stage larvae and (2) to measure the effect of these two formulations of insecticides on Mansonia adult populations emerging from the natural breeding plots. Bti Skeetal and Bactimos briquettes at the lower applied dosages of 2.3 kg/ha and 1 briquette case/20 m2 respectively achieved 39-40% pupation rates and 31.5-34.2% adult emergence rates. At these low applied dosages, there was little or no direct effect on pupation from the surviving larvae and thereafter on the emergence of adults from the pupae. A two-fold increase in dosage, however, produced a drastic decline in the pupation rate and adult emergence rate. The rates dropped to 6.5% (pupation) and 4.3% (adult emergence) of the total larvae for Bactimos briquettes and to merely 1.5% (pupation) and 1.3% (adult emergence) of the total larvae for Skeetal. In studying the effect of Bti on the field populations of Mansonia mosquitos, two plots each were treated with Bactimos at 1 briquette case/10 m2 and Skeetal at 4.6 kg/ha. A wooden pyramid-shaped screened cage was placed on a cluster of host plants for a period of 2 weeks to trap the emerging adult mosquitoes. There were a total of 24 clusters of host plants in each plot.(ABSTRACT TRUNCATED AT 250 WORDS)     

Recovery of Waste with a High Iron Content in the Context of the Circular Economy

In order to apply the concepts that allow the transition from a linear to a circular economy, waste generators and/or processors must identify those variants that generate products that can be used as secondary raw materials, thus also respecting the actions governing sustainable development. This paper presents such a variant, the briquetting of waste with high iron content, waste generated on current flows in steel enterprises or deposited in industrial sites. The obtained briquettes are analyzed for chemical and mechanical characteristics so that can be used as secondary materials in the steel production. An optimization of the chemical composition using generic algorithms is also proposed in order to obtain the mechanical characteristics necessary for the proper handling of these products.     

Effect of Alkali and Sulfate on the Hydration Characteristic of Cement-Based Materials Containing Coal Gasification Slag

Coal gasification slag is an inevitable by-product of the coal gasification process. This paper explored the feasibility of using activators (calcium hydroxide, sodium hydroxide, calcium sulfate, sodium sulfate) to promote the pozzolanic activity of milled coal gasification coarse slags (MCS), and analyzed the effect of alkali and sulfate activators on the hydration characteristic of cement-based materials containing MCS. Coal gasification slags with ignition lossses more than 15% were removed and the remaining slags were considered as cementitious material after milling. Scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA) and hydration heat tests were employed to analyze the hydration mechanism of the samples. Besides, the compressive strength values of cement mortars with MCS and activators were evaluated. The results showed that calcium hydroxide was conductive to the formation of hydration products and its crystallization could contribute to the strength improvement of the sample. Calcium sulfate mainly participated in the hydration process of cement to form ettringite (AFt) phases. Sodium hydroxide could accelerate the dissolution of active mineral phases of MCS, resulting in the pozzolanic activity being enhanced. Moreover, sodium sulfate could not only increase the formation of AFt phases, but also improved the alkalinity in sample to facilitate the production of gels. Among them, a better promotion effect could be obtained from the combined application of calcium hydroxide and sodium sulfate. In addition, the compressive strength values of cement mortars containing MCS tended to increase when activators were used. The sample activated by calcium hydroxide and sodium sulfate exhibited the highest strength, increasing by 18.55% at 28 days compared with the sample without an activator.     

Experimental Compaction of a High-Silica Sand in Quasi-Static Conditions

In the compaction process, an uneven densification of the powder through the entire height of the die is a major problem which determines the strength properties of the final product, which vary throughout the entire volume. The aim of this investigation was to determine the distribution of the forming pressure inside the die and to visualise the differences in compaction. To determine the pressure inside the die during the compaction process, the deformation on the die surface was measured by means of strain gauges. However, in order to visualise the densification of high-silica sand during the compaction process, an X-ray tomograph was used, which permits one to visualise the interior of the die. The authors developed an analytical model of how the change in internal pressure influences the change in stresses arising on the outer surface of the die, and, as a result, the friction force. It has been observed that the highest values of pressure as well as the highest concentrations of the loose medium are found closest to the punch and decrease with distance from the punch. Moreover, based on the measurements of deformation, a dependence of the pressure distribution on the value of friction forces was observed, which prompted further analysis of this phenomenon. As a result, tests to determine the coefficient of friction between the die and the loose medium were carried out. This made it possible to describe the pressure distribution inside the die, based on the pressure applied and the height of the die.     

Tribotechnical Properties of Sintered Antifriction Aluminum-Based Composite under Dry Friction against Steel

The disadvantage of antifriction Al–Sn alloys with high tin content is their low bearing capacity. To improve this property, the aluminum matrix of the alloys was alloyed with zinc. The powder of Al–10Zn alloy was blended with the powder of pure tin in the proportion of 40/60 (wt.%). The resulting mixture of the powders was compacted in briquettes and sintered in a vacuum furnace. The sintered briquettes were subjected to subsequent pressing in the closed press mold at an elevated temperature. After this processing, the yield strength of the sintered (Al–10Zn)–40Sn composite was 1.6 times higher than that of the two-phase Al–40Sn one. The tribological tests of the composites were carried out according to the pin-on-disk scheme without lubrication at pressures of 1–5 MPa. It was established that the (Al–10Zn)–40Sn composite has higher wear resistance compared with the Al–40Sn one. However, this advantage becomes insignificant with an increase in the pressure. It was found that the main wear mechanism of the investigated composites under the dry friction process is a delamination of their highly deformed matrix grains.     

Gradation Design and Parameter Determination of Warm-Mix-Agent-Modified Asphalt Mixture

In order to make up for inadequacies such as high energy cost in the production process and quantities of waste gas and dust release of hot-mix asphalt (HMA), warm-mix asphalt (WMA) has been developed. In this paper, the preparation process of WMA mixture is simply introduced. According to the experimental approach of asphalt binder and asphalt mixture, EC-120 is preliminarily selected as a follow-up research object after a rheological property test and a viscosity test of five kinds of warm-mix-agent-modified asphalts combined with cost analysis. A target mix proportion of SBS~AC-16 is designed, and then through the orthogonal design of the four parameters of the Marshall test of WMA mixture, such as mixing temperature, warm-mix-agent content, compaction blows, and mixing time, the best Marshall test parameters are obtained. The results show that the best parameters are 145 °C of mixing temperature, 3% of warm-mix-agent content, 75 compaction times, and 90 s of mixing time. This study can provide technical support and reference for the construction of WMA pavement in China.     

Enhanced calcium bioavailability from a solubilized form of calcium citrate

An improved formulation of calcium citrate with higher aqueous solubility and bioavailability was sought. Mixtures of calcium hydroxide and citric acid, with a calcium to citrate molar ratio ranging from 0.67-1.5, dissolved rapidly in water, creating a metastably supersaturated solution. The presence of an excess of citrate in the mixture delayed the precipitation of calcium citrate and kept calcium in solution longer. Thus, the mixture with a calcium to citrate molar ratio of 1.25, containing 500 mg elemental calcium, dissolved in 300 mL water within 2 min and could be kept in solution for 1 h at a wide pH range between 2 and 7. Intestinal calcium absorption, measured from the increment in urinary calcium during the second 2 h following an oral calcium load (500 mg) in 15 normal subjects was significantly higher from the mixtures (calcium to citrate molar ratios of 1.5 and 1.25) than from tricalcium dicitrate. The fractional calcium absorption, obtained from fecal recovery of radiocalcium after oral administration of 500 mg calcium prelabeled with 47Ca in 11 normal subjects, was also higher for the mixture with a calcium to citrate molar ratio of 1.25. The most efficient calcium absorption was obtained with the mixture of calcium hydroxide and citric acid with a calcium to citrate molar ratio of 1.25. The increment in urinary calcium after an oral load with this mixture was 62.4% greater than that obtained with tricalcium dicitrate [0.138 +/- 0.056 (+/- SD) vs. 0.085 +/- 0.086 mg/dL glomerular filtrate; P less than 0.05]. The fractional calcium absorption was 88.4% higher (0.324 +/- 0.107 vs. 0.172 +/- 0.061; P less than 0.05). This mixture provided the highest concentration of ionic calcium, indicating that calcium (rather than calcium-citrate complex) is the fraction absorbed from the intestinal tract. This study, therefore, suggests that a liquid calcium preparation formulated from the mixture of calcium hydroxide and citric acid is more effective than a solid preparation of tricalcium dicitrate in providing soluble and bioavailable calcium.     

Long-Term Performance Evolution of RIOHTrack Pavement Surface Layer Based on DMA Method

Asphalt mixture is a typical viscoelastic material, and its road performance will change with the action of environment and load during actual service. This study conducted experimental research on the surface course asphalt mixture of three categories and six typical structures of RIOHTrack based on the Dynamic Mechanical Analysis method. Moreover, this study explored the performance evolution law of asphalt mixture under the coupling action of load and environment in the process of loading from 0 million to 54 million standard axle times. Results demonstrated that the phase transition characteristic temperature of the surface course materials of the three types of typical structures showed a trend of first increasing and then decreasing with the accumulation of load and environmental effects, indicating the presence of two stages of the dual coupling effect of environmental aging and load rolling on the asphalt mixture during service. In addition, the results suggested that the phase transition characteristic temperature, modulus, and phase angle of the surface layer materials have obvious material differences and structure dependencies.     

Effect of Various Forms of Aluminum 6082 on the Mechanical Properties,Microstructure and Surface Modification of the Profile after Extrusion Process

This article presents a method of reusing aluminum scrap from alloy 6082 using the hot extrusion process. Aluminum chips from milling and turning processes, having different sizes and morphologies, were cold pressed into briquettes prior to hot pressing at 400 °C at a ram speed of 2 mm/s. The study of mechanical properties combined with observations of the microstructures, as well as tests of density, hardness and electrical conductivity were carried out. On the basis of the results, the possibility of using the plastic consolidation method and obtaining materials with similar to a solid ingot mechanical properties, density and electrical conductivity was proven. The possibility of modifying the surface of consolidated aluminum scrap was tested in processes examples: polishing, anodizing and coloring. For this purpose, a number of analyses and tests were carried out: comparison of colors on color histograms, roughness determination, SEM and chemical composition analysis. It has been proven there are differences in the surface treatment of the solid material and that of scrap consolidation, and as such, these differences may significantly affect the final quality.     

Effects of Field Aging on Material Properties and Rutting Performance of Asphalt Pavement

This study evaluates field asphalt aging based on material property changes in pavement with time, and investigates if such changes could have an impact on field rutting performance. Four projects from three different climate zones were monitored as part of the NCHRP 9–49A project at two stages: during pavement construction and two to three years after opening it to traffic. Construction information were collected, and field cores were drilled at both stages to evaluate the material properties of recovered asphalt binder and asphalt mixture. Field rut depth was also measured. In addition, pavement structure, climate and base/subgrade modulus information were also obtained. Results indicate that the asphalt mixture stiffening is caused in major part by asphalt aging. However, the effect of asphalt aging on pavement mixture property may not follow a proportional liner trend. The parameters that are most sensitive to field ageing are MSCR R3.2 and dynamic modulus. It is also found that the variables which showed a good ranking trend with the field rut depth are climate condition (relative humidity, high temperature hour, solar radiation), material properties (Hamburg rut depth, rutting resistance index, high temperature performance grade, MSCR, and dynamic modulus, base and subgrade moduli), as well as air voids.     

Growth of Nitrogen Incorporated Ultrananocrystalline Diamond Coating on Graphite by Hot Filament Chemical Vapor Deposition

This article shows the results of experiments to grow Nitrogen incorporated ultrananocrystalline diamond (N-UNCD) films on commercial natural graphite (NG)/Cu anodes by hot chemical vapor deposition (HFCVD) using a gas mixture of Ar/CH₄/N₂/H₂. The experiments focused on studying the effect of the pressure in the HFCVD chamber, filament-substrate distance, and temperature of the substrate. It was found that a substrate distance of 3.0 cm and a substrate temperature of 575 C were optimal to grow N-UNCD film on the graphite surface as determined by Raman spectroscopy, SEM, and TEM imaging. XPS analysis shows N incorporation through the film. Subsequently, the substrate surface temperature was increased using a heater, while keeping the substrate-filament distance constant at 3.0 cm. In this case, Raman spectra and SEM images of the substrate surface showed a major composition of graphite in the film as the substrate-surface temperature increased. Finally, the process pressure was increased to 10 Torr where it was seen that the growth of N-UNCD film occurred at 2.0 cm at a substrate temperature of 675 C. These results suggest that as the process pressure increases a smaller substrate-filament distance and consequently a higher substrate surface temperature can still enable the N-UNCD film growth by HFCVD. This effect is explained by a mean free path analysis of the main precursors H₂ and CH₃ molecules traveling from the filament to the surface of the substrate The potential impact of the process developed to grow electrically conductive N-UNCD films using the relatively low-cost HFCVD process is that this process can be used to grow N-UNCD films on commercial NG/Cu anodes for Li-ion batteries (LIBs), to enable longer stable capacity energy vs. charge/discharge cycles.