Mechanism of Zn salt-induced deactivation of a Cu/activated carbon catalyst for low-temperature denitration via CO-SCR

In the process of industrial flue gas denitration, the presence of heavy metals, especially Zn salts, is known to lead to the deactivation of the denitration catalysts. However, the specific mechanism of the catalyst deactivation remains unclear. In this paper, the mechanism of the ZnCl₂- and ZnSO₄-induced deactivation of low-temperature denitration catalysts in the carbon oxide (CO) selective catalytic reduction (CO-SCR) reaction was investigated using a Cu/activated carbon (AC) catalyst, in which HNO₃/AC was used as the carrier. Cu/AC, ZnCl₂–Cu/AC, and ZnSO₄–Cu/AC catalysts were prepared by the incipient wetness impregnation method. The physicochemical properties of the catalyst were examined via the Brunauer–Emmett–Teller method, X-ray diffraction, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy analyses, which proved the mechanism of catalyst denitrification and enabled the elucidation of the toxicity mechanism of the Zn salts on the Cu/AC catalyst for CO-SCR denitration at low temperatures. The results show that Zn doping reduces the physical adsorption of CO and NO and decreases the concentration of Cu²⁺ and chemisorbed oxygen (O_β), leading to the reduction of active sites and oxygen vacancies, thus inhibiting the denitration reaction. Moreover, ZnCl₂ is more toxic than ZnSO₄ because Cl⁻ not only occupies oxygen vacancies but also inhibits O_β migration. In contrast, SO₄²⁻ increases the surface acidity and promotes O_β supplementation. This study can provide a reference for the development of CO-SCR denitration catalysts with high resistance to Zn salt poisoning.

Zn slats compete with CO and NO for the active sites. Cl⁻ not only occupies oxygen vacancies but also inhibits the O_β migration. SO₄²⁻ increases the surface acidity and promotes the O_β supplementation, which inhibits toxicity.     

Manganese–cerium mixed oxides supported on rice husk based activated carbon with high sulfur tolerance for low-temperature selective catalytic reduction of nitrogen oxides with ammonia

A rice husk-derived activated carbon supported manganese–cerium mixed oxide catalyst (Mn–Ce/RAC) was prepared by an impregnation method and tested for the selective catalytic reduction of nitrogen oxides with ammonia (NH₃-SCR). 5 wt% Mn–Ce/RAC catalyst showed the highest activity, yielding nearly 100% NO_x conversion and N₂ selectivity at 240 °C at a space velocity of 30 000 h⁻¹. Compared with commercial activated carbon supported manganese–cerium mixed oxide catalyst (Mn–Ce/SAC), a higher SCR performance with good SO₂ tolerance could be observed in the tested temperature range over the Mn–Ce/RAC catalyst. The characterization results revealed that the Mn–Ce/RAC catalyst had a higher Mn⁴⁺/Mn³⁺ ratio, amount of chemisorbed oxygen and more Brønsted acid sites than the Mn–Ce/SAC catalyst. The XRD analysis indicated that Mn–Ce oxides were highly dispersed on the RAC support. These properties of Mn–Ce/RAC assisted the SCR reaction. Moreover, in situ DRIFTS results demonstrated that sulfate species formation on Mn–Ce/RAC was much less in the presence of SO₂ than that of Mn–Ce/SAC, which might be ascribed to the reduced alkalinity of the catalyst by the presence of SiO₂ in RAC.

A rice husk derived catalyst exhibited high SCR activity and excellent SO₂ + H₂O tolerance.     

A high-throughput synthesis of large-sized single-crystal hexagonal boron nitride on a Cu–Ni gradient enclosure

Large monolayer two-dimensional h-BN can be employed in novel electronic devices because of its thin insulation, excellent thermal stability, and high mechanical strength. However, the efficient synthesis of an h-BN film with large lateral size still faces a great challenge. Here, we report a method for the high-throughput synthesis of large-sized single-crystal h-BN on a Cu–Ni gradient alloy enclosure as the substrate via a low-pressure chemical vapor deposition (LPCVD) method. By depositing Ni on the Cu foil in different concentrations to obtain a Cu–Ni in-plane gradient concentration alloy enclosure, the highest growth rate of h-BN was 1 μm min⁻¹ with the lateral size of h-BN being higher than 60 μm. Furthermore, the effect of the Ni content on the single crystal h-BN grain size and nucleation density and the mechanisms for the growth of h-BN were also investigated.

Large monolayer two-dimensional h-BN can be employed in novel electronic devices because of its thin insulation, excellent thermal stability, and high mechanical strength.     

Metal–support interaction induced ZnO overlayer in Cu@ZnO/Al2O3 catalysts toward low-temperature water–gas shift reaction

The water–gas shift reaction (WGSR) plays a pivotal role in many important industrial processes as well as in the elimination of residual CO in feed gas for fuel cells. The development of a high-efficiency low-temperature WGSR (LT-WGSR) catalyst has attracted considerable attention. Herein, we report a ZnO-modified Cu-based nanocatalyst (denoted as Cu@ZnO/Al₂O₃) obtained via an in situ topological transformation from a Cu₂Zn₁Al-layered double hydroxide (Cu₂Zn₁Al-LDH) precursor at different reduction temperatures. The optimal Cu@ZnO/Al₂O₃-300R catalyst with appropriately abundant Cu@ZnO interface structure shows superior catalytic performance toward the LT-WGSR with a reaction rate of up to 19.47 μmol_CO g_cat⁻¹ s⁻¹ at 175 °C, which is ∼5 times larger than the commercial Cu/ZnO/Al₂O₃ catalyst. High-resolution transmission electron microscopy (HRTEM) proves that the reduction treatment results in the coverage of Cu nanoparticles by ZnO overlayers induced by a strong metal–support interaction (SMSI). Furthermore, the generation of the coating layers of ZnO structure is conducive to stabilize Cu nanoparticles, accounting for long-term stability under the reaction conditions and excellent start/stop cycle of the Cu@ZnO/Al₂O₃-300R catalyst. This study provides a high-efficiency and low-cost Cu-based catalyst for the LT-WGSR and gives a concrete example to help understand the role of Cu@ZnO interface structure in dominating the catalytic activity and stability toward WGSR.

The water–gas shift reaction (WGSR) plays a pivotal role in many important industrial processes as well as in the elimination of residual CO in feed gas for fuel cells.     

Cu–Cd–Zn–S/ZnS core/shell quantum dot/polyvinyl alcohol flexible films for white light-emitting diodes

We present a facile route for the synthesis of water-soluble Cu–Cd–Zn–S/ZnS core/shell quantum dots (QDs) by simple pH regulation. The PL spectra of Cu–Cd–Zn–S/ZnS core/shell quantum dots can cover the whole visible light region in the case of only two ratios of Cu/Cd/Zn. The emission wavelength of Cu–Cd–Zn–S/ZnS QDs can be conveniently tuned from 474 to 515 and 548 to 629 nm by adjusting the pH value when the ratios of Cu/Cd/Zn are fixed at 1 : 5 : 80 and 1 : 5 : 10, respectively. It is worth noting that under the condition of a constant Cu/Cd/Zn ratio, the UV-vis absorption spectra do not change with the fluorescence spectra, indicating that the band gap of QDs remains unchanged during the change of pH value. The photoluminescence (PL) quantum yield of the as-prepared QDs with yellow emission is up to 76%. The QDs also show excellent chemical stability after the deposition of the ZnS shell. Luminescent and flexible films are fabricated by combining Cu–Cd–Zn–S QDs with polyvinyl alcohol (PVA). The QD/PVA flexible hybrid films are successfully applied on top of a conventional blue InGaN chip for remote-type warm-white LEDs. As-fabricated warm-white LEDs exhibit a higher color rendering index (CRI) of about 89.2 and a correlated color temperature (CCT) of 4308 K.

We present a facile route for the synthesis of water-soluble Cu–Cd–Zn–S/ZnS core/shell quantum dots (QDs) by simple pH regulation.     

Construction of Cu–Ce/graphene catalysts via a one-step hydrothermal method and their excellent CO catalytic oxidation performance

Cu–Ce/graphene catalysts show high dispersion of metal particles and excellent activity and stability for catalytic oxidation. In this study, a hydrothermal method was used to synthesize a series of bimetallic Cu–Ce/graphene catalysts, and the effects of the proportions of Cu and Ce on CO oxidation were investigated in detail. Indispensable characterizations such as XPS, XRD, TEM, BET, and H₂-TPR were conducted to explore the effect of the Cu/Ce molar ratio and the metal valence on the activity and determine the structure–performance relationship. The results showed that bimetallic supported catalysts, such as 3Cu5Ce/graphene, 1Cu1Ce/graphene, and 5Cu3Ce/graphene, possessed significant catalytic activity. Especially, the 5Cu3Ce/graphene catalyst showed highest catalytic activity for CO oxidation, the T₁₀₀ value was 132 °C, and the apparent activation energy was 68.03 kJ mol⁻¹. Furthermore, the stability of the 5Cu3Ce/graphene catalyst was outstanding, which could be maintained for at least 12 h. Moreover, the CeO₂ particles were well crystalline with the size 5–9 nm in these catalysts, and the CuO nanoparticles were well dispersed on CeO₂ and graphene. Notably, the ratio of Cu/Ce in the catalyst was higher, the interaction between the Ce species and the graphene was stronger, and the Cu species were more easily reduced; this was beneficial for the oxidation of CO.

Cu–Ce/graphene catalysts show high dispersion of metal particles and excellent activity and stability for catalytic oxidation.     

Pt–Ni/ZnO-rod catalysts for hydrogen production by steam reforming of methanol with oxygen

Ni, Pt and a mixture of Ni and Pt supported on ZnO-rods were evaluated in autothermal steam reforming of methanol (ASRM) for hydrogen production as a function of the reaction temperature. The catalytic materials were characterized by SEM-EDS, XRD, TEM, HRTEM, TPR and BET. Analysis by SEM and TEM showed structural modifications on the surface of the ZnO rods after Ni impregnation. The reactivity of the catalytic materials in the range of 200–500 °C showed that the bimetallic sample had better catalytic activity among all the catalysts studied. This finding could be associated to PtZn and NiZn alloys present in this catalyst, which were identified by XRD and HRTEM analyses. Catalyst characterization by XRD after the catalytic testing showed that the intermetallic PtZn phase was stable during the reaction in the Pt/ZnO-rod sample. The cubic Ni_0.75–Zn_0.25 structure identified in the Ni/ZnO-rod sample was transformed to Zn_0.1–Ni_0.9–O and metallic Ni phases, respectively. On the bimetallic PtNi/ZnO-rod sample, the cubic Ni_0.75–Zn_0.25 structure remained, although the tetragonal NiZn structure is unstable and was destroyed during the ASRM reaction and then a new phase of Ni_0.7Pt_0.3 emerged. The promotion effect of Pt and/or Ni on the ZnO-rod was clearly shown.

PtZn and NiZn alloys on ZnO-1D samples were evaluated in the ASRM. Bifunctional behavior between PtZn, NiZn alloys and the ZnO were reported. The ZnO provides the adsorption sites for the reagents and the alloy particles facilitate the H₂ transfer.     

Hydrogen storage behavior of nanocrystalline and amorphous Mg–Ni–Cu–La alloys

Alloying and structural modification are two effective ways to enhance the hydrogen storage kinetics and decrease the thermal stability of Mg and Mg-based alloys. In order to enhance the characteristics of Mg₂Ni-type alloys, Cu and La were added to an Mg₂Ni-type alloy, and the sample alloys (Mg₂₄Ni₁₀Cu₂)_100−xLa_x (x = 0, 5, 10, 15, 20) were prepared by melt spinning. The influences of La content and spinning rate on the gaseous and electrochemical hydrogen storage properties of the sample alloys were explored in detail. The structural identification carried out by XRD and TEM indicates that the main phase of the alloys is Mg₂Ni and the addition of La results in the formation of the secondary phases LaMg₃ and La₂Mg₁₇. The as-spun alloys have amorphous and nanocrystalline structures, and the addition of La promotes glass formation. The electrochemical properties examined by an automatic galvanostatic system show that the samples possess a good activation capability and achieve their maximal discharge capacities within three cycles. The discharge potential characteristics were vastly ameliorated by melt spinning and La addition. The discharge capacities of the samples achieve their maximal values as the La content changes, and the discharge capacities always increase with increasing spinning rate. The addition of La leads to a decline in hydrogen absorption capacity, but it can effectively enhance the rate of hydrogen absorption. The addition of La and melt spinning significantly increase the hydrogen desorption rate due to the reduced activation energy.

In order to enhance the characteristics of Mg₂Ni-type alloys, Cu and La were added to an Mg₂Ni-type alloy, and sample alloys were prepared by melt spinning. The effects of La content and spinning rate on the hydrogen storage properties were explored.     

Highly efficient selective hydrogenation of levulinic acid to γ-valerolactone over Cu–Re/TiO2 bimetallic catalysts

Highly active and thermally stable Cu–Re bimetallic catalysts supported on TiO₂ with 2.0 wt% loading of Cu were prepared via an incipient wetness impregnation method and were applied for liquid phase selective hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) in H₂. The effect of the molar ratios of Cu : Re on the physico-chemical properties and the catalytic performance of the Cu–Re/TiO₂ catalysts was investigated. Moreover, the influence of various reaction parameters on the hydrogenation of LA to GVL was studied. The results showed that the Cu–Re/TiO₂ catalyst with a 1 : 1 molar ratio of Cu to Re (Cu–Re(1 : 1)/TiO₂) exhibited the highest performance for the reaction. Complete conversion of LA with a 100% yield of GVL was achieved in 1,4-dioxane solvent under the reaction conditions of 180 °C, 4.0 MPa H₂ for 4 h, and the catalyst could be reused at least 6 times with only a slight loss of activity. Combined with the characterization results, the high performance of the catalyst was mainly attributed to the well-dispersed Cu–Re nanoparticles with a very fine average size (ca. 0.69 nm) and the co-presence of Cu–Re bimetal and ReO_x on the catalyst surface.

Herein, we report a highly efficient and recyclable Cu–Re(1 : 1)/TiO₂ bimetallic catalyst for liquid phase hydrogenation of levulinic acid to γ-valerolactone.     

Chemically activated core–shell structured IF-WS2@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites

Ternary composites have demonstrated better capability than binary composites in enhancing the mechanical properties of the modified epoxy resins and are, therefore, currently under intensive investigation. Herein, we report a novel ternary nanocomposite prepared by filling a binary BPF (bisphenol F epoxy resin)/SCPs (sugarcane-based carbon powders) matrix with C-coated inorganic fullerene-like tungsten disulfide (IF-WS₂@C) nanoparticles, and the analysis of its interface synergetic effect using XPS/FTIR. This activated nano-carbon core–shell structure filler is considered an ideal nanofiller and shows the excellent mechanical performance of the ternary composites. XRD, IR, XPS, SEM, and TEM characterizations were applied in investigating this nanocomposite. The improvement of the thermal and mechanical properties demonstrated the enhancement effects of this nanofiller. The results show that the great improvement of the bending modulus of 39.4% increased with the addition of 0.5 wt% IF-WS₂@C nanoparticles, while 34.1% enhancement of bending strength was obtained with the addition of 0.2 wt% IF-WS₂@C nanoparticles. The hardness and thermal conductivity were also boosted up to 5.2% and 33.1% with 0.5 wt% addition, respectively. The incorporation of a chemically activated coating may provide a novel means for improving graphite crystallization, which could somehow expand the potential application of IF-WS₂@C nanoparticles.

Schematic diagram and typical curing mechanism of epoxy resins and the unique interactions of the IF-WS₂@C nanoparticles introduced into the matrix.     

Electrochemical performance of activated carbon fiber with hydrogen bond-induced high sulfur/nitrogen doping

The sulfur/nitrogen co-doped activated carbon fiber (S/N-ACF) is prepared by the thermal treatment of thiourea-bonded hydroxyl-rich carbon fiber, which can bond the decomposition products of thiourea through hydrogen bond interaction to avoid the significant loss of sulfur and nitrogen sources during the thermal treatment process. The sulfur/nitrogen co-doped carbon fiber (S/N-CF) is prepared by the thermal treatment of thiourea-adsorbed carbon fiber. The doping degree of the carbon fiber is improved by reasonable strategy. S/N-ACF shows a higher amount of S/N doping (4.56 at% N and 3.16 at% S) than S/N-CF (1.25 at% N and 0.61 at% S). S/N-ACF with high S/N doping level involves highly active sites to improve the capacitive performance, and high delocalization electron to improve the conductivity and rate capability when compared with the normal S/N co-doped carbon fiber (S/N-CF). Accordingly, the specific capacitance increases from 1196 mF cm⁻² for S/N-CF to 2704 mF cm⁻² for S/N-ACF at 1 mA cm⁻². The all-solid-state flexible S/N-ACF supercapacitor achieves 184.7 μW h cm⁻² at 350 μW cm⁻². The results suggest that S/N-ACF has potential application as a CF-based supercapacitor electrode material.

Sulfur/nitrogen co-doped activated carbon fiber is prepared by thermal treatment of thiourea-bonded hydroxyl-rich carbon fiber, which achieves high doping level and electrochemical performance.     

Spontaneous alloying of ultrasmall non-stoichiometric Ag–In–S and Cu–In–S quantum dots in aqueous colloidal solutions

The effect of spontaneous alloying of non-stoichiometric aqueous Ag–In–S (AIS) and Cu–In–S (CIS) quantum dots (QDs) stabilized by surface glutathione (GSH) complexes was observed spectroscopically due to the phenomenon of band bowing typical for the solid–solution Cu(Ag)–In–S (CAIS) QDs. The alloying was found to occur even at room temperature and can be accelerated by a thermal treatment of colloidal mixtures at around 90 °C with no appreciable differences in the average size observed between alloyed and original individual QDs. An equilibrium between QDs and molecular and clustered metal–GSH complexes, which can serve as “building material” for the new mixed CAIS QDs, during the spontaneous alloying is assumed to be responsible for this behavior of GSH-capped ternary QDs. The alloying effect is expected to be of a general character for different In-based ternary chalcogenides.

The effect of spontaneous alloying of aqueous glutathione-capped Ag–In–S and Cu–In–S quantum dots (QDs) into quaternary Cu(Ag)–In–S QDs is reported.     

Catalytic decomposition of N2O over Cu–Al–Ox mixed metal oxides

Cu–Al–O_x mixed metal oxides with intended molar ratios of Cu/Al = 85/15, 78/22, 75/25, 60/30, were prepared by thermal decomposition of precursors at 600 °C and tested for the decomposition of nitrous oxide (deN₂O). Techniques such as XRD, ICP-MS, N₂ physisorption, O₂-TPD, H₂-TPR, in situ FT-IR and XAFS were used to characterize the obtained materials. Physico-chemical characterization revealed the formation of mixed metal oxides characterized by different specific surface area and thus, different surface oxygen default sites. The O₂-TPD results gained for Cu–Al–O_x mixed metal oxides conform closely to the catalytic reaction data. In situ FT-IR studies allowed detecting the form of Cu⁺⋯N₂ complexes due to the adsorption of nitrogen, i.e. the product in the reaction between N₂O and copper lattice oxygen. On the other hand, mostly nitrate species and NO were detected but those species were attributed to the residue from catalyst synthesis.

Cu–Al–O_x mixed metal oxides with intended molar ratios of Cu/Al = 85/15, 78/22, 75/25, 60/30, were prepared by thermal decomposition of precursors at 600 °C and tested for the decomposition of nitrous oxide (deN₂O).     

Heterogeneous Cu–Fe oxide catalysts for preferential CO oxidation (PROX) in H2-rich process streams

The influence of Fe loading in Cu–Fe phases and its effect on carbon monoxide (CO) oxidation in H₂-rich reactant streams were investigated with the catalyst material phases characterized by Field Emission Scanning Electron Microscopy (FESEM), X-ray diffraction (XRD) studies and Mössbauer Spectroscopy (MS). There was no change in the oxidation state of the Fe ions with copper or iron loading. The catalytic activity was examined in the feed consisting of H₂, H₂O and CO₂ for the preferential CO oxidation (PROX) process. These catalysts showed an optimized performance in converting CO in WGS streams in the temperature range of 80–200 °C. In addition to the formation of the CuFe₂O₄ phase, the Fe and Cu were found to be incorporated into a Cu–Fe supersaturated solid solution which improved CO oxidation activity, with carbon dioxide and water produced selectively with high catalytic activity in depleted hydrogen streams. Relatively high conversion of CO was obtained with high Fe metal loading. In addition to their catalytic efficiency, the employed heterogeneous catalysts are inexpensive to produce and do not contain any critical raw materials such as platinum group metals.

Fe loading in Cu–Fe phases and its effect on carbon monoxide oxidation in H₂-rich reactant streams were investigated with the catalyst material phases characterized by Field Emission Scanning Electron Microscopy, X-ray diffraction studies and Mössbauer Spectroscopy.     

Comparative advantages of Zn–Cu–In–S alloy QDs in the construction of quantum dot-sensitized solar cells

Alloyed structures of quantum dot light-harvesting materials favor the suppression of unwanted charge recombination as well as acceleration of the charge extraction and therefore the improvement of photovoltaic performance of the resulting solar cell devices. Herein, the advantages of Zn–Cu–In–S (ZCIS) alloy QD serving as light-harvesting sensitizer materials in the construction of quantum dot-sensitized solar cells (QDSCs) were compared with core/shell structured CIS/ZnS, as well as pristine CIS QDs. The built QDSCs with alloyed Zn–Cu–In–S QDs as photosensitizer achieved an average power conversion efficiency (PCE) of 8.47% (V_oc = 0.613 V, J_sc = 22.62 mA cm⁻², FF = 0.610) under AM 1.5G one sun irradiation, which was enhanced by 21%, and 82% in comparison to those of CIS/ZnS, and CIS based solar cells, respectively. In comparison to cell device assembled by the plain CIS and core/shell structured CIS/ZnS, the enhanced photovoltaic performance in ZCIS QDSCs is mainly ascribed to the faster photon generated electron injection rate from QD into TiO₂ substrate, and the effective restraint of charge recombination, as confirmed by incident photon-to-current conversion efficiency (IPCE), open-circuit voltage decay (OCVD), as well as electrochemical impedance spectroscopy (EIS) measurements.

Benefiting from the accelerative electron injection and retarded charge recombination, Zn–Cu–In–S alloy QD based QDSC achieved a PCE of 8.55%, which is 21%, and 82% higher than those of CIS/ZnS, and pristine CIS QDs based solar cells, respectively.     

Effects of Sm on Fe–Mn catalysts for Fischer–Tropsch synthesis

Sm-promoted FeMn catalysts were prepared by the co-precipitation method and characterized by N₂ adsorption, XRD, CO-TPD, H₂-TPD, CO₂-TPD, H₂-TPR, XPS and MES. It was found that compared with the un-promoted catalyst, when Sm was added at a proper content, the catalyst showed a larger BET surface area and promoted the formation of iron particles with a smaller size. The presence of Sm could increase the surface charge density of iron, which enhanced the Fe–C bond and promoted the stability and amount of CO dissociated adsorption, as confirmed by XPS and CO-TPD. Furthermore, according to MES, Sm could promote the formation of Fe₅C₂, which was the active phase of FTS. In addition, Sm could also enhance the basicity of the catalysts and suppress the H₂ adsorption capacity, which inhibited the hydrogenation reaction and the conversion of olefins to paraffins, as verified by the results of CO₂-TPD and H₂-TPD. According to the FTS performance results, compared with the observations for the un-promoted catalysts, when the molar ratio of Sm to Fe was 1%, the CO conversion increased from 63.4% to 70.4%, the sum of light olefins in the product distribution increased from 26.6% to 32.6, and the ratio of olefins to paraffins increased to 4.18 from 4.09.

The effect of samarium on iron-based catalysts for Fischer–Tropsch synthesis was investigated.     

Preparation and photocatalytic activity characterization of activated carbon fiber–BiVO4 composites

Herein, we describe the hydrothermal immobilization of BiVO₄ on activated carbon fibers (ACFs) and characterize the obtained composite by several instrumental techniques, using Reactive Black KN-B (RB5) as a model pollutant for photocatalytic performance evaluation and establishing the experimental conditions yielding maximal photocatalytic activity. The photocatalytic degradation of RB5 is well fitted by a first-order kinetic model, and the good cycling stability and durability of BiVO₄@ACFs highlight the potential applicability of the proposed composite. The enhanced photocatalytic activity of BiVO₄@ACFs compared to those of BiVO₄ and ACFs individually was mechanistically rationalized, and the suggested mechanism was verified by ultraviolet-visible spectroscopy, attenuated total reflectance Fourier-transform infrared spectroscopy, and RB5 degradation experiments. Thus, this work contributes to the development of BiVO₄@ACF composites as effective photocatalysts for environmental remediation applications.

Herein, we describe the hydrothermal immobilization of BiVO₄ on activated carbon fibers, using Reactive Black KN-B photocatalytic performance evaluation and establishing the experimental conditions yielding maximalphotocatalytic activity.     

One-pot synthesis of Ag–Cu–Cu2O/C nanocomposites derived from a metal–organic framework as a photocatalyst for borylation of aryl halide

Mixed metal–metal oxide/C (Ag–Cu–Cu₂O/C) nanocomposites were synthesized by the heat treatment of a metal–organic framework under a N₂ flow using the one-pot synthesis method. The as-prepared nanocomposites were characterized using a range of techniques, such as TEM, elemental mapping, XRD, N₂ sorption, UV-Vis DRS, and XPS. The nanoparticles were successfully formed with high dispersion in porous carbon materials and high crystallinity based on the analysis results. The Ag–Cu–Cu₂O/C nanocomposites (35 nm) showed high photocatalytic activity and good recyclability toward the borylation of aryl halides under a xenon arc lamp. This result can enhance the interest in photocatalysis for various applications, particularly in organic reactions, using a simple and efficient synthesis method.

Ag–Cu–Cu₂O/C nanocomposites derived from metal–organic framework through one-pot thermal reduction method were synthesized. The material exhibits high catalytic activity in the borylation of aryl halide under xenon lamp condition across 7 cycles, with no yield decrease.     

Improvement of low-temperature NH3-SCR catalytic performance over nitrogen-doped MOx–Cr2O3–La2O3/TiO2–N (M = Cu,Fe, Ce) catalysts

A series of MO_x–Cr₂O₃–La₂O₃/TiO₂–N (M = Cu, Fe, Ce) catalysts with nitrogen doping were prepared via the impregnation method. Comparing the low-temperature NH₃-SCR activity of the catalysts, CeCrLa/Ti–N (xCeO₂–yCr₂O₃–zLa₂O₃/TiO₂–N) exhibited the best catalytic performance (NO conversion approaching 100% at 220–460 °C). The physico-chemical properties of the catalysts were characterized by XRD, BET, SEM, XPS, H₂-TPR, NH₃-TPD and in situ DRIFTS. From the XRD and SEM results, N doping affects the crystalline growth of anatase TiO₂ and MO_x (M = Cu, Fe, Ce, Cr, La) which were well dispersed over the support. Moreover, the doping of N promotes the increase of the Cr⁶⁺/Cr ratio and Ce³⁺/Ce ratio, and the surface chemical adsorption oxygen content, which suggested the improvement of the redox properties of the catalyst. And the surface acid content of the catalyst increased with the doping of N, which is related to CeCrLa/TiO₂–N having the best catalytic activity at high temperature. Therefore, the CeCrLa/TiO₂–N catalyst exhibited the best NH₃-SCR performance and the redox performance of the catalysts is the main factor affecting their activity. Furthermore, in situ DRIFTS analysis indicates that Lewis-acid sites are the main adsorption sites for ammonia onto CeCrLa/TiO₂–N and the catalyst mainly follows the L–H mechanism.

A series of MO_x–Cr₂O₃–La₂O₃/TiO₂–N (M = Cu, Fe, Ce) catalysts with nitrogen doping were prepared via the impregnation method.     

Dehydrogenation of methylcyclohexane over Pt-based catalysts supported on functional granular activated carbon

Herein, we developed the dehydrogenation of methylcyclohexane over Pt-based catalysts supported on functional granular activated carbon. Sulphuric acid, hydrogen peroxide, nitric acid and aminopropyl triethoxy silane were adopted to modify the granular activated carbon. The structural characterizations suggested that the carbon materials had a large surface area, abundant pore structure, and a high number of oxygen-containing functional groups, which influenced the Pt-based catalysts on the particle size, dispersion and dehydrogenation activity. The hydrogen temperature-programmed reduction technique was utilized to investigate the interaction between the active component Pt and the various functionalized granular activated carbon materials. The CO pulse technique revealed the particle sizes and dispersion of the as-prepared Pt-based catalysts. Finally, the Pt-based catalysts were successfully applied to study their catalytic activity in the dehydrogenation reaction of methylcyclohexane. The results showed that the Pt-based catalyst over granular activated carbon functionalized with sulphuric acid groups had a higher conversion of methylcyclohexane (63%) and a larger hydrogen evolution rate (741.1 mmol g_Pt⁻¹ min⁻¹) than the other resulting Pt-based catalysts at 300 °C.

Dehydrogenation of methylcyclohexane over Pt-based catalysts supported on functional granular activated carbon.