A flexible polyelectrolyte-based gel polymer electrolyte for high-performance all-solid-state supercapacitor application

A simple polymerization process assisted with UV light for preparing a novel flexible polyelectrolyte-based gel polymer electrolyte (PGPE) is reported. Due to the existence of charged groups in the polyelectrolyte matrix, the PGPE exhibits favorable mechanical strength and excellent ionic conductivity (66.8 mS cm⁻¹ at 25 °C). In addition, the all-solid-state supercapacitor fabricated with a PGPE membrane and activated carbon electrodes shows outstanding electrochemical performance. The specific capacitance of the PGPE supercapacitor is 64.92 F g⁻¹ at 1 A g⁻¹, and the device shows a maximum energy density of 13.26 W h kg⁻¹ and a maximum power density of 2.26 kW kg⁻¹. After 10 000 cycles at a current density of 2 A g⁻¹, the all-solid-state supercapacitor with PGPE reveals a capacitance retention of 94.63%. Furthermore, the specific capacitance and charge–discharge behaviors of the flexible PGPE device hardly change with the bending states.

A simple polymerization process assisted with UV light for preparing a novel flexible polyelectrolyte-based gel polymer electrolyte (PGPE) is reported.     

Ionic self-assembled organogel polyelectrolytes for energy storage applications

High performance organogel polyelectrolytes were synthesized by super acid catalyst step-growth polycondensation of isatin and the non-activated multiring aromatic p-terphenyl. Subsequently, a chemical modification reaction was carried out to obtained quaternary ammonium functionalized polyelectrolytes through a nucleophilic substitution reaction with (3-bromopropyl)trimethylammonium bromide and potassium carbonate at room temperature. Different functionalization degrees were obtained by controlling the molar ratio of the polymer and the modification agent. The organogel polyelectrolytes were formed due to the high phase segregation and self-assembling observed owing to the amphiphilic character of the material (hydrophobic backbone and hydrophilic fragment grafted). The organogel polyelectrolytes were used to fabricate supercapacitors using two commercial graphite electrodes. These polyelectrolytes displayed good ionic conductivity without the use of another doping agent such as salts, acids or ionic liquids. In this work, a strong correlation of functionalization degree and ionic conductivity of the polyelectrolytes and capacitance of the supercapacitors was observed. The ionic conductivity of the polyelectrolytes reached 0.46 mS cm⁻¹ for the 100% functionalization degree, meanwhile the polyelectrolyte with the 10% functionalization degree shows 0.036 mS cm⁻¹. Li-doped polyelectrolytes showed higher ionic conductivity due the presence of extra ionic charges (2.26 and 0.2 mS cm⁻¹ for the polyelectrolytes with the 100% and 10% of functionalization degree, respectively). The principal novelty of this work lies in the possibility of modulating the ionic conductivity of organogels and the capacitance of supercapacitors by chemical modifications. The capacitance of the supercapacitors was 1.17 mF cm⁻² for the 100% functionalized polyelectrolyte and is higher in comparison with the polyelectrolyte with 10% functionalization degree (0.68 mF cm⁻²) measured at a discharge current of 52 μA cm⁻² by galvanostatic charge discharge technique. Additionally, when lithium salt (lithium triflate) was added, the polyelectrolytes retained a gel consistency, increasing the ionic conductivity and capacitance. For the doped polyelectrolytes, the areal capacitance reaches 1.37 mF cm⁻² for the 100% functionalization degree polyelectrolyte with lithium triflate. These organogel polyelectrolytes open the possibility to design flexible and all solid-state supercapacitors without the risk of leakage.

High performance organogel polyelectrolytes were synthesized by super acid catalyst step-growth polycondensation of isatin and the non-activated multiring aromatic p-terphenyl.     

Novel poly(arylene ether ketone)/poly(ethylene glycol)-grafted poly(arylene ether ketone) composite microporous polymer electrolyte for electrical double-layer capacitors with efficient ionic transport

Polymer electrolytes have attracted considerable research interest due to their advantages of shape control, excellent safety, and flexibility. However, the limited use of traditional polymer electrolytes in electric double-layer capacitors due to their unsatisfactory ionic conductivities and poor mechanical properties makes them difficult to operate for long periods of time in large-scale energy storage. Therefore, we fabricated a high-performance microporous electrolyte based on poly(arylene ether ketone) (PAEK)/poly(ethylene glycol)-grafted poly(arylene ether ketone) (PAEK-g-PEG) using a certain amount of carboxylated chitosan with a high electrolyte uptake rate of 322 wt% and a high ionic conductivity of 2 × 10⁻² S cm⁻¹ at room temperature. A symmetric solid-state supercapacitor that uses activated carbon as electrodes and a composite microporous polymer film as the electrolyte shows a high specific capacitance of 134.38 F g⁻¹ at a current density of 0.2 A g⁻¹, while liquid electrolytes demonstrate a specific capacitance of 126.92 F g⁻¹. Energy density of the solid-state supercapacitor was 15.82% higher than that of the liquid supercapacitor at a current density of 5 A g⁻¹. In addition, the solid-state supercapacitor exhibited excellent cycling stability of over 5000 charge/discharge cycles at a current density of 1 A g⁻¹. Furthermore, solid-state supercapacitors display lower self-discharge behavior with an open-circuit potential drop of only 36% within 70 000 s, which is significantly better than that of conventional supercapacitors (52% @ 70 000 s), at a charging current density of 1 mA cm⁻². The satisfactory results indicated that the PAEK/PAEK-g-PEG composite microporous polymer film demonstrates high potential as an electrolyte material in practical applications of solid-state and portable energy storage devices.

Polymer electrolytes have attracted considerable research interest due to their advantages of shape control, excellent safety, and flexibility.     

High ionic conduction,toughness and self-healing poly(ionic liquid)-based electrolytes enabled by synergy between flexible units and counteranions

Polymer electrolytes offer great potential for emerging wearable electronics. However, the development of a polymer electrolyte that has high ionic conductivity, stretchability and security simultaneously is still a considerable challenge. Herein, we reported an effective approach for fabricating high-performance poly(ionic liquids) (PILs) copolymer (denoted as PIL-BA) electrolytes by the interaction between flexible units (butyl acrylate) and counteranions. The introduction of butyl acrylate units and bis(trifluoromethane-sulfonyl)imide (TFSI⁻) counteranions can significantly enhance the mobility of polymer chains, resulting in the effective improvement of ion transport, toughness and self-healability. As a result, the PIL-BA copolymer-based electrolytes containing TFSI⁻ counterions achieved the highest ionic conductivity of 2.71 ± 0.17 mS cm⁻¹, 1129% of that of a PIL homopolymer electrolyte containing Cl⁻ counterions. Moreover, the PIL-BA copolymer-based electrolytes also exhibit ultrahigh tensile strain of 1762% and good self-healable capability. Such multifunctional polymer electrolytes can potentially be applied for safe and stable wearable electronics.

Polymer electrolytes offer great potential for emerging wearable electronics.     

The synergistic effect of the PEO–PVA–PESf composite polymer electrolyte for all-solid-state lithium-ion batteries

Blending with poly(vinyl alcohol) (PVA) and poly(oxyphenylene sulfone) (PESf) has been investigated to improve the properties of a polymer electrolyte based on a poly(ethylene oxide) (PEO) matrix. The composite electrolyte shows a high ionic conductivity of 0.83 × 10⁻³ S cm⁻¹ at 60 °C due to the significant inhibition of crystallization caused by the synergistic effects of PVA and PESf. The symmetrical cell Li/CPE/Li is continuously operated for at least 200 hours at a current density of 0.1 mA cm⁻² without the enhancement in the polarization potential. In addition, the all-solid-state LiFePO₄/CPE/Li cells exhibit small hysteresis potential (about 0.10 V), good cycle stability and excellent reversible capacity (126 mA h g⁻¹ after 100 cycles).

PVA and PESf have synergistic effects for CPE, resulting in a wider electrochemical window, higher ionic conductivity and better cyclic performance.     

Enhanced ionic conductivity in halloysite nanotube-poly(vinylidene fluoride) electrolytes for solid-state lithium-ion batteries

Solid composite electrolytes have gained increased attention, thanks to the improved safety, the prolonged service life, and the effective suppression on the lithium dendrites. However, a low ionic conductivity (<10⁻⁵ S cm⁻¹) of solid composite electrolytes at room temperature needs to be greatly enhanced. In this work, we employ natural halloysite nanotubes (HNTs) and poly(vinylidene fluoride) (PVDF) to fabricate composite polymer electrolytes (CPEs). CPE-5 (HNTs 5 wt%) shows an ionic conductivity of ∼3.5 × 10⁻⁴ S cm⁻¹, which is ∼10 times higher than the CPE-0 (without the addition of HNTs) at 30 °C. The greatly increased ionic conductivity is attributed to the negatively-charged outer surface and a high specific surface area of HNTs, which facilitates the migration of Li⁺ in PVDF. To make a further illustration, a solid-state lithium-ion battery with CPE-5 electrolyte, LiMn₂O₄ cathode and Li metal anode was fabricated. An initial discharge capacity of ∼71.9 mA h g⁻¹ at 30 °C in 1C is obtained, and after 250 cycles, the capacity of 73.5 mA h g⁻¹ is still maintained. This study suggests that a composite polymer electrolyte with high conductivity can be realized by introducing natural HNTs, and can be potentially applied in solid-state lithium-ion batteries.

The special structure of HNTs and the further formation of amorphous PVDF contribute to the enhancement of the Li⁺ transfer.     

A chemically bonded supercapacitor using a highly stretchable and adhesive gel polymer electrolyte based on an ionic liquid and epoxy-triblock diamine network

Despite significant advances in the development of flexible gel polymer electrolytes (GPEs), there are still problems to be addressed to apply them to flexible electric double layer capacitors (EDLCs), including interfacial interactions between the electrolyte and electrode under deformation. Previously reported EDLCs using GPEs have laminated structures with weak interfacial interactions between the electrode and electrolyte, leading to fragility upon elongation and low power density due to lower utilization of the surface area of the carbon material in the electrode. To overcome these problems, we present a new strategy for constructing an epoxy-based GPE that can provide strong adhesion between electrode and electrolyte. The GPE is synthesized by polymerization of epoxy and an ionic liquid. This GPE shows high flexibility up to 509% and excellent adhesive properties that enable strong chemical bonding between the electrode and electrolyte. Moreover, the GPE is stable at high voltage and high temperature with high ionic conductivity of ∼10⁻³ S cm⁻¹. EDLCs based on the developed GPE exhibit good compatibility between the electrode and electrolyte and work properly when deformed. The EDLCs also show a high specific capacitance of 99 F g⁻¹, energy density of 113 W h kg⁻¹, and power density of 4.5 kW g⁻¹. The excellent performance of the GPE gives it tremendous potential for use in next generation electronic devices such as wearable devices.

A chemically bonded supercapacitor using a stretchable and adhesive gel polymer electrolyte based on ionic liquid and epoxy for flexible devices.     

All-solid-state supercapacitors using a highly-conductive neutral gum electrolyte

Recently, the development of safe, stable, and long-life supercapacitors has attracted considerable interest driven by the fast-growth of flexible wearable devices. Herein, we report an MnO₂-based symmetric all-solid-state supercapacitor, using a neutral gum electrolyte that was prepared by embedding aqueous sodium sulfate solution in a biopolymer xanthan gum. Resulting from the high ion conductivity 1.12 S m⁻¹, good water retention, and high structure adaption of such gum electrolyte, the presently described supercapacitor showed high electrochemical performance with a specific capacitance of 347 F g⁻¹ at 1 A g⁻¹ and an energy density of 24 μW h cm⁻² The flexible supercapacitor possesses excellent reliability and achieves a retaining capacitance of 82% after 5000 cycles. In addition, the as-prepared supercapacitor demonstrated outstanding electrochemical stability at temperatures between −15 °C to 100 °C.

A highly-conductive neutral gum electrolyte was used for all-solid-state supercapacitors with outstanding electrochemical performance at temperatures between −15 °C to 100 °C.     

A PVA/LiCl/PEO interpenetrating composite electrolyte with a three-dimensional dual-network for all-solid-state flexible aluminum–air batteries

Aluminum–air batteries are promising electronic power sources because of their low cost and high energy density. However, traditional aluminum–air batteries are greatly restricted from being used in the field of flexible electronics due to the rigid battery structure, and the irreversible corrosion of the anode by the alkaline electrolyte, which greatly reduces the battery life. To address these issues, a three-dimensional dual-network interpenetrating structure PVA/LiCl/PEO composite gel polymer electrolyte (GPE) is proposed. The gel polymer electrolyte exhibits good flexibility and high ionic conductivity (σ = 6.51 × 10⁻³ S cm⁻¹) at room temperature. Meanwhile, benefiting from the high-performance GPE, an assembled aluminum–air coin cell shows a highest discharge voltage of 0.73 V and a peak power density (P_max) of 3.31 mW cm⁻². The Al specific capacity is as high as 735.2 mA h g⁻¹. A flexible aluminum–air battery assembled using the GPE also performed stably in flat, bent, and folded states. This paper provides a cost-effective and feasible way to fabricate a composite gel polymer electrolyte with high performance for use in flexible aluminum–air batteries, suitable for a variety of energy-related devices.

Problems relating to the leakage of alkaline liquid electrolyte, the evaporation of water, and flexibility in traditional aluminum–air batteries are solved in this study.     

Flexible quasi-solid-state zinc ion batteries enabled by highly conductive carrageenan bio-polymer electrolyte

Flexible Zn–MnO₂ batteries as wearable electronic power source have attracted much attention in recent years due to their low cost and high safety. To promote the practical application of flexible Zn–MnO₂ batteries, it is imperative to develop flexible, mechanically robust and high performance solid state electrolyte. Herein, we construct a rechargeable quasi-solid-state zinc ion battery using kappa-carrageenan bio-polymer electrolyte. The kappa-carrageenan electrolyte is eco-friendly, low cost, and highly conductive (3.32 × 10⁻² S cm⁻¹ at room temperature). The mechanical robustness of kappa-carrageenan electrolyte is further reinforced by using a rice paper as scaffold. Benefiting from high ionic conductivity of the bio-polymer electrolyte, our zinc ion battery delivers a significant high energy density and power density (400 W h kg⁻¹ and 7.9 kW kg⁻¹, respectively), high specific capacity (291.5 mA h g⁻¹ at 0.15 A g⁻¹), fast charging and discharging capability (120.0 mA h g⁻¹ at 6.0 A g⁻¹). The zinc ion battery with bio-polymer electrolyte also shows excellent cycling stability and high bending durability. This work brings new research opportunities in developing low-cost flexible solid-state zinc ion batteries using green natural polymer.

The zinc ion batteries with KCR electrolyte show a high specific capacity and fast charging and discharging capability.     

Graphite-type activated carbon from coconut shell: a natural source for eco-friendly non-volatile storage devices

Carbon from biomass as an active material for supercapacitor electrodes has attracted much interest due to its environmental soundness, abundance, and porous nature. In this context, activated carbon prepared from coconut shells via a simple activation process (water or steam as activation agents) was used as an active material in electrodes for eco-friendly supercapacitors. X-ray diffraction (XRD), Raman spectroscopy, conductivity, scanning electron microscopy (SEM), N₂ sorption and thermogravimetry coupled to mass spectrometry (TGA-MS) studies revealed that activated carbon produced by this approach exhibit a graphitic phase, a high surface area, and large pore volume. The energy storage properties of activated carbon electrodes correlate with the morphological and structural properties of the precursor material. In particular, electrodes made of activated carbon exhibiting the largest Brunauer–Emmett–Teller (BET) surface area, i.e. 1998 m² g⁻¹, showed specific capacitance of 132.3 F g⁻¹ in aqueous electrolyte (1.5 M H₂SO₄), using expanded graphite sheets as current collector substrates. Remarkably, this sample in a configuration with ionic liquid (1-methyl-1-propy-pyrrolizinium bis(fluorosulfonyl)mide) (MPPyFSI) as electrolyte and a polyethylene separator displayed an outstanding storage capability and energy-power handling capability of 219.4 F g⁻¹ with a specific energy of 92.1 W h kg⁻¹ and power density of 2046.9 W kg⁻¹ at 1 A g⁻¹ and maintains ultra-high values at 30 A g⁻¹ indicating the ability for a broad potential of energy and power related applications. To the best of our knowledge, these values are the highest ever reported for ionic liquid-based supercapacitors with activated carbon obtained from the biomass of coconut shells.

Simple ecofriendly activation process of carbon obtained from coconut shell-based waste was used for the fabrication of non-volatile high performance supercapacitors.     

Nitrogen and sulfur co-doped graphene aerogel for high performance supercapacitors

The development of high energy density and power density supercapacitors is very necessary in energy storage and application fields. A key factor of such devices is high-performance electrode materials. In this work, nitrogen and sulfur co-doped graphene aerogels (N/S-GA) were synthesized using graphene oxide as the precursor and 2-mercapto-1-methylimidazole as both the reducing agent and the N/S doping agent. The pore size distribution of the as-prepared N/S-GA was measured and the N/S-GA possesses a hierarchical porous structure. As an electrode material of supercapacitors, the N/S-GA could provide a suitable structure for charge accommodation and a short distance for ion transport. When 1-ethyl-3-methylimidazolium tetrafluoroborate ([Emim]BF₄) ionic liquid was used as the electrolyte, the specific capacitance of the N/S-GA electrode material reached 212 F g⁻¹ and 162 F g⁻¹ at the current densities of 1 A g⁻¹ and 10 A g⁻¹, respectively. And the energy density and average power density of the N/S-GA based supercapacitor could reach 117 W h kg⁻¹ and 1.0 kW kg⁻¹ at 1 A g⁻¹, 82 W h kg⁻¹ and 9.5 kW kg⁻¹ at 10 A g⁻¹, respectively. It is believed that the N/S-GA material can be used in high-performance supercapacitors.

A nitrogen and sulfur co-doped graphene aerogel (N/S-GA) was synthesised in one step, and N/S-GA based supercapacitors exhibited high performance.     

Novel poly(epichlorohydrin)-based matrix for monolithic ionogel electrolyte membrane with high lithium storage performances

Based on gelling matrices and ionic liquids (ILs), monolithic ionogel electrolyte membranes (MIEMs) have become a research focus. However, further application is limited by lack of functional matrices. Herein, we proposed the introduction of an ionized polymer, i.e., polyether polymer with side-chain ionic groups obtained via the reaction of quaternary ammonium with uncrystallizable poly (epichlorohydrin) (PECH), as the matrix into the gels to balance the mechanical properties and the ionic conductivity. In combination with lithium bis-(fluorosulfonyl) imide (LiFSI) and 1-ethyl-3-methylimidazolium bis-(fluorosulfonyl)-imide (EMImFSI) via a solvent casting technique, a flexible MIEM was successfully prepared. The as-obtained MIEM exhibited good thermal stability (up to about 250 °C) and a high ionic conductivity of 1.21 mS cm⁻¹ at 20 °C. Moreover, Li|LiFePO₄ coin cells using this MIEM delivered high capacity (150.0 mA h g⁻¹ at 0.2C) with good cycling stability, and an excellent C-rate response. This work discloses a novel and paramount route to exploit PECH-based MIEMs for Li storage, as well as energy storage systems beyond Li.

Novel monolithic ionogel electrolyte membrane based on uncrystallizable poly (epichlorohydrin) is prepared, with high thermal stability and high lithium storage.     

A highly conductive quasi-solid-state electrolyte based on helical silica nanofibers for lithium batteries

The replacement of flammable liquid electrolytes by inorganic solid ones is considered the most effective approach to enhancing the safety of Li batteries. However, solid electrolytes usually suffer from low ionic conductivity and poor rate capability. Here we report a unique quasi-solid-state electrolyte based on an inorganic matrix composed of helical tubular silica nanofibers (HSNFs) derived from the self-assembly of chiral low-molecular-weight amphiphiles. The HSNFs/ionic liquid quasi-solid-state electrolyte has high thermal stability (up to ∼370 °C) and good ionic conductivity (∼3.0 mS cm⁻¹ at room temperature). When tested as the electrolyte in a LiFePO₄/Li cell, excellent rate capability and good cycling stability are demonstrated, suggesting that it has potential be the electrolyte for a new generation of safer Li batteries.

A quasi-solid-state electrolyte of high-ionic conductivity is constructed from an inorganic matrix composed of helical silica nanofibers (HSNFs) derived from the self-assembly of chiral gelators.     

Preparation and characterization of nanofibrous cellulose as solid polymer electrolyte for lithium-ion battery applications

A novel bacterial cellulose (BC)-based nanofiber material has been utilized as an ionic template for the battery system solid polymer electrolyte (SPE). The effect of drying techniques such as oven and freeze-drying on the gel-like material indicate differences in both visual and porous structures. The morphological structure of BC after oven and freeze-drying observed by field-emission scanning electron microscopy indicates that a more compact porous structure is found in freeze-dried BC than oven-dried BC. After the BC-based nanofiber immersion process into lithium hexafluorophosphate solution (1.0 M), the porous structure becomes a host for Li-ions, demonstrated by significant interactions between Li-ions from the salt and the C O groups of freeze-dried BC as shown in the infrared spectra. X-ray diffraction analysis of freeze-dried BC after immersion in electrolyte solution shows a lower degree of crystallinity, thus allowing an increase in Li-ion movement. As a result, freeze-dried BC has a better ionic conductivity of 2.71 × 10⁻² S cm⁻¹ than oven-dried BC, 6.00 × 10⁻³ S cm⁻¹. Freeze-dried BC as SPE also shows a larger electrochemical stability window around 3.5 V, reversible oxidation/reduction peaks at 3.29/3.64 V, and an initial capacity of 18 mAHr g⁻¹ at 0.2C. The high tensile strength of the freeze-dried BC membrane of 334 MPa with thermal stability up to 250 °C indicates the potential usage of freeze-dried BC as flexible SPE to dampen ionic leakage transfer.

Nanofibrous cellulose as solid polymer electrolyte for lithium-ion battery applications.     

Dual-doped hierarchical porous carbon derived from biomass for advanced supercapacitors and lithium ion batteries

Nowadays, designing heteroatom-doped porous carbons from inexpensive biomass raw materials is a very attractive topic. Herein, we propose a simple approach to prepare heteroatom-doped porous carbons by using nettle leaves as the precursor and KOH as the activating agent. The nettle leaf derived porous carbons possess high specific surface area (up to 1951 m² g⁻¹), large total pore volume (up to 1.374 cm³ g⁻¹), and high content of nitrogen and oxygen heteroatom doping (up to 17.85 at% combined). The obtained carbon as an electrode for symmetric supercapacitors with an ionic liquid electrolyte can offer a superior specific capacitance of 163 F g⁻¹ at 0.5 A g⁻¹ with a capacitance retention ratio as high as 67.5% at 100 A g⁻¹, and a low capacitance loss of 8% after 10 000 cycles. Besides, the as-built supercapacitor demonstrates a high specific energy of 50 W h kg⁻¹ at a specific power of 372 W kg⁻¹, and maintains 21 W h kg⁻¹ at the high power of 40 kW kg⁻¹. Moreover, the resultant carbon as a Li-ion battery anode delivers a high reversible capacity of 1262 mA h g⁻¹ at 0.1 A g⁻¹ and 730 mA h g⁻¹ at 0.5 A g⁻¹, and maintains a high capacity of 439 mA h g⁻¹ after 500 cycles at 1 A g⁻¹. These results demonstrate that the nettle leaf derived porous carbons offer great potential as electrodes for advanced supercapacitors and lithium ion batteries.

Nettle leaf derived nitrogen and oxygen dual-doped porous carbons exhibit great potential as anodes for high performance supercapacitors and lithium ion batteries.     

Facile preparation of 3D porous agar-based heteroatom-doped carbon aerogels for high-energy density supercapacitors

The fabrication of heteroatom-doped porous carbon materials with high electrical conductivity and large specific surface area via an environmentally friendly route is critical and challenging. Herein, nitrogen and oxygen co-doped agar porous carbon (APC) was developed for supercapacitors via a one-step carbonization method with agar as the raw material and ammonia as the activator and nitrogen source. APC outperformed pectin porous carbon, tamarind porous carbon, and the previously reported carbon-based supercapacitors with a high capacitance retention of 72% even from 0.5 A g⁻¹ to 20 A g⁻¹ and excellent cycling stability in 6 M KOH solution (retained after 10 000 cycles) with a rate of over 98.5%. Furthermore, the APC electrode-based symmetric device exhibited an impressive energy density of 20.4 W h kg⁻¹ and an ultra-high power density of 449 W kg⁻¹ in 1 M Na₂SO₄ electrolyte together with excellent cycling stability (103.2% primary capacitance retentivity after 10 000 cycles). This study offers a novel method for the synthesis of nitrogen heteroatom-doped hierarchical porous carbon materials for performance-enhanced energy storage devices.

N and O co-doped agar porous carbon (APC) as electrode materials exhibit excellent performance. A respectable energy density of 20.4 W h kg⁻¹ and an ultra-high power density of 449 W kg⁻¹, as well as excellent cycle stability in 1 M Na₂SO₄ electrolyte.     

Enhanced storage behavior of quasi-solid-state aluminum–selenium battery

The current aluminum batteries with selenium positive electrodes have been suffering from dramatic capacity loss owing to the dissolution of Se₂Cl₂ products on the Se positive electrodes in the ionic liquid electrolyte. For addressing this critical issue and achieving better electrochemical performances of rechargeable aluminum–selenium batteries, here a gel-polymer electrolyte which has a stable and strongly integrated electrode/electrolyte interface was adopted. Quite intriguingly, such a gel-polymer electrolyte enables the solid-state aluminum–selenium battery to present a lower self-discharge and obvious discharging platforms. Meanwhile, the discharge capacity of the aluminum–selenium battery with a gel-polymer electrolyte is initially 386 mA h g⁻¹ (267 mA h g⁻¹ in ionic liquid electrolyte), which attenuates to 79 mA h g⁻¹ (32 mA h g⁻¹ in ionic liquid electrolyte) after 100 cycles at a current density of 200 mA g⁻¹. The results suggest that the employment of a gel-polymer electrolyte can provide an effective route to improve the performance of aluminum–selenium batteries in the first few cycles.

A quasi-solid-state aluminum–selenium battery has been established using gel-polymer electrolyte between the Se positive electrode and Al negative electrode which increasing the utilization of the active materials.     

Highly conductive locust bean gum bio-electrolyte for superior long-life quasi-solid-state zinc-ion batteries

Rechargeable aqueous zinc-ion batteries (ZIBs) are promising wearable electronic power sources. However, solid-state electrolytes with high ionic conductivities and long-term stabilities are still challenging to fabricate for high-performance ZIBs. Herein, locust bean gum (LBG) was used as a natural bio-polymer to prepare a free-standing quasi-solid-state ZnSO₄/MnSO₄ electrolyte. The as-obtained LBG electrolyte showed high ionic conductivity reaching 33.57 mS cm⁻¹ at room temperature. This value is so far the highest among the reported quasi-solid-state electrolytes. Besides, the as-obtained LBG electrolyte displayed excellent long-term stability toward a Zn anode. The application of the optimized LBG electrolyte in Zn–MnO₂ batteries achieved a high specific capacity reaching up to 339.4 mA h g⁻¹ at 0.15 A g⁻¹, a superior rate performance of 143.3 mA h g⁻¹ at 6 A g⁻¹, an excellent capacity retention of 100% over 3300 cycles and 93% over 4000 cycles combined with a wide working temperature range (0–40 °C) and good mechanical flexibility (capacity retention of 80.74% after 1000 bending cycles at a bending angle of 90°). In sum, the proposed ZIBs-based LBG electrolyte with high electrochemical performance looks promising for the future development of bio-compatible and environmentally friendly solid-state energy storage devices.

Locust bean gum was utilized to prepare a free-standing quasi-solid-state ZnSO₄/MnSO₄ electrolyte. Zinc-ion batteries with locust bean gum electrolyte achieved high energy density and superior lifetime.     

Sustainable rose multiflora derived nitrogen/oxygen-enriched micro-/mesoporous carbon as a low-cost competitive electrode towards high-performance electrochemical supercapacitors

Cost-efficient carbonaceous materials have been utilized extensively for advanced electrochemical supercapacitors. However, modest gravimetric/volumetric capacitances are the insuperable bottleneck in their practical applications. Herein, we develop a simple yet scalable method to fabricate low-cost micro-/mesoporous N/O-enriched carbon (NOC-K) by using natural rose multiflora as a precursor with KOH activation. The biomass-derived NOC-K is endowed with a large surface area of ∼1646.7 m² g⁻¹, micro-/mesoporosity with ∼61.3% microporosity, high surface wettability, and a high content of N (∼1.2 at%)/O (∼26.7 at%) species. When evaluated as an electroactive material for supercapacitors, the NOC-K electrode (5 mg cm⁻²) yields large gravimetric/volumetric specific capacitances of ∼340.0 F g⁻¹ (∼238.0 F cm⁻³) at 0.5 A g⁻¹, and even ∼200.0 F g⁻¹ (∼140.0 F cm⁻³) at 5.0 A g⁻¹, a low capacitance decay of ∼4.2% after 8200 consecutive cycles, and a striking specific energy of ∼8.3 W h kg⁻¹ in aqueous KOH electrolyte, benefiting from its intrinsic structural and compositional superiorities. Moreover, a remarkable specific energy of ∼52.6 W h kg⁻¹ and ∼96.6% capacitance retention over 6500 cycles for the NOC-K based symmetric cell are obtained with the organic electrolyte. More promisingly, the competitive NOC-K demonstrates enormous potential towards advanced supercapacitors both with aqueous and organic electrolytes as a sustainable electrode candidate.

Hierarchical micro-/mesoporous N/O-enriched carbon was scalably fabricated, and exhibited high gravimetric/volumetric capacitances, a large energy density and long-term cycling stability for supercapacitors with aqueous and organic electrolytes.