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1.
Cobalt telluride nanostructured materials have demonstrated various applications, particularly in energy generation and storage. A high temperature and reducing atmosphere are required for the preparation of cobalt telluride-based materials, which makes this a difficult and expensive process. The development of a facile route for producing the desirable nanostructure of cobalt telluride remains a great challenge. We demonstrated a simple hydrothermal method for preparing cobalt telluride nanorods (CoTe NRs) and telluride nanorods (Te NRs) for supercapacitor applications. The morphology of CoTe NRs and Te NRs was analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The prepared CoTe NR electrode material exhibited a high specific capacity of 170 C g−1 at a current density of 0.5 A g−1 with an exceptional cyclic stability. The asymmetric supercapacitor was assembled using CoTe NRs and orange peel-derived activated carbon (OPAA-700) as a positive and negative electrode, respectively. The fabricated device delivered a high energy density of 40.7 W h kg−1 with a power density of 800 W kg−1 at 1 A g−1 current density. When the current density was increased to 30 A g−1, the fabricated device delivered a high power density of 22.5 kW kg−1 with an energy density of 16.3 W h kg−1. The fabricated asymmetric supercapacitor displayed a good cyclic stability performance for 10 000 cycles at a high current density of 30 A g−1 and retained 85% of its initial capacity for after 10 000 cycles. The prepared materials indicate their applicability for high performance energy storage devices.A one-step hydrothermal derived cobalt telluride nanorods and activated carbon-based hybrid asymmetric supercapacitor delivered a high energy (40.7 W h kg−1) and power density (22.5 kW kg−1) with an electrochemical stability of 85% for 10000 cycles. 相似文献
2.
Saurabh Singh Rakesh K. Sahoo Nanasaheb M. Shinde Je Moon Yun Rajaram S. Mane Wonsub Chung Kwang Ho Kim 《RSC advances》2019,9(55):32154
In the current study, we have explored the coupling of Bi2O3 negative electrode and MnO2 positive electrode materials as an asymmetric faradaic assembly for a high-performance hybrid electrochemical energy storage device (HEESD). Aiming at a low-cost device, both the electrodes have been synthesized by a simple, scalable, and cost-effective chemical synthesis method. After their requisite structure-morphological confirmation and correlation, these electrodes were separately examined for their electrochemical performance in a three-electrode configuration. The results obtained confirm that Bi2O3 and MnO2 exhibit 910 C g−1 and 424 C g−1 specific capacity, respectively, at 2 A g−1 current density. Notably, the performance of both electrodes has been analyzed using Dunn''s method to highlight the distinct nature of their faradaic properties. Afterwards, the asymmetric faradaic assembly of both electrodes, when assembled as a HEESD (MnO2//Bi2O3), delivered 411 C g−1 specific capacity at 1 A g−1 current density due to the inclusive contribution from the capacitive as well as the non-capacitive faradaic quotient. Consequently, the assembly offers an excellent energy density of 79 W h kg−1 at a power density of 702 W kg−1, with a magnificent retention of energy density up to 21.1 W h kg−1 at 14 339 W kg−1 power density. Moreover, it demonstrates long-term cycling stability at 10 A g−1, retaining 85.2% of its initial energy density after 5000 cycles, which is significant in comparison with the previously reported literature. Additionally, to check the performance of the device in real time, two HEESDs were connected in series to power a light-emitting diode. The results obtained provide significant insight into hybrid coupling, where two different faradaic electrodes can be combined in a synergistic combination for a high-performance HEESD.A hybrid electrochemical energy storage device assembled with faradaic Bi2O3 and MnO2 electrodes exhibits superior electrochemical performance with a high energy density of 79 W h kg−1 at a power density of 702 W kg−1. 相似文献
3.
The Li-ion hybrid capacitor (LIHC) is considered as a promising candidate for electrochemical energy storage owing to the high energy and power density. However, the sluggish anodic reaction kinetics and high reaction voltage greatly hinder the overall performance of LIHCs. Herein, a free-standing VN/MXene composite anode with high specific capacity and low reaction voltage was prepared by a simple vacuum filtration method. The obtained VN/MXene composite anode shows a high discharge specific capacity of 501.7 mA h g−1 at 0.1 A g−1 and excellent rate capability (191.8 mA h g−1 at 5 A g−1), as well as much extended cycling stability (1500 cycles at 2 A g−1). When combined with an egg white-derived activated carbon (E-AC) cathode, the assembled LIHC delivers a high specific capacity of 59.1 F g−1 and a high energy density of 129.3 W h kg−1 with a power density of 449.7 W kg−1. Even at a high current density of 5 A g−1, the LIHC still maintains an exciting energy density of 42.81 W h kg−1 at 11 249 W kg−1. Meanwhile, the cycling life can be extended to 5000 cycles with a high capacity retention of 98% at 1 A g−1. We believe that this work opens up new possibilities for developing advanced free-standing MXene-based electrodes for Li-ion storage.The Li-ion hybrid capacitor (LIHC) is considered as a promising candidate for electrochemical energy storage owing to the high energy and power density. 相似文献
4.
It is well known that the structure of an electrode material seriously affects its electrochemical performance. In this study, we prepare hybrid structured NiCo2S4@PPy nanoarchitectures by a hydrothermal method and subsequent electrodeposition process. The specific capacitance of the obtained sample is 1733.23 C g−1 at 1 A g−1. The assembled asymmetric device presents an energy density of 59.59 W h kg−1 at 1404.04 W kg−1. The excellent electrochemical performance can be attributed to the synergistic effect between the high theoretical specific capacitance of the NiCo2S4 sheets and the superior cycling stability of the PPy film. The device also shows an outstanding mechanical flexibility at different bending angles.We prepare hybrid structured NiCo2S4@PPy nanoarchitectures by a hydrothermal method and subsequent electrodeposition process. The assembled asymmetric device presents an energy density of 59.59 W h kg−1 at 1404.04 W kg−1. 相似文献
5.
Construction of delicate nanostructures with a facile, mild-condition and economical method is a key issue for building high-performance electrode materials. We demonstrate a facile and novel “reassembling strategy” to hollow MnCoS nanospheres derived from dual-ZIF for supercapacitors. The spherical shell''s surface structure, thickness and Mn distribution were controlled by regulating the solvothermal reaction time. The chemical composition, phases, specific surface areas and microstructure were studied and the electrochemical performances were systematically estimated. As the unique low-crystalline and optimized hollow nanosphere structure contributes to increasing active sites, MnCoS nanospheres exhibit excellent electrochemical performance. The test results show that the specific capacitance increases with increasing solvothermal time, and the MCS with a 5 h reaction time exhibits optimal electrochemical properties with a high specific capacity of 957 C g−1 (1 A g−1). Furthermore, an MCS-5//AC asymmetric supercapacitor device delivers a specific energy as high as 36.9 W h kg−1 at a specific power of 750 W kg−1.A facial and novel “reassemble strategy” was demonstrated to synthesize hollow MnCoS nanospheres from dual-ZIF. Optimized MnCoS nanospheres exhibits a high specific capacity of 957 C g−1. An MCS-5//AC ASC delivers a specific energy of 36.9 W h kg−1. 相似文献
6.
Hongwei Kang Chengpeng Zhang Yonggui Xu Weiyang Zhang Jianhua Jiao Zhikun Li LeiLei Zhu Xiaoqian Liu 《RSC advances》2020,10(3):1507
In this paper, novel reduced graphene oxide (rGO) composites (DAPrGOs) modified by diaminopyrene (DAP) were successfully synthesized via a facile solvothermal reaction method and used for supercapacitors. Compared with the pristine rGO, the DAPrGO1 electrode showed distinctly better performance (397.63 F g−1vs. 80.29 F g−1 of pristine rGO at 0.5 A g−1) with small charge transfer resistance. When a symmetric device was fabricated using DAPrGO1 as the active material, it also exhibited a high capacitance of 82.70 F g−1 at 0.5 A g−1 with an energy density of 25.84 W h kg−1 at a power density of 375 W kg−1, and even offered a high power density of 7500 W kg−1 (18.71 W h kg−1) at 10 A g−1. Moreover, the device possessed good electrochemical stability up to 20 000 cycles, implying promising applications in energy storage fields.Schematic illustration of the facile synthesis process of DAPrGOs nanocomposites, Ragone plots and the superior cyclic stability of the assembled DAPrGO1//DAPrGO1 SSS. 相似文献
7.
Activated carbon monoliths of kenaf (ACMKs) were prepared by moulding kenaf fibers into a column-shape monolith and then carrying out pyrolysis at 500, 600, 700 or 800 °C, followed by activation with KOH at 700 °C. Then, the sample was characterized using thermogravimetric analyzer (TGA), field-emission scanning electron microscopy (FE-SEM), field-emission transmission electron microscopy (FE-TEM), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, X-ray diffraction (XRD) and N2 sorption instruments. The prepared ACMK was subjected to electrochemical property evaluation via cyclic voltammetry (CV), galvanostatic charge–discharge (GCD) and electrochemical impedance spectroscopy (EIS). The GCD study using a three-electrode system showed that the specific capacitance decreased with higher pyrolysis temperature (PYT) with the ACMK pyrolyzed at 500 °C (ACMK-500) exhibiting the highest specific capacitance of 217 F g−1. A two-electrode system provided 95.9% retention upon a 5000 cycle test as well as the specific capacitance of 212 F g−1, being converted to an energy density of 6 W h kg−1 at a power density of 215 W kg−1.Monolithic carbon from kenaf-based fiber for supercapacitor electrode application provided a specific capacitance of 212 F g−1via GCD at 1 A g−1, converting to an energy density of 6 W h kg−1 at the power density of 215 W kg−1 as well as 95.9% retention upon 5000 cycling test. 相似文献
8.
Fangping Wang Guifang Li Jinfeng Zheng Jing Ma Caixia Yang Qizhao Wang 《RSC advances》2018,8(68):38945
Three-dimensional flower-like molybdenum disulfide microspheres composed of nanosheets were prepared by a hydrothermal method using ammonium molybdate as the molybdenum source and thiourea as the sulfur source. Structural and morphological characterizations were performed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX) spectroscopy and X-ray photoelectron spectroscopy (XPS). The electrochemical properties of MoS2 electrode were studied by performing cyclic voltammetry (CV), galvanostatic charge–discharge analysis and electrochemical impedance spectroscopy (EIS). When used as an electrode material for supercapacitor, the hybrid MoS2 showed a high specific capacity of 518.7 F g−1 at a current density of 1 A g−1 and 275 F g−1 at a high discharge current density of 10 A g−1. In addition, a symmetric supercapacitor composed of MoS2 as positive and negative electrodes was prepared, which exhibited a high energy density of 12.46 W h kg−1 at a power density of 70 W kg−1 and still maintains an impressive energy density of 6.42 W h kg−1 at a large power density of 7000 W kg−1. The outstanding performance of the MoS2 electrode material indicates its great potential for applications in high-performance energy storage systems.Three-dimensional flower-like molybdenum disulfide microspheres composed of nanosheets were prepared by a hydrothermal method using ammonium molybdate as the molybdenum source and thiourea as the sulfur source. 相似文献
9.
Mahesh Verma Rohit Yadav Lichchhavi Sinha Sawanta S. Mali Chang Kook Hong Parasharam
M. Shirage 《RSC advances》2018,8(70):40198
Hierarchical interconnected nanosheets (HIN) of cobalt manganese nickel sulfide (CoMnNiS) were synthesized on Ni foam by a simple and economical electrodeposition technique for energy storage application. Sulfonated thin nanosheets of Co, Mn and Ni provide stability of chemical activity, surface functionalization and surface reactivity to the electrode. The fabricated electrode shows a specific capacity of 257.4 mA h g−1 (at 2.5 A g−1), measured by galvanostatic charging–discharging (GCD). Both diffusion and capacitive mechanisms in the sulfide layer contribute to the high electrical conductivity. Asymmetric devices CoMnNiS/NiCuO and CoMnNiS/CNT (CNT = carbon nanotubes) were fabricated, providing a maximum operating voltage of 1.7 V and 1 V, specific capacity of 20.8 and 50.8 mA h g−1, and energy density of 8.4 and 6.3 W h kg−1 corresponding to a power density of 985 and 211 W kg−1, respectively, at a current density of 0.5 and 0.63 A g−1. These results demonstrate a novel material for application in energy storage devices as an electrode.Hierarchical interconnected nanosheets (HIN) of cobalt manganese nickel sulfide (CoMnNiS) were synthesized on Ni foam by a simple and economical electrodeposition technique for energy storage application. 相似文献
10.
Zhaojin Li Qian Liu Lizhi Sun Ning Li Xiaofeng Wang Qiujun Wang Di Zhang Bo Wang 《RSC advances》2021,11(53):33208
It is a considerable challenge to produce a supercapacitor with inexpensive raw materials and employ a simple process to obtain carbon materials with a high specific surface area, rich pore structure, and appropriate doping of heterogeneous elements. In the current study, yam waste-derived porous carbon was synthesized for the first time by a two-step carbonization and KOH chemical activation process. An ultra-high specific surface area of 2382 m2 g−1 with a pore volume of 1.11 cm3 g−1 and simultaneous co-doping of O–N was achieved for the optimized sample. Because of these distinct features, the optimized material exhibits a high gravimetric capacitance of 423.23 F g−1 at 0.5 A g−1 with an impressive rate capability at 10 A g−1, and prominent cycling durability with a capacity retention of 96.4% at a high current density of 10 A g−1 after 10 000 cycles in 6 M KOH in a three-electrode system. Moreover, in 6 M KOH electrolyte, the assembled symmetrical supercapacitor provides a large C of 387.3 F g−1 at 0.5 A g−1. It also presents high specific energy of 34.6 W h kg−1 when the specific power is 200.1 W kg−1 and a praiseworthy specific energy of 8.3 W h kg−1 when the specific power is 4000.0 W kg−1 in 1 M Na2SO4 electrolyte. Thus, this study provides reference and guidance for developing high-performance electrode materials for supercapacitors.3D porous carbon with ultra-high specific surface area and excellent electrochemical performance is synthesized by a simple activation and carbonization process through adopting biomass yam waste as raw material. 相似文献
11.
Recently, various metal–organic framework (MOF)-based supercapacitors (SCs) have received much attention due to their porosity and well-defined structures. Yet poor conductivity and low capacitance in most MOF-based devices limit their wide application. As an electrode material, 2D MOFs exhibit a rapid electron transfer rate and high specific surface area due to their unique structures. In this work, a 2D layered Ni-MOF is synthesized through a simple solvothermal method and serves as an electrode material for SCs. Electrochemical studies show that the Ni-MOF exhibits low charge transfer resistance, excellent specific capacitance of 1668.7 F g−1 at 2 A g−1 and capacitance retention of 90.3% after 5000 cycles at 5 A g−1. Moreover, Ni-MOF//AC asymmetric SCs are assembled. The device exhibits high specific capacitance of 161 F g−1 at 0.2 A g−1 and the energy density reached 57.29 W h kg−1 at a power density of 160 W kg−1. The high electrochemical performance can be ascribed to the inherent porosity of MOFs and the 2D layered structure.A 2D Ni-MOF was synthesized by a hydrothermal method and used as an electrode for SCs. 相似文献
12.
Vijeth H. Ashokkumar S. P. Yesappa L. Niranjana M. Vandana M. Devendrappa H. 《RSC advances》2018,8(55):31414
An asymmetric supercapacitor (ASC) was constructed using a polythiophene/aluminium oxide (PTHA) nanocomposite as an anode electrode and charcoal as a cathode electrode. The highest specific capacitance (Csp) of the PTHA electrode was found to be 554.03 F g−1 at a current density (CD) of 1 A g−1 and that of the charcoal electrode was 374.71 F g−1 at 1.4 A g−1, measured using a three electrode system. The maximum Csp obtained for the assembled PTHA//charcoal asymmetric supercapacitor (ASC) was 265.14 F g−1 at 2 A g−1. It also showed a high energy density of 42.0 W h kg−1 at a power density of 735.86 W kg−1 and capacitance retention of 94.61% even after 2000 cycles. Moreover, it is worth mentioning that the asymmetric device was used to illuminate a light emitting diode (LED) for more than 15 minutes. This PTHA//charcoal ASC also possesses stable electrochemical properties in different bending positions and hence finds a promising application in flexible, wearable and portable energy storage electronic devices.A high energy density flexible solid-state asymmetric supercapacitor is fabricated using polythiophene nanocomposites and charcoal which exhibits stable electrochemical properties in different bending position. 相似文献
13.
Yongquan Du Ruibin Liang Junxi Wu Yingyi Ye Shaoyong Chen Jian Yuan Jianwen Chen Peng Xiao 《RSC advances》2022,12(10):5910
NiCo metal–organic framework (MOF) electrodes were prepared by a simple hydrothermal method. The flower-like NiCo MOF electrode exhibited an exciting potential window of 1.2 V and an excellent specific capacitance of 927.1 F g−1 at 1 A g−1. The flower-like NiCo MOF//activated carbon (AC) device delivered a high energy density of 28.5 W hkg−1 at a power density of 400.5 W kg−1 and good cycle stability (95.4% after 5000 cycles at 10 A g−1). Based on the flower-like NiCo MOF electrode, the asymmetric quasi-solid-state flexible supercapacitor (AFSC) was prepared and exhibited good capacitance retention after bending (79% after 100 bends and 64.4% after 200 bends). Furthermore, two AFSCs in series successfully lit up ten parallel red LED lights, showing great application potential in flexible and wearable energy storage devices.The flower-like NiCo MOF prepared by a hydrothermal has a specific capacitance of 927.1 F g−1 at 1 A g−1 and a capacitance retention of 69.7% from 1 A g−1 to 10 A g−1, showing excellent electrochemical performance. 相似文献
14.
Nickel cobalt sulfide nanoparticles (NCS) embedded onto a nitrogen and sulfur dual doped graphene (NS-G) surface are successfully synthesized via a two-step facile hydrothermal process. The electrical double-layer capacitor of NS-G acts as a supporting host for the growth of pseudocapacitance NCS nanoparticles, thus enhancing the synergistic electrochemical performance. The specific capacitance values of 1420.2 F g−1 at 10 mV s−1 and 630.6 F g−1 at 1 A g−1 are achieved with an impressive capability rate of 76.6% preservation at 10 A g−1. Furthermore, the integrating NiCo2S4 nanoparticles embedding onto the NS-G surface also present a surprising improvement in the cycle performance, maintaining 110% retention after 10 000 cycles. Owing to the unique morphology an impressive energy density of 19.35 W h kg−1 at a power density of 235.0 W kg−1 suggests its potential application in high-performance supercapacitors.Newly developed in situ hydrothermal synthesis governs morphology of Ni–Co–S embedded on N–S doped graphene thus providing exceptional capacitive behavior. 相似文献
15.
Here, nickel–cobalt sulphide particles embedded in graphene layers (porous Ni–Co–S@G), were successfully prepared by one-step annealing of metallocene/metal–organic framework (MOF) hybrids involving simultaneous carbonization and sulfidation. Benefiting from the porous structure, highly conductive graphene layers and large loading of super-capacitive Ni–Co–S, the obtained Ni–Co–S@G composites exhibited excellent electrochemical performance with a specific capacitance of 1463 F g−1 at a current density of 1 A g−1. A flexible solid-state asymmetric supercapacitor (ASC), assembled with Ni–Co–S@G and active carbon, demonstrated a high energy density of 51.0 W h kg−1 at a power density of 650.3 W kg−1. It is noteworthy that the ASC offered robust flexibility and excellent performance that was maintained when the devices were bent at various angles. The results indicate that the as-prepared materials could potentially be applied in high-performance electrochemical capacitors.Ni–Co–S@graphene composites, derived from a metallocene/MOF precursor, presents high energy density and excellent cycling stability. 相似文献
16.
Guolang Zhou Jingzhou Yin Zechun Sun Xiaoliang Gao Fengxia Zhu Pusu Zhao Rongqing Li Jiaying Xu 《RSC advances》2020,10(6):3246
Biomass porous carbon materials are ideal supercapacitor electrode materials due to their low price, rich source of raw materials and environmental friendliness. In this study, an ultrasonic-assisted method was applied to synthesize the rice-straw-based porous carbon (UPC). The obtained UPC exhibited a two-dimensional structure and high specific surface area. In addition, the electrochemical test results showed that the UPC with a 1 hour ultrasonic treatment and lower activation temperature of 600 °C (UPC-600) demonstrated optimal performance: high specific capacitances of 420 F g−1 at 1.0 A g−1 and 314 F g−1 at a high current of 10 A g−1. Significantly, the symmetric supercapacitors showed a high energy density of 11.1 W h kg−1 and power density of 500 W kg−1. After 10 000 cycles, 99.8% of the specific capacitance was retained at 20 A g−1. These results indicate that UPC-600 is a promising candidate for supercapacitor electrode materials.Rice-straw-based porous carbon was successfully prepared via an ultrasonic-assisted method to lower activation temperature and for ultra-stable electrode materials of symmetric supercapacitors. 相似文献
17.
A simple polymerization process assisted with UV light for preparing a novel flexible polyelectrolyte-based gel polymer electrolyte (PGPE) is reported. Due to the existence of charged groups in the polyelectrolyte matrix, the PGPE exhibits favorable mechanical strength and excellent ionic conductivity (66.8 mS cm−1 at 25 °C). In addition, the all-solid-state supercapacitor fabricated with a PGPE membrane and activated carbon electrodes shows outstanding electrochemical performance. The specific capacitance of the PGPE supercapacitor is 64.92 F g−1 at 1 A g−1, and the device shows a maximum energy density of 13.26 W h kg−1 and a maximum power density of 2.26 kW kg−1. After 10 000 cycles at a current density of 2 A g−1, the all-solid-state supercapacitor with PGPE reveals a capacitance retention of 94.63%. Furthermore, the specific capacitance and charge–discharge behaviors of the flexible PGPE device hardly change with the bending states.A simple polymerization process assisted with UV light for preparing a novel flexible polyelectrolyte-based gel polymer electrolyte (PGPE) is reported. 相似文献
18.
Awais Ali Muhammad Ammar Muddassir Ali Zaid Yahya Muhammad Yasar Javaid Sadaf ul Hassan Toheed Ahmed 《RSC advances》2019,9(47):27432
A single-step hydrothermal route for synthesizing molybdenum doped zinc oxide nanoflakes was employed to accomplish superior electrochemical characteristics, such as a specific capacitance of 2296 F g−1 at current density of 1 A g−1 and negligible loss in specific capacitance of 0.01025 F g−1 after each charge–discharge cycle (up to 8000 cycles). An assembled asymmetric supercapacitor (Mo:ZnO@NF//AC@NF) also exhibited a maximum energy density and power density of 39.06 W h/kg and 7425 W kg−1, respectively. Furthermore, it demonstrated a specific capacitance of 123 F g−1 at 1 A g−1 and retained about 75.6% of its initial capacitance after 8000 cycles. These superior electrochemical characteristics indicate the potential of this supercapacitor for next-generation energy storage devices.Mo:ZnO nanoflakes were synthesized by single-step hydrothermal route to achieve superior electrochemical performance. 相似文献
19.
Yedluri Anil Kumar Araveeti Eswar Reddy Jin-Soo Bak In-Ho Cho Hee-Je Kim 《RSC advances》2019,9(37):21225
NF/ZnOx nanocone and NF/CoOx nanoparticle electrode materials were fabricated on a nickel foam surface using a simple chemical bath deposition approach and assessed as an electrode material for high-performance supercapacitors (SCs). The electrochemical properties of the NF/ZnOx and NF/CoOx electrodes were examined by cyclic voltammetry, galvanostatic charge–discharge tests, and electrochemical impedance spectroscopy. The fabricated NF/ZnOx and NF/CoOx SCs devices exhibited a good specific capacitance of 2437 and 2142 F g−1 at a current density of 20 mA g−1, respectively, in a three electrode system. Furthermore, the NF/ZnOx and NF/CoOx electrode materials showed acceptable long cycle-life stability with 97.8% and 95.8% specific capacitance retention after 3000 cycles at a current density of 22 mA g−1 in a 2 M aqueous KOH solution. Furthermore, the NF/ZnOx and NF/CoOx SCs showed a high energy density of 54.15 W h kg−1 and 47.6 W h kg−1 at a power density of 499.8 W kg−1 and 571.2 W kg−1, respectively, with maximum operating voltage of 0.5 V. Overall, NF/ZnOx and NF/CoOx electrode materials are promising electrodes for electrochemical energy storage applications.NF/ZnOx nanocone and NF/CoOx nanoparticle electrode materials were fabricated on a nickel foam surface using a simple chemical bath deposition approach and assessed as an electrode material for high-performance supercapacitors. 相似文献
20.
Flexible energy storage devices have received great interest due to the increasing demand for wearable and flexible electronic devices with high-power energy sources. Herein, a novel hybrid flexible hexagonal boron nitride integrated graphene paper (BN/GrP) is fabricated from 2D hexagonal boron nitride (h-BN) nanosheets integrated with graphene sheets dispersion via a simple vacuum filtration method. FE-SEM indicated that layered graphene nanosheets tightly confined with h-BN nanosheets. Further, the Raman spectroscopy confirmed successful integration of BN with graphene. As-prepared BN/GrP free-standing flexible conductive paper showed high electrical conductivity of 5.36 × 104 S m−1 with the sheet resistance of 8.87 Ω sq−1. However, after 1000 continuous bending cycles, the BN/GrP sheet resistance increased just about 8.7% which indicated good flexibility of the paper. Furthermore, as-prepared BN/GrP showed excellent specific capacitance of 321.95 F g−1 at current density of 0.5 A g−1. In addition, the power and energy densities were obtained as 3588.3 W kg−1, and 44.7 W h kg−1, respectively. The stability of the prepared flexible electrode was tested in galvanostatic charge/discharge cycles, where the results showed the 96.3% retention even after 6000 cycles. These results exhibited that the proposed BN/GrP may be useful to prepare flexible energy-storage systems.As-prepared BN/GrP free-standing flexible conductive paper showed high electrical conductivity of 5.36 × 104 S m−1 with the sheet resistance of 8.87 Ω sq−1. Furthermore, BN/GrP showed excellent specific capacitance of 321.95 F g−1 at current density of 0.5 A g−1. In addition, the power and energy densities were obtained as 3588.3 W kg−1, and 44.7 W h kg−1. 相似文献