Synthesis of Fe3O4 nanocomposites for efficient separation of ultra-small oil droplets from hexadecane–water emulsions

Eco-friendliness and low cost are critical when investigating new oil–water separation agents with high separation efficiencies for the treatment of emulsified oily wastewater in industrial applications, including crude oil exploitation. Treatment methods specifically suited to wastewater containing ultra-small oil droplets are lacking and urgently required. This study investigated the one-pot synthesis of humic acid and polydimethyldiallylammonium chloride coated Fe₃O₄ nanoparticles. A low dosage of the nanoparticles (375 μg mL⁻¹) exhibited excellent separation efficiency (nearly 100%) and reusability when applied to hexadecane–water emulsions containing ultra-small droplets (200–300 nm). Electrostatic interactions and the strong interfacial activity of the nanoparticles played essential roles in achieving oil–water separation. This study provided an efficient extraction material synthesized by a facile and cheap method for separating ultra-small oil droplets from emulsions.

A facile one-pot synthesis of Fe₃O₄ nanoparticles exhibited excellent separation efficiency with a low dosage and reusability when applied to hexadecane–water emulsions containing ultra-small droplets.     

Synthesis and evaluation of the SERS effect of Fe3O4–Ag Janus composite materials for separable,highly sensitive substrates

Fe₃O₄–Ag Janus composites were synthesized using a two-step solvothermal method. The optimal growth process was determined by investigating the relationship between the particle morphologies and reaction time. Magnetic and Raman spectroscopic measurements showed that the as-synthesized Janus composites have both good magnetic response and significant surface-enhanced Raman scattering (SERS) effects, as well as reproducibility. The calculated Raman enhancement factor reached an unprecedented magnitude of 10⁹ compared with the values of other Fe₃O₄–Ag compounds. Furthermore, the SERS effect was exhibited even at a concentration of probe molecules as low as 10⁻¹³ M. This demonstrates that the as-synthesized Fe₃O₄–Ag Janus composite particles have promise for application as separable, highly sensitive SERS substrates.

Fe₃O₄–Ag Janus composites were synthesized using a two-step solvothermal method.     

Facile solvothermal preparation of Fe3O4–Ag nanocomposite with excellent catalytic performance

Functional nanocomposites demonstrate excellent comprehensive properties and outstanding characteristics for numerous applications. Magnetic nanocomposites are an important type of composite materials, due to their applications in optics, medicine and catalysis. In this report, a new Fe₃O₄-loaded silver (Fe₃O₄–Ag) nanocomposite has been successfully synthesized via a simple solvothermal method and in situ growth of silver nanowires. The silver nanowires were prepared via the reduction of silver vanadate with the addition of uniformly dispersed Fe₃O₄ nanoparticles. Structural and morphological characterizations of the obtained Fe₃O₄–Ag nanocomposite were carried out using many characterization methods. As a new composite catalyst, the synthesized magnetic Fe₃O₄–Ag nanocomposite displayed a high utilization rate of catalytically active sites in catalytic reaction medium and showed good separation and recovery using an external magnetic field. The facile preparation and good catalytic performance of this Fe₃O₄–Ag nanocomposite material demonstrate its potential applications in catalytic treatment and composite materials.

A new Fe₃O₄–Ag nanocomposite was prepared via solvothermal method, demonstrating potential application in catalytic degradation of wastewater treatment and composite materials.     

Improved liquid–liquid extraction by modified magnetic nanoparticles for the detection of eight drugs in human blood by HPLC-MS

Magnetic nanoparticles modified with porous titanium dioxide were used as clean-up nanospheres for the detection of eight drug poisons in human blood by high-performance liquid chromatography-mass spectrometry. The magnetic clean-up nanospheres (Fe₃O₄@mTiO₂) with a mesoporous structure were successfully synthesized and characterized by scanning electron microscopy/energy dispersive spectroscopy, transmission electron microscopy, X-ray diffractometry, vibrating sample magnetometry, infrared spectroscopy, and Brunauer–Emmett–Teller techniques. Lipid co-extractives, such as phosphatidic acid and fatty acids, which are major interferences in HPLC-MS analysis causing ion suppression in the MS spectra of blood, could be efficiently removed by Fe₃O₄@mTiO₂ based on the Lewis acid–Lewis base interactions. Following the optimization of the quantities of Fe₃O₄@mTiO₂, the method was applied to the determination of eight drugs in spiked blood. The analytical ranges typically extended from 2 to 500 ng mL⁻¹, and the recoveries ranged from 79.5–99.9% at different concentrations of blood. The limits of quantitation for drug poisons were 0.14–1.03 ng mL⁻¹, which makes the method a viable tool for drug poison monitoring in blood.

High-performance magnetic Fe₃O₄@TiO₂, nanospheres with mesoporous structures was synthesized for cleanup phosphatidic acid and fatty acids in blood sample for 8 drugs test with HPLC-MS.     

Polymer grafted magnetic graphene oxide as a potential nanocarrier for pH-responsive delivery of sparingly soluble quercetin against breast cancer cells

In this work, polymer grafted magnetic graphene oxide (GO–PVP–Fe₃O₄) was successfully synthesized for efficient delivery of anticancer drug. Firstly, GO was functionalized with the hydrophilic and biocompatible polymer polyvinylpyrrolidone (PVP) and then grafted with magnetic nanoparticles (Fe₃O₄) through an easy and effective chemical co-precipitation method. Quercetin (QSR) as an anticancer drug was loaded onto the surface of GO–PVP–Fe₃O₄via non-covalent interactions. The drug loading capacity was as high as 1.69 mg mg⁻¹ and the synthesized magnetic nanocarrier shows pH-responsive controlled release of QSR. The cellular cytotoxicity of the synthesized nanocarrier with and without drugs was investigated in human breast cancer MDA MB 231 cells and their effects compared on non-tumorigenic epithelial HEK 293T cells. These results reveal that the drug loaded GO–PVP–Fe₃O₄ nanohybrid was found to be more toxic than the free drug towards MDA MB 231 cells and exhibits biocompatibility towards HEK 293T cells. Overall, a smart drug delivery system including polymer grafted magnetic graphene oxide as a pH-responsive potential nanocarrier could be beneficial for targeted drug delivery, controlled by an external magnetic field as an advancement in chemotherapy against cancer.

Polymer grafted magnetic graphene oxide (GO–PVP–Fe₃O₄) as an efficient nanocarrier for the delivery of anticancer drug quercetin.     

Facile synthesis of silver nanocatalyst decorated Fe3O4@PDA core–shell nanoparticles with enhanced catalytic properties and selectivity

In this work, we have successfully prepared core–shell nanoparticles (Fe₃O₄@PDA) wrapped with Ag using a simple and green synthesis method. Without an external reducing agent, silver nanoparticles (Ag NPs) with good dispersibility were directly reduced and deposited on a polydopamine (PDA) layer. Fe₃O₄@PDA@Ag showed excellent catalytic activity and recyclability for 4-nitrophenol, and also exhibited good catalytic selectivity for organic dyes (MO and MB). This simple and green synthesis method will provide a platform for other catalytic applications.

In this work, we have successfully prepared core–shell nanoparticles (Fe₃O₄@PDA) wrapped with Ag using a simple and green synthesis method.     

Facile synthesis of porous Fe3O4@C core/shell nanorod/graphene for improving microwave absorption properties

Porous Fe₃O₄@C core/shell nanorods decorated with reduced graphene oxide (RGO) were fabricated through a facile one-pot method. The microwave absorption properties of the samples can be adjusted by the weight ratio of RGO. The addition of RGO not only effectively reduces the agglomeration of Fe₃O₄@C, but also has a great effect on impedance matching and dielectric loss, resulting in enhanced microwave absorption abilities. The thickness corresponding to optimum reflection loss (R_L) decreases as the weight ratio of RGO increases. For the Fe₃O₄@C/RGO composite, a maximum R_L value of −48.6 dB can be obtained at 13.9 GHz with a thickness of 3.0 mm, and the absorption bandwidth with R_L below −10 dB is 7.1 GHz from 10.9 GHz to 18 GHz. These results demonstrate a facile method to prepare a highly efficient microwave absorption material with special microstructure.

Porous Fe₃O₄@C core/shell nanorods decorated with reduced graphene oxide were synthesized by a facile one-pot method, and exhibit high microwave absorption performance: maximum reflection loss reaches −48.6 dB.     

Design and synthesis of magnetic Fe3O4@NFC-ImSalophCu nanocatalyst based on cellulose nanofibers as a new and highly efficient,reusable, stable and green catalyst for the synthesis of 1,2,3-triazoles

The Fe₃O₄@NFC-ImSalophCu catalyst was used as a highly stable, reusable, active, green catalyst for the synthesis of 1,2,3-triazoles via one-pot three-component reaction of phenacyl bromides, sodium azide and alkynes. A Cu(ii)–Schiff base complex containing an imidazolium ionic phase was prepared and decorated on core shell Fe₃O₄@NFC magnetic nanoparticles (Fe₃O₄@NFC-ImSalophCu) and was used as an efficient catalyst. The heterogeneous catalyst was characterized by FT-IR spectroscopy, FE-SEM, TEM, XRD spectroscopy, EDX spectroscopy, VSM, and ICP spectroscopy. This catalyst shows the dual function of the metal sites and imidazolium moieties. The catalytic system mentioned above also showed excellent activity in the synthesis of bis 1,4-disubstituted 1,2,3-triazoles. Moreover, the catalyst could be recycled and reused for four cycles without any decrease in its catalytic activity.

A new and efficient method has been developed for click chemistry reactions using a bifunctional Fe₃O₄@NFC-ImSalophCu catalyst with part imidazolium under moderate conditions.     

CuO and CeO2 assisted Fe2O3/attapulgite catalyst for heterogeneous Fenton-like oxidation of methylene blue

In this paper, CuO and CeO₂ were screened as co-catalyst components for Fe₂O₃/attapulgite (ATP) catalyst, and three new catalysts (CuO–Fe₂O₃/ATP, CeO₂–Fe₂O₃/ATP and CuO–CeO₂–Fe₂O₃/ATP) were prepared for degradation of methylene blue (MB). The three catalysts'' characteristics were determined by BET, XRD, FT-IR, SEM and XPS. MB degradation in different systems and at different pH values was also studied. Under the conditions of H₂O₂ concentration of 4.9 mmol L⁻¹, catalyst dosage of 5 g L⁻¹, pH of 5, reaction temperature of 60 °C and MB initial concentration of 100 mg L⁻¹, the as-synthesized catalysts showed much greater reaction rate and degradation efficiency of MB than Fe₂O₃/ATP catalyst. In addition, the reusability of the as-prepared composites was evaluated. The intermediate products of MB degradation were identified by LC-MS and the possible degradation process of MB was put forward.

A novel heterogeneous catalyst CuO–CeO₂–Fe₂O₃/ATP was synthesized for MB degradation and the catalytic mechanism was put forward.     

Activated carbon fiber/Fe3O4 composite with enhanced electromagnetic wave absorption properties

To obtain a low-density material that is capable of absorbing electromagnetic waves over a wide bandwidth, an activated carbon fiber/Fe₃O₄ composite material (ACF/Fe₃O₄) was prepared using an in situ reduction method. Scanning electron microscopy images show that Fe₃O₄ nanoparticles, approximately 10–40 nm in size, were spread uniformly over the surface of the ACF. The resulting composite exhibited superparamagnetic behavior at room temperature. The ability of the ACF and ACF/Fe₃O₄ composite to absorb electromagnetic waves over a frequency range of 8.2–18 GHz was measured using the arch method. The results showed that the maximum reflectivity of an ACF felt was −12.9 dB at 18 GHz, and the effective microwave-absorbing bandwidth (R < −10 dB) was 1.9 GHz (16.10–18 GHz). The absorption performance of the ACF was greatly enhanced by being loaded with Fe₃O₄ nanoparticles; the maximum reflectivity of the 2 mm layer of the ACF/Fe₃O₄ composite was −30.07 dB at 16.45 GHz, and the effective bandwidth (R < −10 dB) increased to 8.62 GHz (9.38–18 GHz). Coating with nano-Fe₃O₄ magnetic particles can effectively improve the absorption of electromagnetic waves by the ACF, and this technique therefore has great potential for application to the field of electromagnetic shielding.

To obtain a low-density material that is capable of absorbing electromagnetic waves over a wide bandwidth, an activated carbon fiber/Fe₃O₄ composite material (ACF/Fe₃O₄) was prepared using an in situ reduction method.     

Preparation and properties of CF–Fe3O4–BN composite electromagnetic wave-absorbing materials

A three-layered electromagnetic (EM) wave-absorbing material was prepared by depositing a Fe₃O₄ and boron nitride (BN) coating onto the surface of a carbon fiber (CF) by in situ hybridization. The structure, chemical composition, morphology, high-temperature resistance, EM characteristics and EM wave absorption of the composite materials were analyzed. The composite materials contained CFs, and Fe₃O₄ was distributed along the axial direction of the fiber, whereas BN was found in the outermost coating layer. The proposed preparation method improved the oxidation resistance and EM wave absorption of CF. When the solubility of the metal salt was 20 g/100 ml, the decomposition temperature of the prepared CF/Fe₃O₄(3)/BN increased by more than 200 °C compared with that of CF/Fe₃O₄(3). The EM wave loss of less than −5 dB ranged within 8.8–18 GHz, and the effective EM wave-absorbing bandwidth (R < −10 dB) was 4.2 GHz (11.2–15.4 GHz). The prepared CF-based composite material had a lightweight structure, wide absorption band, and strong oxidation resistance. All these findings can serve as a reference for the study of other EM wave-absorbing materials.

A three-layered electromagnetic (EM) wave-absorbing material was prepared by depositing a Fe₃O₄ and boron nitride (BN) coating onto the surface of a carbon fiber (CF) by in situ hybridization.     

An Na-modified Fe@C core–shell catalyst for the enhanced production of gasoline-range hydrocarbons via Fischer–Tropsch synthesis

Although numerous studies have been conducted in the field of converting syngas to value-added fuels, selectively converting syngas to gasoline-range hydrocarbons (C_5–12 hydrocarbons) remains a big challenge. Alkali metal (namely, K, Na and Li)-modified Fe@C core–shell catalysts were synthesized by a one-step hydrothermal method for Fischer–Tropsch synthesis. An optimized selectivity of 56% for the C_5–12 hydrocarbons with a higher CO conversion of about 95% was obtained for the FeNa_2.0@C catalyst compared to that for other alkali metal-modified Fe@C catalysts. According to the characterization results, the incorporation of alkali metals into Fe@C enhanced the conversion of FeCO₃ to Fe₃O₄, which promoted the formation of the FTS active phase iron carbides. In particular, the strongest interaction of Fe–alkali metal and the highest amount of surface carbon layers were observed after adding an Na promoter into Fe@C in contrast to that observed for K and Li promoters, which strengthened the synergistic effect of Fe–Na metals and the spatial confinement of the core–shell structure, further improving the C_5–12 hydrocarbon selectivity.

A one-pot synthesized Fe@C core–shell catalyst with a sodium promoter exhibited high gasoline-range product selectivity with high FTS activity.     

Using magneto-electroluminescence as a fingerprint to identify the spin polarization and spin–orbit coupling of magnetic nanoparticle doped polymer light emitting diodes

The spin polarization and spin–orbit coupling (SOC) in polymer light emitting diodes (PLEDs) with the active layer doped with Fe₃O₄ nanoparticles (NPs) were identified through magneto-electroluminescence (MEL). By comparing the MEL characteristics such as linewidth and magnitude between PLEDs with and without Fe₃O₄ dopant, we confirmed the existence of spin polarization, but ruled out the existence of SOC. Although the spin polarization is positive to electroluminescence, the brightness–current characteristics suggested that the current efficiency of the doped PLED does not improve. We attributed it to the current leakage caused by the Fe₃O₄ NPs in the active layer. This work is beneficial for us to further understand the effect of magnetic nanoparticle doping on the dynamic behavior of excitons and polaron pairs in organic semiconductor devices.

The existence of spin polarization was confirmed while spin–orbit coupling was ruled out in Fe₃O₄-based PLEDs by magneto-electroluminescence analysis.     

Computer-aided design of magnetic molecularly imprinted polymer nanoparticles for solid-phase extraction and determination of levetiracetam in human plasma

Analytical methods should be accurate and specific to measure plasma drug concentration. Nevertheless, current sample preparation techniques suffer from limitations, including matrix interference and intensive sample preparation. In this study, a novel technique was proposed for the synthesis of a molecularly imprinted polymer (MIP) on magnetic Fe₃O₄ nanoparticles (NPs) with uniform core–shell structure. The Fe₃O₄@MIPs NPs were then applied to separate and enrich an antiepileptic drug, levetiracetam, from human plasma. A computational approach was developed to screen the functional monomers and polymerization solvents to provide a suitable design for the synthesized MIP. Different analysis techniques and re-binding experiments were performed to characterize the Fe₃O₄@MIP NPs, as well as to identify optimal conditions for the extraction process. Adsorption isotherms were best fitted to the Langmuir model and adsorption kinetics were modeled with pseudo-second-order kinetics. The Fe₃O₄@MIP NPs showed reasonable adsorption capacity and improved imprinting efficiency. A validated colorimetric assay was introduced as a comparable method to a validated HPLC assay for the quantitation of levetiracetam in plasma in the range of 10–80 μg mL⁻¹ after extraction. The results from the HPLC and colorimetric assays showed good precision (between 1.08% and 9.87%) and recoveries (between 94% and 106%) using the Fe₃O₄@MIP NPs. The limit of detection and limit of quantification were estimated to be 2.58 μg mL⁻¹ and 7.81 μg mL⁻¹, respectively for HPLC assay and 2.32 μg mL⁻¹ and 7.02 μg mL⁻¹, respectively for colorimetric assay. It is believed that synthesized Fe₃O₄@MIP NPs as a sample clean-up technique combined with the proposed assays can be used for determination of levetiracetam in plasma.

A novel molecularly imprinted polymer on Fe₃O₄ nanoparticles was applied to extract antiepileptic drug; levetiracetam from plasma for TDM purposes.     

TiO2/Fe2O3 heterostructures with enhanced photocatalytic reduction of Cr(vi) under visible light irradiation

We report a study on the synthesis of TiO₂/Fe₂O₃ (TF) nanocomposites and their photocatalytic performance under visible-light irradiation. The characterization of structure and morphology shows that hematite Fe₂O₃ was deposited on anatase TiO₂ nanoparticles with particle sizes in the range of 20–100 nm. In contrast to pure TiO₂ and pure Fe₂O₃, the nanocomposites exhibited remarkable photocatalytic activity. For example, the photoreduction efficiency of TF0.5 reaches 100% for a 100 ppm Cr(vi) solution within 160 minutes. The photochemical properties were studied by various methods. Finally, we conclude that the excellent performance of the photocatalysts is mainly attributed to two aspects: the enhanced absorption of visible light and the synergistic effect of an internal electric field at the heterojunction and citric acid for promoting the separation of electron–hole pairs.

A TiO₂/Fe₂O₃ heterojunction with an internal electric field was constructed for enhancing photocatalytic reduction efficiency of Cr(vi).     

Graphene oxide–metal oxide nanocomposites: fabrication,characterization and removal of cationic rhodamine B dye

The fabrication and characterization of graphene oxide (GO) nanosheets and their reaction with Fe₃O₄ and ZrO₂ metal oxides to form two nanocomposites, namely graphene oxide–iron oxide (GO–Fe₃O₄) and graphene oxide–iron oxide–zirconium oxide (GO–Fe₃O₄@ZrO₂), have been examined. The fabricated nanocomposites were examined using different techniques, e.g.transmission electron microscopy, X-ray diffraction, zeta potential measurement and Fourier transform infrared spectroscopy. Compared to GO, the newly fabricated GO–Fe₃O₄ and GO–Fe₃O₄@ZrO₂ nanocomposites have the advantage of smaller band gaps, which result in increased adsorption capacity and photocatalytic effects. The results also showed the great effect of the examined GO–metal oxide nanocomposites on the decomposition of cationic rhodamine B dye, as indicated by steady-state absorption and fluorescence, time correlated single photon counting and nanosecond laser photolysis techniques. The antibacterial activity of the fabricated GO and GO–metal oxides has been studied against Gram-positive and Gram-negative bacteria.

The fabrication and characterization of graphene oxide–iron oxide and graphene oxide–iron oxide–zirconium oxide nanocomposites have been reported. The decomposition of cationic rhodamine B dye by both nanocomposites has been examined.     

Phase controlled one-pot synthesis of heterostructured FePt–Fe3O4 nanocubes with excellent biocompatibility

We demonstrated a simple one-pot synthesis approach for the controlled composition of homogeneous FePt and phase-controlled heterostructured FePt/Fe₃O₄ nanocubes (NCs) utilizing 1,2-hexadecanediol and 1-octadecene as the reducing agents, respectively. When the Fe : Pt precursor ratio was varied from 1 : 1 to 4 : 1 and 1,2-hexadecanediol was utilized as the reducing agent, homogeneous FePt NCs were formed, whereas the heterostructures of FePt/Fe₃O₄ NCs were obtained when utilizing 1-octadecene as the reducing agent at Fe : Pt ratio of 4 : 1. The initial domination of nucleation of Pt-rich species and the subsequent deposition of Fe atoms leads to the formation of homogeneous FePt NCs. Heterostructured FePt/Fe₃O₄ NCs were obtained by the initial FePt seed formation, which was then followed by the heterogeneous growth of Fe₃O₄. The heterostructured FePt/Fe₃O₄ NCs exhibited two phases, i.e., FePt phase with a (111) facet of the fcc and Fe₃O₄ phase with an inverse cubic spinel structure. Moreover, both the FePt and the FePt/Fe₃O₄ NCs demonstrated almost negligible coercivity, which confirmed a typical superparamagnetic behavior. Furthermore, the cell viability tests of the FePt and FePt/Fe₃O₄ NCs demonstrated excellent biocompatibilities. Hence, the NCs could be useful for various biomedical applications, including MRI contrast agents, hyperthermia, and as a label in magnetic biochips.

We demonstrated a simple one-pot synthesis approach for the controlled composition of homogeneous FePt and phase-controlled heterostructured FePt/Fe₃O₄ nanocubes (NCs) utilizing 1,2-hexadecanediol and 1-octadecene as the reducing agents, respectively.     

Enhanced catalytic degradation of amoxicillin with TiO2–Fe3O4 composites via a submerged magnetic separation membrane photocatalytic reactor (SMSMPR)

A novel photo-Fenton catalytic system for the removal of organic pollutants was presented, including the use of photo-Fenton process and a submerged magnetic separation membrane photocatalytic reactor (SMSMPR). We synthesized TiO₂–Fe₃O₄ composites as the photocatalyst and made full use of the magnetism of the photocatalyst to realize the recollection of the catalyst from the medium, which is critical to the commercialization of photocatalytic technology for wastewater treatment. The photo-Fenton performance of TiO₂–Fe₃O₄ is evaluated with amoxicillin trihydrate (AMX) as a target pollutant. The results indicate that the TiO₂–Fe₃O₄/H₂O₂ oxidation system shows efficient degradation of AMX. Fe₃O₄ could not only enhance the heterogeneous Fenton degradation of organic compounds but also allow the photocatalyst to be magnetically separated from treated water. After four reaction cycles, the TiO₂–Fe₃O₄ composites still exhibit 85.2% removal efficiency of AMX and show excellent recovery properties. Accordingly, the SMSMPR with the TiO₂–Fe₃O₄ composite is a promising way for removing organic pollutants.

With a TiO₂–Fe₃O₄ composite as the catalyst, amoxicillin was degraded via a photo-Fenton process using a submerged magnetic separation membrane photocatalytic reactor.     

Magnetic molecularly imprinted polymers for the detection of aminopyralid in milk using dispersive solid-phase extraction

A method for dummy molecular imprinting-magnetic dispersive solid-phase extraction (MI-MDSPE) coupled with liquid chromatography-tandem mass spectrometry (LC-MS/MS) was developed for the selective determination of aminopyralid in milk. The magnetic material and polymers were combined via a series of modifications in Fe₃O₄. Fe₃O₄@SiO₂–NH₂@MIP, Fe₃O₄@SiO₂–COOH@MIP and two types of aminopyralid-specific magnetic molecularly imprinted polymers (MMIPs) were prepared on the surface of magnetic nanoparticles modified with amino and carboxyl groups. The morphology and magnetic properties of the polymer were characterized. Fe₃O₄@SiO₂–NH₂@MIP exhibits not only good dispersibility and magnetic properties, but also an outstanding recognition pattern to the target analyte. Adsorption experiments demonstrated that Fe₃O₄@SiO₂–NH₂@MIP, with a high specific surface area and fast mass transfer rate, had a higher affinity than Fe₃O₄@SiO₂–COOH@MIP towards aminopyralid. Under the optimized MI-MDSPE conditions, the method had good linearity (R² > 0.9972), excellent recoveries (83.3–90%), and good precision (relative standard deviations (RSDs) < 12.6%). This method has limits of detection (LOD) and quantification (LOQ) of 0.231 and 0.77 μg kg⁻¹, respectively, indicating that these MMIPs can be used to analyse trace levels of aminopyralid in real samples.

(a) Preparation of Fe₃O₄@SiO₂–NH₂@MMIP. (b) Diagram of magnetic molecularly imprinted polymers for the detection of aminopyralid in milk using dispersive solid-phase extraction.     

Sulfonated graphene oxide/Nafion composite membranes for high temperature and low humidity proton exchange membrane fuel cells

Iron oxide (Fe₃O₄) nanoparticles anchored over sulfonated graphene oxide (SGO) and Nafion/Fe₃O₄–SGO composites were fabricated and applied as potential proton exchange membranes in proton exchange membrane fuel cells (PEMFCs) operated at high temperature and low humidity. Fe₃O₄ nanoparticles bridge SGO and Nafion through electrostatic interaction/hydrogen bonding and increased the intrinsic thermal and mechanical stabilities of Nafion/Fe₃O₄–SGO composite membranes. Nafion/Fe₃O₄–SGO composite membranes increased the compactness of ionic domains and enhanced the water absorption and proton conductivity while restricting hydrogen permeability across the membranes. The proton conductivity of Nafion/Fe₃O₄–SGO (3 wt%) composite membrane at 120 °C under 20% relative humidity (RH) was 11.62 mS cm⁻¹, which is 4.74 fold higher than that of a pristine recast Nafion membrane. PEMFC containing the Nafion/Fe₃O₄–SGO composite membrane delivered a peak power density of 258.82 mW cm⁻² at a load current density of 640.73 mA cm⁻² while operating at 120 °C under 25% RH and ambient pressure. In contrast, under identical operating conditions, a peak power density of only 144.89 mW cm⁻² was achieved with the pristine recast Nafion membrane at a load current density of 431.36 mA cm⁻². Thus, Nafion/Fe₃O₄–SGO composite membranes can be used to address various critical problems associated with commercial Nafion membranes in PEMFC applications.

Preparation process of Nafion/Fe₃O₄–SGO composite membranes.