共查询到20条相似文献,搜索用时 31 毫秒
1.
Lingren Zhou Yuzhen Li Ziqi Wang Mengying Zhang Xiaodong Wang Hongqing Niu Dezhen Wu 《RSC advances》2019,9(13):7314
A series of polyimide (PI) films based on aromatic heterocyclic monomers of 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA), p-phenylenediamine (p-PDA) and 4,4′-oxydianiline (ODA) were prepared via a microwave-assisted thermal imidization and conventional thermal imidization method at different temperatures. The effects of microwave irradiation on the imidization degree, microstructures, mechanical and thermal properties of PI films were investigated. The imidization degree of the PI films treated with microwave-assisted heating reached a relatively high value at 250 °C, which was twice as much as those treated with traditional thermal imidization. The tensile strength and modulus of PI films treated with microwave-assisted imidization at 300 °C were 187.61 MPa and 2.71 GPa respectively, which were 30% higher than those of PI films treated with thermal imidization. Moreover, the order degree of polymer chains was improved by the microwave-assisted imidization method. The PI films prepared by the microwave-assisted imidization method showed excellent thermal stability with a 5% weight loss temperature of 573 °C under N2. The microwave-assisted thermal imidization proved to be a rapid and efficient way to prepare high-performance polyimide materials.A series of polyimide films were prepared via a microwave-assisted thermal imidization and conventional thermal imidization method at different temperatures. 相似文献
2.
Feiyan Liu Zhihong Liu Shuyu Gao Qingliang You Liyong Zou Jia Chen Jiyan Liu Xueqing Liu 《RSC advances》2018,8(34):19034
A facile approach to synthesize a polyimide (PI) film with enhanced dimensional stability, a high mechanical property and optical transparency is presented by embedding the partial imidized PI/SiC nanofiber-net in a poly(amic acid) (PAA) solution, followed by removing the solvent and imidization of the PAA. The nanofiber-network self-filled PI film demonstrates a much lower thermal expansion coefficient (CTE), an excellent mechanical property and high transparency retention in comparison to the film fabricated by solution cast. When the SiC content is 6 wt% in PI/SiC nanofibers, the CTE values for the PI film containing 25 wt% PI/SiC nanofibers are 2.80 times lower than the solution cast PI/SiC film. The tensile strength and modulus for the PI/SiC fiber filled film are also improved by 159% and 91% respectively in comparison to the solution cast SiC/PI film. In addition, the PI/SiC nanofiber-network filled PI film exhibits a high optic transparency. The significant improvement in aforementioned properties is contributed to by the long and continuous nanonetwork which acts as a frame to maintain the stable dimension and endow the film with high mechanical properties. Moreover, the nanosized SiC particles were constricted within the nano-fiber to avoid light scattering, so the high transparency of the film was retained.Polyimide films with low thermal expansion and high transparency were fabricated by homogeneity enhancement of nanofibers net. The nanofibers net that composed of polyimide and SiC nanoparticles is obtained by electrospinning technic. 相似文献
3.
Fabricating high thermal conductivity rGO/polyimide nanocomposite films via a freeze-drying approach
Shiyang Wei Qiaoxi Yu Zhenguo Fan Siwei Liu Zhenguo Chi Xudong Chen Yi Zhang Jiarui Xu 《RSC advances》2018,8(39):22169
The preparation of polymeric composite materials with low filler content as well as high thermal conductivity has been an important subject for the field of polymer material research. During our recent investigation on polyimide (PI), it was found that poly(amic acid) (PAA) solution (in dimethylacetamide, DMAc) could crystallize at low temperature. When adding reduced graphene oxide (rGO) as the thermal conductive fillers in the PAA solution, it was also found that the crystallization process of PAA would impel the rGO to rearrange in order and form an aligned thermal conductive network. To retain the rGO network structure, the freeze-drying technique was used to remove the solvent. Subsequently, through a thermal imidization process the final rGO/PI films containing a 3D rGO network could be obtained. The PI composite films retain good flexibility, excellent thermal stability, and exhibit excellent thermal conductivity. When the content of rGO added is 8 wt%, the thermal conductivity of the rGO/PI film can reach a high value of 2.78 W m−1 K−1, which is about 15.4 times that of neat PI and 5.5 times that of the rGO/PI composite film prepared by the conventional two-step routine with the same content of rGO.PI composite films with excellent thermal conductivity (as high as 2.78 W m−1 K−1) have been fabricated by a freeze drying approach. 相似文献
4.
Wei Jia Lingren Zhou Ming Jiang Jiang Du Mengying Zhang Enlin Han Hongqing Niu Dezhen Wu 《RSC advances》2021,11(52):32647
Here, a rapid and efficient strategy was introduced to prepare polyimide/graphene nanosheet (PI/GN) composite fibers by microwave-assisted imidization. The mechanical properties of the PI/GNs (1 wt%) fibers treated by microwave-assisted imidization were apparently improved with the tensile strength of 1.12 GPa at 350 °C, which was approximately 1.7 times as much as those treated with traditional thermal imidization. The PI/GNs (1 wt%) fibers heated by the microwave-assisted imidization method exhibited excellent thermal stabilities of up to 570.3 °C in nitrogen for a 5% weight loss, and a glass transition temperature above 339 °C. The results of the infrared spectrum and thermal properties indicated that the microwave-assisted treatment could promote the imidization degree of the PI/GN fibers prominently. Meanwhile, as a microwave absorber, graphene nanosheets (GNs) could also promote the imidization process by converting microwave energy into thermal energy. The microwave-polyimide/graphene nanosheet (MW-PI/GN) fibers possessed an optimum tensile strength of 1.38 GPa and modulus of 56.82 GPa at the GN content of 0.25 wt%. The 5% weight loss temperature in nitrogen ranged from 520.9 °C to 570.3 °C, and the glass transition temperature was increased from 305.7 °C to 339.1 °C with increasing the GN content.Here, a rapid and efficient strategy was introduced to prepare polyimide/graphene nanosheet (PI/GN) composite fibers by microwave-assisted imidization. 相似文献
5.
Hang Xu Chuanqiang Yin Xinran Hou Man Gong Changshu Yang Lexiang Xu Jinpeng Luo Lei Ma Lang Zhou Xiaomin Li 《RSC advances》2022,12(34):21904
Free-standing and flexible carbon nanofiber membranes (CNMs) with a three-dimensional network structure were fabricated based on PMDA/ODA polyimide by combining electrospinning, imidization, and carbonization strategies. The influence of carbonization temperature on the physical-chemical characteristics of CNMs was investigated in detail. The electrochemical performances of CNMs as free-standing electrodes without any binder or conducting materials for lithium-ion batteries were also discussed. Furthermore, the surface state and internal carbon structure had an important effect on the nitrogen state, electrical conductivity, and wettability of CNMs, and then further affected the electrochemical performances. The CNMs/Li metal half-cells exhibited a satisfying charge–discharge cycle performance and excellent rate performance. They showed that the reversible specific capacity of CNMs carbonized at 700 °C could reach as high as 430 mA h g−1 at 50 mA g−1, and the value of the specific capacity remained at 206 mA h g−1 after 500 cycles at a high current density of 1 A g−1. Overall, the newly developed carbon nanofiber membranes will be a promising candidate for flexible electrodes used in high-power lithium-ion batteries, supercapacitors and sodium-ion batteries.Free-standing and flexible carbon nanofiber membranes (CNMs) with a three-dimensional network structure were fabricated based on PMDA/ODA polyimide by combining electrospinning, imidization, and carbonization strategies. 相似文献
6.
Wang Chunbo Li Liaoliao Jiang Haifu Tian Dongbo Qin Wei Liu Changwei Zhao Xiaogang Chen Chunhai Wang Daming 《RSC advances》2018,8(39):21728
The tolerance of silvered polyimide films synthesized by an in situ self-metalization method against atomic oxygen (AO) was evaluated. The results showed that the mass loss of R–Ag/PI was markedly increased as the AO fluence increased; Ag/PI showed an identical trend. SEM data showed that the silver particles on the surfaces of R–Ag/PI and Ag/PI disappeared. The surfaces achieved a “carpet condition” that was more obvious as the AO fluence increased. Poly(siloxane amic acid) ammonium salt was synthesized and made via imidization to produce a flexible organic coating that was characterized by ATR-FTIR, 1HNMR, TGA, and XPS. This could be used to improve the tolerance of silvered polyimide films against AO. The AO resistance and the impacts on mass loss, surface morphology, and surface compositions were also evaluated after surface modification by poly(siloxane amic acid) ammonium salts. 20 wt% Foc/Ag/PI had a lower mass loss and smoother surface than the others due to the formation of a compact surface-SiO2-type layer. This flexible organic coating can be produced via an environmentally-friendly method, and it maintains the inherent thermal stability of the polyimide which cannot be achieved by other anti-AO coatings.Poly(siloxane amic acid) ammonium salt with good AO resistance was synthesized, and used to protect silvered polyimide films from AO erosion. 相似文献
7.
Andrey W. Golubkov Ren Planteu Philipp Krohn Bernhard Rasch Bernhard Brunnsteiner Alexander Thaler Viktor Hacker 《RSC advances》2018,8(70):40172
Damaged or heavily over-heated Li-ion batteries in electric vehicles can transit into a thermal runaway reaction with further heat and gas release. The heat may cause a battery fire and fast gas release may damage the battery-pack casing. To characterise heat and gas release of large automotive Li-ion cells, a heavy duty test bench was developed and a test series was performed.Damaged or heavily over-heated Li-ion batteries in electric vehicles can transit into a thermal runaway reaction with further heat and gas release. 相似文献
8.
Lithium-ion batteries (LIBs) are currently the most widely used portable energy storage devices due to their high energy density and long lifespan. The separator plays a key role in the battery, and its function is to prevent the two electrodes of the battery from contacting, causing the internal short circuit of the battery, and ensuring the lithium ions transportation. Currently, lithium ion battery separators widely used commercially are polyolefin separators, such as polyethylene (PE) and polypropylene (PP) based separators. However, polyolefin separators would shrink at high temperatures, causing battery safety issues, and also causing white pollution. To solve these issues, the use of natural minerals to prepare composite separators for LIBs has attracted widespread attention owing to their unique nano-porous structure, excellent thermal and mechanical stability and being environmentally friendly and low cost. In this review, we present recent application progress of natural minerals in separators for LIBs, including halloysite nanotubes, attapulgite, sepiolite, montmorillonite, zeolite and diatomite. Here, we also have a brief introduction to the basic requirements and properties of the separators in LIBs. Finally, a brief summary of recent developments in natural minerals in the separators is also discussed.Based on the issues of polyolefin separators, the application of natural minerals with unique properties to lithium-ion battery separators has attracted widespread attention. 相似文献
9.
Polymers of intrinsic microporosity (PIMs) have numerous advantages such as good thermal stability (Tg > 300 °C) and mechanical stability (tensile strength at break > 60 MPa) as well as excellent electrical insulation performance and chemical/electrochemical stability. Herein, a macroporous membrane made up of a polymer of intrinsic microporosity (PIM-1) was fabricated and used as a separator of a rechargeable Li-ion battery for the first time. The PIM-1-based separator showed good thermal resistance with Tg > 300 °C, high electrolyte uptake, and excellent Li-ion conductivity.A PIM-1 macroporous membrane was successfully fabricated and used as a separator of rechargeable Li-ion batteries for the first time. 相似文献
10.
A novel high-strength polyimide (PI) nanocomposite film was designed and constructed by the copolymerization of epoxidized polyhedral oligomeric silsesquioxane-modified hexagonal boron nitride and polyamic acid (PAA). The composite filler (EPPOSS@Gh-BN) was composed of silane coupling agent KH550 modified hexagonal boron nitride (Gh-BN) and epoxidized polyhedral oligomeric silsesquioxanes (EPPOSS), which improved not only the dispersion of the h-BN but also the effective interfacial stress transfer, leading to an enhanced mechanical strength of the resultant PI nanocomposite film of 114 MPa even with a slight EPPOSS@Gh-BN loading of 0.30 wt%, and the storage modulus was increased by more than 30% to 4 GPa compared to pure PI. Meanwhile, the PI/EPPOSS@Gh-BN nanocomposite has better heat transfer performance, higher hydrophobicity, lower dielectric properties, and higher heat stability than pure PI, and is therefore expected to provide an ideal platform for the development of highly flexible electronics in the future.A novel high-strength polyimide nanocomposite film was obtained by the copolymerization of epoxidized polyhedral oligomeric silsesquioxane-modified hexagonal boron nitride and polyamic acid. 相似文献
11.
Flexible materials have drawn considerable attention due to the demand for wearable and flexible electronic products. Seeking new kinds of precursors for preparing carbon nanofibers with good flexibility for high-performance supercapacitors is a hot issue. In this work, a flexible polypyrrolone (BBB)/polyimide (PI) composite-based carbon nanofiber membrane (PBPICF) is prepared by a facile electrospinning and carbonization process. The PBPICF membranes exhibit a three-dimensional (3D) porous, fluffy and self-standing structure with good mechanical performance and flexibility, and can be arbitrarily bent and folded. PBPICF-65-35 (consisting of BBB (65 wt%) and PI (35 wt%)) exhibits a high specific capacitance of 172.44 F g−1 in 6 M KOH aqueous solution, which is two-fold more than that of commercial polyacrylonitrile-based carbon nanofibers. In addition, PBPICF-65-35 also displays good power density (90 W kg−1) and energy density (19.4 W h kg−1), and the capacitance remains at 96% even after 10 000 cycles at 1.0 A g−1. Therefore, the simple preparation and good capacitance performance of PBPICFs make them a promising binder-free electrode for wearable supercapacitors.A flexible polypyrrolone (BBB)/polyimide (PI) composite-based carbon nanofiber membrane (PBPICF) has been prepared by a facile electrospinning and carbonization process. 相似文献
12.
Wu Bai Yunhua Lu Zhizhi Hu Guoyong Xiao Hongbin Zhao Jianmin Zhu Zhaobin Liu 《RSC advances》2021,11(57):36066
In this work, a triarylimidazole-containing diamine 2-(4-methylphenyl)-4,5-bis(4-(4-amino-2-trifluoromethylphenoxy)phenyl)imidazole (MPBAI) was firstly synthesized and polymerized with 1,2,3,4-cyclobutanetetracarboxylic dianhydride (CBDA) to prepare transparent polyimide (PI) films by means of thermal imidization. Then, inorganic nanoparticles including silica (SiO2), alumina (Al2O3) and silicon nitride (Si3N4) were separately introduced into the PI(MPBAI-CBDA) with different mass fractions of 0.02%, 0.10%, 0.50% and 2.50% to obtain three series of PI nanocomposite films. All these films were close to colorless and transparent, although the light transmittance showed a downward trend due to the introduction of nanoparticles. Moreover, as the content of inorganic nanoparticles increased, the fluorescence intensities of these films were increased. Comparatively, the improvement effect of nano-SiO2 was the most obvious. When the content of SiO2 was 2.50%, the maximum intensity of the fluorescence absorption peak was increased by 9.6 times, and the absolute fluorescence quantum yield reached 17.2%, about 5.2 times that of the original PI film. Moreover, the maximum absorption peak produced a red shift of 85 nm due to the addition of 2.50% Si3N4, which was probably caused by the weakening of fluorescence quenching effect and high permittivity. The nanocomposites exhibited high glass transition temperatures of around 300 °C and excellent thermal stabilities. The surface hydrophobicity was changed by adjusting the mass and type of nanoparticles. Thus, this work provided a simple way to improve the photoluminescence effect by introducing the nanoparticles. The functional films will be expected to be applied in some optical applications.Three series of triarylimidazole-containing polyimide nanocomposite films were prepared via thermal imidization. Due to the introduction of inorganic nanoparticles including SiO2, Al2O3 and Si3N4, the fluorescence intensities of these composite films were clearly increased. 相似文献
13.
Guoyun Fang Yao Huang Wei Yuan Yang Yang Yong Tang Weida Ju Fujian Chu Zepeng Zhao 《RSC advances》2019,9(18):9951
A novel battery thermal management system (BTMS) based on water evaporation (WE) and air-cooling (AC) for a tube–shell Li-ion battery (LIB) pack is designed. A sodium alginate (SA) film with a higher water content above 99% is fortified by adding polyethylene (PE) fibers. The air flow and PE-fiber composite sodium alginate (PECSA) film are both used to control the temperature of the battery pack. Results show that the maximum temperature of the battery pack can be controlled below 32 °C, when WE coupled with AC is used at a discharge rate of 1.8C within a discharge time of 1000 s. This method yields the highest performance of thermal management. The experimental results validate the numerical data, confirming that the design of WE combined with AC helps prevent overheating of a battery pack. This work also provides an automatic refilling system to solve the dehydration problem of the PECSA film.A novel battery thermal management system (BTMS) based on water evaporation (WE) and air-cooling (AC) for a tube–shell Li-ion battery (LIB) pack is designed. 相似文献
14.
Zhou Mao Jialiang Li Wenjie Huang Hao Jiang Bhahat Lawlley Zimba Li Chen Jiangling Wan Qingzhi Wu 《RSC advances》2018,8(30):16619
Nanofiber membranes display promising potential in biomedical fields, especially as scaffolds for drug delivery and tissue engineering. The structures and components of nanofibers play crucial roles in improving the mechanical properties and drug-releasing performance of nanofiber membranes. In this work, poly(lactic acid) (PLA)/graphene oxide (GO) nanofiber membranes with different structures (single-axial and co-axial structure) were prepared by electrospinning. The morphologies, structures, and mechanical properties of the as-prepared nanofiber membranes were characterized and compared. Furthermore, the drug-releasing performance of the as-prepared nanofiber membranes with different structures was evaluated by using an organic dye (Rhodamine B, RhB) as a drug model. Results show that the addition of GO not only significantly improved the thermal stability and mechanical properties of the PLA nanofiber membranes, but also promoted the cumulative release and release rate of RhB from nanofiber membranes. At the same GO concentration, the nanofiber membrane with the co-axial structure displayed a higher tensile strength and Young''s modulus, but exhibited a lower cumulative release and release rate. The formation of the co-axial structure is beneficial in suppressing the initial burst release of RhB from nanofiber membranes.PLA/GO nanofiber membrane with the co-axial structure exhibited the improved mechanical properties, which is also beneficial to separately loading different drugs in core-/sheath-structure and suppressing the initial burst release of drugs. 相似文献
15.
Wu Bai Zhizhi Hu Yunhua Lu Guoyong Xiao Hongbin Zhao Jianmin Zhu Zhaobin Liu 《RSC advances》2021,11(38):23802
In this paper, three kinds of triphenyl imidazole-containing diamines including 2-phenyl-4,5-bis(4-(4-amino-2-trifluoromethylphenoxy)phenyl)imidazole (PBAI), 2-(4-methylphenyl)-4,5-bis(4-(4-amino-2-trifluoromethyl phenoxy)phenyl)imidazole (MPBAI) and 2-(4-trifluoromethylphenyl)-4,5-bis(4-(4-amino-2-trifluoromethylphenoxy)phenyl)imidazole (TFPBAI) were synthesized. Then, a series of polyimide (PI) films were prepared by the solution polymerization of the three diamines and various dianhydrides, such as 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 1,2,4,5-pyromellitic dianhydride (PMDA) and 1,2,3,4-cyclobutanetetracarboxylic dianhydride (CBDA), followed by thermal imidization. The effects of chemical structures on the solubilities and thermal, optical and electrochemical properties of polyimides were explored. All the polyimides exhibited higher glass transition temperatures around 300 °C and excellent solubilities in common polar solvents. The polyimide films derived from CBDA or 6FDA showed better optical properties with light color and transparent characteristics. The fluorescence test showed that the photoluminescence color of CBDA-based polyimide films is in the blue range in the CIE 1931 spectrum, while the polyimide film based on PMDA and 6FDA presented black or weak yellow light. However, all these polyimides in solution exhibited similar blue luminescence. Electrochemical tests indicated that the HOMO and LUMO values of these films were around −6.5 and −3.6 eV, and the energy gap difference was about 3.0 eV. Therefore, the triphenyl imidazole-containing polyimides exhibit comprehensive performance, which will be expected as a new kind of functional material for certain application in the optical and optoelectronics fields.The triphenyl imidazole-containing polyimide films exhibit excellent solubility and thermal and photoluminescence properties. 相似文献
16.
Yan Wang Radoslaw Pawel Grecki Eugen Stamate Kion Norrman David Aili Min Zuo Weihong Guo Claus Hlix-Nielsen Wenjing Zhang 《RSC advances》2018,9(1):278
Electrospun nanofiber membrane-supported thin film composite (TFC) membranes exhibit great potential in water purification. In this work, electrospun polyphenylsulfone (PPSU) nanofiber membranes were prepared and modified by heat and plasma treatments. The resulting membranes were used as support layers for biomimetic TFC-based forward osmosis membranes. Thermal treatment transformed a loose non-woven nanofiber structure into a robust interconnected 3-dimensional PPSU network displaying a 930% increase in elastic modulus, 853% increase in maximum stress, and two-fold increase in breaking strain. Superior hydrophilicity of PPSU nanofiber membranes was achieved by low-pressure plasma treatment, changing the contact angle from 137° to 0°. The fabricated exemplary TFC-based forward osmosis membrane showed an osmotic water flux Jw > 14 L m−2 h−1 with a very low reserve salt flux Js (Js/Jw = 0.08 g L−1) demonstrating the potential for making high quality membranes for water treatment using PPSU-based support layers for TFC membranes.A 3-dimensional nanofiber membrane with superior hydrophilicity and mechanical properties significantly improves flux and salt rejection in thin film forward osmosis. 相似文献
17.
The demands for novel approaches that ensure stability in lithium-ion batteries are increasing and have led to the development of new materials and fabrication strategies. In this study, sandwich structure-like polysulfonamide (PSA)/polyacrylonitrile (PAN)/polysulfonamide (PSA) composite nanofibrous membranes were prepared via an electrospinning method and used as a separator in lithium-ion batteries. The spinning time of each polymer nanofiber layer of the composite membranes was respectively and precisely controlled to maximize the merits of each component. It was found that the PSA/PAN/PSA composite nanofibrous membranes exhibited superior thermal stability and excellent porosity, liquid electrolyte uptake and ionic conductivity, showing obvious enhancement as compared to those of the commercial microporous polyolefin separator (Celgard 2400), pure PSA and pure PAN membranes. In addition, they were evaluated in the assembled Li/LiFePO4 cells with an electrolyte solution, and good cycling performance and C-rate capacity were obtained; especially for the case of the PP6P membrane, the first discharge capacity of the battery reached 152 mA h g−1, and the discharge capacity retention ratio was 85.94% from 0.2C to 2C; moreover, the battery displayed highest capacity retention ratio after 70 cycles, which was found to be 96.2% of its initial discharge capacity. Therefore, the PSA/PAN/PSA composite nanofibrous membranes can be regarded as a promising candidate for application in lithium-ion batteries.The demands for novel approaches that ensure stability in lithium-ion batteries are increasing and have led to the development of new materials and fabrication strategies. 相似文献
18.
Abdullah Alamri Chao Wu Shamima Nasreen Huan Tran Omer Yassin Ryan Gentile Deepak Kamal Rampi Ramprasad Yang Cao Gregory Sotzing 《RSC advances》2022,12(15):9095
Polymer dielectrics with ultra-high charge–discharge rates are significant for advanced electrical and electronic systems. Despite the fact that polymers possess high breakdown strength, the low dielectric constant (k) of polymers gives rise to low energy densities. Incorporating metal into polyimides (PI) at the polyamic acid (PAA) precursor stage of the synthetic process is a cheap and versatile way to improve the dielectric constant of the hybrid system while maintaining a high breakdown strength. Here, we explore inclusion of different percentages of Sn as a coordinated complex in a polyimide matrix to achieve metal homogeneity within the dielectric film to boost dielectric constant. Sn–O bonds with high atomic polarizability are intended to enhance the ionic polarization without sacrificing bandgap, a measurable property of the material to assess intrinsic breakdown strength. Enhancements of k from ca. 3.7 to 5.7 were achieved in going from the pure PI film to films containing 10 mol% tin.Polyimide with high dielectric constant and breakdown strength is synthesized via tin complexation of the polyamide acid precursor. Sn–O bonds with high atomic polarizability are intended to enhance the ionic polarization without sacrificing bandgap. 相似文献
19.
In this article, polyketone (PK) micro/nano fiber membranes were successfully fabricated by electrospinning and a post treatment process and the membrane characteristics were investigated. The morphology of the fiber membranes showed that ambient humidity during electrospinning changed the roughness of the fiber surface and the addition of NaCl decreased the fiber diameter. In particular, the changes in surface roughness was a very rare and novel discovery. The effect of this discovery on membrane properties was also analyzed. Additionally, the nanofiber membrane was modified by in situ surface reduction. FT-IR spectroscopy indicated the successful reduction modification and water contact angle results proved the improved wetting ability by this modification process. DSC and TGA analysis showed that the micro/nano fiber membranes possessed a high melting point and thermal decomposition temperature. Mechanical tests showed that as fiber membranes, PK micro/nano fiber membranes had relatively high mechanical strength, furthermore the mechanical strength can be easily enhanced by controlling the fiber morphology. From these results, it was concluded that the PK micro/nano fiber membranes could be a promising candidate for many applications such as organic solvent-resistant membranes, high-safety battery separators, oil–water separation, etc.In this article, polyketone (PK) micro/nano fiber membranes were successfully fabricated by electrospinning and a post treatment process and the membrane characteristics were investigated. 相似文献
20.
None of the currently commercialized shielding materials in Generation IV nuclear energy systems are satisfactory in their performance. Developing a candidate neutron shielding material with good heat resistance and high strength is a challenging task. In this work, various gadolinium metal–organic frameworks (Gd-MOFs) with obvious advantages, such as porous structures, organic surfaces and strong neutron-absorbing nuclei, were synthesized to constrain polyimide (PI) chains. A series of Gd-MOF/PI conjugates were subsequently assessed for their thermal stability, mechanical properties and neutron shielding performance. The increase of the Gd-MOF content improved the thermal neutron shielding ability but slightly reduced the fast neutron shielding ability. Compared with those of pure PI, the Gd-MOF/PI films demonstrate a higher glass transition temperature (Tg), which is considered the gold standard of engineering plastics. It was also observed that the tensile strength directly correlates with the Gd-MOF content, which continuously increases until a maximum is reached, and then subsequently decreases. Furthermore, the high-temperature tensile test showed that these tunable Gd-MOF/PI films are intact and robust, indicating their potential application for neutron shielding materials in Generation IV nuclear energy systems.None of the currently commercialized shielding materials in Generation IV nuclear energy systems are satisfactory in their performance. 相似文献