Special Issue: “Microstructures and Durability of Cement-Based Materials”

Cement-based materials play an irreplaceable role in building and sustaining our society by meeting the performance demand imposed on structures and sustainability. Cement-based materials are no longer limited to derivatives of Portland cement, and appreciate a wider range of binders that come from various origins. It is therefore of utmost importance for understanding and expanding the relevant knowledge on their microstructure and likely durability performance. This Special Issue “Microstructures and Durability of Cement-Based Materials” presents recent studies reporting microstructural and durability investigation revealing the characteristics of cement-based materials.     

Modification of Lightweight Aggregate Concretes with Silica Nanoparticles—A Review

The use of lightweight concrete (LWC) for structural and non-structural applications has attracted great interest in recent years. The main benefits include reduced deadload of structural elements and generally lower production and transportation costs. However, a decrease in concrete density often leads to a decrease in strength and durability. Typically, concretes are mostly modified with mineral additives such as silica fume or fly ash. Because of the recent developments in nanotechnology, research attention has turned to the possibility of improving concrete properties with nanomaterials, i.e., nano-SiO₂. However, there are still certain issues with the dosage and efficiency of nanomaterials. Therefore, in order to establish the current state of knowledge in this field, this review gathers most recent results about the performance of LWC modified with nanomaterials. The review is divided into sections about the influence of nanoparticles on the fresh properties of concrete and their influence on the mechanical and durability characteristics. The paper studies in depth the most common approach to nanomaterials in concrete technology and proposes areas for further development.     

Mechanical and Durability Performance of Coconut Fiber Reinforced Concrete: A State-of-the-Art Review

The push for sustainability in the construction sector has demanded the use of increasingly renewable resources. These natural fibers are biodegradable and non-toxic, and their mechanical capabilities are superior to those of synthetic fibers in terms of strength and durability. A lot of research recommends coconut fibers as an alternative to synthetic fibers. However, the knowledge is scattered, and no one can easily judge the suitability of coconut fibers in concrete. This paper presents a summary of research progress on coconut fiber (natural fibers) reinforced concrete. The effects of coconut fibers on the properties of concrete are reviewed. Factors affecting the fresh, hardened, and durability properties of concrete reinforced with coconut fiber are discussed. Results indicate that coconut fiber improved the mechanical performance of concrete due to crack prevention, similar to the synthetic fibers but decreased the flowability of concrete. However, coconut fibers improved flexure strength more effectively than compressive strength. Furthermore, improvement in some durability performance was also observed, but less information is available in this regard. Moreover, the optimum dose is an important parameter for high-strength concrete. The majority of researchers indicate that 3.0% coconut fiber is the optimum dose. The overall study demonstrates that coconut fibers have the creditability to be used in concrete instead of synthetic fibers.     

Deterioration and Protection of Concrete Elements Embedded in Contaminated Soil: A Review

Coating materials are considered one of the most antique materials of human civilization; they have been used for decoration and the protection of surfaces for millennia. Concrete structures—due to their permanent exposure to different types of environments and contaminants—require the use of coatings that contribute to its preservation by reducing the corrosion of its components (steel and aggregates). This article intends to introduce the principal causes of concrete deterioration and the coating materials used to protect concrete structures, including a summary of the coating types, their advantages and disadvantages, and the latest developments and applications. Furthermore, this paper also assesses brief information about the potential challenges in the production of eco-friendly coating materials.     

Protection of Concrete Structures: Performance Analysis of Different Commercial Products and Systems

The increasing demand for reconstructions of concrete structures and the wide availability on the market of surface protective products and systems could lead to misunderstandings in the decision of the most effective solution. Surface protectors have become increasingly widespread in recent years in concrete restoration interventions thanks to their properties: they are able to protect the substrate from aggressive agents and consequently extend the useful life of the structures. The aim of this article is first of all to present the surface protective treatments available on the market, outlining their strengths and weaknesses. Subsequently, a characterization of seven different commercial coatings for reinforced-concrete structures is provided, taking into account chemical nature, fields of use and effectiveness, both in terms of physic and elastic performance and resistance to aggressive agents that undermine the durability of the treated concrete elements.     

A Study on Sustainable Concrete with Partial Substitution of Cement with Red Mud: A Review

Every year, millions of tons of red mud (RDM) are created across the globe. Its storage is a major environmental issue due to its high basicity and tendency for leaching. This material is often kept in dams, necessitating previous attention to the disposal location, as well as monitoring and maintenance during its useful life. As a result, it is critical to develop an industrial solution capable of consuming large quantities of this substance. Many academics have worked for decades to create different cost-effective methods for using RMD. One of the most cost-effective methods is to use RMD in cement manufacture, which is also an effective approach for large-scale RMD recycling. This article gives an overview of the use of RMD in concrete manufacturing. Other researchers’ backgrounds were considered and examined based on fresh characteristics, mechanical properties, durability, microstructure analysis, and environmental impact analysis. The results show that RMD enhanced the mechanical properties and durability of concrete while reducing its fluidity. Furthermore, by integrating 25% of RDM, the environmental consequences of cumulative energy demand (CED), global warming potential (GWP), and major criteria air pollutants (CO, NO_X, Pb, and SO₂) were minimized. In addition, the review assesses future researcher guidelines for concrete with RDM to improve performance.     

Mechanical Properties and Durability of Rubberized and Glass Powder Modified Rubberized Concrete for Whitetopping Structures

This paper analyzes concrete fine aggregate (sand) modification by scrap tire rubber particles-fine crumb rubber (FCR) and coarse crumb rubber (CCR) of fraction 0/1 mm. Such rubberized concrete to get better bonding properties were modified by car-boxylated styrene butadiene rubber (SBR) latex and to gain the strength were modified by glass waste. The following tests—slump test, fresh concrete density, fresh concrete air content, compressive strength, flexural strength, fracture energy, freezing-thawing, porosity parameter, and scanning electron microscope—were conducted for rubberized concretes. From experiments, we can see that fresh concrete properties decreased when crumb rubber content has increased. Mostly it is related to crumb rubber (CR) lower specific gravity nature and higher fineness compared with changed fine aggregate-sand. In this research, we obtained a slight loss of compressive strength when CR was used in concrete However, these rubberized concretes with a small amount of rubber provided sufficient compressive strength results (greater than 50 MPa). Due to the pozzolanic reaction, we see that compressive strength results after 56 days in glass powder modified samples increased by 11–13% than 28 days com-pressive strengths, while at the same period control samples increased its compressive strength about 2.5%. Experiments have shown that the flexural strength of rubberized concrete with small amounts of CR increased by 3.4–15.8% compared to control mix, due the fact that rubber is an elastic material and it will absorb high energy and perform positive bending toughness. The test results indicated that CR can intercept the tensile stress in concrete and make the deformation more plastic. Fracturing of such conglomerate concrete is not brittle, there is no abrupt post-peak load drop and gradually continues after the maximum load is exceeded. Such concrete requires much higher fracture energy. It was obtained that FCR particles (lower than A300) will entrap more micropores content than coarse rubbers because due to their high specific area. Freezing-thawing results have confirmed that Kf values can be conveniently used to predict freeze-thaw resistance and durability of concrete. The test has shown that modification of concrete with 10 kg fine rubber waste will lead to similar mechanical and durability properties of concrete as was obtained in control concrete with 2 kg of prefabricated air bubbles.     

Assessment of Destructive Impact of Different Factors on Concrete Structures Durability

The durability of concrete structure members is dependent on several factors that should be analyzed at each stage of the construction process. Omitting any of these factors might lead to the augmentation of harmful interactions and, as an effect, to safety hazards and the degradation of a structure or its parts. The article, based on several years of studies on exploited concrete structures, presents the effects of an incorrect analysis of selected factors resulting in the occurrence of faults significantly influencing the possibility of safe use of the objects. The described cases include, but are not limited to, the consequences of an improper assessment of building conditions after a biogas explosion in a fermentation chamber, the effect of a wood dust explosion, fire temperature and firefighting action on the prestressed girders, the stages of degradation of bearing structures supporting gas tanks exploited in an aggressive environment, and the consequences of omitting the temperature load in relation to the upper surface of a plate covering the fire pond. In each case, methods of restoration of the damaged elements were proposed, and their application to engineering practice was described. The practical aspects of the conducted research and implemented interventions were indicated.     

Basalt Fiber Reinforced Concrete: A Compressive Review on Durability Aspects

The creation of sustainable composites reinforced with natural fibers has recently drawn the interest of both industrial and academics. Basalt fiber (BF) stands out as the most intriguing among the natural fibers that may be utilized as reinforcement due to their characteristics. Numerous academics have conducted many tests on the strength, durability, temperature, and microstructure characteristics of concrete reinforced with BF and have found promising results. However, because the information is dispersed, readers find it problematic to assess the advantages of BF reinforced concrete, which limits its applications. Therefore, a condensed study that provides the reader with an easy route and summarizes all pertinent information is needed. The purpose of this paper (Part II) is to undertake a compressive assessment of basalt fiber reinforced concrete’s durability features. The results show that adding BF significantly increased concrete durability. The review also identifies a research deficiency that must be addressed before BF is used in practice.     

A Review of Research on Mechanical Properties and Durability of Concrete Mixed with Wastewater from Ready-Mixed Concrete Plant

The wastewater from ready-mixed concrete plants is currently being recycled as concrete mixing water. It has attracted significant attention from the construction industry and researchers since it promotes sustainable development through environmental protection, energy-saving, and emissions reduction. This article review first introduces the nature of wastewater in ready-mixed concrete plants in different regions. Then the effects of solid content in water on various properties of concrete, including working performance, durability and microscopic properties, are reviewed, respectively, when concrete is mixed with wastewater instead of tap water. Furthermore, the microscopic mechanism of action in concrete mixing with wastewater is discussed, and future work is recommended. This review provides fundamentals on the study of the properties of concrete after wastewater is mixed into concrete.     

Impact of Magnetization on the Evaluation of Reinforced Concrete Structures Using DC Magnetic Methods

The magnetic method is the most promising method that can be used to inspect large areas of reinforced concrete (RC) structures. Magnetization is a crucial process in this method. The paper aims to present the impact of the magnetization method on the results in the detection of reinforced bars (rebars) and the evaluation of concrete cover thickness in reinforced concrete (RC) structures. Three cases (without magnetization, same pole magnetization, and opposite pole magnetization) were considered in the experiments. Results achieved in all the methods are presented and evaluated. Two different sensing elements were used in the measurements: a magneto-optical (MO) sensor and an AMR sensor. The advantages and disadvantages of both mentioned transducers are presented and discussed in the context of a large areas inspection. The new approach involves using various magnetization methods to improve measurement results for complex structures.     

Electrical Resistivity Measurements for Nondestructive Evaluation of Chloride-Induced Deterioration of Reinforced Concrete—A Review

The objective of this study is to review, evaluate, and compare the existing research and practices on electrical resistivity as a nondestructive technique in evaluating chloride-induced deterioration of reinforced concrete elements in buildings and civil infrastructure systems. First, this paper summarizes the different measurement techniques for gathering electrical resistivity (ER) values on concrete. Second, comparison analyses are performed to review the correlation of ER to different parameters representing corrosive environment and activity of steel corrosion in concrete, such as degree of water saturation, chloride penetration and diffusivity, and corrosion rate. In addition, this research enumerates and individually discusses the different environmental and interference factors that are not related to the electrochemical process of steel corrosion in concrete but directly affect the ER measurements, including temperature, the presence of steel reinforcement, cracks and delamination defects, specimen geometry, and concrete composition. Lastly and most importantly, discussions are made to determine the current gap of knowledge, to improve the utilization of this method in field and laboratory measurements, and future research.     

The Realization of Clinker-Reduced,Performance-Based Sustainable Concrete by the Micro-Filler,Eco-Filler Concept

In times of climate change, the reduction in embodied greenhouse gas emissions is a premise for sustainable concrete infrastructure. As Portland cement clinker is mainly responsible for the high CO₂ emissions of concrete, its reduction is necessary. In order to be sustainable, the concrete must meet processing, mechanical and durability properties while taking cost aspects into account. The paper presents (i) the “micro-filler/eco-filler concept” for achieving a clinker reduced, optimised binder and (ii) a performance-based approach to put sustainable “Eco-concrete” into practice. Clinker is substituted by locally available inert fillers by at least two different particle size fractions and supplementary cementitious materials. The method is based on particle packing optimisation, reduction in water demand and optimisation of the mix ratio of the binder blend, which allows the performance requirements to be met. The new Eco-concretes deliver the desired performance in terms of processability, strength and durability (water penetration, frost, carbonation and chloride resistance) while lowering the environmental impact in comparison to standard concrete. One of the new mixes was used for a small animal passage tunnel. The direct comparison of the developed Eco-concrete and standard concrete showed a 24% reduction in CO₂, while achieving satisfactory workability, stripping strength and durability performance.     

Azadirachta indica Leaf Extract as Green Corrosion Inhibitor for Reinforced Concrete Structures: Corrosion Effectiveness against Commercial Corrosion Inhibitors and Concrete Integrity

The construction industry has extensively demanded novel green inhibition strategies for the conservation and protection of carbon steel-reinforced concrete structures. For the first time, the effect of Azadirachta indica leaf extract (Neem) as a potential corrosion inhibitor of carbon steel in reinforced concrete under corrosion in saline simulated media was evaluated. To assess the corrosion inhibition behavior of the Neem natural organic extract, three inorganic commercial inhibitors were tested to compare following the criteria established by Stratful for half-cell potential under a simulated chloride environment. Moreover, the effect of concrete integrity by the Neem treatment was recorded after different temperature conditions, slump, weight alteration, air content, compressive strength, and chloride-ions penetration. The results suggested that the Neem treatments did not alter the concrete integrity and the physicochemical parameters. We reached a promoted long-term corrosion protection of 95% after 182 days of evaluation. Thus far, our current results open up a new promising “green” road to the conservation of carbon steel in reinforced concrete for the construction industry.     

The Durability of Recycled Fine Aggregate Concrete: A Review

With the rapid development of urbanization, many new buildings are erected, and old ones are demolished and/or recycled. Thus, the reuse of building materials and improvements in reuse efficiency have become hot research topics. In recent years, scholars around the world have worked on improving recycle aggregates in concrete and broadening the scope of applications of recycled concrete. This paper reviews the findings of research on the effects of recycled fine aggregates (RFAs) on the permeability, drying shrinkage, carbonation, chloride ion penetration, acid resistance, and freeze–thaw resistance of concrete. The results show that the content of old mortar and the quality of recycled concrete are closely related to the durability of prepared RFA concrete. For example, the drying shrinkage value with a 100% RFA replacement rate is twice that of normal concrete, and the depth of carbonation increases by approximately 110%. Moreover, the durability of RFA concrete decreases as the RFA replacement rate and the water–cement ratio improve. Fortunately, the use of zeolite materials such as fly ash, silica fume, and meta kaolin as surface coatings for RFAs or as external admixtures for RFA concrete had a positive effect on durability. Furthermore, the proper mixing methods and/or recycled aggregates with optimized moisture content can further improve the durability of RFA concrete.     

The Effect of Low-Modulus Plastic Fiber on the Physical and Technical Characteristics of Modified Heavy Concretes Based on Polycarboxylates and Microsilica

Manufacturers of building materials strive to optimize the three basic concrete properties—strength, durability, and shrinkage deformation, of which the focus is generally on the durability in the structure when designing and monitoring the poured concrete. Studying concretes’ structural performance and the change in their characteristics over time enables the solution of many important issues associated with the design of reliable, durable, and cost-effective buildings and structures. This article presents studies aimed at improving the physical, technical, and operational characteristics of cement concrete and reducing cement consumption in heavy concretes through the use of complex modifiers and volumetric fiber reinforcement. Four concrete compositions of widely recognized grades were developed, of which samples were molded and tested for compressive and flexural strength, frost resistance, volumetric water absorption, and density. Test results confirmed the possibility of binder (cement) economy up to 18% and increasing frost resistance up to W300 when using microsilica, reduction in volumetric water absorption of up to 40% when using both microsilica and hyperplasticizer, and increasing flexural strength by over 30% when using polymer fiber. The developed compositions passed the industrial tests, and were successfully introduced in the production process of the operating reinforced concrete products’ manufacturer.     

3D Concrete Printing: A Systematic Review of Rheology,Mix Designs,Mechanical, Microstructural,and Durability Characteristics

This paper provides a state-of-the-art report on the up-to-date research on the emerging 3D concrete printing technology from the concrete materials perspective. It reviews the recent research focused on understanding and characterizing the rheological necessities of the concrete printing process and discusses how the researchers are tailoring compatible mix proportions for the 3D concrete printing process by using eco-friendly binders, waste aggregates, chemical admixtures, and nano-additives. This paper systematically evaluates anisotropic behavior in the mechanical properties of printed concrete and establishes an order for anisotropic behavior in the compressive, flexural, and tensile strengths along three different axes (X, Y, and Z axes) of printed concrete. It evaluates the ratio of flexural strength to the compressive strength of printed concrete along the above three axes. This article explains the influence of variation of printing process parameters on the mechanical properties and discusses reinforcement approaches used for increasing structural performance. The microstructure at the interface of adjacent layers and also at the interface of the reinforcement-cement matrix is discussed. The recent research on the durability performance of printed concrete is critically discussed and future research needs for 3D concrete printing are identified in this paper.     

The Present State of the Use of Waste Wood Ash as an Eco-Efficient Construction Material: A Review

A main global challenge is finding an alternative material for cement, which is a major source of pollution to the environment because it emits greenhouse gases. Investigators play a significant role in global waste disposal by developing appropriate methods for its effective utilization. Geopolymers are one of the best options for reusing all industrial wastes containing aluminosilicate and the best alternative materials for concrete applications. Waste wood ash (WWA) is used with other waste materials in geopolymer production and is found in pulp and paper, wood-burning industrial facilities, and wood-fired plants. On the other hand, the WWA manufacturing industry necessitates the acquisition of large tracts of land in rural areas, while some industries use incinerators to burn wood waste, which contributes to air pollution, a significant environmental problem. This review paper offers a comprehensive review of the current utilization of WWA with the partial replacement with other mineral materials, such as fly ash, as a base for geopolymer concrete and mortar production. A review of the usage of waste wood ash in the construction sector is offered, and development tendencies are assessed about mechanical, durability, and microstructural characteristics. The impacts of waste wood ash as a pozzolanic base for eco-concreting usages are summarized. According to the findings, incorporating WWA into concrete is useful to sustainable progress and waste reduction as the WWA mostly behaves as a filler in filling action and moderate amounts of WWA offer a fairly higher compressive strength to concrete. A detail study on the source of WWA on concrete mineralogy and properties must be performed to fill the potential research gap.     

Influence of Rock Dust Additives as Fine Aggregate Replacement on Properties of Cement Composites—A Review

Concrete production consumes enormous amounts of fossil fuels, raw materials, and is energy intensive. Therefore, scientific research is being conducted worldwide regarding the possibility of using by-products in the production of concrete. The objective is not only to identify substitutes for cement clinker, but also to identify materials that can be used as aggregate in mortar and concrete productions. Among the potential alternative materials that can be used in cement composite production is rock dust of different geological origin. However, some adversarial effects may be encountered when using rock dust regarding the properties and durability of mortars and concrete. Therefore, comprehensive research is needed to evaluate the adequacy of rock dust use in cementitious composite production. This paper presents a comprehensive review of the scientific findings from past studies concerning the use of various geological origins of rock dust in the production of mortars and concrete. The influence of rock dust as a replacement of fine aggregates on cementitious composites was analyzed and evaluated. In this assessment and review, fresh concrete and mortar properties, i.e., workability, segregation, and bleeding, mechanical properties, and the durability of hardened concrete and mortar were considered.     

Green Concrete for a Circular Economy: A Review on Sustainability,Durability, and Structural Properties

A primary concern of conventional Portland cement concrete (PCC) is associated with the massive amount of global cement and natural coarse aggregates (NCA) consumption, which causes depletion of natural resources on the one hand and ecological problems on the other. As a result, the concept of green concrete (GC), by replacing cement with supplementary cementitious materials (SCMs) such as ground granulated blast furnace slag (GGBFS), fly ash (FA), silica fume (SF), and metakaolin (MK), or replacing NCA with recycled coarse aggregates, can play an essential role in addressing the environmental threat of PCC. Currently, there is a growing body of literature that emphasizes the importance of implementing GC in concrete applications. Therefore, this paper has conducted a systematic literature review through the peer-reviewed literature database Scopus. A total of 114 papers were reviewed that cover the following areas: (1) sustainability benefits of GC, (2) mechanical behavior of GC in terms of compressive strength, (3) durability properties of GC under several environmental exposures, (4) structural performance of GC in large-scale reinforced beams under shear and flexure, and (5) analytical investigation that compares the GC shear capacities of previously tested beams with major design codes and proposed models. Based on this review, the reader will be able to select the optimum replacement level of cement with one of the SCMs to achieve a certain concrete strength range that would suit a certain concrete application. Also, the analysis of durability performance revealed that the addition of SCMs is not recommended in concrete exposed to a higher temperature than 400 °C. Moreover, combining GGBFS with FA in a concrete mix was noticed to be superior to PCC in terms of long-term resistance to sulfate attack. The single most striking observation to emerge from the data comparison of the experimentally tested beams with the available concrete shear design equations is that the beams having up to 70% of FA as a replacement to OPC or up to 100% of RCA as a replacement to NCA were conservatively predicted by the equations of Japan Society of Civil Engineers (JSCE-1997), the American Concrete Institute (ACI 318-19), and the Canadian Standards Association (CSA-A23.3-14).