A Fenton-like method using ZnO doped MIL-88A for degradation of methylene blue dyes

MIL-88A with different sizes was prepared by hydrothermal method by changing the content of ZnO. The samples were characterized by SEM, TEM, XRD, XPS and FT-IR. The synthesized material was used for the removal of methylene blue dye in a Fenton-like reaction, and the optimal reaction conditions were studied through single factor experiments. The experimental results show that when the molar ratio of the amount of ZnO introduced to FeCl₃·6H₂O is 1 : 1, the obtained materials have better catalytic performance than others. Under the optimal conditions, MIL-88A(Fe₁Zn₁) has the best catalytic performance for 300 mg L⁻¹ methylene blue. The removal rate can reach 96.15% within 40 minutes.

MIL-88A with different sizes were prepared by changing the content of ZnO. The prepared nanocomposites were used as catalysts in Fenton-like reaction of removing MB. The effects of the main reaction parameters on the reaction activity were studied.     

Synthesis of N-doped ZnO nanoparticles with cabbage morphology as a catalyst for the efficient photocatalytic degradation of methylene blue under UV and visible light

In this study, the synthesis of nitrogen-doped zinc oxide nanoparticles with a cabbage like morphology (N-ZnONCBs) by a hydrothermal method using zinc acetate dihydrate as a precursor and hydrazine monohydrate as a nitrogen source is reported. N-ZnONCB were characterized using UV-visible Spectroscopy (UV-Vis), Fluorescence Spectroscopy, Fourier Transmittance Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), Raman Spectroscopy, Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Electron Dispersive Spectroscopy (EDS) and EDX elemental mapping. N-ZnONCBs were tested for their photocatalytic capabilities in the degradation of methylene blue (MB) under UV-light and visible light irradiation for about 0 to 80 minutes and 0 to 50 min respectively. The N-ZnONCB catalyst demonstrated improved photodegradation efficiency (98.6% and 96.2%) and kinetic degradation rates of MB (k = −0.0579 min⁻¹ and k = −0.0585 min⁻¹) under UV light and visible light irradiation at different time intervals. The photodegradation study was also evaluated with different dosages of N-ZnONCB catalyst, different initial concentrations of MB and variation in the pH (3, 5, 9 and 11) of the solution of MB under UV light and visible light irradiation. The photocatalytic degradation intermediate products were obtained by liquid chromatography mass spectra (LC-MS) and also complete mineralization was determined by using Total Organic Carbon (TOC) studies. This photocatalyst was also tested with 2,4-dichlorophenol (2,4-DCP) under visible light irradiation at different time intervals. Fluorescence and quenching studies were performed for the binding interaction between the N-ZnONCB catalyst and MB dye. A Zetasizer was used to find the charge and average size of the N-ZnONCB catalyst and also the charge of the N-ZnONCB catalyst before and after MB dye solution adsorption. The N-ZnONCB catalyst was also tested for its photostability and reusability with a percentage degradation rate of MB (93.2%) after 4 cycle experiments. These results have clearly demonstrated that the N-ZnONCB catalyst can be applied for the photocatalytic degradation of MB from wastewater samples.

In this study, the synthesis of nitrogen-doped zinc oxide nanoparticles with a cabbage like morphology (N-ZnONCBs) by a hydrothermal method using zinc acetate dihydrate as a precursor and hydrazine monohydrate as a nitrogen source is reported.     

Unveiling the enhanced photoelectrochemical and photocatalytic properties of reduced graphene oxide for photodegradation of methylene blue dye

Graphene oxide (GO) and reduced graphene oxide (rGO) can act as metal-free photocatalysts to remove aqueous dye pollutants under light illumination. However, there is some disparity in past reports on the origin of the photoactivity of GO and rGO for photodegradation of dye pollutants. In this work, the photoactivity of GO and rGO for methylene blue (MB) dye photodegradation were investigated with photoelectrochemical (PEC) measurements. The optimized rGO sample (G-2) exhibited a stable photocatalytic rate, which was 2.5 times higher than that of pure GO. PEC measurements revealed that the photocatalytic activity of G-2 was elevated due to higher photocurrent density, higher charge carrier density, and better charge separation. The changes in band gap and band positions of rGO were determined through optical characterization and Mott–Schottky (M–S) plots. Finally, the photocatalytic degradation mechanism of GO and rGO on MB dye was determined.

Photoactivity of graphene oxide (GO) was enhanced after reduction, this is due to improved photoelectrochemical properties.     

ZnS coating for enhanced environmental stability and improved properties of ZnO thin films

Low environmental stability of ZnO nanostructures in hydrophilic systems is a crucial factor limiting their practical applications. ZnO nanomaterials need surface passivation with different water-insoluble compounds. This study describes a one-step passivation process of polycrystalline ZnO films with ZnS as a facile method of ZnO surface coating. A simple sulfidation reaction was carried out in gas-phase H₂S and it resulted in formation of a ZnS thin layer on the ZnO surface. The ZnS layer not only inhibited the ZnO dissolving process in water but additionally improved its mechanical and electrical properties. After the passivation process, ZnO/ZnS films remained stable in water for over seven days. The electrical conductivity of the ZnO films increased about 500-fold as a result of surface defect passivation and the removal of oxygen molecules which can trap free carriers. The nanohardness and Young''s modulus of the samples increased about 64% and 14%, respectively after the ZnS coating formation. Nanowear tests performed using nanoindentation methods revealed reduced values of surface displacements for the ZnO/ZnS system. Moreover, both ZnO and ZnO/ZnS films showed antimicrobial properties against Escherichia coli.

ZnS coating improves mechanical, electrical, antibacterial properties and environmental stability of ZnO nanofilms.     

2D–3D graphene-coated diatomite as a support toward growing ZnO for advanced photocatalytic degradation of methylene blue

In this work, a diatomite@graphene@ZnO (ZGD) photocatalyst was synthesized by chemical vapor deposition and hydrothermal methods and used for the photocatalytic degradation of methylene blue. The characterization of the prepared nanocomposite was performed by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction (XRD), and N₂ adsorption–desorption techniques. Ultraviolet-visible diffuse reflectance spectroscopy (DRS) showed that the prepared ZGD photocatalyst enhanced the absorption of visible light and induced a red-shift. Photoluminescence spectroscopy (PL) revealed that the recombination of electron and hole pairs can be effectively suppressed. Besides, the synergistic effect of diatomite and graphene avoids the agglomeration of ZnO, increases the number of surface adsorption sites, and limits the electron transport, consequently improving the photocatalytic activity of ZnO. When ZGD-3 was UV-irradiated (λ = 663 nm) for 90 minutes, the degradation effectiveness of methylene blue (MB) was 100%. After the fifth repetition, the photocatalytic degradation efficiency was always greater than 95%. Simply put, the ZGD nanocatalyst can be used as an efficient photocatalyst for dye wastewater treatment.

In this work, a diatomite@graphene@ZnO (ZGD) photocatalyst was synthesized by chemical vapor deposition and hydrothermal methods and used for the photocatalytic degradation of methylene blue.     

Transparent and conducting boron doped ZnO thin films grown by aerosol assisted chemical vapor deposition

ZnO based transparent conducting oxides are important as they provide an alternative to the more expensive Sn : In₂O₃ that currently dominates the industry. Here, we investigate B-doped ZnO thin films grown via aerosol assisted chemical vapour deposition. B : ZnO films were produced from zinc acetate and triethylborane using either tetrahydrofuran or methanol (MeOH) as the solvent. The lowest resistivity of 5.1 × 10⁻³ Ω cm along with a visible light transmittance of ∼75–80% was achieved when using MeOH as the solvent. XRD analysis only detected the wurtzite phase of ZnO suggesting successful solid solution formation with B³⁺ substituting Zn²⁺ sites in the lattice. Refinement of the XRD patterns showed minimal distortion to the ZnO unit cell upon doping when MeOH was the solvent due to the immiscibility of the [BEt₃] solution (1.0 M solution in hexane) in methanol that limited the amount of B going into the films, thus preventing excessive doping.

Boron doped zinc oxide thin films via aerosol assisted chemical vapor deposition with resisitivities as low as 5.1 × 10⁻³ Ω cm.     

Tubular g-C3N4/carbon framework for high-efficiency photocatalytic degradation of methylene blue

The preparation of high-efficiency, pollution-free photocatalysts for water treatment has always been one of the research hotspots. In this paper, a carbon framework formed from waste grapefruit peel is used as the carrier. A simple one-step chemical vapor deposition (CVD) method allows tubular g-C₃N₄ to grow on the carbon framework. Tubular g-C₃N₄ increases the specific surface area of bulk g-C₃N₄ and enhances the absorption of visible light. At the same time, the carbon framework can effectively promote the separation and transfer of charges. The dual effects of static adsorption and photodegradation enable the g-C₃N₄/carbon (CNC) framework to quickly remove about 98% of methylene blue within 180 min. The recyclability indicates that the tubular g-C₃N₄ can stably exist on the carbon framework during the photodegradation process. In the dynamic photocatalytic test driven by gravity, roughly 77.65% of the methylene blue was degraded by the CNC framework. Our work provides an attractive strategy for constructing a composite carbon framework photocatalyst based on the tubular g-C₃N₄ structure and improving the photocatalytic performance.

Tubular g-C₃N₄ grown on a carbon framework increased the surface area of bulk g-C₃N₄, enhanced the absorption of visible light and promoted the photocatalytic performance.     

Structural,optical and photocatalytic properties of erbium (Er3+) and yttrium (Y3+) doped TiO2 thin films with remarkable self-cleaning super-hydrophilic properties

The self-cleaning and super hydrophilic properties of pristine TiO₂ and of TiO₂ doped with Er³⁺ or Y³⁺ transparent thin films deposited onto glass substrates were investigated. The thin films prepared by multiple dipping and drying cycles of the glass substrate into the pristine TiO₂ sol and Er³⁺ or Y³⁺-doped TiO₂ sol were characterized by X-ray diffraction, UV-vis spectrophotometry, and atomic force microscopy (AFM). The self-cleaning photocatalytic activity of the thin films towards the removal of oleic acid deposited on the surface under UVA irradiation was evaluated. A remarkable enhancement was observed in the hydrophilic nature of the TiO₂ thin films under irradiation. The optical properties and wettability of TiO₂ were not affected by Er³⁺ or Y³⁺ doping. However, the photocatalytic degradation of oleic acid under UVA irradiation improved up to 1.83 or 1.95 fold as the Er³⁺ or Y³⁺ content increased, respectively, due to the enhanced separation of the photogenerated carriers and reduced crystallite size. AFM analysis showed that the surface roughness increased by increasing the Er³⁺ or Y³⁺ content due to the formation of large aggregates. This in turn contributes to the increase of the active surface area enhancing the photodegradation process. This study demonstrates that TiO₂ doped with low amounts of Er³⁺ or Y³⁺ down to 0.5 mol% can produce transparent, super-hydrophilic, thin film surfaces with remarkable self-cleaning properties.

The self-cleaning and super hydrophilic properties of pristine TiO₂ and of TiO₂ doped with Er³⁺ or Y³⁺ transparent thin films deposited onto glass substrates were investigated.     

Synergistic effect of modified pore and heterojunction of MOF-derived α-Fe2O3/ZnO for superior photocatalytic degradation of methylene blue

Mesoporous heterojunction MOF-derived α-Fe₂O₃/ZnO composites were prepared by a simple calcination of α-Fe₂O₃/ZIF-8 as a sacrificial template. The optical properties confirm that coupling of both the modified pore and the n–n heterojunction effectively reduces the possibility of photoinduced charge carrier recombination under irradiation. The mesoporous Fe(25)ZnO with 25% loading of α-Fe₂O₃ exhibited the best performance in MB degradation, up to ∼100% after 150 minutes irradiation, higher than that of pristine ZnO and α-Fe₂O₃. Furthermore, after three cycles reusability, mesoporous Fe(25)ZnO still showed an excellent stability performance of up to 95.42% for degradation of MB. The proposed photocatalytic mechanism of mesoporous Fe(25)ZnO for the degradation of MB corresponds to the n–n heterojunction system. This study provides a valuable reference for preparing mesoporous MOF-derived metal oxides with an n–n heterojunction system to enhance MB photodegradation.

Mesoporous heterojunction MOF-derived α-Fe₂O₃/ZnO composites were prepared by a simple calcination of α-Fe₂O₃/ZIF-8 as a sacrificial template.     

Ag nanoparticles on ZnO nanoplates as a hybrid SERS-active substrate for trace detection of methylene blue

Decorating two-dimensional (2D) nanomaterials with nanoparticles provides an effective method to integrate their physicochemical properties. In this work, we present the hydrothermal growth process of 2D zinc oxide nanoplates (ZnO NPls), then silver nanoparticles (AgNPs) were uniformly distributed on the surface of ZnO NPls through the reduction procedure of silver nitrate with sodium borohydride to create a metal–semiconductor hybrid. The amount of AgNPs on the ZnO NPls'' surface was carefully controlled by varying the volume of silver nitrate (AgNO₃) solution. Moreover, the effect of AgNPs on the surface-enhanced Raman scattering (SERS) property of ZnO NPls was thoroughly investigated by using methylene blue (MB) as the target molecule. After calculation, the maximum enhancement factor value for 10⁻⁴ M of MB reached 6.2 × 10⁶ for the peak at 1436 cm⁻¹ and the limit of detection was 10⁻⁹ M. In addition, the hybrid nanosystem could distinguish MB with good reproducibility over a wide range of concentrations, from 10⁻⁹ to 10⁻⁴ M. The SERS mechanism is well elucidated based on the chemical and electromagnetic mechanisms related to the synergism of ZnO and Ag in the enhancement of Raman signal. Abundant hot spots located at the gap between adjacent separate Ag nanoparticles and ZnO nanoplates which formed a strong local electromagnetic field and electron transfer between ZnO and Ag are considered to be the key factors affecting the SERS performance of our prepared ZnO/Ag substrates. In this research, we found high sensitivity of ZnO nanoplates/Ag nanoparticles in detecting MB molecules. This unique metal–semiconductor hybrid nanosystem is advantageous for the formation of Raman signals and is thus suitable for the trace detection of methylene blue.

Decorating two-dimensional (2D) nanomaterials with nanoparticles provides an effective method to integrate their physicochemical properties.     

Surface modification of TiO2/ZnO nanoparticles by organic acids with enhanced methylene blue and rhodamine B dye adsorption properties

The United Nations Organization (UNO) has revealed that approximately 2.1 billion people do not have access to treated water. Methylene blue (MB) and rhodamine B are produced as water pollutants in textile, plastic, and dye industries. In this study, oxalic acid or lactic acid surface-modification were applied to TiO₂/ZnO nanoparticles aiming to improve antibacterial and adsorption properties. The mixtures containing the corresponding acid and nanoparticles in 0.25 : 1/0.5 : 1 ratios of ZnO and TiO₂ correspondingly were subjected to ultrasonic treatment with a catenoidal ultrasonic probe coupled to a homemade ultrasonic generator with an output power of 750 W, wave amplitude of 50% and variable frequency in the range of 15–50 kHz. To verify the influence of the ultrasonic treatment, different treatment times of 30, 45, 60, and 90 min were applied. Unmodified and modified TiO₂/ZnO nanoparticles were characterized by FTIR, TGA, XRD, SEM, and XPS. From the results, obtained from the physicochemical characterization, in the ZTO90 and ZTL90 samples a greater modification was shown. The SEM images showed that a coating was present on the surface of the ceramic particles of the ZTL90 sample. The O 1s deconvolution in the XPS spectra indicates a greater presence of C O bonds in the ZTL90 sample. In parallel, the sample ZTL90 presented 85 and 89% adsorption efficiency for MB and rhodamine B dyes in a time of 12 min, and important antibacterial activity against E. coli and S. epidermis could be evidenced.

The possible chemical modification of TiO₂/ZnO with lactic acid and oxalic acid.     

Porous zinc-discs as nanocatalysts for methylene blue dye treatment in water: sensing,adsorption and photocatalytic degradation

This paper reports a zinc derived (ZD) porous nanosystem that has been used for selective sensing, adsorption, and photocatalytic degradation of the known hazardous dye, Methylene blue (MB). Using zinc nitrate and 2-aminoterphthalic acid as precursors, the synthesis has been optimized to yield disc-shaped nanoparticles. This luminescent ZD nanoparticles exhibit absorption and emission wavelengths of 328 nm and 427 nm, respectively at an excitation wavelength of 330 nm. In the presence of MB, there is a sharp decrease in the photoluminescence emission intensity of ZD nanoparticles. The detection limit, quenching constant and the binding constant of ZD nanoparticles with MB are found to be 0.31 × 10⁻⁹ M, 3.30 × 10⁶ M⁻¹ and 2.27 × 10⁶ M⁻¹ respectively. The impact of contact time, initial MB concentration, and pH on the adsorption process were investigated. The equilibrium data fit well with the Langmuir adsorption isotherm model (R² = 0.989) and superlatively fitted to the pseudo-second-order rate model (rate constant: 0.00011 g mg⁻¹ min⁻¹; adsorption capacity (q_{e, calc.}): 386.1 mg g⁻¹; R²: 0.990). Further, the MB dye degradation was performed under ultra-violet irradiation and ∼95% MB degradation was achieved within 70 min. The experimental data are well fitted to the pseudo-first order kinetics (R²: 0.99; rate constant: 0.015 min⁻¹). These disc shaped ZD nanoparticles can not only facilitate the detection, but also the adsorption and photocatalytic degradation of MB, which can be further processed for environmental remediation applications.

Herein, we demonstrate multiutility zinc-based porous disc particles as a nano-catalyst, for highly sensitive detection, adsorption, and photocatalytic degradation of methylene blue up to ∼95% MB within 70 min of ultra-violet irradiation treatment.     

Effect of localized UV irradiation on the crystallinity and electrical properties of dip-coated polythiophene thin films

Ensuring high performance in polymer devices requires conjugated polymers with interchain π–π stacking interactions via van der Waals forces, which can induce structural changes in the polymer thin film. Here, we present a systematic study of using simple localized UV irradiation to overcome the low crystallinity and poor charge carrier transport in dip-coated poly(3-hexylthiophene) (P3HT) thin films, which are consequences of the limited selection of solvents compatible with the dip-coating process. UV irradiation for only a few minutes effectively promoted P3HT chain self-assembly and association in the solution state. Brief UV irradiation of a P3HT solution led to well-ordered molecular structures in the resultant P3HT films dip-coated using a low boiling point solvent with rapid solvent evaporation. In addition, the position at which UV light was irradiated on the dip-coating solutions was varied, and the effects of the irradiation position and time on the crystallinity and electrical properties of the resultant P3HT thin films were investigated.

When the top part of the solution was irradiated with UV light, the dip-coated P3HT film showed enhanced crystallinity and electrical properties.     

Unveiling the charge transfer behavior within ZSM-5 and carbon nitride composites for enhanced photocatalytic degradation of methylene blue

ZSM-5/graphitic carbon nitride (g-C₃N₄) composites were successfully prepared using a simple solvothermal method. By varying the amount of ZSM-5 and g-C₃N₄ in the composites, the charge carrier (electrons and holes) transfer within the materials, which contributes to the enhanced photocatalytic performance, was unraveled. The X-ray diffraction (XRD), Fourier-transform infrared (FTIR), and scanning electron microscopy (SEM) analysis revealed that more ZSM-5 component leads to a stronger interaction with g-C₃N₄. The photocatalytic performance test toward methylene blue (MB) degradation shows that more ZSM-5 in the composites is beneficial in enhancing photocatalytic activity. Meanwhile, the impedance electron spectroscopy (EIS) and photoluminescence (PL) analysis revealed that ZSM-5 facilitates the charge carrier transfer of photogenerated electrons and holes from g-C₃N₄ to the catalyst surface due to its lower charge transfer resistance. During the charge carrier migration, the interface between g-C₃N₄ and ZSM-5 particles may induce higher resistance for the charge carrier transfer, however after passing through the interface from g-C₃N₄ to ZSM-5 particles, the charge carrier can be efficiently transferred to the surface, hence suppressing the charge carrier recombination.

In the ZSM-5/g-C₃N₄ composite, ZSM-5 facilitates the charge transfer from g-C₃N₄ to the surface due to its lower charge transfer resistance.     

Effective photocatalytic degradation and physical adsorption of methylene blue using cellulose/GO/TiO2 hydrogels

Environmentally friendly cellulose/GO/TiO₂ hydrogel photocatalyst has been successfully fabricated via a green, simple, and one-step method and evaluated as the photocatalyst and adsorbent for the removal of methylene blue (MB). The XRD and FTIR analysis suggested the strong interaction among cellulose, GO and TiO₂, resulting from the formation of hydrogen bonds. Due to the unique porous structure of cellulose hydrogel and introduction of GO, the cellulose/GO/TiO₂ hydrogel showed superior (degradation ratio ∼ 93%) and reproducible (no significant change during the ten consecutive cycles) performance in the removal of MB under UV light. Consequently, the prepared cellulose/GO/TiO₂ hydrogel can be applied as an eco-friendly, high-performance, reproducible, and stable photocatalyst and adsorbent for the removal of MB. This green hydrogel is a promising candidate for dye wastewater treatment. Moreover, this work is expected to extend the scope of bio-templated synthesis of other nanomaterials for various applications.

New functional cellulose/GO/TiO₂ hydrogels are prepared via a simple method, showing superior and reproducible performance in the removal of MB.     

Identification of the local electrical properties of crystalline and amorphous domains in electrochemically doped conjugated polymer thin films

Doped polymer thin films have several applications in electronic, optoelectronic and thermoelectric devices. Often the electrical properties of doped conjugated polymer thin films are affected by their local physical and mechanical characteristics. However, investigations into the effects of doping on local domain properties have not been carried out. Here, we study the physical, mechanical and optical properties of electrochemically doped P3HT thin films at the nanoscale and establish a relation between doping level and the physical properties of P3HT thin films. Bulk crystallinity of both pristine and doped P3HT thin films, characterized using grazing incidence X-ray diffraction, shows a clear loss in crystallinity upon doping. Nanoscale crystalline and amorphous domains in the films are visualized by multimode atomic force microscopy (AFM). It is apparent that the crystalline domains are most affected by doping and have a higher degree of doping compared to amorphous domains. This results in crystalline domains exhibiting superior electrical conductivity at a local level. These results are further supported by Raman mapping and elemental analysis of doped films. A direct relation is established between the physical, mechanical and electrical properties of doped P3HT thin films based on the AFM data. The findings demonstrate that higher dopant concentrations are found in crystalline domains compared to amorphous domains, which has not been shown before to the best of our knowledge. This study can be used to optimize the electronic properties of doped P3HT thin films for use in electronic and optoelectronic device applications.

The effects of electrochemical doping on the local domain properties of conjugated polymer films are investigated. Nanoscale crystalline domains are most affected by doping and have a higher degree of doping compared to amorphous domains.     

Visible light driven photocatalytic degradation of aqueous acetamiprid over nitrogen and graphene oxide doped ZnO composites

The present investigation focused on the photocatalytic degradation of acetamiprid in aqueous solutions under visible light over bare ZnO as well as N- and N-GO-doped photocatalysts. The synthesised materials were characterised using SEM, TEM, XRD, nitrogen sorption, photoluminescence, UV-Vis, FTIR and electrochemical impedance spectroscopy techniques. The obtained results pointed out the high photocatalytic performances of the N-GO-ZnO allowing complete degradation of the acetamiprid after 5 hours of reaction at ambient temperature. Under otherwise the same operating conditions, 12, 38 and 68% conversion were reached in the absence of any photocatalyst, over the bare ZnO and N-doped ZnO materials, respectively.

The present investigation focused on the photocatalytic degradation of acetamiprid in aqueous solutions under visible light over bare ZnO as well as N- and N-GO-doped ZnO photocatalysts.     

Preparation and properties of CA/ATP-g-CDs gel fibers for simultaneous detection and adsorption of methylene blue

To detect and adsorb methylene blue (MB) from wastewater simultaneously, a solid fluorescent and absorbent material was designed by immobilizing attapulgite (ATP) on calcium alginate (CA) and reacting with carbon dots (CDs) which were modified by the activation of γ-(2,3-epoxypropoxy) propyltrimethoxysilane (KH-560), then the CA/ATP-g-CDs gel fibers were prepared. The problem of CDs easily falling out of materials was solved. The structures of the gel fibers were characterized by field emission scanning electron microscopy (FE-SEM), specific surface area (BET) and X-ray photoelectron spectroscopy (XPS). The thermal properties were analyzed by thermogravimetry (TG). The adsorption capacity was measured and the effect of initial pH was investigated. The results showed that ATP was successfully reacted with CA and the adsorption capacity was enhanced with the increase of the pH value. CA/ATP-g-CDs gel fibers were favorable materials to detect and adsorb MB simultaneously, and MB could be adsorbed by gel fibers and also the fluorescence of CA/ATP-g-CDs was weakened. At low concentrations of MB (1 μg L⁻¹), the removal efficiency could even be as high as 100%.

To detect and adsorb methylene blue (MB) from wastewater simultaneously, a solid fluorescent and absorbent material was designed by immobilizing attapulgite (ATP) on calcium alginate (CA) and reacting with carbon dots (CDs), then the CA/ATP-g-CDs gel fibers were prepared.     

Investigation of the effect of S/In molar ratio on physical properties of sprayed In2S3 thin films

Indium sulfide (In₂S₃) thin films have been synthesized on glass substrates using the spray technique (CSP). The S : In molar ratio was varied from 1 to 4 in the starting solution. The Raman analysis confirms the formation of the β-In₂S₃ material and the absence of a secondary phase. The EDS analysis reveals that our layers are pure. The thin film surface is free of cracks, as observed in AFM images. Optical transmission achieved 80% in the visible and near infrared region. The refractive index (n) is affected by the changes in the S/In molar ratio. The optical parameters, single oscillator energy (E₀), dispersion energy (E_d) and high frequency dielectric constant (ε_∞), are calculated via the Wemple–DiDomenico model. In addition, the photoconductivity kinetics in In₂S₃ films for S/In = 2 were investigated and analyzed. The I–V characteristics and the photoresponse were also studied.

Indium sulfide (In₂S₃) thin films have been synthesized on glass substrates using the spray technique (CSP).     

Aquatic photodegradation of clofibric acid under simulated sunlight irradiation: kinetics and mechanism analysis

Clofibric acid is one of the most frequently detected pharmaceuticals in various aquatic environments. Photodegradation of clofibric acid in water under simulated sunlight was investigated. The effects of different initial concentrations, pH conditions and dissolved oxygen were examined. Photodegradation of clofibric acid followed a pseudo-first-order kinetics model, and the rate decreased gradually with the increasing initial concentration of clofibric acid. Dissolved oxygen inhibited the photodegradation of clofibric acid. As a result of varying reaction species of clofibric acid, the initial pH conditions greatly influenced its photodegradation. Quenching experiments showed that the self-sensitization process via ·OH and ¹O₂ occured during photodegradation of clofibric acid, and the bimolecular reaction rate constants of clofibric acid with ·OH and ¹O₂ were determined via the competition kinetics method to be 3.93(±0.20) × 10⁸ and 2.38(±0.12) × 10⁶ L mol⁻¹ s⁻¹, respectively. In addition, the transformation products of clofibric acid were identified by the UPLC-Q-TOF-MS microsystem, and eight products were detected. It is proposed that the photodegradation of clofibric acid occurred mainly via decarboxylation, dechlorination, ·OH addition and ¹O₂ attack reaction.

Clofibric acid is one of the most frequently detected pharmaceuticals in various aquatic environments.