Preparation and visible-light photocatalytic properties of the floating hollow glass microspheres – TiO2/Ag3PO4 composites

A novel floating visible-light photocatalyst (HGMs–TiO₂/Ag₃PO₄) composite was prepared using amino modified low-density hollow glass microspheres (HGMs) as carriers to disperse and support TiO₂ and Ag₃PO₄ photocatalysts. The surface morphology, crystal structure and optical properties of the HGMs–TiO₂/Ag₃PO₄ composites were characterized and the Ag₃PO₄ content on the surface of the microspheres was determined by atomic absorption spectrometry (AAS). Methylene blue (MB) was chose as the organic pollutant to investigate the visible-light catalytic properties of the HGMs–TiO₂/Ag₃PO₄ composites. For HGM composite photocatalysts, when the theoretical mass ratio of TiO₂ to Ag₃PO₄ on the surface of HGMs is 1 : 1.5, the visible-light catalytic activity of the composite is superior to pure Ag₃PO₄ and a TiO₂/Ag₃PO₄ photocatalyst with a mass ratio of 1 : 1.5 under the same conditions, due to the increased light-contact area and the photocatalytic active sites, since the TiO₂ and Ag₃PO₄ particles can be well dispersed on the surface of the floating HGMs. Furthermore, the deposits of TiO₂ and Ag₃PO₄ on the HGM surface form a heterostructure, facilitating the separation of electron–hole (e⁻ – h⁺) in the energy band, and elevating the photocatalytic activity and cycle stability of Ag₃PO₄. This work indicates that floating HGMs–TiO₂/Ag₃PO₄ composites could become a promising photocatalyst for organic dye removal due to the low cost and high visible-light responsiveness.

The amino modified low-density hollow glass microspheres were used as carriers of TiO₂ and Ag₃PO₄ photocatalysts to prepare the floating visible-light photocatalyst composite.     

Natural assembly of a ternary Ag–SnS–TiO2 photocatalyst and its photocatalytic performance under simulated sunlight

Natural assembly method was utilized to prepare a novel ternary Ag–SnS–TiO₂ nanocomposite, in which TiO₂ nanobelts were used as templates. The co-loading of Ag and SnS nanoparticles endows TiO₂ nanobelts with enhanced photocatalytic capability, resulting from the broadened light absorption spectra and decreased band gaps. Comparing with raw TiO₂ nanobelts and commercial Degussa P25, an improvement in photodegradation of simulated organic pollutants was successfully demonstrated due to the decreasing recombination of photogenerated electron–hole pairs. Our work presents a new strategy for the preparation of ternary TiO₂-based photocatalysts in the practical application of wastewater treatment.

Natural assembly method was utilized to prepare a novel ternary Ag–SnS–TiO₂ nanocomposite, in which TiO₂ nanobelts were used as templates.     

Regenerable g-C3N4–chitosan beads with enhanced photocatalytic activity and stability

In this study, a series of regenerable graphitic carbon nitride–chitosan (g-C₃N₄–CS) beads were successfully synthesized via the blend crosslinking method. The prepared beads were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), diffuse reflectance spectroscopy (DRS), photoluminescence (PL) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The structural characterization results indicate that the g-C₃N₄ granules were uniformly distributed on the surface of the chitosan matrix, and the structures of g-C₃N₄ and CS are maintained. In addition, the prepared g-C₃N₄–CS beads exhibited efficient MB degradation and stability. The optimum photocatalytic activity of our synthesized g-C₃N₄–CS beads was higher than that of the bulk g-C₃N₄ by a factor of 1.78 for MB. The improved photocatalytic activity was predominantly attributed to the synergistic effect between in situ adsorption and photocatalytic degradation. In addition, the reacted g-C₃N₄–CS beads can be regenerated by merely adding sodium hydroxide and hydrogen peroxide. Additionally, the regenerated g-C₃N₄–CS beads exhibit excellent stability after four runs, while the mass loss is less than 10%. This work might provide guidance for the design and fabrication of easily regenerated g-C₃N₄-based photocatalysts for environmental purification.

In this study, a series of regenerable graphitic carbon nitride–chitosan (g-C₃N₄–CS) beads were successfully synthesized via the blend crosslinking method.     

Efficient detoxification of triclosan by a S–Ag/TiO2@g-C3N4 hybrid photocatalyst: process optimization and bio-toxicity assessment

Owing to their persistency and toxicity, development of an effective strategy to eliminate antibiotic residues from the aquatic system has become a major environmental concern. Doping TiO₂ with hetero atoms and forming a hybrid structure with g-C₃N₄ could serve as an efficient visible light active photocatalytic candidate. In this study, a novel S–Ag/TiO₂@g-C₃N₄ hybrid catalyst was prepared for visible light degradation and detoxification of triclosan (TS) antibiotic. The effect of various operational parameters towards the photocatalytic degradation was systematically evaluated through response surface methodology (RSM) based on central composite design (CCD). The highest TS degradation (92.3%) was observed under optimal conditions (TS concentration = 10 mg L⁻¹, pH = 7.8, and catalyst weight = 0.20 g L⁻¹) after 60 min. Efficient charge separation resulted from the doped nanoparticles (silver and sulphur), the existing integrated electric field of the heterojunction and the overlying light response of hybridized TiO₂ and g-C₃N₄, thus the S–Ag/TiO₂@g-C₃N₄ composite showed impressively higher activity. The main degradation products of TS were identified by LC/ESI-MS analysis. In addition, the toxicity of the degradation products was investigated through an Escherichia coli (E. coli) colony forming unit assay and the results revealed that under optimal conditions a significant reduction in biotoxicity was noticed.

Owing to their persistency and toxicity, development of an effective strategy to eliminate antibiotic residues from the aquatic system has become a major environmental concern.     

Novel TiO2/GO/CuFe2O4 nanocomposite: a magnetic,reusable and visible-light-driven photocatalyst for efficient photocatalytic removal of chlorinated pesticides from wastewater

A TiO₂/GO/CuFe₂O₄ heterostructure photocatalyst is fabricated by a simple and low-cost ball-milling pathway for enhancing the photocatalytic degradation of chlorinated pesticides under UV light irradiation. Based on the advantages of graphene oxide, TiO₂, and CuFe₂O₄, the nanocomposite exhibited visible light absorption, magnetic properties, and adsorption capacity. Integrated analyses using XRD, SEM, TEM, and UV-visible techniques demonstrated that the nanocomposite exhibited a well-defined crystalline phase, sizes of 10–15 nm, and evincing a visible light absorption feature with an optical bandgap energy of 2.4 eV. The photocatalytic degradations of 17 different chlorinated pesticides (persistent organic pollutants) were assayed using the prepared photocatalyst. The photocatalytic activity of the nanocomposite generated almost 96.5% photocatalytic removal efficiency of typical pesticide DDE from water under UV irradiation. The superior photocatalytic performance was exhibited by the TiO₂/GO/CuFeO₄ catalyst owing to its high adsorption performance and separation efficiency of photo-generated carriers. The photocatalyst was examined in 5 cycles for treating uncolored pesticides with purposeful separation using an external magnetic field.

A TiO₂/GO/CuFe₂O₄ heterostructure photocatalyst is fabricated by a simple and low cost ball milling pathway for enhancing the photocatalytic degradation of chlorinated pesticides under UV light irradiation.     

Visible-light-driven Ag/Bi3O4Cl nanocomposite photocatalyst with enhanced photocatalytic activity for degradation of tetracycline

In this study, a novel Ag/Bi₃O₄Cl photocatalyst has been synthesized by a facile photodeposition process. Its photocatalytic performance was evaluated from the degradation of tetracycline (TC) under visible light irradiation (λ > 420 nm). The 1.0 wt% Ag/Bi₃O₄Cl photocatalyst could significantly enhance the degradation of TC compared with pure Bi₃O₄Cl, with the degradation level reaching 94.2% in 120 minutes. The enhancement of photocatalytic activity could be attributed to the synergetic effect of the photogenerated electrons (e⁻) of Bi₃O₄Cl and the surface plasmon resonance (SPR) caused by Ag nanoparticles, which could improve the absorption capacity of visible light and facilitate the separation of photogenerated electron–hole pairs. In addition, electron spin resonance (ESR) analysis and trapping experiments demonstrated that the superoxide radicals (˙O²⁻), hydroxyl radicals (˙OH) and holes (h⁺) played crucial roles in the photocatalytic process of TC degradation. The present work provides a promising approach for the development of highly efficient photocatalysts to address current environmental pollution, energy issues and other related areas.

A novel Ag/Bi₃O₄Cl photocatalyst has been synthesized by a facile photodeposition process. The Ag/Bi₃O₄Cl photocatalyst exhibited excellent photocatalytic activity for the degradation of tetracycline.     

Correction: Enhanced visible light photocatalytic activity of a floating photocatalyst based on B–N-codoped TiO2 grafted on expanded perlite

Correction for ‘Enhanced visible light photocatalytic activity of a floating photocatalyst based on B–N-codoped TiO₂ grafted on expanded perlite’ by Xin Wang et al., RSC Adv., 2015, 5, 41385–41392, https://doi.org/10.1039/c5ra06056g.

The Royal Society of Chemistry has been made aware of a closely related paper, published by the authors at nearly the same time in Applied Surface Science.¹ Although different data and results are reported in each article, the Applied Surface Science article should have been cited in this RSC Advances article.The authors have been contacted but have not responded to our communication.The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.     

Synthesis and photocatalytic properties of visible-light-responsive,three-dimensional,flower-like La–TiO2/g-C3N4 heterojunction composites

We prepared a new three-dimensional, flower-like La–TiO₂/g-C₃N₄ (LaTiCN) heterojunction photocatalyst using a solvothermal method. Analysis and characterization were performed by conducting scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform-infrared spectroscopy, ultraviolet-visible spectrophotometry, and nitrogen adsorption and desorption. The prepared g-C₃N₄ nanosheets could reach 100 nm in size and covered the TiO₂ surface. A tightly bound interface formed between the g-C₃N₄ and TiO₂, speeding up the effective transfer of photo-induced electrons. In addition, the incorporation of La³⁺ reduced the electron–hole recombination efficiency. Consequently, the prepared La–TiO₂/g-C₃N₄ composite material exhibited better visible-light catalytic activity than pure TiO₂.

A new visible-light-responsive, three-dimensional, flower-like La–TiO₂/g-C₃N₄ heterojunction photocatalyst was prepared by a solvothermal method.     

Enhanced photocatalytic activity of a visible-light-driven ternary WO3/Ag/Ag3PO4 heterojunction: a discussion on electron transfer mechanisms

WO₃/Ag₃PO₄ with different weight ratios were prepared by ultrasonic assisted two-step deposition method. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectroscopy (PL) and transmission electron microscopy (TEM). The photocatalytic activities of all samples were evaluated by the degradation of rhodamine B (RhB) under visible light irradiation. WA-60 shows the highest photocatalytic activity in the WA-x series composite, while the photocatalytic activity of WAA-60 is the best among all samples. The free radical trapping experiments show that photogenerated holes (h⁺) are the main active species. The Ag nanoparticles produced by the decomposition of Ag₃PO₄ are located at the interface of Ag₃PO₄/WO₃, which promotes the separation efficiency of photogenerated electrons and holes. To further explain the photocatalytic mechanism, electrochemical and physical tests are introduced to explore the flow of electrons inside the catalyst.

WO₃/Ag₃PO₄ with different weight ratios were prepared by ultrasonic assisted two-step deposition method.     

Novel mesoporous Co3O4–Sb2O3–SnO2 active material in high-performance capacitive deionization

Capacitive deionization (CDI), as an emerging eco-friendly electrochemical brackish water deionization technology, has widely benefited from carbon/metal oxide composite electrodes. However, this technique still requires further development of the electrode materials to tackle the ion removal capacity/rate issues. In the present work, we introduce a novel active carbon (AC)/Co₃O₄–Sb₂O₃–SnO₂ active material for hybrid electrode capacitive deionization (HECDI) systems. The structure and morphology of the developed electrodes were determined using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and Brunauer–Emmett–Teller (BET)/Barrett–Joyner–Halenda (BJH) techniques, as well as Fourier-transform infrared (FT-IR) spectroscopy. The electrochemical properties were also investigated by cyclic voltammetry (CV) and impedance spectroscopy (EIS). The CDI active materials AC/Co₃O₄ and AC/Co₃O₄–Sb₂O₃–SnO₂ showed a high specific capacity of 96 and 124 F g⁻¹ at the scan rate of 10 mV s⁻¹, respectively. In addition, the newly-developed electrode AC/Co₃O₄–Sb₂O₃–SnO₂ showed high capacity retention of 97.2% after 2000 cycles at 100 mV s⁻¹. Moreover, the electrode displayed excellent CDI performance with an ion removal capacity of 52 mg g⁻¹ at the applied voltage of 1.6 V and in a solution of potable water with initial electrical conductivity of 950 μs cm⁻¹. The electrode displayed a high ion removal rate of 7.1 mg g⁻¹ min⁻¹ with an excellent desalination–regeneration capability while retaining about 99.5% of its ion removal capacity even after 100 CDI cycles.

Capacitive deionization (CDI), as an emerging eco-friendly electrochemical brackish water deionization technology, has widely benefited from carbon/metal oxide composite electrodes.     

Synergistic effect of Ni–Ag–rutile TiO2 ternary nanocomposite for efficient visible-light-driven photocatalytic activity

P25 comprising of mixed anatase and rutile phases is known to be highly photocatalytically active compared to the individual phases. Using a facile wet chemical method, we demonstrate a ternary nanocomposite consisting of Ni and Ag nanoparticles, decorated on the surface of XTiO₂ (X: P25, rutile (R)) as an efficient visible-light-driven photocatalyst. Contrary to the current perspective, RTiO₂-based Ni–Ag–RTiO₂ shows the highest activity with the H₂ evolution rate of ∼86 μmol g⁻¹ W⁻¹ h⁻¹@535 nm. Together with quantitative assessment of active Ni, Ag and XTiO₂ in these ternary systems using high energy synchrotron X-ray diffraction, transmission electron microscopy coupled energy dispersive spectroscopy mapping evidences the metal to semiconductor contact via Ag. The robust photocatalytic activity is attributed to the improved visible light absorption, as noted by the observed band edge of ∼2.67 eV corroborating well with the occurrence of Ti³⁺ in Ti 2p XPS. The effective charge separation due to intimate contact between Ni and RTiO₂via Ag is further evidenced by the plasmon loss peak in Ag 3d XPS. Moreover, density functional theory calculations revealed enhanced adsorption of H₂ on Ti₈O₁₆ clusters when both Ag and Ni are simultaneously present, owing to the hybridization of the metal atoms with d orbitals of Ti and p orbitals of O leading to enhanced bonding characteristics, as substantiated by the density of states. Additionally, the variation in the electronegativity in Bader charge analysis indicates the possibility of hydrogen evolution at the Ni sites, in agreement with the experimental observations.

Robust photocatalytic activity of Ni–Ag–RTiO₂ is attributed to the improved visible light absorption and effective charge separation due to intimate contact between Ni and RTiO₂via Ag, as evidenced by Ti³⁺ in Ti 2p XPS and energy dispersive mapping.     

Unraveling the relationship between exposed surfaces and the photocatalytic activity of Ag3PO4: an in-depth theoretical investigation

Over the years, the possibility of using solar radiation in photocatalysis or photodegradation processes has attracted remarkable interest from scientists around the world. In such processes, due to its electronic properties, Ag₃PO₄ is one of the most important semiconductors. This work delves into the photocatalytic activity, stability, and reactivity of Ag₃PO₄ surfaces by comparing plane waves with projector augmented wave and localized Gaussian basis set simulations, at the atomic level. The results indicate that the (110) surface, in agreement with previous experimental reports, displays the most suitable characteristics for photocatalytic activity due to its high reactivity, i.e. the presence of a large amount of undercoordinated Ag cations and a high value work function. Beyond the innovative results, this work shows a good synergy between both kinds of DFT approaches.

Over the years, the possibility of using solar radiation in photocatalysis or photodegradation processes has attracted remarkable interest from scientists around the world.     

An investigation of Li2TiO3–coke composite anode material for Li-ion batteries

Anode material Li₂TiO₃–coke was prepared and tested for lithium-ion batteries. The as-prepared material exhibits excellent cycling stability and outstanding rate performance. Charge/discharge capacities of 266 mA h g⁻¹ at 0.100 A g⁻¹ and 200 mA h g⁻¹ at 1.000 A g⁻¹ are reached for Li₂TiO₃–coke. A cycling life-time test shows that Li₂TiO₃–coke gives a specific capacity of 264 mA h g⁻¹ at 0.300 A g⁻¹ and a capacity retention of 92% after 1000 cycles of charge/discharge.

Anode material Li₂TiO₃–coke was prepared and tested for lithium-ion batteries. The as-prepared material exhibits excellent cycling stability and outstanding rate performance.     

Ag3PO4 nanocrystals and g-C3N4 quantum dots decorated Ag2WO4 nanorods: ternary nanoheterostructures for photocatalytic degradation of organic contaminants in water

Visible-light-driven Ag₃PO₄/graphite-like carbon nitride/Ag₂WO₄ photocatalysts with different weight fractions of Ag₃PO₄ were synthesized. Ag₂WO₄ nanorods with a scale of 500 nm to 3 μm were prepared by using a hydrothermal reaction. Via a facile deposition–precipitation technique, graphite-like carbon nitride (g-C₃N₄) quantum dots and Ag₃PO₄ nanocrystals were then deposited onto the surface of Ag₂WO₄ nanorods sequentially. Under visible-light irradiation (λ > 420 nm), the Ag₃PO₄/g-C₃N₄/Ag₂WO₄ nanorods degraded Rh B efficiently and displayed much higher photocatalytic activity than that of pure Ag₂WO₄ and the g-C₃N₄/Ag₂WO₄ composite, and the Ag₃PO₄/g-C₃N₄/Ag₂WO₄ hybrid photocatalyst with 30 wt% of Ag₃PO₄ exhibited the highest photocatalytic activity. The quenching effects of different scavengers demonstrated that reactive h⁺ and ·O²⁻ played the major roles in Rh B degradation. It was elucidated that the excellent photocatalytic activity of Ag₃PO₄/g-C₃N₄/Ag₂WO₄ for the degradation of Rh B under visible light (λ > 420 nm) can be ascribed to the efficient separation of photogenerated electrons and holes through the Ag₃PO₄/g-C₃N₄/Ag₂WO₄ heterostructure.

The ternary heterostructured Ag₃PO₄/g-C₃N₄/Ag₂WO₄ photocatalysts were successfully synthesized. The ternary composites exhibited enhanced photocatalytic activity.     

Synthesis and enhanced visible light photocatalytic CO2 reduction of BiPO4–BiOBrxI1−x p–n heterojunctions with adjustable energy band

A series of novel BiPO₄–BiOBr_xI_1−x p–n heterojunctions were successfully prepared by a facile solvothermal method. The morphology, structure and optical properties of photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and ultraviolet visible diffuse reflectance spectroscopy. The visible light photocatalytic activities of BiPO₄–BiOBr_xI_1−x heterojunctions were investigated by photocatalytically reducing CO₂. After 4 hours of irradiation, the 5% BiPO₄–BiOBr_0.75I_0.25 heterojunction showed the highest photocatalytic activity with the yields of CO and CH₄ up to 24.9 and 9.4 μmol g_cat⁻¹ respectively. The improved photocatalytic activity may be due to the formation of BiPO₄–BiOBr_xI_1−x p–n heterojunctions which can effectively restrict the recombination rate of the photoexcited charge carriers. Moreover, the energy band structure of BiPO₄–BiOBr_xI_1−x heterojunctions could be easily adjusted by changing the mole ratio of I and Br. The possible mechanism of the enhancement of the photocatalytic performance was also proposed based on experimental and theoretical analysis. The present study may provide a rational strategy to design highly efficient heterojunctions with an adjustable energy band for environmental treatment and energy conversion.

A series of novel BiPO₄–BiOBr_xI_1−x p–n heterojunctions were successfully prepared by a facile solvothermal method.     

Binder-free SnO2–TiO2 composite anode with high durability for lithium-ion batteries

A SnO₂–TiO₂ electrode was prepared via anodization and subsequent anodic potential shock for a binder-free anode for lithium-ion battery applications. Perpendicularly oriented TiO₂ microcones are formed by anodization; SnO₂, originating in a Na₂SnO₃ precursor, is then deposited in the valleys between the microcones and in their hollow cores by anodic potential shock. This sequence is confirmed by SEM and TEM analyses and EDS element mapping. The SnO₂–TiO₂ binder-free anode is evaluated for its C-rate performance and long-term cyclability in a half-cell measurement apparatus. The SnO₂–TiO₂ anode exhibits a higher specific capacity than the one with pristine TiO₂ microcones and shows excellent capacity recovery during the rate capability test. The SnO₂–TiO₂ microcone structure shows no deterioration caused by the breakdown of electrode materials over 300 cycles. The charge/discharge capacity is at least double that of the TiO₂ microcone material in a long-term cycling evaluation.

A binder-free SnO₂–TiO₂ composite, where SnO₂ is encapsulated into hollow TiO₂, is designed for inhibiting performance degradation for a stable LIB anode.     

Photocatalytic activity of Ag/Al2O3–Gd2O3 photocatalysts prepared by the sol–gel method in the degradation of 4-chlorophenol

The photocatalytic activity in the degradation of 4-chlorophenol (4-ClPh) in aqueous medium (80 ppm) using 2.0 wt% Ag/Al₂O₃–Gd₂O₃ (Ag/Al–Gd-x; where x = 2.0, 5.0, 15.0, 25.0 and 50.0 wt% of Gd₂O₃) photocatalysts prepared by the sol–gel method was studied under UV light irradiation. The photocatalysts were characterized by N₂ physisorption, X-ray diffraction, SEM, HRTEM, UV-Vis, XPS, FTIR and fluorescence spectroscopy. About 67.0% of 4-ClPh was photoconverted after 4 h of UV light irradiation using Ag/γ-–Al₂O₃. When Ag/Al–Gd-x photocatalysts were tested, the 4-ClPh photoconversion was improved and more than 90.0% of 4-ClPh was photoconverted after 3 h of UV light irradiation in the materials containing 15.0 and 25.0 wt% of Gd₂O₃. Ag/Al–Gd-25 was the material with the highest efficacy to mineralize dissolved organic carbon, mineralizing more than 85.0% after 4 h of UV light irradiation. Silver nanoparticles and micro-particles of irregular pentagonal shape intersected by plane nanobelts of Al₂O₃–Gd₂O₃ composite oxide were detected in the Ag/Al–Gd-25 photocatalyst. This material is characterized by a lowest recombination rate of electron–hole pairs. The low recombination rate of photo-induced electron–hole pairs in the Ag/Al–Gd-x photocatalysts with high Gd₂O₃ contents (≥15.0 wt%) confirmes that the presence of silver nanoparticles and microparticles interacting with Al₂O₃–Gd₂O₃ composite oxide entities favors the separation of photo-induced charges (e⁻ and h⁺). These materials could be appropriate to be used as highly efficient photocatalysts to eliminate high concentrations of 4-ClPh in aqueous medium.

Ag/Al₂O₃–Gd₂O₃ showed high efficacy to photodegradate 4-chlorophenol, the strong interaction between silver nano-particles and micro-particles and Al₂O₃–Gd₂O₃ entities favors the decrease in the recombination rate.     

An acetylcholinesterase biosensor with high stability and sensitivity based on silver nanowire–graphene–TiO2 for the detection of organophosphate pesticides

An electrochemical acetylcholinesterase biosensor based on silver nanowire, graphene, TiO₂ sol–gel, chitosan and acetylcholinesterase has been fabricated successfully for the detection of organophosphate pesticides. The outstanding electrical properties of silver nanowires and graphene, and moreover the self-assembly of these two nanomaterials make the biosensor highly sensitive. Simultaneously, the immobilization efficiency of the enzyme is greatly improved by the action of the TiO₂ fixed matrix. Under optimum conditions, the biosensor exhibited excellent performance for the detection of dichlorvos with a linearity in the range of 0.036 μM to 22.63 μM and the detection limit was found to be 7.4 nM. The biosensor was highly reproducible and stable during detection and storage.

An electrochemical acetylcholinesterase (AChE) biosensor based on silver nanowire, graphene stripped by 1-methyl-2-pyrrolidinone, TiO₂ sol–gel, chitosan and AChE has been fabricated successfully for the detection of organophosphate pesticides.     

Crystalline phase regulation of anatase–rutile TiO2 for the enhancement of photocatalytic activity

Biphasic TiO₂ with adjustable crystalline phases was prepared by the hydrothermal-calcination method assisted by nitric acid (HNO₃) and hydrogen peroxide (H₂O₂), using potassium titanate oxalate (K₂TiO(C₂O₄)₂) as the titanium source. The influences of H₂O₂ volume on anatase and rutile contents and photocatalytic activity of biphasic TiO₂ were investigated and the photocatalytic mechanism was explored. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (UV-vis DRS) and specific surface area (BET) were employed to characterize crystal structure, physical morphology, absorbable light, chemical composition, specific surface area and pore size distribution. The photocatalytic degradation efficiency towards a methylene blue (MB) solution under xenon light was tested, and the photocatalytic stability of the sample was investigated by photocatalytic cycle experiments. The prepared biphasic TiO₂ was nanorod-shaped and had a large specific surface area. The results showed the anatase TiO₂ content increased and the photocatalytic efficiency was enhanced as the H₂O₂ volume solution increased. Among the catalysts, the biphasic TiO₂ prepared with 30 mL of H₂O₂ had the best photocatalytic effect and could entirely degrade the MB solution after 30 minutes under irradiation. After three repeated degradations, the photocatalytic degradation rate was still estimated to be as high as 95%. It is expected that the work will provide new insights into fabricating heterophase junctions of TiO₂ for environmental remediation.

Biphasic TiO₂ with adjustable crystalline phases was prepared by the hydrothermal-calcination method assisted by nitric acid (HNO₃) and hydrogen peroxide (H₂O₂), using potassium titanate oxalate (K₂TiO(C₂O₄)₂) as the titanium source.     

Synthesis and visible-light photocatalytic degradation of Ag3PO4/AgBr/hydroxyapatite ternary nanocomposites prepared from oyster shells

In this paper, a new type of Ag₃PO₄/AgBr/hydroxyapatite (HAP) composite was successfully prepared from oyster shells and silver nitrate by a hydrothermal method. The samples were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, electron spin resonance and other precision instruments, and their catalytic activity was characterized by visible light degradation of methylene blue (MB). The experimental results show that the Ag₃PO₄/AgBr/HAP photocatalyst has a nanoscale rod-like structure and excellent photodegradation performance. Although the content of Ag₃PO₄ or AgBr had a significant effect on the reaction activity, the effects did not all positively correlate, and only the appropriate ratio could produce an improved catalytic effect. The catalytic performance of the 1:1-Ag₃PO₄/AgBr/HAP composite was the best: complete degradation of MB was achieved within 40 min, and the reaction rate was 15 times that of Ag₃PO₄/AgBr. In the process of photocatalytic degradation, ˙O²⁻ and h⁺ are the main active species involved in the reaction, and the synergistic catalysis of Ag₃PO₄, AgBr and HAP promotes the degradation rate.

A new type of Ag₃PO₄/AgBr/hydroxyapatite photocatalyst was prepared from oyster shells, which showed high efficiency in the degradation of organic dyes.