A facile synthesis of Zn-doped TiO2 nanoparticles with highly exposed (001) facets for enhanced photocatalytic performance

It is a great challenge to simultaneously improve the visible light absorption capacity and enhance photon-generated carrier separation efficiency of photocatalysts. Herein, Zn-doped TiO₂ nanoparticles with high exposure of the (001) crystal face were prepared via a one-step hydrothermal decomposition method. A detailed analysis reveals that the electronic structures were modulated by Zn doping; thus, the responsive wavelength was extended to 600 nm, which effectively improved the visible light absorption of TiO₂. More importantly, the surface heterojunction of TiO₂ was created because of the co-existing specific facets of (101) and (001). Therefore, the surface separation efficiency of photogenerated electron and hole pairs was greatly enhanced. So, the optimal TiO₂ photocatalyst exhibited excellent photocatalytic activity, in which the Rhodamine B (RhB) degradation efficiency was 98.7% in 60 min, under the irradiation of visible light. This study is expected to provide guidance for the rational design of TiO₂ photocatalysts.

It is a great challenge to simultaneously improve the visible light absorption capacity and enhance photon-generated carrier separation efficiency of photocatalysts.     

Photocatalytic degradation of methylene blue by a cocatalytic PDA/TiO2 electrode produced by photoelectric polymerization

This study reports a new method for photocatalysts to degrade organic dyes on organic semiconductors. A novel strategy is reported to form TiO₂ nanorod (NR)/polydopamine (PDA) electrodes with a photoelectric polymerization strategy for PDA (pep-PDA) to produce cocatalytic electrodes. Amperometric i–t curves and UV-vis diffuse reflectance spectra were recorded and showed that compared with traditional self-polymerization (sp-PDA) and electropolymerization (ep-PDA), TiO₂ NR/pep-PDA exhibited an enhanced photocatalytic activity under visible light. As expected, TiO₂ NR/pep-PDA showed a significant improvement for the degradation of methylene blue (MB) under visible light, which can be attributed to the strong absorption of PDA in the visible light region and the more complete and uniform coverage of the TiO₂ NRs by the pep-PDA film. This study not only proposes a novel and highly efficient way to load PDA on TiO₂ NRs but also provides useful insights for the loading of other photocatalysts on organic semiconductors to degrade organic dyes.

This study reports a new method for photocatalysts to degrade organic dyes on organic semiconductors.     

Unbiased spontaneous solar hydrogen production using stable TiO2–CuO composite nanofiber photocatalysts

We report on the optimization of electrospun TiO₂–CuO composite nanofibers as low-cost and stable photocatalysts for visible-light photocatalytic water splitting. The effect of different annealing atmospheres on the crystal structure of the fabricated nanofibers was investigated and correlated to the photocatalytic activity of the material. The presence of CuO resulted in narrowing the bandgap of TiO₂ and shifting the absorption edge into the visible region of the light spectrum. The effect of incorporating CuO within TiO₂ nanofibers on the crystal structure and composition was also investigated using X-ray diffraction (XRD), electron paramagnetic resonance (EPR), and X-ray photoelectron spectroscopy (XPS) techniques. The fabricated TiO₂–CuO composite nanofibers showed 117% enhancement in the amount of hydrogen evolved during the photocatalytic water splitting process compared to pure TiO₂. This enhancement was related to the created shallow defect states that facilitate charge transfer from TiO₂ to CuO and distinct characteristics of the composite nanofibers, such as the high surface area and directional charge transfer. The study showed that Cu is a promising alternative to noble metals as a catalyst in photocatalytic water splitting, with the advantage of being an Earth abundant element and a relatively cheap material.

We report on the optimization of electrospun TiO₂–CuO composite nanofibers as low-cost and stable photocatalysts for visible-light photocatalytic water splitting.     

Enhanced photocatalytic performance of carbon fiber paper supported TiO2 under the ultrasonic synergy effect

In the present work, TiO₂ rutile nanorods and anatase nanoflakes have been grown on carbon fiber paper (CFP) by the hydrothermal method. Their photoelectrochemical properties and photocatalytic performances have been investigated. The introduction of CFP is found to improve visible light absorption intensity and effective surface areas apparently, and also make TiO₂ photocatalysts easier to recycle from aqueous waste. An ultrasonic field was employed during the process of photocatalysis. Sono-photocatalytic efficiency is found to be enhanced significantly in comparison with those of photocatalysis and sonocatalysis, which indicates a positive ultrasonic synergy effect. The scavenger experiments reveal that superoxide radicals (˙O₂⁻) and hydroxyl (˙OH) are the predominant active species during the dye degradation sono-photocatalytic process assisted by CFP-supported TiO₂ catalysts. To investigate the ultrasonic synergy photocatalytic effect, the generated amount of reactive oxygen species (ROS) was detected and quantitatively evaluated under visible light, ultrasound, and the combined condition of visible light and ultrasound. As a result, the present work provides an efficient way to improve photocatalytic performance and to realize easy recovery of photocatalyst, which will be helpful for better design of advanced photocatalysts for practical applications.

SEM images of TiO₂(R) nanorods and TiO₂(A) nanoflakes grown on CFP. And the corresponding catalytic performances under solely visible light, solely ultrasonic field, and the combined conditions of visible light and ultrasonic field.     

Origin of the enhanced photocatalytic activity of (Ni,Se, and B) mono- and co-doped anatase TiO2 materials under visible light: a hybrid DFT study

The characteristic properties of TiO₂ (anatase) make doping necessary to enhance its photocatalytic activity. Herein, a density functional theory (DFT) study using the Heyd–Scuseria–Ernzerhof (HSE) hybrid functional was performed to precisely investigate the effect of mono- and co-doping (Ni, Se and B) on the structural, electronic and optical properties of anatase TiO₂. Notably, the origin of the enhanced photocatalytic activity of the modified systems was determined. The response to visible light was enhanced for all the mono- and co-doped materials except for B_int, and the highest absorption coefficient was observed for Se⁴⁺ mono-doping and Se/B_int+sub and Ni/B_sub co-doping. The decrease in bandgap is associated with a red shift in the absorption edges with the smallest bandgap calculated for Ni/B_sub (2.49 eV). Additionally, the Ni, Se⁴⁺ and Se²⁻ mono-doped systems and Ni/Se⁴⁺ co-doped systems are proposed as promising photocatalysts for water splitting applications and further experimental validation. Moreover, the Ni/B_int+sub and Se/B_int+sub co-doped materials can also be valuable photocatalysts for other energy applications due to their enhanced visible light activity and the prolonged lifetime of their produced charge carriers.

Hybrid DFT calculations demonstrate that Ni, Se⁴⁺ and Se²⁻ mono-doped and Ni/Se⁴⁺ co-doped TiO₂ are potential photocatalysts for water splitting and hydrogen production.     

Controllable growth of three-dimensional CdS nanoparticles on TiO2 nanotubes to enhance photocatalytic activity

Exploiting photocatalysts with characteristics of low cost, high reactivity and good recyclability is a great significance for environmental remediation and energy conversion. Herein, hollow TiO₂ nanotubes were fabricated by a novel and efficient method via electrospinning and an impregnation calcination method. With the hydrothermal method, the CdS nanoparticles were modified on the surface and in walls of the TiO₂ nanotubes. By changing the reaction conditions, the morphology of CdS nanoparticles presents a controllable three-dimensional (3D) structure. The morphology of the samples was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The structure and components of samples were characterized by X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX) and X-ray photoelectron spectroscopy (XPS). The light absorption efficiency was detected using UV-vis diffuse reflectance spectroscopy (DRS) and photoluminescence (PL). The photocatalytic properties were evaluated by degradation of methyl orange (MO) and photocatalytic hydrogen evolution under visible light irradiation. From the results, the TiO₂/CdS nanotubes exhibit better photocatalytic activity than the pure TiO₂. The synthetic mechanism of TiO₂/CdS heterostructures and a possible photocatalytic mechanism based on the experimental results were proposed.

Exploiting photocatalysts with characteristics of low cost, high reactivity and good circularity is a great significance for environmental remediation and energy conversion.     

Goethite–titania composite: disinfection mechanism under UV and visible light

Goethite–titania (α-FeOOH–TiO₂) composites were prepared by co-precipitation and mechanical milling. The structural, morphological and optical properties of as-synthesized composites were characterized by X-ray powder diffraction, scanning electron microscopy and UV-Vis diffuse reflectance spectroscopy, respectively. α-FeOOH–TiO₂ composites and TiO₂-P25, as reference, were evaluated as photocatalysts for the disinfection of Escherichia coli under UV or visible light in a stirred tank reactor. α-FeOOH–TiO₂ exhibited better photocatalytic activity in the visible region than TiO₂-P25. The mechanical activation increased the absorption in the visible range of TiO₂-P25 and the photocatalytic activity of α-FeOOH–TiO₂. In the experiments with UV light and α-FeOOH–TiO₂, mechanically activated, a 5.4 log-reduction of bacteria was achieved after 240 min of treatment. Using visible light the α-FeOOH–TiO₂ and the TiO₂-P25 showed a 3.1 and a 0.7 log-reductions at 240 min, respectively. The disinfection mechanism was studied by ROS detection and scavenger experiments, demonstrating that the main ROS produced in the disinfection process were superoxide radical anion, singlet oxygen and hydroxyl radical.

A photocatalytic mechanism for FeOOH–TiO₂ composite is proposed under UV-Vis light, the FeOOH–TiO₂ composite showed higher photocatalytic activity than TiO₂-P25.     

Synthesis and photocatalytic properties of three dimensional laminated structure anatase TiO2/nano-Fe0 with exposed (001) facets

Three dimensional laminated structure anatase TiO₂/nano-Fe⁰ with exposed (001) facets used as photocatalysts were synthesized by a two-step solvothermal route and a liquid phase reduction deposition method. The resulting samples were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy, scanning electron microscopy, transmission electron microscopy and selected-area electron diffraction. Characterization and experimental results indicated that the three dimensional laminated structure of anatase TiO₂ was assembled by two dimensional TiO₂-sheets with a thickness of approximately 30 nm. The three dimensional laminated structure anatase TiO₂/nano-Fe⁰ photocatalysts with improved visible-light responsive capability, high charge-hole mobility, and low electron–hole recombination exhibited higher photocatalytic performance in the photocatalytic degradation of methylene blue. The composite of nano-Fe⁰ and TiO₂ could effectively promote the generation of hydroxyl radicals (˙OH) with a synergistic effect and Photo-Fenton theory. This study provided new insights into the fabrication and practical application of high-performance photocatalysts in degrading organic pollutants.

Three dimensional laminated structure anatase TiO₂/nano-Fe⁰ with exposed (001) facets were successfully synthesized, which exhibited higher photocatalytic performance in the photocatalytic degradation of methylene blue.     

A facile method for the preparation of black TiO2 by Al reduction of TiO2 and their visible light photocatalytic activity

Black TiO₂ has attracted widespread attention due to its visible light absorption and wide range of applications. However, the currently reported preparation methods for black TiO₂ are not suitable for large-scale production due to its being prepared under high vacuum and over a long time. We have successfully prepared black TiO₂ under normal pressure and short time conditions. The as-prepared black titanium dioxide was characterized by XRD, XPS, TEM, UV-visible absorption spectrum and other characterization methods. The result shows that the as prepared black titanium dioxide had a disordered structure and oxygen vacancy defects on the surface, and exhibits excellent visible and near infrared absorption performance. The black TiO₂ sample was prepared under 650 °C 60 min exhibits excellent visible light photocatalytic performance, and can degrade 56% MO after visible light irradiation for 120 min.

Black TiO₂ has attracted widespread attention due to its visible light absorption and wide range of applications.     

Construction of carbon quantum dots/single crystal TiO2 nanosheets with exposed {001} and {101} facets and their visible light driven catalytic activity

Carbon quantum dots were successfully doped into anatase TiO₂ single crystal nanosheets (TNS) with exposed {001} and {101} reactive facets by a facile solvothermal process. SEM and TEM confirmed the as-prepared TiO₂ nanosheet structure and that the dominant exposed face is the {001} facet, and the loaded N-CDs are nearly spherical with an average size of about 3 nm. XPS results confirmed that the deposited N-CDs were chemically integrated into the TiO₂ nanosheets. UV-vis DRS spectroscopy shows that with the dotting of N-CDs, the absorption edge of N-CDs/TNS has been extended into the visible light region. The ability of the N-CDs/TNS to degrade Rhodamine B (RhB) in aqueous solution under visible light irradiation (λ ≥ 400 nm) was investigated. The results show that the photocatalytic performance of N-CDs/TNS was substantially improved relative to pure TNS. The photodegradation efficiency reached its maximum value with 6 mL of N-CDs/TNS, showing a 9.3-fold improvement in photocatalytic activity over TNS. Fluorescence spectroscopy (PL) and electron paramagnetic resonance (EPR) studies were conducted to characterize the active species during the degradation period, based on which the possible photodegradation mechanism of N-CDs/TNS by visible light irradiation was given.

Carbon quantum dots were doped into anatase TiO₂ single crystal nanosheets (TNS) with highly exposed {001} and {101} reactive facets by a facile solvothermal process.     

Enhanced photocatalytic activity of TiO2/UiO-67 under visible-light for aflatoxin B1 degradation

TiO₂ has great potential in photocatalytic degradation of organic pollutants, but poor visible light response and low separation efficiency of photogenerated electron–hole pairs limit its wide applications. In this study, we have successfully prepared TiO₂/UiO-67 photocatalyst through an in situ solvothermal method. The degradation rate of aflatoxin B1 (AFB1) is 98.9% in only 80 min, which is superior to the commercial P25, commercial TiO₂ and most of reported photocatalysts under visible light irradiation. In addition, the TiO₂/UiO-67 photocatalyst showed excellent recyclability. We demonstrated that the enhanced photocatalytic mechanism was owing to the heterojunction between TiO₂ and UiO-67, which enhanced effectively the separation photogenerated charge carriers and visible light response. The free radical trapping tests demonstrated that superoxide radicals (˙O₂⁻), holes (h⁺) and hydroxyl radicals (˙OH) were the main active species and then oxidized AFB1 to some small molecules.

Enhanced photocatalytic activity of TiO₂/UiO-67 under visible-light for aflatoxin B1 degradation.     

Rationally designed La and Se co-doped bismuth ferrites with controlled bandgap for visible light photocatalysis

Development of efficient visible light photocatalysts for water purification and hydrogen production by water splitting has been quite challenging. The activities of visible light photocatalysts are generally controlled by the extent of absorption of incident light, band gap, exposure of catalyst surface to incident light and adsorbing species. Here, we have synthesized nanostructured, La and Se co-doped bismuth ferrite (BLFSO) nanosheets using double solvent sol–gel and co-precipitation methods. Structural analysis revealed that the La and Se co-doped BFO i.e. Bi_0.92La_0.08Fe_1−xSe_xO₃ (BLFSO) transformed from perovskite rhombohedral to orthorhombic phase. As a result of co-doping and phase transition, a significant decrease in the band gap from 2.04 eV to 1.76 eV was observed for BLFSO-50% (having Se doping of 50%) which requires less energy during transfer of electrons from the valence to the conduction band and ultimately enhances the photocatalytic activity. Moreover, upon increase in Se doping, the BLFSO morphology gradually changed from particles to nanosheets. Among various products, BLFSO-50% exhibited the highest photocatalytic activities under visible light owing to homogenous phase distribution, regular sheet type morphology and larger contact with dye containing solutions. In summary, La, Se co-doping is an effective approach to tune the electronic structure of photocatalysts for visible light photocatalysis.

Development of efficient visible light photocatalysts for water purification and hydrogen production by water splitting has been quite challenging.     

Research progress of photocatalytic sterilization over semiconductors

Considering the situation that environmental issues become more serious day by day, research on practical applications of semiconductor photocatalysis for environmental purification has attracted broad attention, including the remediation of water pollution, air contaminant treatment, photocatalytic sterilization etc., among which the application of semiconductor photocatalytic properties for the disinfection of soil surfaces, air and water, such as TiO₂, is of great interest. In this paper, we give an overview of the photocatalytic antibacterial ability of TiO₂ and other novel carbon material semiconductors. We have introduced the background information of photocatalytic disinfection and the disinfection mechanism of pure TiO₂. Furthermore, other modified TiO₂ sterilization materials are listed, such as those with doping modification. In addition, some novel carbon based nanomaterials are discussed as well in this review, for instance, g-C₃N₄, carbon nanotubes and graphene nanosheets. Finally, we present an outlook over two dimensional (2D) materials and coupling techniques based on the combination of photocatalysis and other sterilization technologies.

With increasingly serious environmental issues, practical applications of semiconductor photocatalysts for environmental purification have attracted broad attention. Semiconductor photocatalysts for the disinfection of soil surfaces, air and water are of great interest.     

Microwave-assisted synthesis of an RGO/CdS/TiO2 step-scheme with exposed TiO2 {001} facets and enhanced visible photocatalytic activity

Semiconductor-based heterojunction photocatalysts with a special active crystal surface act as an essential part in environmental remediation and renewable energy technologies. In this study, an RGO/CdS/TiO₂ step-scheme with high energy {001} TiO₂ facets was successfully fabricated via a microwave-assisted solvothermal method. The photocatalytic performance of as-prepared samples was assessed by degrading methylene blue under visible light irradiation. We found that the photocatalytic activity of the RGO/CdS/TiO₂ step-scheme heterojunction was related to the proportion of TiO₂. A ternary sample with a TiO₂ content of 10 wt% exhibited superior photocatalytic performance, and approximately 99.7% of methylene blue was degraded during 50 min of visible illumination which was much higher than the percentages found for TiO₂, CdS, RGO/TiO₂, and RGO/CdS. The greatly improved photocatalytic performance is due to the exposure of the reactive {001} surface of TiO₂ and the formation of a CdS/TiO₂ heterojunction step-scheme, which effectively inhibits the recombination of charge carriers at the heterogeneous interfaces. Moreover, the incorporation of graphene further enhances the visible light harvesting and serves as an electron transport channel for rapidly separating photogenerated carriers. Based on the PL, XPS, photoelectrochemical properties and the free radical capturing experiment results, a possible photodegradation mechanism was proposed.

The photocatalytic enhancement of RGO/CdS/TiO₂ is due to the high-energy {001} surface of TiO₂ and CdS forming a stepped heterojunction, which is dispersed on the surface of reduced graphene oxide.     

Enhanced visible light absorption performance of SnS2 and SnSe2via surface charge transfer doping

The layered two-dimensional (2D) SnS₂ and SnSe₂ have received intensive attention due to their sizable band gaps and potential properties. However, it has been shown that the visible light absorption of SnS₂ and SnSe₂ are restricted as photocatalysts and light-harvesting material absorbers for water splitting and high-performance optoelectronic devices. Herein, to enhance the visible light absorption performance of SnS₂ and SnSe₂, we performed a systematic investigation on tuning the electronic and optical properties of monolayers SnS₂ and SnSe₂via surface charge transfer doping (SCTD) with the adsorption of molybdenum trioxide (MoO₃) and potassium (K) as surface dopants based on density functional theory. Our calculations reveal that MoO₃ molecules and K atoms can draw/donate electrons from/to SnS₂ and SnSe₂ as acceptors and donors, respectively. The adsorption of MoO₃ molecules introduces a new flat impurity state in the gap of the monolayers SnS₂/SnSe₂, and the Fermi level moves correspondingly to the top of valence band, resulting in a p-type doping of the monolayer SnS₂/SnSe₂. With the adsorption of K atoms, the electrons can transfer from K atoms to the monolayer of SnS₂ and SnSe₂, making K an effective electron-donating dopant. Meanwhile, the bandgaps of monolayers SnS₂ and SnSe₂ decrease after the MoO₃ and K doping, which leads to the appearance of appreciable new absorption peaks at around ∼650/480 and ∼600/680 nm, respectively, and yielding an enhanced visible light absorption of SnS₂ and SnSe₂. Our results unveil that SCTD is an effective way to improve the photocatalytic and light-harvesting performance of SnS₂ and SnSe₂, broadening their applications in splitting water and degrading environmental pollutants under sunlight irradiation.

Enhanced visible light absorption performance of monolayer SnS₂ and SnSe₂via surface charge transfer doping (SCTD).     

TiO2/Fe2O3 heterostructures with enhanced photocatalytic reduction of Cr(vi) under visible light irradiation

We report a study on the synthesis of TiO₂/Fe₂O₃ (TF) nanocomposites and their photocatalytic performance under visible-light irradiation. The characterization of structure and morphology shows that hematite Fe₂O₃ was deposited on anatase TiO₂ nanoparticles with particle sizes in the range of 20–100 nm. In contrast to pure TiO₂ and pure Fe₂O₃, the nanocomposites exhibited remarkable photocatalytic activity. For example, the photoreduction efficiency of TF0.5 reaches 100% for a 100 ppm Cr(vi) solution within 160 minutes. The photochemical properties were studied by various methods. Finally, we conclude that the excellent performance of the photocatalysts is mainly attributed to two aspects: the enhanced absorption of visible light and the synergistic effect of an internal electric field at the heterojunction and citric acid for promoting the separation of electron–hole pairs.

A TiO₂/Fe₂O₃ heterojunction with an internal electric field was constructed for enhancing photocatalytic reduction efficiency of Cr(vi).     

Hydrothermal in situ synthesis of Rb and S co-doped Ti-based TiO2 sheet with a thin film showing high photocatalytic activities

TiO₂ is considered as one of the most promising semiconductor photocatalysts used to degrade organic pollutants. Element doping has a good effect on improving the properties of TiO₂. Herein, by using Rb₂SO₄, we explored the in situ synthesis of Ti-based TiO₂ sheets with a thin film through a hydrothermal reaction. Then, the photocatalyst was successfully fabricated by calcination. All samples were characterized by FT-IR, XRD, SEM, XPS, PL and UV-vis DRS measurements. The results indicate that the S doping together with surface hydroxyl groups lead to the band gap narrowing. S and a trace amount of Rb element can enable the formation of uniform microspheres on the surface of the Ti plate and the major phase transformed from titanium to anatase. The band gap absorption extended from 400 nm to 600 nm. The photocatalytic properties were investigated by performing the degradation of methyl orange (MO) and 4-chlorophenol (4-CP) in the aqueous solutions under UV and simulated sunlight. In the series of TiO₂ photocatalysts, Rb/S/TiO₂-48 shows the best photocatalytic efficiency and good photocatalytic performance on recycling. Interestingly, when H₂O₂ was added to the MO aqueous solution, a synergistic effect of the TiO₂ thin film and H₂O₂ on degrading the pollutant was observed.

Rb₂SO₄ helps the in situ synthesis of the TiO₂ thin film with microsphere and needle-like structure, which shows the remarkable photocatalytic properties.     

Efficient photocatalysis with graphene oxide/Ag/Ag2S–TiO2 nanocomposites under visible light irradiation

Lack of visible light response and low quantum yield hinder the practical application of TiO₂ as a high-performance photocatalyst. Herein, we present a rational design of TiO₂ nanorod arrays (NRAs) decorated with Ag/Ag₂S nanoparticles (NPs) synthesized through successive ion layer adsorption and reaction (SILAR) and covered by graphene oxide (GO) at room temperature. Ag/Ag₂S NPs with uniform sizes are well-dispersed on the TiO₂ nanorods (NRs) as evidenced by electron microscopic analyses. The photocatalyst GO/Ag/Ag₂S decorated TiO₂ NRAs shows much higher visible light absorption response, which leads to remarkably enhanced photocatalytic activities on both dye degradation and photoelectrochemical (PEC) performance. Its photocatalytic reaction efficiency is 600% higher than that of pure TiO₂ sample under visible light. This remarkable enhancement can be attributed to a synergy of electron-sink function and surface plasmon resonance (SPR) of Ag NPs, band matching of Ag₂S NPs, and rapid charge carrier transport by GO, which significantly improves charge separation of the photoexcited TiO₂. The photocurrent density of GO/Ag/Ag₂S–TiO₂ NRAs reached to maximum (i.e. 6.77 mA cm⁻²vs. 0 V). Our study proves that the rational design of composite nanostructures enhances the photocatalytic activity under visible light, and efficiently utilizes the complete solar spectrum for pollutant degradation.

The photocatalytic reaction efficiency of GO/Ag/Ag₂S–TiO₂ nanorod arrays is 600% higher than that of a pure TiO₂ sample under visible light.     

Novel TiO2/GO/CuFe2O4 nanocomposite: a magnetic,reusable and visible-light-driven photocatalyst for efficient photocatalytic removal of chlorinated pesticides from wastewater

A TiO₂/GO/CuFe₂O₄ heterostructure photocatalyst is fabricated by a simple and low-cost ball-milling pathway for enhancing the photocatalytic degradation of chlorinated pesticides under UV light irradiation. Based on the advantages of graphene oxide, TiO₂, and CuFe₂O₄, the nanocomposite exhibited visible light absorption, magnetic properties, and adsorption capacity. Integrated analyses using XRD, SEM, TEM, and UV-visible techniques demonstrated that the nanocomposite exhibited a well-defined crystalline phase, sizes of 10–15 nm, and evincing a visible light absorption feature with an optical bandgap energy of 2.4 eV. The photocatalytic degradations of 17 different chlorinated pesticides (persistent organic pollutants) were assayed using the prepared photocatalyst. The photocatalytic activity of the nanocomposite generated almost 96.5% photocatalytic removal efficiency of typical pesticide DDE from water under UV irradiation. The superior photocatalytic performance was exhibited by the TiO₂/GO/CuFeO₄ catalyst owing to its high adsorption performance and separation efficiency of photo-generated carriers. The photocatalyst was examined in 5 cycles for treating uncolored pesticides with purposeful separation using an external magnetic field.

A TiO₂/GO/CuFe₂O₄ heterostructure photocatalyst is fabricated by a simple and low cost ball milling pathway for enhancing the photocatalytic degradation of chlorinated pesticides under UV light irradiation.     

Flake-like InVO4 modified TiO2 nanofibers with longer carrier lifetimes for visible-light photocatalysts

Highly efficient solar light absorption capabilities and quantum yields in photocatalysts are key to their application in photocatalytic fields. Towards this end, TiO₂/InVO₄ nanofibers (NFs) have been designed and fabricated successfully by a one-pot electrospinning process. The resulting TiO₂/InVO₄ NFs display excellent visible-light photocatalytic activity, owing to their prominent visible-light absorption and electron–hole separation properties. Time-resolved transient PL spectroscopy demonstrated that the TiO₂/InVO₄ NFs display longer emission decay times (22.0 ns) compared with TiO₂ NFs (15.5 ns), implying that the heterojunction can remarkably suppress the electron–hole recombination and promote the carrier transfer efficiency. With tailored heterostructure features, TiO₂/InVO₄ NFs exhibit superior visible-light photodegradation activity, and after 80 min of visible-light irradiation, almost 95% of RhB molecules can be decomposed by TiO₂/InVO₄ NFs, while only 18% of RhB molecules can be decomposed by pure TiO₂ NFs.

TiO₂/InVO₄ nanofibers have been designed and fabricated successfully by one-pot electrospinning process, which display longer carrier lifetime (22 ns) and enhanced visible-light photocatalytic activity.