Sprayable copper and copper–zinc nanowires inks for antiviral surface coating

Copper alloys are known for their high antimicrobial efficacy. Retrofitting high-touch surfaces in public space with solid copper components is expensive and often impractical. Directly coating copper onto these high-touch surfaces can be achieved with hot or cold spray, but the procedure is complicated and requires special equipment. This article reports on the development of sprayable copper and copper–zinc nanowire inks for antiviral surface coating applications. Our results show that copper nanowires inactivate the SARS-CoV-2 virus faster than bulk copper. And a trace amount of zinc addition has a significant effect in enhancing the virucidal effect. More importantly, these nanowire inks are sprayable. They can be easily applied on high-touch surfaces with a spray can. When combined with common chemical disinfectants, the copper-based nanowire ink spray may prolong the disinfecting effect well after application.

SEM and TEM images of copper and copper–zinc nanowires that are sprayable for antiviral surface coating.     

Efficient nickel or copper oxides decorated graphene–polyaniline interface for application in selective methanol sensing

Graphene sheets decorated with nickel or copper oxides that were anchored on polyaniline (denoted as PANI-graphene/NiO and PANI-graphene/CuO) were prepared by a simple, easy to-control electrochemical method and applied as novel materials for sensitive and selective methanol sensing. The fabricated sensors exhibited good electrocatalytic activity, appropriate dynamic linear range (20–1300 mM), sensitivity (0.2–1.5 μA mM⁻¹ cm⁻²) and excellent selectivity towards methanol. It should be highlighted from the selectivity tests that no significant interference was observed from ethanol and other alcohols. To our best knowledge, using inexpensive but efficient transition metals like Ni, Cu instead of Pt, Pd and their composites with PANI, graphene would be scientifically novel and practically feasible approach for sensor fabrication that could be potentially used to identify methanol adulteration in counterfeit alcoholic beverages.

PANI/graphene/NiO or PANI/graphene/CuO were prepared by a simple, easy to-control electrochemical method and applied as novel materials for sensitive and selective methanol sensing.     

Development of a nanoscale electroless plating procedure for bismuth and its application in template-assisted nanotube fabrication

Electroless plating is a versatile technique for the facile and controlled synthesis of metallic thin films and nanostructures. While there are numerous known procedures involving transition metals, reports on the electroless plating of post-transition metals are particularly rare, even without considering specific nanofabrication requirements. In this work we outline the development of a remarkably stable electroless plating bath for nanoscale bismuth coatings, based on the reduction of Bi–EDTA by borane dimethylamine. Its suitability for nanostructure fabrication is showcased by coating ion-track etched polycarbonate membranes, creating Bi tubes with sub-micron diameters in the process. This procedure could be particularly useful for the development and improvement of high surface-area Bi based catalysts and heavy metal sensors.

We outline the development of a remarkably stable electroless bismuth plating bath. Its nanofabrication potential is showcased by coating ion-track etched polymer membranes, enabling the synthesis of sub-micron diameter bismuth tubes.     

Waste eggshell membrane-templated synthesis of functional Cu2+–Cu+/biochar for an ultrasensitive electrochemical enzyme-free glucose sensor

A fast and sensitive test of blood glucose levels is very important for monitoring and reducing diabetic complications. Herein, a simple and sensitive non-enzymatic glucose sensing platform was fabricated by employing Cu²⁺–Cu⁺/biochar as the catalyst. The Cu²⁺–Cu⁺/biochar was synthesized through a bio-inspired synthesis, in which waste eggshell membrane (ESM) was introduced as a template to absorb Cu²⁺, then converting it into Cu²⁺–Cu⁺ biochar via a rapid pyrolysis. The structure and properties of the as-prepared Cu²⁺–Cu⁺ biochar were determined by scanning electron microscopy (SEM), FT-IR spectroscopy, Raman spectroscopy and cyclic voltammetry (CV). Due to great advantages of Cu²⁺–Cu⁺/biochar, such as high electrical conductivity, unique three-dimensional porous network and large electrochemically active surface area, the as-prepared Cu²⁺–Cu⁺ biochar modified electrode showed high catalytic activity towards glucose oxidization. The fabricated enzyme-free glucose sensor showed excellent performance for glucose determination with a linear range of 12.5–670 μM, and a limit of detection (LOD) of 1.04 μM. Moreover, the as-fabricated sensor has good anti-interference ability and stability. Finally, the proposed senor has been successfully applied to detect glucose in clinical samples (human serum). Owing to the green synthesis method, using biowaste ESM as a template, and the superior catalytic performance and low cost of Cu²⁺–Cu⁺/biochar, the developed sensor shows great potential in clinical applications for direct sensing of glucose.

The fabrication process of the nonenzyme glucose sensing based Cu²⁺–Cu⁺/biochar.     

A novel fabrication method of copper–reduced graphene oxide composites with highly aligned reduced graphene oxide and highly anisotropic thermal conductivity

Recently, metals with graphene and graphene oxide have been extensively used to enhance the mechanical and anisotropic thermal properties of composites. A novel facile fabrication approach of layer by layer self-assembly followed by hot press sintering was adopted to make copper–reduced graphene oxide composites. The microstructure and heat dissipation properties of pure copper and copper–reduced graphene oxide composites were analyzed with the help of SEM and continuous laser machine analysis. Thermal diffusivity of pure copper and copper–reduced graphene oxide composites was examined in different directions to measure the anisotropic thermal properties by using different volumetric percentages of reduced graphene oxide in the composites. Extraordinarily high anisotropic thermal conductivity of the copper–reduced graphene oxide composites was obtained at a very low concentration of 0.8 vol% reduced graphene oxide, with the difference between the thermal conductivity in-plane and through-plane being a factor of 8.82. Laser test results confirmed the highly anisotropic behavior of our copper–reduced graphene oxide composite with the remarkable property of heat dissipation. The three point bending test was also performed to check the flexural strength of the composites. At 0.6 vol% rGO, the flexural strength was noted (∼127 MPa), and it is 22% higher than that of pure sintered Cu. The high value of anisotropic thermal conductivity and higher flexural strength exhibited by the copper–reduced graphene oxide composite produced using a simple two-step fabrication method give us new hope to use these materials as heat sinks in thermal packaging systems.

Highly aligned rGO with anisotropic thermal conductivity was obtained in this work.     

Facile fabrication and low-temperature bonding of Cu@Sn–Bi core–shell particles for conductive pastes

The rapid development of flexible wearable electronics arouses huge demand for low-temperature sintering metal inks applied to temperature-sensitive substrates. The high sintering temperature and easy oxidation limited the application of Cu-based pastes. A two-step method involving liquid co-reduction and heat ripening was developed to synthesize Cu@Sn–Bi core–shell particles. The thickness of Sn–Bi shells can be flexibly adjusted via changing the mass ratio of Cu to Sn–Bi. The volume resistivity of printed circuits using Cu@Sn–Bi pastes solidified at 200 °C was as low as 481 μΩ cm, which increased by 11.8% after an aging process at 190 °C for 6 h. The outstanding stability in a harsh environment would attribute to the effective protection of Sn–Bi alloy shells. This work suggests a new pathway toward the low-temperature bonding and anti-oxidation of Cu particles as conductive fillers, which can be widely applied to the additive manufacturing of flexible wearable electronics.

Cu@Sn–Bi core–shell particles were synthesized and used as conductive fillers of ink applied to flexible printed circuits. This work provides new insights into the low-temperature bonding and anti-oxidation protection of Cu-based conductive pastes.     

Magnetization of graphene oxide nanosheets using nickel magnetic nanoparticles as a novel support for the fabrication of copper as a practical,selective, and reusable nanocatalyst in C–C and C–O coupling reactions

Catalyst species are an important class of materials in chemistry, industry, medicine, and biotechnology. Moreover, waste recycling is an important process in green chemistry and is economically efficient. Herein, magnetic graphene oxide was synthesized using nickel magnetic nanoparticles and further applied as a novel support for the fabrication of a copper catalyst. The catalytic activity of supported copper on magnetic graphene oxide (Cu–ninhydrin@GO–Ni MNPs) was investigated as a selective, practical, and reusable nanocatalyst in the synthesis of diaryl ethers and biphenyls. Some of the obtained products were identified by NMR spectroscopy. This nanocatalyst has been characterized by atomic absorption spectroscopy (AAS), scanning electron microscopy (SEM), wavelength dispersive X-ray spectroscopy (WDX), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometer (VSM) techniques. The results obtained from SEM shown that this catalyst has a nanosheet structure. Also, XRD and FT-IR analysis show that the structure of graphene oxide and nickel magnetic nanoparticles is stable during the modification of the nanoparticles and synthesis of the catalyst. The VSM curve of the catalyst shows that this catalyst can be recovered using an external magnet; therefore, it can be reused several times without a significant loss of its catalytic efficiency. The heterogeneity and stability of this nanocatalyst during organic reactions was confirmed by the hot filtration test and AAS technique.

Catalytic activity of supported copper on magnetic graphene oxide was investigated as a selective and reusable nanocatalyst in the synthesis of diaryl ethers and biphenyls.     

The kinetics process of a Pb(ii)/Pb(0) couple and selective fabrication of Li–Pb alloys in LiCl–KCl melts

The electrode reaction of Pb(ii) and co-reduction of Li(i) and Pb(ii) were investigated on a tungsten electrode in LiCl–KCl eutectic melts by a range of electrochemical techniques. From cyclic voltammetry and square wave voltammetry measurements, the reduction of Pb(ii) was found to be a one-step diffusion-controlled reversible process with the exchange of 2 electrons. The diffusion coefficients of Pb(ii) were computed, and they obey the Arrhenius law. Using the linear polarization technique, the kinetic parameters, such as exchange current intensity (j₀), standard rate constant (k⁰) and charge transfer resistance (R_ct) for the Pb(ii)/Pb(0) couple on a tungsten electrode were studied at different temperatures, and the activation energy is 27.32 kJ mol⁻¹, smaller than the one for diffusion of Pb(ii), which further confirmed that the reduction of Pb(ii) was controlled by diffusion. A depolarisation effect for Li(i) reduction was observed from the results of cyclic voltammetry, square wave voltammetry and chronopotentiometry due to the formation of Li–Pb alloys by co-reduction of Li(i) and Pb(ii). Furthermore, five Li–Pb intermetallic compounds, LiPb, Li₈Pb₃, Li₃Pb, Li₁₀Pb₃ and Li₁₇Pb₄ characterized by scanning electronic microscopy and X-ray diffraction, were selectively prepared by potentiostatic electrolysis on a tungsten electrode and galvanostatic electrolysis on a liquid Pb electrode, respectively.

Five Li–Pb intermetallic compounds are selectively prepared according to their deposition potentials and characterized by XRD and SEM.     

A dual-functional luminescent Tb(iii) metal–organic framework for the selective sensing of acetone and TNP in water

Herein, a novel water-stable luminescent terbium metal–organic framework, {[Tb(L₁)(L₂)_0.5(NO₃)(DMF)]·DMF}_n (TPA-MOF), with 1,10-phenanthroline (phen) and 3,3′,5,5′-azobenzene-tetracarboxylic acid (H₄abtc) ligands was solvothermally synthesized and structurally characterized. TPA-MOF possesses a two-dimensional (2D) extended framework featuring an 8-connected uninodal SP2-periodic net topology with the Schläfli point symbol of {3^12;4^14;5^2}. The π-electron rich luminescent TPA-MOF exhibits four characteristic emission bands of Tb³⁺ ion and acts as a selective and sensitive probe for acetone as well as the electron deficient 2,4,6-trinitrophenol (TNP). Moreover, gas sorption studies confirm that TPA-MOF displays ultra-micropores and adsorbs moderate amounts of N₂ and CO₂.

A novel 2D luminescent terbium metal–organic framework demonstrating highly efficient and selective sensing for acetone and 2,4,6-trinitrophenol (TNP) in an aqueous solution was solvothermally synthesized and structurally characterized.     

Colorimetric sensing of glucose and GSH using core–shell Cu/Au nanoparticles with peroxidase mimicking activity

The catalytic properties of bimetallic nanoparticles have been widely studied by researchers in many fields. In this paper, core–shell Cu/Au nanoparticles (Cu/Au NPs) were synthesized by a simple and mild one-pot method, and their peroxidase activity was proved by catalyzing the oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) with color change to blue. The change of solution color and absorbance strongly depends on the concentration of H₂O₂, so it can be used for direct detection of H₂O₂ and indirect detection of glucose. What''s more, GSH can efficiently react with the hydroxyl radicals from H₂O₂ catalyzed by core–shell Cu/Au NPs to inhibit the production of ox-TMB. Thus, the concentration of GSH can be determined by the decrease in the absorbance of the solution at 652 nm. The results showed that our proposed strategy had good detection range and detection limit for the detection of glucose and GSH. This method has been used in the detection of practical samples and has great application potential in environmental monitoring and clinical diagnosis.

Core–shell Cu/Au nanoparticles were synthesized by a one pot method, their peroxidase activity was proved by catalysing the oxidation of 3,3′,5,5′-tetramethylbenzidine with colour change to blue. Results showed a good range and limit for the detection of glucose and GSH.     

Assembly with copper(ii) ions and D–π–A molecules on a graphene surface for ultra-fast acetic acid sensing at room temperature

In this study, a graphene-based composite 4HQ-rGO/Cu²⁺ was prepared via the supramolecular assembly of graphene nanosheets with 4-hydroxyquinoline (4HQ) and copper(ii) ions. The as-prepared supramolecular assembly exhibited an excellent and enhanced sensing performance towards acetic acid at room-temperature, which was due to the fact that the D–π–A molecules, i.e. 4HQ, were able to accelerate the charge transfer between the graphene nanosheets and 4HQ molecules when acetic acid was attached. In addition, at room temperature, the copper(ii) ions also played a critical role as the main active site for gas adsorption, and thus the as-fabricated sensor exhibited a high response, outstanding selectivity, and ultra-fast response/recovery time. To examine the selectivity of the Cu²⁺ ions for the supramolecular assembly, various other transition metal ions such as Mn²⁺, Fe³⁺, Co²⁺, Ni²⁺, Cu²⁺, and Cd²⁺ were attached to the 4HQ-rGO assembly, and their acetic sensing performance was determined. Interestingly, the supramolecular assembly with the Cu²⁺ ions (4HQ-rGO/Cu²⁺) exhibited the best sensing performance compared to other metal ion-based 4HQ-rGO materials. Compared with the typical acetic acid gas sensors reported in the literature, it is noteworthy to mention that the as-prepared 4HQ-rGO/Cu²⁺ supramolecular assembly exhibited the shortest gas response time (within 5 s) at room temperature. The presented study demonstrates that the as-prepared supramolecular assembly is a promising material as a room temperature acetic acid gas sensor in practical applications.

The as-prepared 4HQ-rGO/Cu²⁺ sensor possessed a high response, outstanding selectivity and fast response-recovery characteristic, which was mainly attributed to the supramolecularly assemble of 4-hydroxyquinoline, and Cu²⁺ with graphene nanosheets.     

Amino group dependent sensing properties of metal–organic frameworks: selective turn-on fluorescence detection of lysine and arginine

Recently, metal–organic frameworks (MOFs) have been extensively investigated as fluorescence chemsensors due to their tunable porosity, framework structure and photoluminescence properties. In this paper, a well-known Zr(iv)-based MOF, UiO-66-NH₂ was demonstrated to have capability for detection of l-lysine (Lys) and l-arginine (Arg) selectively from common essential amino acids in aqueous media via a fluorescence turn-on mechanism. Further investigation reveals its high sensitivity and strong anti-interference properties. Moreover, the possible mechanism for sensing Lys and Arg was explored by FT-IR and ¹H-NMR, and the results indicate that the enhancement of the fluorescence could be ascribed to the adsorption of Lys/Arg and the hydrogen bonding interactions between Lys/Arg and the amino group of UiO-66-NH₂. The difference of the sensing capacity and sensitivity between UiO-66 and UiO-66-NH₂ revealed that the amino group plays an essential role in the sensing performance. This work presents a unique example of the functional group dependent sensing properties of MOFs.

The amino group of UiO-66-NH₂ was demonstrated to play an important role in selective fluorescence turn-on sensing of lysine and arginine.     

Synthesis and spectroscopic investigation of a novel sensitive and selective fluorescent chemosensor for Ag+ based on a BINOL–glucose derivative

Based on a versatile 2,2′-binaphthol (BINOL) backbone, a novel BINOL–glucose derivative fluorescent sensor was synthesized using a click reaction. The fluorescence responses of the BINOL–glucose derivative (S,β-d)-1 conclude that it can be used as a specific fluorescent chemical sensor for Ag⁺ in the presence of a large number of competing metal ions without any obvious interference from other metal ions. Mass spectrometric and NMR spectroscopic data were used to study the mechanism, and implied the formation of a 1 + 1 complex between BINOL–glucose 1 and Ag⁺. Both the oxygen atoms of S-BINOL and two nitrogen atoms of triazole were involved in coordinating the silver ion.

A BINOL–glucose derivative fluorescent sensor was synthesized to detect only Ag⁺ with high selectivity and sensitivity in a 1 + 1 formation.     

Bimetallic cobalt–iron diselenide nanorod modified glassy carbon electrode: an electrochemical sensing platform for the selective detection of isoniazid

The increasing demand of a sensitive and portable electrochemical sensing platform in pharmaceutical analysis has developed widespread interest in preparing electrode materials possessing remarkable properties for the electrochemical determination of target drug analytes. Herein, we report the synthesis, characterization and application of bimetallic cobalt-iron diselenide (FeCoSe₂) nanorods as electrode modifiers for the selective detection of a commonly used anti-tuberculosis drug Isoniazid (INZ). We prepared FeCoSe₂ nanorods by a simple hydrothermal route and characterized these by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and temperature-programmed reduction (TPR) techniques. The electrochemical characterization of FeCoSe₂ modified GCE was performed by cyclic voltammetry (CV) and square wave anodic stripping voltammetry (SWASV). Under optimized experimental conditions, a linear current-concentration response was obtained for INZ in the range of 0.03–1.0 μM, with very low limit of detection 1.24 × 10⁻¹⁰ M. The real applicability of the designed FeCoSe₂/GCE sensing platform was adjudicated by the detection of INZ in biological samples.

FeCoSe₂ bimetallic nanorods were synthesized by hydrothermal method. The modified electrode responded excellently towards isoniazid detection with LOD of 1.24 × 10⁻¹⁰ M. FeCoSe₂/GCE showed applicability for INZ detection in real samples.     

One pot fabrication of fluorescein functionalized manganese dioxide for fluorescence “Turn OFF–ON” sensing of hydrogen peroxide in water and cosmetic samples

In recent decades, H₂O₂ has been promoted as a health indicator because its moderate to high levels can cause some health problems. Herein, we developed a new fluorescent nanoprobe for rapid, selective and sensitive detection of H₂O₂. The fluorescent nanoprobe is composed of fluorescein dye (FLS) as a fluorescent probe and MnO₂ nanosheets (MnO₂ NS) as a quencher. In this study, H₂O₂ can reduce MnO₂ NS in the synthesized composite and release FLS, causing sufficient recovery of fluorescent signal related to the concentration of H₂O₂. The nanoprobe, with λ_ex/λ_em at 495/515 nm, has a linear range of 0.04–30 μM, with a limit of detection (LOD) of 7.5 nM and a limit of quantitation (LOQ) of 21 nM. The mean relative standard deviation (RSD) was 2.6% and the applicability of the method was demonstrated by the determination of H₂O₂ in water and cosmetic samples.

The fluorometric nanoprobe was fabricated via doping of fluorescein dye in MnO₂ nanosheets (FLS/MnO₂ NS) via facile co-precipitation method. It was used for analysis of H₂O₂ in different matrices through liberation of FLS after reduction of MnO₂ NS.     

Boronate sol–gel method for one-step fabrication of polyvinyl alcohol hydrogel coatings by simple cast- and dip-coating techniques

The self-assembly of polyvinyl alcohol (PVA) and benzene-1,4-diboronic acid (DBA) is employed as a sol–gel method for one-step fabrication of hydrogel coatings with versatile functionalities. A mixture of PVA and DBA in aqueous ethanol is prepared as a coating agent. The long pot life of the mixture allows for the coating of a wide range of materials with hydrogel films by simple cast- and dip-coating techniques. The resultant films show negligible dissolution in water and the intrinsic hydrophilicity of PVA provides the films with functional properties, such as improved antifogging property and resistance to protein and cell fouling. The self-assembling process shows adaptive inclusion properties toward nanoscale materials, such as metal–organic coordination polymers and inorganic nanoparticles, affording composite films. Furthermore, the coating film exhibits a unique secondary functionalization reactivity toward boronic acid-appended fluorescent dyes, through which a variety of materials are converted into fluorescent materials.

The self-assembly of polyvinyl alcohol (PVA) and benzene-1,4-diboronic acid (DBA) is employed as a sol–gel method for one-step fabrication of hydrogel coatings with versatile functionalities.     

Synthesis and application of tuneable carbon–silica composites from the microwave pyrolysis of waste paper for selective recovery of gold from acidic solutions

Microwave pyrolysis bio-oil from waste paper and K60 silica gel has successfully been utilised to synthesise mesoporous carbon–silica composites with uniquely tuneable surface properties, where functionality and structural characteristics can be altered and even enhanced by curing at different temperatures. This temperature-dependence resulted in composites ranging from highly oxygenated polymerised bio-oil composites at 300 °C to aromatic carbonaceous materials covering the silica surface at 800 °C, making them attractive materials for gold recovery from mining wastewater. The composite materials exhibit exceptional ability and selectivity to recover gold from dilute solutions. Metal adsorption on the surface of these composites proceeded via both chemisorption and physisorption leading to the reduction of Au(iii) to Au(0), resulting in high recovery capacities for gold. Composite material prepared at 500 °C demonstrated the optimum combination of surface functionality and porosity, allowing for an adsorption capacity of 320 mg g⁻¹ of gold and with 99.5% removal being achieved at concentrations mimicking those of real-life mine tailing wastes. All materials pioneered in this research display great potential as selective adsorbents for the recovery of gold from acidic media.

Microwave pyrolysis bio-oil from waste paper and K60 silica gel have been utilised to synthesise mesoporous carbon–silica composites with uniquely tuneable surface properties for the selective recovery of gold from acidic solutions.     

Temperature-induced structural diversity of metal–organic frameworks and their applications in selective sensing of nitrobenzene and electrocatalyzing the oxygen evolution reaction

Structural diversities are presented in four new Co-MOFs containing 1,5-bi(imidazolyl)anthracene and different dibenzobarrelene skeletons based on dicarboxylic acid, in which MOFs 1–3 exhibit 2D networks in a 4-connected node sql topology with the point symbol of {4⁴·6²}, while MOF 4 forms a 1D chain structure. It is clearly observed that the 2D-1D structural transformation of 2–4 has been realized by temperature modulated hydrothermal synthesis procedures from 120–160 °C, suggesting the key role of temperature for constructing MOFs. In addition, obvious π–π interactions between anthracene rings can be observed in the architectures of 1–3, which may favorably stabilize their 2D supramolecular networks. More importantly, fluorescence behaviors of 1–4 have been investigated in water among various nitro-aromatic compounds (NACs) and the results show that all samples exhibit high selectivity and fine sensitivity to nitrobenzene (NB) with fluorescence quenching, which is confirmed to be the result of electron transfer from the excited state of ligands to that of NB by density functional theory. Furthermore, MOFs 1–4 have been directly employed as electrocatalysts for the oxygen evolution reaction (OER), in which MOF 4 gives the best activity towards the OER among all as-synthesized samples with an overpotential of 398 mV at a current density of 10 mA cm⁻² and a low Tafel slope of 59 mV dec⁻¹.

Structure diversities can be observed in four new Co-MOFs by temperature modulated hydrothermal synthesis, which show high selectivity to nitrobenzene (NB) as well as promising oxygen evolution reaction (OER) activities.     

Selective sensing and visualization of pesticides by ABW-type metal–organic framework based luminescent sensors

A new ABW-type luminescent metal–organic framework (MOF) namely (H₃O)[Zn₂L(H₂O)]·3NMP·6H₂O (1), constructed with eco-friendly Zn²⁺ and the multicarboxylate intraligand (LH₅) was designed, synthesized and fully characterized by X-ray single-crystal diffraction, steady-state absorption and emission spectroscopy, and SEM observations. The MOF-based suspension sensor 1 (NMP) demonstrated high sensitivity to low-concentration pesticides of chlorothalonil (CTL), nitrofen (NF), trifluralin (TFL), and 2,6-dichloro-4-nitroaniline (DCN), which was assigned to the synergistic effect of the photoinduced electron transfer and the fluorescence resonance energy transfer. With the highest luminescent detection efficiency (K_SV up to 11.194 μmol⁻¹ and LOD down to 2.93 ppm) to DCN, 1 (NMP) was successfully applied for the selective sensing of DCN. The MOF-based film sensor 1 (film) illustrated the selective visualization sensing of trace amounts of DCN. In addition, based on the high saturated vapor pressure of TFL and the unique bathochromic shift effect to the emission maxima of 1, the MOF-based luminescent vapor sensing device 1 (LED) successfully exhibited operability for sensing of TFL vapor. The results illustrated a feasible approach to construct new MOF-based luminescent sensors for selective sensing and visualization of pesticides.

A novel ABW-type luminescent metal–organic framework was applied for selective visualization sensing of trace amounts of 2,6-dichloro-4-nitroaniline and vapor sensing of trifluralin.     

Advancing fabrication and properties of three-dimensional graphene–alginate scaffolds for application in neural tissue engineering

Neural tissue engineering provides enormous potential for restoring and improving the function of diseased/damaged tissues and promising opportunities in regenerative medicine, stem cell technology, and drug discovery. The conventional 2D cell cultures have many limitations to provide informative and realistic neural interactions and network formation. Hence, there is a need to develop three-dimensional (3D) bioscaffolds to facilitate culturing cells with matched microenvironment for cell growth and interconnected pores for penetration and migration of cells. Herein, we report the synthesis and characterization of 3D composite bioscaffolds based on graphene-biopolymer with porous structure and improved performance for tissue engineering. A simple, eco-friendly synthetic method is introduced and optimized for synthesis of this hybrid fibrous scaffold by combining Graphene Oxide (GO) and Sodium Alginate (Na-ALG) which are specifically selected to match the mechanical strength of the central nervous system (CNS) tissue and provide porous structure for connective tissue engineering. Properties of the developed scaffold in terms of the structure, porosity, thermal stability, mechanical properties, and electrical conductivity are presented. These properties were optimised through key synthesis conditions including GO concentrations, reduction process and crosslinking time. In contrast to other studies, the presented structure maintains its stability in aqueous media and uses a bio-friendly reducing agent which enable the structure to enhance neuron cell interactions and act as nerve conduits for neurological diseases.

In this study, a bio-fabrication method has been developed for the preparation of 3D graphene–alginate composite scaffolds with great potential for neural tissue engineering.