Electrochemical performance of graphene-coated activated mesocarbon microbeads as a supercapacitor electrode

Hybrid activated carbon/graphene materials are prospective candidates for use as high performance supercapacitor electrode materials, since they have the superior characteristics of high surface area, abundant micro/mesoporous structure due to the presence of activated carbon and good electrical conductivity as a result of the presence of graphene. In this work, the electrochemical performance of facile and low-cost graphene-coated activated mesocarbon microbeads (g-AM) is carefully studied. The results show that g-AM can only be formed at a very high temperature over a long activation time, resulting in the formation of a large pore size and low specific surface area, further resulting in poor electrochemical performance (110 F g⁻¹ at 0.1 A g⁻¹ in 6 M KOH solution). Ball milling for a short time is an effective way to improve the electrochemical performance (191 F g⁻¹ at 0.1 A g⁻¹ in 6 M KOH solution). Moreover, due to the strong resistance to aggregation and good electrical conductivity of graphene flowers, the g-AM had nearly 100% rate capability when increasing the current density from 5 to 50 A g⁻¹. The as-assembled two-electrode symmetric supercapacitor exhibits a high energy and power density (5.28 W h kg⁻¹ at 10 000 W kg⁻¹) in organic LiPF₆ electrolyte, due to its better electrical conductivity. It is expected that this type of hybrid structure holds great potential for scalable industrial manufacture as supercapacitor electrodes.

Activated carbon/graphene materials are prospective candidates as high performance supercapacitor electrodes, due to the presence of aggregation resisted graphene on the surface of activated carbon.     

Functional utilization of biochar derived from Tenebrio molitor feces for CO2 capture and supercapacitor applications

Biochar has attracted great interest in both CO₂ capture and supercapacitor applications due to its unique physicochemical properties and low cost. Fabrication of eco-friendly and cost-effective biochar from high potential biomass Tenebrio molitor feces can not only realize the functional application of waste, but also a potential way of future carbon capture and energy storage technology. In this study, a novel KOH activation waste-fed Tenebrio molitor feces biochar (TMFB) was developed and investigated in terms of CO₂ capture and electrochemical performance. When activated at 700 °C for 1 h, the specific surface area of the feces biochar (TMFB-700A) increased significantly from 232.1 to 2081.8 m² g⁻¹. In addition, well-developed pore distribution facilitates CO₂ capture and electrolyte diffusion. TMFB-700A can quickly adsorb a large amount of CO₂ (3.05 mol kg⁻¹) with excellent recycling performance. TMFB-700A also exhibited promising electrochemical performance (335.8 F g⁻¹ at 0.5 A g⁻¹) and was used as electrode material in a symmetrical supercapacitor. It provided a high energy density of 33.97 W h kg⁻¹ at a power density of 0.25 kW kg⁻¹ with 90.47% capacitance retention after 10 000 charge–discharge cycles. All the results demonstrated that TMFB could be a potential bifunctional material and provided valuable new insights for Tenebrio molitor feces high-value utilization.

Biochar has attracted great interest in both CO₂ capture and supercapacitor applications due to its unique physicochemical properties and low cost.     

“Water-in-salt” electrolyte enhanced high voltage aqueous supercapacitor with carbon electrodes derived from biomass waste-ground grain hulls

To design high specific surface area and optimize the pore size distribution of materials, we employ a combination of carbonization and KOH activation to prepare activated carbon derived from ground grain hulls. The resulting carbon material at lower temperature (800, BSAC-A-800) exhibits a porous structure with a high specific surface area of 1037.6 m² g⁻¹ and a pore volume of 0.57 m³ g⁻¹. Due to the synergistic structural characteristics, BSAC-A-800 reveals preferable capacitive performance, showing a specific capacitance as high as 313.3 F g⁻¹ at 0.5 A g⁻¹, good rate performance (above 73%), and particularly stable cycling performance (99.1% capacitance retention after 10 000 cycles at a current density of 10 A g⁻¹). More importantly, the assembled symmetric supercapacitor using a water-in-salt electrolyte (17 m NaClO₄) with high discharge specific capacitance (59 F g⁻¹ at 0.5 A g⁻¹), high energy density (47.2 W h kg⁻¹) and high voltage (2.4 V) represents significant progress towards performance comparable to that of commercial salt-in-water electrolyte supercapacitors (with discharge specific capacitance of 50 F g⁻¹, energy densities of ∼28.1 W h kg⁻¹ and voltages of 2.0 V).

To design high specific surface area and optimize the pore size distribution of materials, we employ a combination of carbonization and KOH activation to prepare activated carbon derived from ground grain hulls.     

Biochar derived from corn stalk and polyethylene co-pyrolysis: characterization and Pb(ii) removal potential

Biochar is widely used as adsorbents for gaseous or liquid pollutants due to its special pore structure. Previous studies have shown that the adsorption performance of untreated biomass pyrolysis crude carbon is poor, which can be improved by optimizing physicochemical properties such as pore structure and surface area. The study focused on the co-pyrolysis of skins, pith, and leaves with polyethylene and potassium hydroxide modification to adjust the quality of the biochar, compared with raw materials of corn stalks without separation. The physical and chemical properties of the biochar were analyzed and the adsorption effect, adsorption isotherms, and kinetics of Pb(ii) removal were investigated. Results demonstrated that co-pyrolysis of biomass and polyethylene increase the yield of biochar with an average increase of about 20%. Polyethylene brought high aromaticity, high calorific value and stable material structure to biochar. Potassium hydroxide modification increased its specific surface area and made the pore structure of biochar more uniform, mainly microporous structure. The specific surface areas of the four modified biochar were 521.07 m² g⁻¹, 581.85 m² g⁻¹, 304.99 m² g⁻¹, and 429.97 m² g⁻¹. The adsorption capacity of biochar for Pb(ii) was greatly improved with the increase of the OH functional group of biochar. The stem-pith biochar had the best adsorption effect, with an adsorption amount of 99.95 mg g⁻¹ and a removal efficiency of 50.35%. The Pseudo-second-order model and Langmuir adsorption isotherm model could preferably describe the adsorption process, indicating the adsorption of lead was monolayer accompanied by chemical adsorption. It can be concluded that co-pyrolysis of biomass and polyethylene and modification may be favorable to enhance the properties of biochar. In addition to syngas and bio-oil from co-pyrolysis, biochar may be a valuable by-product for commercial use, which can be used to remove heavy metals in water, especially stem-pith biochar.

Biochar is widely used as adsorbents for gaseous or liquid pollutants due to its special pore structure.     

An ultrasound-assisted approach to bio-derived nanoporous carbons: disclosing a linear relationship between effective micropores and capacitance

Ultrasound irradiation is a technique that can induce acoustic cavitation in liquids, leading to a highly interactive mixture of reactants. In pursuit of high-performance and cost-effective supercapacitor electrodes, pore size distributions of carbonaceous materials should be carefully designed. Herein, fruit skins (mango, pitaya and watermelon) are employed as carbon precursors to prepare nanoporous carbons by the ultrasound-assisted method. Large BET specific surface areas of the as-prepared carbons (2700–3000 m² g⁻¹) are reproducible with pore diameters being concentrated at about 0.8 nm. Among a suite of the bio-derived nanoporous carbons, one reaches a maximum specific capacitance of up to 493 F g⁻¹ (at 0.5 A g⁻¹ in 6 M KOH) in the three-electrode system and achieves high energy densities of 27.5 W h kg⁻¹ (at 180 W kg⁻¹ in 1 M Na₂SO₄) and 10.9 W h kg⁻¹ (at 100 W kg⁻¹ in 6 M KOH) in the two-electrode system. After 5000 continuous charge/discharge cycles, the capacitances maintain 108% in 1 M Na₂SO₄ and 98% in 6 M KOH, exhibiting long working stability. Moreover, such high capacitive performance can be attributed to the optimization of surface areas and pore volumes of the effective micropores (referred to as 0.7–2 nm sized pores). Notably, specific capacitances have been found linearly correlated with surface areas and pore volumes of the effective micropores rather than those of any other sized pore (i.e., <0.7, 2–50 and 0.5–50 nm). Consequently, the fit of electrolyte ions into micropore frameworks should be an important consideration for the rational design of nanopore structures in terms of supercapacitor electrodes.

There is a linear relationship between the effective micropore volume (surface area) and the specific capacitance of bio-derived nanoporous carbons, regardless of biomass type and activation temperature employed.     

Nitrogen and oxygen Co-doped porous carbon derived from yam waste for high-performance supercapacitors

It is a considerable challenge to produce a supercapacitor with inexpensive raw materials and employ a simple process to obtain carbon materials with a high specific surface area, rich pore structure, and appropriate doping of heterogeneous elements. In the current study, yam waste-derived porous carbon was synthesized for the first time by a two-step carbonization and KOH chemical activation process. An ultra-high specific surface area of 2382 m² g⁻¹ with a pore volume of 1.11 cm³ g⁻¹ and simultaneous co-doping of O–N was achieved for the optimized sample. Because of these distinct features, the optimized material exhibits a high gravimetric capacitance of 423.23 F g⁻¹ at 0.5 A g⁻¹ with an impressive rate capability at 10 A g⁻¹, and prominent cycling durability with a capacity retention of 96.4% at a high current density of 10 A g⁻¹ after 10 000 cycles in 6 M KOH in a three-electrode system. Moreover, in 6 M KOH electrolyte, the assembled symmetrical supercapacitor provides a large C of 387.3 F g⁻¹ at 0.5 A g⁻¹. It also presents high specific energy of 34.6 W h kg⁻¹ when the specific power is 200.1 W kg⁻¹ and a praiseworthy specific energy of 8.3 W h kg⁻¹ when the specific power is 4000.0 W kg⁻¹ in 1 M Na₂SO₄ electrolyte. Thus, this study provides reference and guidance for developing high-performance electrode materials for supercapacitors.

3D porous carbon with ultra-high specific surface area and excellent electrochemical performance is synthesized by a simple activation and carbonization process through adopting biomass yam waste as raw material.     

Rapid microwave activation of waste palm into hierarchical porous carbons for supercapacitors using biochars from different carbonization temperatures as catalysts

A rapid, simple and cost-effective approach to prepare hierarchical porous carbons (PCs) for supercapacitors is reported by microwave activation of abundant and low-cost waste palm, biochar (BC) and KOH. BCs from waste palm at different carbonization temperatures (300–700 °C), as catalysts and microwave receptors, were used here for the first time to facilitate the conversion of waste palm into hierarchical PCs. As a result, the high-graphitization PC obtained at a BC carbonization temperature of 300 °C (PC-300) possessed a high surface area (1755 m² g⁻¹), a high pore volume (0.942 cm³ g⁻¹) and a moderate mesoporosity (37.79%). Besides their high-graphitization and hierarchical porous structure, the oxygen doping in PC-300 can also promote the rapid transport of electrolyte ions. The symmetric supercapacitor based on the PC-300 even in PVA/LiCl gel electrolyte exhibited a high specific capacitance of 164.8 F g⁻¹ at a current density of 0.5 A g⁻¹ and retained a specific capacitance of 121.3 F g⁻¹ at 10 A g⁻¹, demonstrating a superior rate capacity of 73.6%. Additionally, the PC-300 supercapacitor delivered a high energy density of 14.6 W h kg⁻¹ at a power density of 398.9 W kg⁻¹ and maintained an energy density of 10.8 W h kg⁻¹ at a high power density of 8016.5 W kg⁻¹, as well as an excellent cycling stability after 2000 cycles with a capacitance retention of 92.06%.

A rapid, simple and cost-effective approach to prepare hierarchical porous carbons (PCs) for supercapacitors is reported by microwave activation of abundant and low-cost waste palm, biochar (BC) and KOH.     

Dual-doped hierarchical porous carbon derived from biomass for advanced supercapacitors and lithium ion batteries

Nowadays, designing heteroatom-doped porous carbons from inexpensive biomass raw materials is a very attractive topic. Herein, we propose a simple approach to prepare heteroatom-doped porous carbons by using nettle leaves as the precursor and KOH as the activating agent. The nettle leaf derived porous carbons possess high specific surface area (up to 1951 m² g⁻¹), large total pore volume (up to 1.374 cm³ g⁻¹), and high content of nitrogen and oxygen heteroatom doping (up to 17.85 at% combined). The obtained carbon as an electrode for symmetric supercapacitors with an ionic liquid electrolyte can offer a superior specific capacitance of 163 F g⁻¹ at 0.5 A g⁻¹ with a capacitance retention ratio as high as 67.5% at 100 A g⁻¹, and a low capacitance loss of 8% after 10 000 cycles. Besides, the as-built supercapacitor demonstrates a high specific energy of 50 W h kg⁻¹ at a specific power of 372 W kg⁻¹, and maintains 21 W h kg⁻¹ at the high power of 40 kW kg⁻¹. Moreover, the resultant carbon as a Li-ion battery anode delivers a high reversible capacity of 1262 mA h g⁻¹ at 0.1 A g⁻¹ and 730 mA h g⁻¹ at 0.5 A g⁻¹, and maintains a high capacity of 439 mA h g⁻¹ after 500 cycles at 1 A g⁻¹. These results demonstrate that the nettle leaf derived porous carbons offer great potential as electrodes for advanced supercapacitors and lithium ion batteries.

Nettle leaf derived nitrogen and oxygen dual-doped porous carbons exhibit great potential as anodes for high performance supercapacitors and lithium ion batteries.     

Facile synthesis of bio-based nitrogen- and oxygen-doped porous carbon derived from cotton for supercapacitors

Biomass-derived O- and N-doped porous carbon has become the most competitive supercapacitor electrode material because of its renewability and sustainability. We herein presented a facile approach to prepare O/N-doped porous carbon with cotton as the starting material. Absorbent cotton immersed in diammonium hydrogen phosphate (DAP) was activated at 800 °C (CDAP800s) and then was oxidized in a temperature range of 300–400 °C. The electrochemical capacitance of the impregnated cotton was significantly improved by doping with O and N, and the yield was improved from 13% to 38%. The sample oxidation at 350 °C (CDAP800-350) demonstrated superior electrical properties. CDAP800-350 showed the highest BET surface area (1022 m² g⁻¹) and a relatively high pore volume (0.53 cm³ g⁻¹). In a three-electrode system, the CDAP800-350 electrodes had high specific capacitances of 292 F g⁻¹ in 6 M KOH electrolyte at a current density of 0.5 A g⁻¹. In the two-electrode system, CDAP800-350 electrode displayed a specific capacitance of 270 F g⁻¹ at 0.5 A g⁻¹ and 212 F g⁻¹ at 10 A in KOH electrolyte. In addition, the CDAP800-350-based symmetric supercapacitor achieved a high stability with 87% of capacitance retained after 5000 cycles at 5 A g⁻¹, as well as a high volumetric energy density (18 W h kg⁻¹ at 250 W kg⁻¹).

Biomass-derived O- and N-doped porous carbon has become one of the most competitive supercapacitor electrode material because of its renewability and sustainability.     

Nitrogen-doped micro-nano carbon spheres with multi-scale pore structure obtained from interpenetrating polymer networks for electrochemical capacitors

A chemical process was developed to prepare N-doped micro-nano carbon spheres with multi-scale pore structures via carbonization of N-PF/PMMA interpenetrating polymer networks, which contain melamine resin as the nitrogen source, PF as the carbon source, and polymethylmethacrylate (PMMA) as the pore-former. The N-content of N-doped micro-nano carbon spheres was controlled by adjusting the mass ratio of melamine and phenol before polymerization. The N-doped micro-nano carbon spheres as electrode materials possess appropriate pore size distribution, higher specific surface area (559 m² g⁻¹) and consistently dispersed nitrogen atoms with adjustable doping content. These distinct characteristics endow the prospective electrode materials with excellent performance in electrochemical capacitors. In particular, N-CS-IPN-4 exhibits the highest specific capacitance of 364 F g⁻¹ at 0.5 A g⁻¹ in 6 M KOH aqueous electrolyte in a three-electrode system. It also possesses superior rate capability (57.7% retention at current densities ranging from 0.5 to 50 A g⁻¹) and excellent cycling performance at 2 A g⁻¹ (100% retention after 10 000 cycles). All these results confirm that the N-doped micro-nano carbon spheres are promising electrochemical capacitor materials, which possesses the advantages of simple preparation procedure, multi-scale pore structures, higher specific surface areas, easy adjustment of N-content and excellent electrochemical properties.

The N-doped micro-nano carbon spheres with multi-scale pore structures was prepared via carbonization of N-PF/PMMA interpenetrating polymer networks, which contain melamine resin as nitrogen source, PF as carbon source, and PMMA as pore-former.     

Processing-properties-performance triad relationship in a Washingtonia robusta mesoporous carbon materials-based supercapacitor device

Two-electrode electrochemical tests provide a close performance approximation to that of an actual supercapacitor device. This study presents mesoporous carbon materials successfully derived from Washingtonia robusta bark (Mexican fan palm) and their electrical performance in a 2-electrode supercapacitor device. The triad relationship among carbon materials “processing, properties, and performance” was comprehensively investigated. X-ray diffraction reveal that amorphousness increases with activating KOH ratio and decreases with both activation time and temperature. Raman spectroscopy shows an increase in structural defects and degree of graphitization with an increase in KOH ratio, temperature and time while transmission electron microscopy shows conversion of aggregated particles to materials with interconnected porosity and subsequent destruction of porosity with an increase in KOH ratio. A nitrogen-sorption study reveals varying trends between BET, micro and mesopore surface areas, however, pore size and volume and hysteresis loop size decreases with KOH ratio and temperature. Electrochemical studies on the other hand reveal that both the specific capacitance and charge–discharge time increase with KOH ratio, temperature and time while both charge transfer and Warburg resistances decrease and the phase angles increases towards the ideal −90° with an increase in KOH ratio, temperature and time. The device fabricated with the HHPB sample prepared at 700 °C, KOH ratio 3 for 60 min attained a specific capacitance of 179.3 and 169 F g⁻¹ at a scan rate of 5 mV s⁻¹ and current density of 0.5 A g⁻¹, respectively, good cycling stability with 95% capacitance retention and 100% coulombic efficiency when cycled 5000 times at a current density of 2 A g⁻¹. HHPB electrodes reveal perfect EDLC behavior with an energy density of 20 W h kg⁻¹ and power density of 2000 W kg⁻¹ when used in a symmetric coin supercapacitor cell with 6 M KOH solution. These findings show the potential of fan palm bark as electrode materials with good stability and high-rate capability for supercapacitor application.

Electrode materials processing conditions, electrode properties and supercapacitor device performance show a triad relationship.     

Hierarchical porous carbons from carboxylated coal-tar pitch functional poly(acrylic acid) hydrogel networks for supercapacitor electrodes

A gel carbonization strategy for the synthesis of hierarchical porous carbons (HPCs) from carboxylated coal-tar pitches (CCP) functional poly(acrylic acid) (PAA) hydrogel networks for advanced supercapacitor electrodes was reported. The amphiphilic CCP and PAA polymer could be easily self-assembled to gel by the major driving force of hydrogen bonding and π–π stacking. The HPCs containing interconnected macro-/meso-/micropores were fabricated by direct carbonization of the dried hydrogels. The resultant HPCs with a high specific surface area and total pore volume of 1294.6 m² g⁻¹ and 1.34 cm³ g⁻¹ respectively, as a supercapacitor electrode exhibit a high specific capacitance of 292 F g⁻¹ at 1.0 A g⁻¹ in two-electrode system. The electrode also exhibits ultra-long cycle life with a capacitance retention as high as 94.2% after 10 000 cycles, indicating the good electrochemical stability. Furthermore, the concept of such hierarchical architecture and synthesis strategy would expand to other materials for advanced energy storage systems, such as Na-ion batteries and metal oxides for supercapacitors.

As a supercapacitor electrode exhibit a high specific capacitance of 292 F g⁻¹ at 1.0 A g⁻¹.     

Preparation of activated carbon nanofibers using degradative solvent extraction products obtained from low-rank coal and their utilization in supercapacitors

In this study, low-rank coal was separated into three solid fractions by a degradative solvent extraction method. The high-molecular-weight extract (termed Deposit) had some outstanding properties such as high carbon content, almost no ash, high aromaticity, good thermoplasticity and high solubility in DMF. Therefore, Deposit with some proportion of polyacrylonitrile (PAN) was used to prepare activated carbon nanofibers by electrospinning and CO₂ activation. Moreover, the utilization of these carbon nanofibers as a supercapacitor electrode was preliminarily investigated. The results showed that the specific surface area of the Deposit-based carbon nanofibers (1005 m² g⁻¹) was significantly higher than that of the nanofibers obtained from pure PAN (688 m² g⁻¹). TGA simulations showed that this was caused by the different thermal decomposition behaviors of Deposit and PAN during the stabilization and activation processes. In addition, the Deposit-based carbon nanofibers showed a better specific capacitance (192.6 F g⁻¹ at 1 A g⁻¹) and cycling performance (retention rate of 89.8% after 1000 cycles at 5 A g⁻¹) in a 6 M KOH electrolyte. The factors, such as the enhanced surface area and pore volume and decreased average fiber diameter, affected the electrochemical properties of the carbon nanofibers. Thus, it has been proven that the high-molecular-weight extract obtained from low-rank coal by degradative solvent extraction is a promising precursor for the preparation of carbon nanofibers with unique electrochemical properties.

Activated carbon nanofibers for supercapacitor electrodes were prepared by the electrospinning method using degradative solvent extracts from low-rank coal and PAN.     

An ultrasonic-assisted synthesis of rice-straw-based porous carbon with high performance symmetric supercapacitors

Biomass porous carbon materials are ideal supercapacitor electrode materials due to their low price, rich source of raw materials and environmental friendliness. In this study, an ultrasonic-assisted method was applied to synthesize the rice-straw-based porous carbon (UPC). The obtained UPC exhibited a two-dimensional structure and high specific surface area. In addition, the electrochemical test results showed that the UPC with a 1 hour ultrasonic treatment and lower activation temperature of 600 °C (UPC-600) demonstrated optimal performance: high specific capacitances of 420 F g⁻¹ at 1.0 A g⁻¹ and 314 F g⁻¹ at a high current of 10 A g⁻¹. Significantly, the symmetric supercapacitors showed a high energy density of 11.1 W h kg⁻¹ and power density of 500 W kg⁻¹. After 10 000 cycles, 99.8% of the specific capacitance was retained at 20 A g⁻¹. These results indicate that UPC-600 is a promising candidate for supercapacitor electrode materials.

Rice-straw-based porous carbon was successfully prepared via an ultrasonic-assisted method to lower activation temperature and for ultra-stable electrode materials of symmetric supercapacitors.     

Homogeneous coating of carbon nanotubes with tailored N-doped carbon layers for improved electrochemical energy storage

The combination of activity-enriched heteroatoms and highly-conductive networks is a powerful strategy to craft carbon-based electrodes for high-efficiency electrochemical energy storage. Herein, N-doped carbon (N-C) coated carbon nanotubes (N-CNTs) were fabricated via a facile in situ synthesis of polyimide in the presence of carbon nanotubes (CNTs), followed by carbonization. The polyimide-divided N-C layers were uniformly covered on the surface of CNTs with a tailored layer thickness. The as-fabricated N-CNTs were further used as electrode active materials for energy storage. When employed as the electrodes for supercapacitors, the N-CNTs exhibited a specific capacitance of 63 F g⁻¹ at 0.1 A g⁻¹ (an energy density of 1.4 W h kg⁻¹ at a power density of 20 W kg⁻¹), which was much higher than that of pure N-C (5 F g⁻¹) and CNTs (13 F g⁻¹). The supercapacitor also retained 66.7% of its initial capacitance (42 F g⁻¹ at 10 A g⁻¹) after a 100-fold increase in the current density and nearly 100% of its initial capacitance after running 10 000 cycles. Furthermore, functioning as an anode material for a Li-ion battery, the N-CNTs also delivered a larger reversible capacity (432 mA h g⁻¹ at 50 mA g⁻¹), higher rate capability, and better cycling stability compared to pure CNTs. The electrochemical performances of the N-CNTs were improved overall due to the synergistic effects of interconnected 3D networks and core–shell structures capable of facilitating electrolyte percolation and charge transportation, enhancing conductivity and surface/interface wettability, and contributing additional pseudocapacitance.

Polyimide-derived N-doped carbon layers were coated onto carbon nanotubes for high-rate electrodes with enhanced energy storage.     

Preparation of cellulose acetate derived carbon nanofibers by ZnCl2 activation as a supercapacitor electrode

Porous carbon nanofibers are fabricated by one-step carbonization and activation of electrospun cellulose acetate (CA) nanofibres. Electrospun CA nanofibers were obtained by the electrospinning of a CA/DMAC/acetone solution, followed by deacetylation in NaOH/ethanol solution. One-step carbonization and activation was achieved by dipping the as-spun fibers in ZnCl₂ solution, followed by one-step high temperature treatment. The effects of the concentration of the dipping solution on the microstructure of the CA-based carbon nanofibers (CACNFs), including the morphology, crystal structure, porous structure, specific surface area and surface chemical properties, have been investigated. The coating of ZnCl₂ effectively improves the thermal stability of electrospun CA nanofibers and obviously enhances the oxygen-containing surface groups of the CACNFs. The CACNFs have a norrow pore size distribution (0.6–1.2 nm) and a high specific surface area (∼1188 m² g⁻¹). Electrochemical performances of the CACNFs were evaluated as supercapacitor electrodes in 6 M KOH solution. The CACNFs demonstrate high specific capacitance (202 F g⁻¹ at 0.1 A g⁻¹) and excellent rate capability (61% of the retention from 0.1 to 20 A g⁻¹). After 5000 cycles of the electrode, the capacitance is maintained at 92%, and the coulombic efficiency is close to 100%, showing high electrochemical stability and reversibility. The renewable features and excellent performance make CACNFs quite a promising alternative to efficient supercapacitor electrodes for energy storage applications.

Porous carbon nanofibers are fabricated by one-step carbonization and activation of electrospun cellulose acetate (CA) nanofibres.     

Facile synthesis of high-surface-area nanoporous carbon from biomass resources and its application in supercapacitors

It is critical for nanoporous carbons to have a large surface area, and low cost and be readily available for challenging energy and environmental issues. The pursuit of all three characteristics, particularly large surface area, is a formidable challenge because traditional methods to produce porous carbon materials with a high surface area are complicated and expensive, frequently resulting in pollution (commonly from the activation process). Here we report a facile method to synthesize nanoporous carbon materials with a high surface area of up to 1234 m² g⁻¹ and an average pore diameter of 0.88 nm through a simple carbonization procedure with carefully selected carbon precursors (biomass material) and carbonization conditions. It is the high surface area that leads to a high capacitance (up to 213 F g⁻¹ at 0.1 A g⁻¹) and a stable cycle performance (6.6% loss over 12 000 cycles) as shown in a three-electrode cell. Furthermore, the high capacitance (107 F g⁻¹ at 0.1 A g⁻¹) can be obtained in a supercapacitor device. This facile approach may open a door for the preparation of high surface area porous carbons for energy storage.

High-surface-area nanoporous carbon is obtained by direct pyrolysis of biomass resources without an activation process. An electrochemical test shows high capacitance.     

Improved pseudocapacitive charge storage in highly ordered mesoporous TiO2/carbon nanocomposites as high-performance Li-ion hybrid supercapacitor anodes

A Li-ion hybrid supercapacitor (Li-HSCs), an integrated system of a Li-ion battery and a supercapacitor, is an important energy-storage device because of its outstanding energy and power as well as long-term cycle life. In this work, we propose an attractive material (a mesoporous anatase titanium dioxide/carbon hybrid material, m-TiO₂-C) as a rapid and stable Li⁺ storage anode material for Li-HSCs. m-TiO₂-C exhibits high specific capacity (∼198 mA h g⁻¹ at 0.05 A g⁻¹) and promising rate performance (∼90 mA h g⁻¹ at 5 A g⁻¹) with stable cyclability, resulting from the well-designed porous structure with nanocrystalline anatase TiO₂ and conductive carbon. Thereby, it is demonstrated that a Li-HSC system using a m-TiO₂-C anode provides high energy and power (∼63 W h kg⁻¹, and ∼4044 W kg⁻¹).

A mesoporous TiO₂/carbon nanocomposite prepared by block copolymer self-assembly improves pseudocapacitive behavior and achieves high energy/power density Li-ion hybrid supercapacitors.     

All-solid-state supercapacitors using a highly-conductive neutral gum electrolyte

Recently, the development of safe, stable, and long-life supercapacitors has attracted considerable interest driven by the fast-growth of flexible wearable devices. Herein, we report an MnO₂-based symmetric all-solid-state supercapacitor, using a neutral gum electrolyte that was prepared by embedding aqueous sodium sulfate solution in a biopolymer xanthan gum. Resulting from the high ion conductivity 1.12 S m⁻¹, good water retention, and high structure adaption of such gum electrolyte, the presently described supercapacitor showed high electrochemical performance with a specific capacitance of 347 F g⁻¹ at 1 A g⁻¹ and an energy density of 24 μW h cm⁻² The flexible supercapacitor possesses excellent reliability and achieves a retaining capacitance of 82% after 5000 cycles. In addition, the as-prepared supercapacitor demonstrated outstanding electrochemical stability at temperatures between −15 °C to 100 °C.

A highly-conductive neutral gum electrolyte was used for all-solid-state supercapacitors with outstanding electrochemical performance at temperatures between −15 °C to 100 °C.     

Porous carbon derived from metal–organic framework@graphene quantum dots as electrode materials for supercapacitors and lithium-ion batteries

The C@GQD composite was prepared by the combination of metal–organic framework (ZIF-8)-derived porous carbon and graphene quantum dots (GQDs) by a simple method. The resulting composite has a high specific surface area of 668 m² g⁻¹ and involves numerous micro- and mesopores. As a supercapacitor electrode, the material showed an excellent double-layer capacitance and a high capacity retention of 130 F g⁻¹ at 2 A g⁻¹. The excellent long-term stability was observed even after ∼10 000 charge–discharge cycles. Moreover, the composite as an anode material for a lithium-ion battery exhibited a good reversible capacity and outstanding cycle stability (493 mA h g⁻¹ at 100 mA g⁻¹ after 200 cycles). The synergistic effect of a MOF-derived porous carbon and GQDs was responsible for the improvement of electrochemical properties.

The C@GQD composite was prepared by the combination of metal–organic framework (ZIF-8)-derived porous carbon and graphene quantum dots (GQDs) by a simple method.