The effects of Sn content on the corrosion behavior and mechanical properties of Mg–5Gd–3Y–xSn–0.5Zr alloys

The effects of Sn content on the corrosion behavior and mechanical properties of Mg–5Gd–3Y–0.5Zr alloy were studied by SEM, EDS, XRD and electrochemical testing. Results show that Sn can refine the grain size and promote the precipitation of Mg₅(Gd,Y) phase. When the Sn content is 1.5–2 wt%, a needle-like Mg₂Sn phase will be precipitated in the alloy. Mg–5Gd–3Y–1Sn–0.5Zr alloy had the lowest corrosion rate, which is attributed to the barrier effect of the grain boundary and dispersed Mg₅(Gd,Y) phase on corrosion. However, the Mg₂Sn phase formed by excessive Sn addition will accelerate galvanic corrosion. At the same time, Mg–5Gd–3Y–1Sn–0.5Zr alloy had best mechanical properties. In 1.5Sn and 2Sn alloys, the cleavage effect of the needle-like Mg₂Sn phase on the matrix reduced mechanical properties.

The effects of Sn content on the corrosion behavior and mechanical properties of Mg–5Gd–3Y–0.5Zr alloy were studied by SEM, EDS, XRD and electrochemical testing. Results show that Sn can refine the grain size and promote the precipitation.     

Enhanced thermal conductivity and tensile strength of Al–17Si–3.5Cu with SiC-nanoparticle addition

The morphology and size of primary Si has a significant influence on the thermal conductivity (TC) and strength of Al–17Si–3.5Cu. In this study, the effect of a 1–3 wt% SiC nanoparticle (SiC_nps) addition on TC and tensile strength of Al–17Si–3.5Cu was investigated. Nanoparticles distributed at the interface between primary Si and Al led to a significant refinement of primary Si; for example, a primary Si size of 2 μm with 3 wt% SiC_nps addition was achieved. TC of SiC_nps/Al–17Si–3.5Cu improved with an increase in nanoparticle content. Nanoparticles distributed at the interface between Si and Al reduced the interfacial thermal resistance. Thus, the effective TC of eutectic Si increased. Owing to the refinement of the primary Si and the increased interfacial thermal resistance, originating from the high content of SiC_nps at the interface, the effective TC of primary Si decreased. Compared with Al–17Si–3.5Cu, contribution to the improvement of the TC of SiC_nps/Al–17Si–3.5Cu resulted mainly from eutectic Si. Due to the refinement of primary Si, the tensile strength of SiC_nps/Al–17Si–3.5Cu improved with an increase in SiC_nps content. When the SiC_nps content was 3 wt%, the yield strength, ultimate tensile strength and elongation of SiC_nps/Al–17Si–3.5Cu were ∼176 MPa, 418 MPa and 7%, respectively, which were improved by 37.5%, 53.7% and 218%, respectively, when compared with Al–17Si–3.5Cu.

An interfacial nanocomposite layer was proposed to investigate the effect of SiC_nps on interfacial thermal resistance between Si and Al.     

Application of hydrotalcite in soil immobilization of iodate (IO3−)

Radioactive iodine is quite mobile in soil and poses threats to human health and the ecosystem. Many materials, including layered double hydroxides (LDH), have been synthesized to successfully capture iodine from aqueous environments. However, limited information is available on the application of LDH in soil to immobilize iodine species. In the present study, the feasibility of using Mg–Al–NO₃ LDH for retention of soil iodate (IO₃⁻) in both batch and column systems was analyzed. The 2 : 1 Mg–Al–NO₃ LDH exhibited the greatest removal efficiency of IO₃⁻ from aqueous solution, compared with 3 : 1 and 4 : 1 Mg–Al–NO₃ LDH. The Mg₂–Al–NO₃ LDH demonstrated a strong affinity for IO₃⁻, with a high sorption capacity of 149 528 mg kg⁻¹ and a Freundlich affinity constant K_F of 21 380 L kg⁻¹. The addition of Mg₂–Al–NO₃ LDH in soil resulted in significant retention of IO₃⁻ in both the batch and column experiments. The affinity parameter K_F of soil with the addition of 1.33% Mg₂–Al–NO₃ LDH was 136 L kg⁻¹, which was 28.6 times higher than soil without LDH added. Moreover, the eluted iodate percentage was only 12.9% in the soil column with the 1.33% Mg₂–Al–NO₃ LDH addition, whereas almost 43.5% iodate was washed out in the soil column without LDH addition. The results suggested that Mg₂–Al–NO₃ LDH could effectively immobilize iodate in soil without obvious interference.

Addition of Mg₂–Al–NO₃ LDH at a very low dosage significantly retarded iodate in soil.     

Electrochemical preparation and properties of a Mg–Li–Y alloy via co-reduction of Mg(ii) and Y(iii) in chloride melts

Mg–Li based alloys have been widely used in various fields. However, the widespread use of Mg–Li based alloys were restricted by their poor properties. The addition of rare earth element in Mg–Li can significantly improve the properties of alloys. In the present work, different electrochemical methods were used to investigate the electrochemical behavior of Y(iii) on the W electrode in LiCl–KCl melts and LiCl–KCl–MgCl₂ melts. In LiCl–KCl melts, typical cyclic voltammetry was used to study the electrochemical mechanism and thermodynamic parameters for the reduction of Y(iii) to metallic Y. In LiCl–KCl–MgCl₂ melts, the formation mechanism of Mg–Y intermetallic compounds was investigated, and the results showed that only one kind of Mg–Y intermetallic compound was formed under our experimental conditions. Mg–Li–Y alloys were prepared via galvanostatic electrolysis, and XRD and SEM equipped with EDS analysis were used to analyze the samples. Because of the restrictions of EDS analysis, ICP-AES was used to analyze the Li content in Mg–Li–Y alloys. The microhardness and Young''s modulus of the Mg–Li–Y alloys were then evaluated.

Mg–Li based alloys have been widely used in various fields.     

Synthesis of biodiesel from waste cooking oil catalyzed by β-cyclodextrin modified Mg–Al–La composite oxide

In this study, Mg–Al–La composite oxide loaded with ionic liquid [Bmim]OH was used as a catalyst for the synthesis of fatty acid isobutyl ester (FAIBE) via transesterification between waste cooking oil and isobutanol. Mg–Al–La composite oxide was synthesized from the β-cyclodextrin (β-CD) intercalation modification of Mg–Al–La layered double hydroxides. The structure of the catalyst was characterized via XRD, BET and EDS. The results showed that the interlayer space of the catalyst was increased due to β-CD intercalation modification. The IL/CD–Mg–Al–La catalyst exhibited significant catalytic activity and regeneration performance in transesterification due to large interlayer space and strongly alkaline ionic liquid. The yield of FAIBE achieved was 98.3% under the optimum reaction condition and 95.2% after regeneration for six times. The viscosity–temperature curve of FAIBE was determined and the phase transition temperature was −1 °C. The pour point of FAIBE was only −10 °C, which exhibited excellent low temperature fluidity.

In this study, Mg–Al–La composite oxide loaded with ionic liquid [Bmim]OH was used as a catalyst for the synthesis of fatty acid isobutyl ester (FAIBE) via transesterification between waste cooking oil and isobutanol.     

A modified random network model for P2O5–Na2O–Al2O3–SiO2 glass studied by molecular dynamics simulations

We investigated the short- and medium-range structural features of sodium aluminosilicate glasses with various P₂O₅ (0–7 mol%) content and Al/Na ratios ranging from 0.667 to 2.000 by using molecular dynamics simulations. The local environment evolution of network former cations (Si, Al, P) and the extent of clustering behavior of modifiers (Na⁺) is determined through pair distribution function (PDF), total correlation function (TDF), coordination number (CN), Q_xⁿ distribution and oxygen speciation analysis. We show that Al–O–P and Si–O–Al linkage is preferred over other connections as compared to a random model and that Si–O–Si linkage is promoted by the P₂O₅ addition, which is related to structural heterogeneity and generates well-separated silicon-rich and aluminum–phosphorus-rich regions. Meanwhile, due to the relatively high propensity of Al to both Si and P, heterogeneity can be partly overcome with high Al content. A small amount of Si–O–P linkages have been detected at the interface of separated regions. Clustering of Na⁺ is also observed and intensified with the addition of P₂O₅. Based on the simulated structural information, a modified random network model for P₂O₅-bearing sodium aluminosilicate glass has been proposed, which could be useful to optimize the mobility of sodium ions and design novel functional glass compositions.

(A) A modified structural model proposed for P₂O₅-bearing sodium aluminosilicate glasses. (B) Degree of preferred connection (DPC) of different T–O–T network linkage for LAP, MAP and HAP glass compositions with various P₂O₅ content.     

Efficient in situ generation of H2O2 by novel magnesium–carbon nanotube composites

Hydrogen peroxide (H₂O₂) is widely employed as an environmentally friendly chemical oxidant and an energy source. In this study, a novel magnesium–carbon nanotube composite was prepared by a ball milling process in argon atmosphere using polyvinylidene fluoride (PVDF) as a binder. The resulting material was then tested for the in situ generation of H₂O₂. The preparation and operation conditions of the composite were systemically investigated and analyzed to improve the efficiency of the in situ generation of H₂O₂. Under the optimized conditions, while aerating with oxygen for 60 min, a maximum H₂O₂ concentration of 194.73 mg L⁻¹ was achieved by the Mg–CNTs composite prepared using Mg : CNT : PVDF with a weight ratio of 5 : 1 : 2.4. In the Mg–CNTs/O₂ system, dissolved oxygen molecules were reduced to H₂O₂, while magnesium was oxidized owing to the electrochemical corrosion. In addition, a part of dissolved magnesium ions converted into magnesium hydroxide and precipitated as nanoflakes on the surfaces of CNTs. A mechanism was proposed, suggesting that the formation of a magnesium/carbon nanotubes corrosion cell on the Mg–CNT composite promoted the in situ synthesis of H₂O₂. Overall, this study provides a promising and environmentally friendly strategy to fabricate magnesium/CNT composites for the in situ generation of H₂O₂, which could be applied in energy conversion and advanced oxidation processes for refractory wastewater treatment.

Mg–CNTs composite prepared by ball milling with PVDF promoted the in situ synthesis of H₂O₂.     

First-principles study of thermoelectric properties of Mg2Si–Mg2Pb semiconductor materials

Mg₂X^IV (X^IV = Si, Ge, Sn) compounds are semiconductors and their solid solutions are believed to be promising mid-temperature thermoelectric materials. By contrast, Mg₂Pb is a metal and few studies have been conducted to investigate the thermoelectric properties of Mg₂Si–Mg₂Pb solid solutions. Here, we present a theoretical study exploring whether Mg₂Pb–Mg₂Si solid solutions can be used as thermoelectric materials or not. We firstly constructed several Mg₂Si_1−xPb_x (0 ≤ x ≤ 1) structures and calculated their electronic structures. It is suggested that Mg₂Si_1−xPb_x are potential thermoelectric semiconductors in the range of 0 ≤ x ≤ 0.25. We then explicitly computed the electron relaxation time and both the electronic and lattice thermal conductivities of Mg₂Si_1−xPb_x (0 ≤ x ≤ 0.25) and studied the effect of Pb concentration on the Seebeck coefficient, electrical conductivity, thermal conductivity, and thermoelectric figure of merit (ZT). At low Pb concentration (x = 1/16), the ZT of the Mg₂Si_1−xPb_x solid solutions (up to 0.67 at 900 K) reaches a maximum and is much higher than that of Mg₂Si.

Thermoelectric figure of merit of Mg₂Si_1−xPb_x solid solutions as a function of temperature.     

Acid–base sites synergistic catalysis over Mg–Zr–Al mixed metal oxide toward synthesis of diethyl carbonate

In heterogeneous catalysis processes, development of high-performance acid–base sites synergistic catalysis has drawn increasing attention. In this work, we prepared Mg/Zr/Al mixed metal oxides (denoted as Mg₂Zr_xAl_1−x–MMO) derived from Mg–Zr–Al layered double hydroxides (LDHs) precursors. Their catalytic performance toward the synthesis of diethyl carbonate (DEC) from urea and ethanol was studied in detail, and the highest catalytic activity was obtained over the Mg₂Zr_0.53Al_0.47MMO catalyst (DEC yield: 37.6%). By establishing correlation between the catalytic performance and Lewis acid–base sites measured by NH₃-TPD and CO₂-TPD, it is found that both weak acid site and medium strength base site contribute to the overall yield of DEC, which demonstrates an acid–base synergistic catalysis in this reaction. In addition, in situ Fourier transform infrared spectroscopy (in situ FTIR) measurements reveal that the Lewis base site activates ethanol to give ethoxide species; while Lewis acid site facilitates the activated adsorption of urea and the intermediate ethyl carbamate (EC). Therefore, this work provides an effective method for the preparation of tunable acid–base catalysts based on LDHs precursor approach, which can be potentially used in cooperative acid–base catalysis reaction.

Mg/Zr/Al mixed metal oxides were prepared via a facile phase transformation process of hydrotalcite precursors, which showed acid–base sites synergistic catalytic performance toward the synthesis of diethyl carbonate from ethanol and urea.     

Study of Ag precipitation and mechanical properties of Ti–Ta–Ag ternary alloy

Ti–25Ta–xAg alloy samples with different content of Ag were prepared by spark plasma sintering method. X-ray diffraction, microscopic metallographic, scanning electron microscopy, and transmission electron microscopy were used to analyze the phase structure and morphology of the alloy samples. Ti–Ta–Ag can form a stable ternary alloy system. Furthermore, with the increase of Ag content and sintering temperature, Ag will be precipitated at the grain boundary. In order to explore the precipitation mechanism of Ag in the alloy and its influence on the mechanical properties, the crystal structure, electronic structure, and elastic constant under different Ag solid solubility were calculated systematically by using first-principles calculations. The results show that the critical temperature of Ag in Ti–Ta–Ag ternary alloy is about 2200 K, and the high temperature is favorable for the aging precipitation of Ag. The lattice constants and mechanical properties of (Ti_1−xAg_x)₃Ta solid solution suddenly change when the Ag solid solubility x value is equal to 0.8, and their changes will follow different rules. The internal mechanism of this phenomenon is that the 4d¹⁰ electronic states of Ag have changed from obvious local electronic states to mixed local and non-local electronic states. These results provide theoretical guidance for the application of Ti–Ta–Ag ternary alloys in biomedicine.

Precipitation of columnar Ag particles from Ti–Ta–Ag ternary alloys improves mechanical properties.     

The role of alloyed strontium in the microstructures and alkaline electrochemistry of Mg–5Al–4Sn alloys

In this study, strontium is used as an alloying element for improving the pitting resistance of Mg–5Al–4Sn based alloys in an alkaline solution. Potentiodynamic polarization measurements suggest that the addition of strontium increases the robustness of the pitting resistance as a result of the higher pitting potential and wider range of passive potential. Electrochemical impedance spectroscopy (EIS) confirms the formation of a solid passive film on the alloy surface due to a significant increase in the passive film and the charge transfer resistance, as well as lower film and double layer constant phase element magnitude values. Additionally, the potentiostatic polarisation results also show a lower passive current density and passive film stability, resulting in an increase in the breakdown time when the amount of strontium added to the alloy increases from 0.0 to 1.0 wt%. Furthermore, the scanning electron microscopy results indicate that insignificant corrosion is observed on alloy specimens containing strontium, whereas there is fierce corrosion on alloy based surfaces. This robust corrosion resistance could be attributed to the α-grain reduction and refined precipitates at the alloy grain boundaries, resulting in promoted formation of the passive film which is formed from a mixture of magnesium, aluminum and tin oxides/hydroxides, as confirmed by the X-ray photoelectron spectroscopy results.

The development of Mg–5Al–4Sn–xSr alloys with α-grain reduction, refined precipitates and pitting corrosion resistance by die casting.     

Black Si-doped TiO2 nanotube photoanode for high-efficiency photoelectrochemical water splitting

Black Si-doped TiO₂ (Ti–Si–O) nanotubes were fabricated through Zn metal reduction of the Ti–Si–O nanotubes on Ti–Si alloy in an argon atmosphere. The nanotubes were used as a photoanode for photoelectrochemical (PEC) water splitting. Both Si element and Ti³⁺/oxygen vacancies were introduced into the black Ti–Si–O nanotubes, which improved optical absorption and facilitated the separation of the photogenerated electron–hole pairs. The photoconversion efficiency could reach 1.22%, which was 7.18 times the efficiency of undoped TiO₂. It demonstrated that a Si element and Ti³⁺/oxygen vacancy co-doping strategy could offer an effective method for fabricating a high-performance TiO₂-based nanostructure photoanode for improving PEC water splitting.

Black Si-doped TiO₂ (Ti–Si–O) nanotubes were fabricated through Zn metal reduction of the Ti–Si–O nanotubes on Ti–Si alloy in an argon atmosphere.     

Mechanical and tribological performance of a hybrid MMC coating deposited on Al–17Si piston alloy by laser composite surfacing technique

Laser composite surfacing (LCS) is a photon driven manufacturing technology that can be utilized for depositing hybrid metal matrix composite coatings (HMMC) on softer Ti/Al/Mg alloys to enhance their tribo-mechanical properties. LCS offers the advantages of higher directionality, localized microstructural refinement and higher metallurgical bonding between coating and substrate. The current research presents the tribo-mechanical evaluation and characterization of solid lubricant based Ni–WC coatings deposited by LCS on Al–Si piston alloy by varying the concentration of graphite between 5-to-15-weight percentage. The tribological behavior of LCS samples was investigated using a ball-on-plate tribometer. Results indicate that the surface hardness, wear rate and friction coefficient of the Al–Si hypereutectic piston alloy were improved after LCS of graphite based HMMC coatings. The maximum surface hardness of 781H_v was acquired for the Ni–WC coating containing 5 wt% graphite. The friction coefficient of Al–Si under dry sliding conditions was reduced from 0.47 to 0.21. The reduction in the friction coefficient was attributed to the formation of a shearable transfer layer, which prevented delamination and reduced adhesion, abrasion and fatigue cracking.

The addition of graphite as solid lubricant has significantly reduced the friction coefficient and wear of a Ni–WC composite coating.     

Na–Ga–Si type-I clathrate single crystals grown via Na evaporation using Na–Ga and Na–Ga–Sn fluxes

Single crystals of a Na–Ga–Si clathrate, Na₈Ga_5.70Si_40.30, of size 2.9 mm were grown via the evaporation of Na from a Na–Ga–Si melt with the molar ratio of Na : Ga : Si = 4 : 1 : 2 at 773 K for 21 h under an Ar atmosphere. The crystal structure was analyzed using X-ray diffraction with the model of the type-I clathrate (cubic, a = 10.3266(2) Å, space group Pm$\bar{3}$n, no. 223). By adding Sn to a Na–Ga–Si melt (Na : Ga : Si : Sn = 6 : 1 : 2 : 1), single crystals of Na₈Ga_xSi_46−x (x = 4.94–5.52, a = 10.3020(2)–10.3210(3) Å), with the maximum size of 3.7 mm, were obtained via Na evaporation at 723–873 K. The electrical resistivities of Na₈Ga_5.70Si_40.30 and Na₈Ga_4.94Si_41.06 were 1.40 and 0.72 mΩ cm, respectively, at 300 K, and metallic temperature dependences of the resistivities were observed. In the Si L_2,3 soft X-ray emission spectrum of Na₈Ga_5.70Si_40.30, a weak peak originating from the lowest conduction band in the undoped Si₄₆ was observed at an emission energy of 98 eV.

Single crystals of a Na–Ga–Si clathrate, Na₈Ga_4.94Si_41.06, of size 3.7 mm were grown via the evaporation of Na from a Na–Ga–Si–Sn melt with the molar ratio of Na : Ga : Si : Sn = 6 : 1 : 2 : 1 at 873 K for 3 h under an Ar atmosphere.     

Enhanced thermoelectric properties in N-type Mg2Si0.4−xSn0.6Sbx synthesized by alkaline earth metal reduction

Mg₂Si_1−xSn_x-based compounds have been recognized as promising thermoelectric materials owing to their high figure-of-merit ZTs, abundance of raw constituent elements and nontoxicity. However, further improvement in the thermoelectric performance in this type of material is still constrained by the high thermal conductivity. In this work, we prepared a series of representative Mg₂Si_0.4−xSn_0.6Sb_x (x = 0, 0.0075, 0.008, 0.009, 0.01, 0.011) samples via the alkaline earth metal reduction method through a combination of ball milling and spark plasma sintering (SPS) processes. The samples featured many dislocations at the grain boundaries and plenty of nanoscale-coherent Mg₂Si–Mg₂Sn spinodal phases; both of which can effectively scatter heat-carrying phonons and have nearly no impact on the carrier transport. Meanwhile, Sb-doping can efficiently optimize the carrier concentration and significantly suppress the bipolar effects. As a result, a maximal ZT of 1.42 at 723 K and engineering (ZT)eng of 0.7 are achieved at the optimal Sb-doping level of x = 0.01. This result indicates that the alkaline earth metal reduction method could be an effective route to engineer phonon transport and improve the thermoelectric performance in Mg₂Si_1−xSn_x-based materials.

Sb doped Mg₂Si_0.4Sn_0.6 materials feature with lots of dislocations at grain boundaries and plenty of nanoscale Mg₂Si–Mg₂Sn spinodal phases, both of which can scatter heat carrying phonons and suppress the bipolar effects, with a optimal ZT of 1.42.     

Influence of alkalinity on the synthesis of hierarchical LTA zeolite by using bridged polysilsesquioxane

The mechanism of formation of hierarchical LTA zeolite involved the methoxyl groups of bridged polysilsesquioxane hydrolyzing into hydroxyl groups. The covalent Si–O–Si bond between silicon hydroxyl in the above solution and other silica sources forms by dehydration, avoiding phase separation. The influence of alkalinity on the synthesis of hierarchical LTA zeolites was investigated by using bridged polysilsesquioxane. XRD patterns indicate the synthesis of sodalite at the same molar composition of the hierarchical LTA zeolites without bridged polysilsesquioxane. The characterization results from TG and DTG revealed that bridged polysilsesquioxane was successfully incorporated into the as-synthesized hierarchical LTA zeolite. N₂-adsorption/desorption results proved that mesopores and the porosities of the hierarchical LTA zeolites are adjustable by a change of alkalinity. SEM images indicated that the morphologies of the hierarchical LTA zeolites changed with increasing alkalinity. The hierarchical LTA zeolites showed faster initial exchange rates of Na⁺ to Mg²⁺ compared with conventional LTA.

The mechanism of formation of hierarchical LTA zeolite involved the methoxyl groups of bridged polysilsesquioxane hydrolyzing into hydroxyl groups. The Si–O–Si bond was formed between silicon hydroxyl and silica by dehydration, avoiding phase separation.     

Heat treatment effect on the mechanical properties,roughness and bone ingrowth capacity of 3D printing porous titanium alloy

The weak mechanical strength and biological inertia of Ti–6Al–4V porous titanium alloy limit its clinical application in the field of orthopedics. The present study investigated the influence of different solution temperatures (e.g. 800 °C, 950 °C and 1000 °C) on the mechanical properties, roughness and bone ingrowth capacity of Ti–6Al–4V porous titanium alloy prepared by Electron Beam Melting. It was found that the compressive and shear strength were promoted with the increase of solution temperature because of the transformed crystallinity of Ti–6Al–4V titanium alloy and phase changes from TiAl to TiAl + TiV. In addition, the topological morphology, surface roughness and wettability of the porous titanium alloy scaffolds were improved after heat treatment, and in turn, the adhesion rate and cell proliferation of bone marrow mesenchymal stem cells were enhanced. Compared with the scaffolds before and after heat treatment at 800 °C, the scaffolds heat-treated at 950 °C and 1000 °C achieved better bone ingrowth, extracellular matrix deposition and osseointegration. These findings indicate the great potential of heat treatment in possessing Ti–6Al–4V porous titanium alloy for orthopedic implant.

The weak mechanical strength and biological inertia of Ti–6Al–4V porous titanium alloy limit its clinical application in the field of orthopedics.     

Study of the structure and characteristics of mesoporous TiO2 photocatalyst,and evaluation of its factors on gaseous formaldehyde removal by the analysis of ANOVA and S/N ratio

This study differs from previous studies of TiO₂/SiO₂ in that 0.5–10 μm microsized TiO₂-rutile based catalysts (TR catalysts) with varying proportions of titanium and silicon were synthesized using a one-step modified hydrothermal method. At Ti/Si = 1/9, a two-dimensional channel-structured catalyst with a morphology resembling that of SBA-15 was obtained. In contrast, at Ti/Si = 3/7 or 5/5, a three-dimensional porous structure was formed, and Ti–O–Si–C bonds appeared. The structure of the TR catalyst transformed due to the decrease in C–Si bond content and the increase in C–C bond content with increasing Ti/Si ratio. The results indicated that the rutile phase was the main crystal phase of the TR catalyst. The small crystal size and large rutile phase content of the mesoporous TR catalyst contributed to the low band gap energy below 3.0 eV. Under 2 × 10 W lamp irradiation with either UVA or visible light, the three TR catalysts showed better formaldehyde (HCHO) removal efficiency than P25. Furthermore, the Taguchi method was employed to evaluate the catalytic factors by analysis of variance (ANOVA) and S/N ratio. The results revealed the contributions of each of the three factors to HCHO removal efficiency over TR catalysts to be as follows: space velocity (62%), Ti ratio (32%), and time on stream (5%). The TR catalyst with Ti/Si = 1/9 showed good HCHO removal efficiency with a high S_BET (787.1 m² g⁻¹) and large pore volume (0.95 cm³ g⁻¹) for a residence time of over 2.29 × 10⁻¹ s under visible light irradiation. Microwave-assisted EG reduction was successfully applied to dope a TR catalyst with nanosized Pt particles in a short synthesis time. After Pt doping, the removal efficiency in the stream improved and stabilized. The Pt particles were Pt⁰ and proved effective for improving the photocatalytic removal of HCHO over the TR catalyst by prolonging the separation time of the electron–hole pairs. Overall, the Pt/TR catalyst is a potential material for pollutant removal and can be easily separated from the pollutant removal system since the catalysts are microsized.

This study differs from previous studies of TiO₂/SiO₂ in that 0.5–10 μm microsized TiO₂-rutile based catalysts (TR catalysts) with varying proportions of titanium and silicon were synthesized using a one-step modified hydrothermal method.     

Catalytic decomposition of N2O over Cu–Al–Ox mixed metal oxides

Cu–Al–O_x mixed metal oxides with intended molar ratios of Cu/Al = 85/15, 78/22, 75/25, 60/30, were prepared by thermal decomposition of precursors at 600 °C and tested for the decomposition of nitrous oxide (deN₂O). Techniques such as XRD, ICP-MS, N₂ physisorption, O₂-TPD, H₂-TPR, in situ FT-IR and XAFS were used to characterize the obtained materials. Physico-chemical characterization revealed the formation of mixed metal oxides characterized by different specific surface area and thus, different surface oxygen default sites. The O₂-TPD results gained for Cu–Al–O_x mixed metal oxides conform closely to the catalytic reaction data. In situ FT-IR studies allowed detecting the form of Cu⁺⋯N₂ complexes due to the adsorption of nitrogen, i.e. the product in the reaction between N₂O and copper lattice oxygen. On the other hand, mostly nitrate species and NO were detected but those species were attributed to the residue from catalyst synthesis.

Cu–Al–O_x mixed metal oxides with intended molar ratios of Cu/Al = 85/15, 78/22, 75/25, 60/30, were prepared by thermal decomposition of precursors at 600 °C and tested for the decomposition of nitrous oxide (deN₂O).     

Hydrogen storage in Mg2Ni(Fe)H4 nano particles synthesized from coarse-grained Mg and nano sized Ni(Fe) precursor

In this work, Mg₂Ni(Fe)H₄ was synthesized using precursors of nano Ni(Fe) composite powder prepared through arc plasma method and coarse-grained Mg powder. The microstructure, composition, phase components and the hydrogen storage properties of the Mg–Ni(Fe) composite were carefully investigated. It is observed that the Mg₂Ni(Fe)H₄ particles formed from the Mg–Ni(Fe) composite have a diameter of 100–240 nm and a portion of Fe in the Ni(Fe) nano particles transformed into α-Fe nano particles with the diameter of 40–120 nm. DSC measurements showed that the peak desorption temperature of the Mg₂Ni(Fe)H₄ was reduced to 501 K and the apparent activation energy for hydrogen desorption of the Mg₂Ni(Fe)H₄ was 97.2 kJ mol⁻¹ H₂. The formation enthalpy of Mg₂Ni(Fe)H₄ was measured to be −53.1 kJ mol⁻¹ H₂. The improvements in hydrogen sorption kinetics and thermodynamics can be attributed to the catalytic effect from α-Fe nano particles and the destabilization of Mg₂NiH₄ caused by the partial substitution of Ni by Fe, respectively.

Mg₂Ni(Fe)H₄ was synthesized from precursors of coarse grained Mg powder and Ni(Fe) nano particles with improved hydrogen sorption kinetics and thermodynamics as compared to Mg₂Ni(Fe)H₄.